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1.
A. E. Frumkin A. M. Churakov Yu. A. Strelenko V. A. Tartakovsky 《Russian Chemical Bulletin》1999,48(11):2103-2107
Oxidation of one of the amino groups of 2-bromo-4,6-dichloro-1,3-phenylenediamine to the nitroso group followed by its conversion
into thetert-butyl-NNO-azoxy group afforded a derivative ofm-(tert-butyl-NNO-azoxy)aniline,viz., 2-bromo-3-(tert-butyl-NNO-azoxyl)-4,6-dichloroaniline. Analogously, the second amino group was converted into thetert-butyl-NNO-azoxy group to form a derivative of 1,3-bis(tert-butyl-NNO-azoxy)benzene,viz., 3-bromo-2,4-bis(tert-butyl-NNO-azoxyl)-1,5-dichlorobenzene The reaction of the latter with ammonia yielded 2-amino- and 2,4-diamino-substituted 1,3-bis-(tert-butyl-NNO-azoxyl)benzenes.
For Part 1, see Ref. 1.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2126–2130, November, 1999. 相似文献
2.
A. M. Churakov O. Yu. Smirnov S. L. Ioffe Yu. A. Strelenko V. A. Tartakovsky 《Russian Chemical Bulletin》1994,43(9):1532-1535
2-(tert-Butyl-NNO-azoxy)aniline was prepared by selective reduction of 2-(tert-butyl-NNO-azoxy)nitrobenzene. Its bromination yielded the correspondingpara-bromo- andortho, para-dibromoanilines (3a,b).meta-Bromoanilines (6a,b) were synthesized by selective replacement of theortho-bromine atoms in ortho,para-bromo(tert-butylazoxy)benzenes (5a,b) by ammonia in toluene under pressure.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1620–1623, September, 1994.This work was carried out with the financial support of the Russian Foundation for Basic Research (Project No. 93-03-18461). 相似文献
3.
Synthesis of bis(glycosylamino)benzenes, derived from disaccharides lactose, maltose, and cellobiose, by direct condensation
and their characterization are described.
Dedicated to Academician N. K. Kochetkov on the occasion of his 90th birthday.
__________
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1235–1238, May, 2005. 相似文献
4.
Base-catalyzed reactions of propane-1,3-dithiols with 2-chloronitrobenzene, 3,4-dichloronitrobenzene, and 2-chloro-3-nitropyridine
afforded 1,3-bis(nitroarylthio)propanes, whose thiolate-thiolate exchange with propane-1,3-dithiols gave dihydrobenzodithiepines.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 163–166, January, 2006. 相似文献
5.
Irina C. Covaci Petre Ionita Miron T. Caproiu Radu Socoteanu Titus Constantinescu Alexandru T. Balaban 《Central European Journal of Chemistry》2003,1(1):53-64
Starting from N-hydroxyphthalimide (5) and 1,3-dibromopropane (6) we obtained 1,3-bis(phthalimidooxy)propane (7) which led
to 1,3-bis(aminooxy)propane dihydrochloride (8). From its reaction with picryl chloride or 4-cyano-2,6-dinitrochlorobenzene,
the two title compounds (4b, 4a) were obtained.
1H-NMR and 13C-NMR spectra are presented. For comparison with the analogous N-methoxy-2,6-dinitro-4-R-anilines 1a, 1b (R=CN or R=NO2), wer report the hydrophobic characteristics (by RPTLC), electronic spectra for the neutral compounds and their anions, pK
a
values, and the behavior towards oxidizers (DPPH, PbO2, Pb(CH3COO)4, KMnO4 and Ag2O); DPPH converts compounds 1a, 1b and 4a, 4b into betainic structures 2a, 2b respectively. 相似文献
6.
G. A. Abakumov V. K. Cherkasov T. N. Kocherova N. O. Druzhkov Yu. A. Kurskii M. P. Bubnov G. K. Fukin L. G. Abakumova 《Russian Chemical Bulletin》2007,56(9):1849-1856
New sterically hindered functionalized o-quinones were synthesized by the 1,4-nucleophilic addition of secondary cyclic amines to 3,6-di(tert-butyl)-o-benzoquinone. The ability of these o-quinones to form o-semiquinone complexes with transition and main-group metals was studied by ESR spectroscopy in solution.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1786–1793, September, 2007. 相似文献
7.
V. A. Sergeev N. I. Bekasova E. A. Baryshnikova M. Surikova N. M. Mishina 《Russian Chemical Bulletin》1996,45(11):2661-2662
By the interaction of the corresponding amino acids with the dichloride ofm-carboranedicarboxylic acid, 1,7-bis-(carboxyalkylcarbamoyl)-m-carboranes were prepared are characterized for the first time. These compounds are of interest as intermediates for the synthesis of water-soluble preparations for the boron-neutron-capture therapy of cancer.Deceased.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11 pp. 2803–2804, November 1996. 相似文献
8.
