A relaxation phenomenon observed in fine gold wire

Two modulation techniques were used to determine the heat capacity of 1 mil gold wire as a function of temperature. A frequency effect was observed at high temperature in the directly measured parameter C_p/(1/R_m) (dR/dT)T_m where C_p is the specific heat at constant pressure and R_m is the resistance of the specimen at temperature T_m. It is believed that the vacancy defect is responsible for this frequency effect. The relaxation phenomenon observed suggests the surface of the wire as the source of the vacancies.     

On the heat capacity discontinuity for a gas of nuclear spin waves in ferromagnets

It is demonstrated that the heat capacity discontinuity for a gas of nuclear spin waves occurs in ferromagnetic materials. The heat capacity discontinuity manifests itself at ultralow temperatures and stems from the specific spectrum of these quasiparticles. The effect is observed at the temperature T _K?2.37?ω_n. The heat capacity discontinuity is found at this temperature.     

Heat capacity of BiFeO3-based multiferroics

The heat capacity of Bi_{1 ? x} Re _x FeO₃ (Re = La, Eu, Ho; x = 0, x = 0.05) multiferroics has been studied in the temperature range of 120–800 K. The substitution of a small amount of rare-earth elements for bismuth leads to a significant increase in the heat capacity in the broad temperature range studied. It is established that the temperature dependence of the excess heat capacity is related to the Schottky effect for three-level states certain that appear as a result of structure distortions in the rare-earth-doped compositions.     

Performance characteristic of a Stirling refrigeration cycle in micro/nano scale

The aim of the paper is to present the performance characteristics of a Stirling refrigeration cycle in micro/nano scale, in which the working substance of cycle is an ideal Maxwellian gas. Due to the quantum boundary effect on the gas particles confined in the finite domain, the cycle no longer possesses the condition of perfect regeneration. The inherent regenerative losses, the refrigeration heat and coefficient of performance (COP) of the cycle are derived. It is found that, for the micro/nano scaled Stirling refrigeration cycle devices, the refrigeration heat and COP of cycle all depend on the surface area of the system (boundary of cycle) besides the temperature of the heat reservoirs, the volume of system and other parameters, while for the macro scaled refrigeration cycle devices, the refrigeration heat and COP of cycle are independent of the surface area of the system. Variations of the refrigeration heat ratio r_R and the COP ratio r_ε with the temperature ratio τ and volume ratio r_V for the different surface area ratio r_A are examined, which reveals the influence of the boundary of cycle on the performance of a micro/nano scaled Stirling refrigeration cycle. The results are useful for designing of a micro/nano scaled Stirling cycle device and may conduce to confirming experimentally the quantum boundary effect in the micro/nano scaled devices.     

Heat flux near critical density in laser-plasma interaction

A general nonlocal theory of heat transport in laser-plasma interaction experiments is presented. It is shown that the inverse bremsstrahlung absorption and the plasma expansion are responsible for heat fluxes q_ib and q_h which add to the heat flux due to the temperature gradient itself.     

Heat capacity and the p-T phase diagram of Pb2MgTeO6 elpasolite

The heat capacity of Pb₂MgTeO₆ is measured in the temperature range 80–300 K. It is found that the heat capacity exhibits an anomaly associated with the phase transition at T ₀=186.9 K. The thermodynamic parameters of the structural transformation are determined. The effect of hydrostatic pressure up to 0.5 GPa on the phase transition temperature is examined.     

Effects of spin fluctuations in itinerant electron ferromagnets

Effects of spin fluctuations on the paramagnetic spin susceptibility, magnetization and specific heat are calculated in gaussian statistics as a power series of k_BT. The results are applied to nickel and iron. It is shown that in effect spin fluctuations reduce the molecular field coefficient above the Curie temperature.     

Effect of heat treatment on the surface parameters of cadmium-telluride single-crystal substrates

The effect of the heat treatment of n-CdTe single-crystal substrates in different environments on the surface recombination velocity v _s is investigated. It is established that the surface recombination velocity of substrates annealed in air is two orders of magnitude smaller than the v _s of chemically polished samples.     

On the problem of electron-emission mechanisms in the cathode spot of a vacuum arc discharge

A criterion for the F-type mechanism of electron emission in a vacuum-arc cathode spot is developed. It is shown that the implementation of F-electron emission in the cathode spot necessitates the fulfillment of three conditions: first, generation of the optimal electric field E _opt, second, implementation of atomic-ionic balance at which the E _opt field is generated and, third, retention of the cathode temperature lower than the inversion temperature of Nottingham’s effect. The calculations show that the heat of the evaporation of cathode atoms which meets these requirements does not exceed λ_a ～ 1.1–1.2 eV. Taking the possibility of F-T-emission into account, the evaporation heat can be slightly higher than λ_a ～ 1.5–1.6 eV. However, in this case, it turns out to be fairly small. Note that the number of such metals is not very large.     