D. L. Lipilin A. M. Churakov Yu. A. Strelenko V. A. Tartakovsky 《Russian Chemical Bulletin》2007,56(8):1566-1568
Treatment of 2-(tert-butyl-NNO-azoxy)anilines with phosgene at 20 °C was proposed as a novel route to 1,2,4-benzotriazin-3(4H )-one 1-oxides. This method involves a new reaction, viz., an intramolecular interaction of the tert-butyl-NNO-azoxy group with a C-electrophile (leading to the formation of the N(2)—C(3) bond of the triazine ring) followed by elimination
of the tert-butyl group. Complete assignment of the signals in the 1H and 13C NMR spectra of the compounds obtained was performed.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1507–1509, August, 2007. 相似文献
9.
G. A. Abakumov V. K. Cherkasov T. N. Kocherova N. O. Druzhkov Yu. A. Kurskii L. G. Abakumova 《Russian Chemical Bulletin》2006,55(7):1195-1199
Reactions of 3,6-di(tert-butyl)-o-benzoquinone with primary amines occur by the nucleophilic 1,4-addition mechanism and lead to the corresponding 2-hydroxy-p-quinonimines, which exist in solutions in equilibrium with tautomeric 4-amino-o-quinones. The thermodynamic parameters of this prototropic isomerism were determined by NMR spectroscopy. In the case of
a secondary amine (piperidine), a derivative of 4-amino-o-quinone was obtained; the corresponding o-semiquinone complexes were studied in solution by ESR spectroscopy.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1151–1155, July, 2006. 相似文献
10.
A. M. Starosotnikov A. V. Lobach Yu. A. Khomutova S. A. Shevelev 《Russian Chemical Bulletin》2006,55(3):543-548
The action of various anionic O-, N-, and S-nucleophiles on 3-cyano-4,6-dinitro-benzo[d]isoxazole mostly resulted in regiospecific nucleophilic substitution for the nitro group in position 4. With an excess of
an nucleophilic reagent, the nitro group in position 6 was also replaced.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 523–528, March, 2006. 相似文献
11.
A. V. Shastin T. I. Godovikova B. L. Korsunskii 《Chemistry of Heterocyclic Compounds》2003,39(5):624-631
The reaction of 2,4,6-tris[di(tert-butoxycarbonyl)nitromethyl]-1,3,5-triazine with ammonia, amines, and hydrazine has been studied. It was possible to substitute one of the di(tert-butoxycarbonyl)nitromethyl groups in this compound in the presence of ammonia, primary aliphatic amines, dimethylamine, and morpholine. The reaction with hydrazine leads to both mono- and disubstituted products. A double dealkoxylation occurs in the presence of diethylamine to give the bis(dimethylammonium) salt of 2,4-bis(tert-butoxycarbonylnitromethyl)-6-[di(tert-butoxycarbonyl)nitromethyl]-1,3,5-triazine. 相似文献
12.
Diazophenoxides (quinone diazides) constitute an interesting class of compounds that are seemingly high-energy species on the nonaromatic/aromatic interface. With appropriate substitution and/or annelation, they have found use in the fields of explosives, medicine, and photolithography. Thermochemical information about them is sparse. To aid further understanding of these important chemical species, the current paper discusses a few extant enthalpies of formation from which we tentatively derive a resonance energy of ca. 15 kJ-mol–1 for the parent, p-species, 4-diazo-2,5-cyclohexadiene-1-one. Interestingly, this value is nearly identical to that recently found for the likewise conjugated diazo compound, ethyl diazoacetate. 相似文献
13.
Jakub Wantulok Daniel Swoboda Jacek E. Nycz Maria Ksiek Joachim Kusz Jan Grzegorz Maecki Vladimír Kubí
ek 《Molecules (Basel, Switzerland)》2021,26(7)
The vicarious nucleophilic substitution of hydrogen (VNS) reaction in electron-deficient nitroquinolines was studied. Properties of all new products have been characterized by several techniques: MS, HRMS, FTIR, GC-MS, electronic absorption spectroscopy, and multinuclear NMR. The structures of 4-chloro-8-nitroquinoline, 8-(tert-butyl)-2-methyl-5-nitroquinoline, 9-(8-nitroquinolin-7-yl)-9H-carbazole and (Z)-7-(9H-carbazol-9-yl)-8-(hydroxyimino)quinolin-5(8H)-one were determined by single-crystal X-ray diffraction measurements. The 9-(8-nitroquinolin-7-yl)-9H-carbazole and (Z)-7-(9H-carbazol-9-yl)-8-(hydroxyimino)quinolin-5(8H)-one illustrate the nitro/nitroso conversion within VNS reaction. Additionally, 9-(8-isopropyl-2-((8-isopropyl-2-methyl-5-nitroquinolin-6-yl)methyl)-5-nitrosoquinolin-6-yl)-9H-carbazole is presented as a double VNS product. It is postulated that the potassium counterion interacts with the oxygen on the nitro group, which could influence nucleophile attack in that way. 相似文献
14.