Numerical Investigation of Heat Transfer Characteristics of scCO2 Flowing in a Vertically-Upward Tube with High Mass Flux

In this work, the heat transfer characteristics of supercritical pressure CO₂ in vertical heating tube with 10 mm inner diameter under high mass flux were investigated by using an SST k-ω turbulent model. The influences of inlet temperature, heat flux, mass flux, buoyancy and flow acceleration on the heat transfer of supercritical pressure CO₂ were discussed. Our results show that the buoyancy and flow acceleration effect based on single phase fluid assumption fail to explain the current simulation results. Here, supercritical pseudo-boiling theory is introduced to deal with heat transfer of scCO₂. scCO₂ is treated to have a heterogeneous structure consisting of vapor-like fluid and liquid-like fluid. A physical model of scCO₂ heat transfer in vertical heating tube was established containing a gas-like layer near the wall and a liquid-like fluid layer. Detailed distribution of thermophysical properties and turbulence in radial direction show that scCO₂ heat transfer is greatly affected by the thickness of gas-like film, thermal properties of gas-like film and turbulent kinetic energy in the near-wall region. Buoyancy parameters Bu < 10⁻⁵, Bu* < 5.6 × 10⁻⁷ and flow acceleration parameter K_v < 3 × 10⁻⁶ in this paper, which indicate that buoyancy effect and flow acceleration effect has no influence on heat transfer of scCO₂ under high mass fluxes. This work successfully explains the heat transfer mechanism of supercritical fluid under high mass flux.     

Broadband copper luminescence in potassium-aluminum borate glasses

Broadband luminescence in the visible spectral range has been investigated for copper-containing potassium-aluminum borate glasses. It is shown that the luminescence in initial glasses (before their heat treatment) is due to the presence of molecular clusters Cu _n (n < 10) in them. Chemical reactions during heat treatment lead to the formation of Cu _n Cl _x and Cu _n O _x clusters with luminescence bands lying in the spectral range of 450–600 nm.     

Theoretical investigation on cross-flow heat exchangers with axial dispersion in one fluid

The axial dispersion model for cross-flow heat exchangers is investigated to predict steady state thermal performance more accurately. This model takes flow maldistribution and backmixing into account and is simple and effective in describing their effect on the temperature effectiveness of a heat exchanger. An exact solution together with its asymptotic form for high dispersive Péclet numbers is obtained. The analysis shows that the temperature effectiveness deterioration caused by axial dispersion is significant for the dispersive Péclet number P_e < 20, particularly when the thermal capacity rate ratio is close to one. The P₁, P₂-charts are presented, which are useful for the design of compact cross-flow heat exchangers.     

Heat capacity of La1−x SrxMnO3 single crystals in different magnetic states

The heat capacity of three single-crystal samples of La_1?x Sr_xMnO₃ (x=0, 0.2, and 0.3) is measured in the temperature range 4–400 K. It is found that the heat capacity undergoes abrupt changes due to the transitions from the antiferromagnetic phase to the paramagnetic phase (x=0) and from the ferromagnetic phase to the paramagnetic phase (x=0.2 and 0.3). The phonon contribution to the heat capacity and the Debye characteristic temperatures for the La_0.7Sr_0.3MnO₃ sample are determined over a wide range of temperatures. The electronic density of states at the Fermi level is evaluated. It is demonstrated that an increase in the strontium concentration x brings about an increase in the electronic density of states at the Fermi level. The contributions of spin waves to the heat capacity and the entropy are estimated under the assumption that the phonon spectrum remains unchanged upon doping with Sr.     

Heat capacity and dielectric properties of multiferroics Bi1 − x Gd x FeO3 (x = 0–0.20)

The heat capacity and the permittivity of multiferroics Bi_{1 ? x} Gd _x FeO₃ (x = 0, 0.05, 0.10, 0.15, 0.20) have been studied in the temperature range 130–800 K. It has been found that insignificant substitution of gadolinium for bismuth markedly shifts the temperature of antiferromagnetic phase transition and increases the heat capacity over a wide temperature range. It has been shown that the temperature dependence of the excess heat capacity is due to the manifestation of three-level states. Additional anomalies characteristic of the phase transitions have been revealed in the temperature dependences of the heat capacity for the compositions with x = 0.1 and 0.15 at T ≈ 680 K and T ≈ 430 K, respectively. The results of studies of the heat capacity have been discussed simultaneously with the data of structural studies.     

Heat capacity and entropy of two electrons quantum dot in a magnetic field with parabolic interaction

The thermodynamic properties of two electrons in two dimensional parabolic GaAs quantum dot are studied where both the magnetic field and the e–e interaction are fully considered. The e–e interaction has been treated by a model potential which makes the Hamiltonian exactly solvable. The energy spectrum is used to calculate the canonical partition function, and then we obtain the thermodynamic properties; mean energy, heat capacity and entropy as a function of temperature (T) and magnetic field (B).A steep transition from zero to 4k_B is observed in the heat capacity as a function of temperature for small values of magnetic field and saturates within a small temperature range, also the heat capacity has a peak-like structure at low temperature, while for high magnetic field heat capacity develops a shoulder at 2k_B then it approaches the saturation value with further increase in temperature. The entropy increases with increasing temperature, but at higher temperature, it remains almost independent of the magnetic field. It is shown that, at low magnetic field values, the effect of magnetic field on heat capacity is tangible and it attains a constant value with further increase in magnetic field. Entropy is almost linearly proportional with increasing magnetic field strength.     

Anomalies in the thermodynamic properties of mixtures near the liquid-vapor critical point

The behavior of the specific heat at constant volume and the derivative (?P/?T)_{ρ, x} has been studied experimentally near the liquid-vapor critical point of the methane-propane-pentane mixture. It has been shown that the derivative ?P/?T)_{ρ, x} for mixtures, in contrast to one-component systems, has a characteristic anomaly directly associated with an anomaly in the specific heat at constant volume. It is impossible to distinguish between the infinite increase in the specific heat or finite peak when processing of the experimental data only for the heat capacity. However, according to the joint analysis of the experimental data for both indicated quantities, both the specific heat of the mixture and the derivative ?P/?T)_{ρ, x} are singular finite quantities.     

Bose–Einstein condensation of a relativistic Bose gas in a harmonic potential

Using semiclassical method, Bose–Einstein condensation (BEC) of a relativistic ideal Bose gas (RIBG) with and without antibosons in the three-dimensional (3D) harmonic potential is investigated. Analytical expressions for the BEC transition temperature, condensate fraction, specific heat and entropy of the system are obtained. Relativistic effects on the properties of the system are discussed and it is found that the relativistic effect decreases the transition temperature T_c but enlarges the gap of specific heat at T_c. We also study the influence of antibosons on a RIBG. Comparing with the system without antibosons, the system with antibosons has a higher transition temperature and a lower Helmholtz free energy. It implies that the system with antibosons is more stable.     

Specific heat jump for superconducting virtual bound state alloys

Using Anderson model in the non-magnetic limit, we have calculated the jump in specific heat at T_c, (ΔC), for superconducting virtual bound state alloys. It is found that the normalized (ΔC) vs normalized T_c curves deviate considerably from the BCS value. A more significant result of the present study is that the initial slope of such a curve has a maximum value of 3.638. It is the highest value reported in literature for the impurity problem and is much larger than obtained even in a large pair breaking situation like Kondo effect (2.481).     

Influence of metallic nanoparticles in water driven along a wavy circular cylinder

In the present study, simultaneous effects of metallic nanoparticles and magnetohydrodynamic due to stagnation point flow of nanofluid along a wave circular cylinder is presented. The effect of induced magnetic field is incorporated to deal the boundary and thermal boundary layer domain. Mathematical modelling for momentum and energy equation is constructed that is based upon three different kinds of nanoparticles namely: copper (Cu), Titanium di oxide (TiO₂), and alumina (Al₂O₃) within the working fluid water. Each mixture is analysed at the individual level and made comparison amongst all the mixture to examine the resistance and thermal conductivity of nanofluid within the boundary layer region. The solutions are exposed via boundary value problem using shooting method along with the Runge-Kutta-Fehlberg method. The characteristics of emerging parameters for the fluid flow and heat transfer are discussed through graphs and tables. The effects of ϕ (nanoparticle volume fraction) on heat transfer and shear stress at the wall are analysed in detail. It is finally concluded that by increasing the ratio of nanoparticles there is a significant increase in the temperature but slight decrease in the velocity profile.     

Investigation of magnetocaloric effect in La0.45Pr0.25Ca0.3MnO3 by magnetic,differential scanning calorimetry and thermal analysis

We investigated magnetocaloric effect in La_0.45Pr_0.25Ca_0.3MnO₃ by direct methods (changes in temperature and latent heat) and indirect method (magnetization isotherms). This compound undergoes a first-order paramagnetic to ferromagnetic transition with T_C=200 K upon cooling. The paramagnetic phase becomes unstable and it transforms into a ferromagnetic phase under the application of magnetic field, which results in a field-induced metamagnetic transition (FIMMT). The FIMMT is accompanied by release of latent heat and temperature of the sample as evidenced from differential scanning calorimetry and thermal analysis experiments. A large magnetic entropy change of ΔS_m=−7.2 J kg⁻¹ K⁻¹ at T=212.5 K and refrigeration capacity of 228 J kg⁻¹ are found for a field change of ΔH=5 T. It is suggested that destruction of magnetic polarons and growth of ferromagnetic phase accompanied by a lattice volume change with increasing magnetic field is responsible for the large magnetocaloric effect in this compound.