A. M. Starosotnikov A. V. Lobach V. V. Kachala S. A. Shevelev 《Russian Chemical Bulletin》2004,53(3):584-587
The reactions of 4,6-dinitro-1-phenyl-1H-indazole with anionic nucleophiles RS– and N3
– lead to the regiospecific replacement of the nitro group at position 4. The reaction with N2H4·H2O + FeCl3 also results in reduction of only the 4-NO2 group. Based on this fact, a procedure was developed for the preparation of previously unknown 3-unsubstituted 4-X-6-nitro-1-phenyl-1H-indazoles (X is a residue of a nucleophile or NH2). Comparison of the data on the selective nucleophilic substitution (4-NO2 group) in 3-Z-1-aryl-4,6-dinitro-1H-indazoles shows that in the case of Z = H, the regiospecificity of substitution is determined by the electronic effect of the annelated pyrazole ring. 相似文献
15.
Pentacoordination of boron, carbon, aluminum, and silicon atoms in bicyclic organic compounds of the pentalene type was studied
using theab initio RHF/6-31G** and MP2(full)/6-31G** methods. It was shown that the ability of the atom to form pentacoordinate structures increases on going from B to Al and
from C to Si atom,i.e. as the number of the element of Groups IIIA and IVA of the periodic system increases. At the same time, the reverse tendencies
are observed in the 2nd and 3rd periods of the periodic system,viz., the ability of the atom to form pentacoordinate structures increases on going from C to B and from Al to Si atom.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1238–1245, July, 1999. 相似文献
16.
Mironov V. F. Petrov R. R. Shtyrlina A. A. Litvinov I. A. Gubaidullin A. T. Varaksina E. N. Konovalov A. I. 《Russian Chemical Bulletin》2001,50(4):693-696
The reaction of 4,6-bis(tert-butyl)-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphosphole with phenylacetylene follows the mechanism of ipso-substitution of the tert-butyl group that is in para-position relative to the endocyclic O atom of the heterocycle, predominantly yielding 8-(tert-butyl)-2,6-dichloro-2-oxo-4-phenylbenzo[e]-1,2-oxaphosphorinine (NMR data). The structure of its hydrolysis product, 8-(tert-butyl)-6-chloro-2-hydroxy-2-oxo-4-phenylbenzo[e]-1,2-oxaphosphorinine, was proved by X-ray diffraction analysis. 相似文献
17.
A. V. Popov A. V. Shastin E. L. Luzina A. N. Pushin T. N. Gavrishova 《Russian Chemical Bulletin》1999,48(8):1548-1552
A procedure was developed for the synthesis of substituted 2-amino-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazines from 2-chloro-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazine and aliphatic and aromatic amines. The data of19F NMR spectroscopy are indicative of the presence of a barrier to internal rotation.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1568–1572, August, 1999. 相似文献
18.
We have obtained for the first time the halo derivatives of a novel heterocyclic system, 1,3-dithiolo[4,5-d]pyrimidine-2-thione and -2-selone, by reaction of 5,7-dioxo(4H,6H)-1,3-dithiolo[4,5-d]pyrimidine-2-thione and -2-selone with POCl3. The crystal structure of thione confirms that we had obtained the desired compound. The electronic absorption spectra reveal an interesting solvatochromism connected with the appearance of low-intensity n transitions from selenium and sulfur atoms in the visible region of the spectrum. The chlorine atoms in the studied compounds have significant mobility in reactions with nucleophiles (amines, thiourea, azidione), which ensures that new derivatives of 1,3-dithiolo[4,5-d]pyrimidine-2-selone are obtained, and specifically 7-N,N-dialkylamino, 7-N-alkyl-N-arylamino derivatives and 7-isothiuronium salts. The 2-selones obtained can be used in synthesis of new tetrathiafulvalenes. 相似文献
19.
Rajeev Gupta Debalina Ghosh Rabindranath Mukherjee 《Journal of Chemical Sciences》2000,112(3):179-186
Activation of dioxygen on dicopper(I) centres was systematically investigated using a group of open-chain and a macrocyclicm-xylyl-based dinucleating ligand from a bioinorganic viewpoint. Even though intermediate peroxodicopper(II) species was not
detected (even at −80°C for the open-chain system), the putative intermediate reacted with C–H groups in ligands giving oxygenated
products (C–OH groups). Absorption, spectroscopic and magnetic properties of the final dicopper(II) complexes have been investigated. 相似文献
20.
V. A. Kuropatov V. K. Cherkasov Yu. A. Kurskii G. K. Fukin L. G. Abakumova G. A. Abakumov 《Russian Chemical Bulletin》2006,55(4):708-711
In a reaction of 3,6-di(tert-butyl)-4-chloro-1,2-benzoquinone with potassium ethyl xanthate, the halogen atom was replaced by the ethyl xanthate group.
Acid hydrolysis of the product gave 4,7-di(tert-butyl)-5,6-dihydroxy-1,3-benzodithiol-2-one containing a pyrocatechol fragment, which was oxidized into the corresponding
quinone. When irradiated in solution with visible light, this quinone quantitatively eliminated a CO molecule with contraction
of the ring to a five-membered one. The quinones obtained were studied as ligands in coordination spheres of metals by ESR
spectroscopy.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 683–686, April, 2006. 相似文献