共查询到20条相似文献,搜索用时 234 毫秒
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为解决检定变压器油中溶解气体分析专用气相色谱仪时遇到样品进样量计算不准,检测器对甲烷气体标准物质无响应,专用软件分析方法不能更改等问题,建立变压器油中溶解气体分析专用气相色谱仪的检定与校准方法。当进样模式为一次进样双柱分流时,按分流比计算分流到检测器的样品体积,其它进样模式按进样体积计算进样量;因色谱软件禁止积分导致CH_4在热导检测器上无响应时,应采用有证标准物质中的H_2或O_2进行检定与校准。以7890B型专用气相色谱仪为例,详细说明了变压器油中溶解气体分析专用气相色谱仪的检定与校准流程。该法为检定人员检定该类专用仪器时提供了参考。 相似文献
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气相色谱仪检定结果的不确定度评定 总被引:2,自引:0,他引:2
气相色谱仪检定结果的不确定度主要来源于流速稳定性、柱箱温度稳定性、基线噪声、定量重复性和标准物质进样量的不确定度。以TCD检测器为例进行分析,对气相色谱仪检定结果的不确定度进行评定,相对扩展不确定度为5%。 相似文献
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为了保证天然气工业用气相色谱仪分析结果准确可靠和量值溯源有效,依据JJG 1055—2009《在线气相色谱仪》、JJF1033—2016《计量标准考核规范》等规程规范要求,配置建标所需计量标准器,研究开展了重复性试验、不确定度评定、检定结果的验证等工作,建立了天然气气相色谱仪检定装置,通过了国家市场监督管理总局的现场考... 相似文献
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探讨了非色散原子荧光光度计检定中部分技术指标与检测方法对高灵敏度、智能化新型仪器的适应性,提出了相关修改补充建议。经实际计量检定证明行之有效,较好的解决了实际工作中遇到的无法实施或检定指标与具体检测要求不相适应的问题,保证了计量检定后仪器分析结果的准确程度与公正性。 相似文献
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《Fluid Phase Equilibria》1988,39(1):53-74
Procedures are presented for calculating higher order critical points in thermodynamic models. The procedures arise from an analysis of the Gibbs tangent plane criterion for phase stability. New methods are proposed for evaluating the functions that must be zero at critical points and the ease with which these functional evaluations can be carried out is the major element in permitting calculation of higher order critical points in mixtures of any number of components. Comparison is made between experimental data and tri-critical points for ternary mixtures as calculated with the Peng-Robinson and SRK equations. 相似文献
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Summary Equilibrium prevails at all points in plutonium predominance region diagrams. Triple points combine equilibrium with equal
fractions of three Pu oxidation states. A rearrangement equation can be used to describe plutonium at a triple point. Two-reaction-product
disproportionation equations are not satisfactory for that purpose. 相似文献
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H. J. Seifert 《Journal of Thermal Analysis and Calorimetry》2005,82(3):575-580
The melting temperatures and absolute values of melting enthalpies of lanthanide trichlorides decrease from LaCl3to TbCl3and then increase to LuCl3. The preceding decrease cannot be explained by the lattice energies of the trichlorides, since they increase continuously
from the lanthanum to the lutetium compounds. However, it may be attributed to the structural features of the liquid state.
The liquids near the melting points consist of clusters of complex units, which become larger with decreasing radii of the
metal ions. To prove this assumption additional quantitative investigations are necessary. 相似文献
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Marcelo Castier 《Fluid Phase Equilibria》2011,301(1):105-109
A new algorithm to find the saturation conditions of a pure substance or mixture of specified entropy is proposed. An interesting aspect is that the type of saturation point, whether a dew or bubble point, is a priori unknown. This poses particular challenges to providing good initial estimates that ensure numerical convergence of the phase equilibrium equations. A safe initialization procedure is proposed. The examples show applications of the model to computations with pure methane, pure carbon dioxide, natural gas, and contaminated carbon dioxide. The algorithm succeeds in determining the saturation condition in all of these cases. 相似文献
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Ton That Minh Tan Bernd Michael Rode 《Journal of Polymer Science.Polymer Physics》1996,34(13):2139-2143
Quantitative structure-property relationships (QSPR) between the melting points of oligomethylenes and quantum chemical data calculated by the semiempirical method CNDO/2 were investigated. A linear relationship between the average net charges of hydrogen and carbon atoms in the molecules and the melting points could be established, achieving good fit as well as predictability. Further, the relation between the net charges and the chain length was evaluated. The evaluated net charges of polyethylene lead to a calculated melting point of 141.4°C (experimental: 141.4°C). © 1996 John Wiley & Sons, Inc. 相似文献
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I. N. Nurgaliev A. A. Toropov V. O. Kudyshkin I. N. Ruban N. L. Voropaeva S. Sh. Rashidova 《Journal of Structural Chemistry》2006,47(2):362-366
QSPR-modeling of melting temperatures has been performed for oligophenylenes of diverse structures and different molecular weights. It has been shown that optimization of correlation weights of graph local invariants can be used for prediction of melting points of oligomers. The best statistical quality of the model is observed for correlation weights calculated using third-order Morgan degrees. 相似文献
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QSPR analysis of flash points. 总被引:5,自引:0,他引:5
A R Katritzky R Petrukhin R Jain M Karelson 《Journal of chemical information and computer sciences》2001,41(6):1521-1530
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C. W. Bunn 《Journal of Polymer Science.Polymer Physics》1996,34(5):799-819
The molecular characteristics which determine the melting points of high polymer crystals are considered, and it is shown that the properties of monomeric crystals often throw light on those of the polymers. The principal factors controlling melting points appear to be molar cohesion energy (of the whole molecule for monomers, or per chain unit for polymers), molecular flexibility (due to rotation round bonds), and molecular shape effects. Figures for the cohesion energy increments of a number of chain units and substituent groups are given, and melting points of polymer series are correlated with cohesion energy per chain unit. The flexibility factor is less easy to assess; barriers to rotation in appropriate monomer molecules are relevant, but available data are very rough. The approach therefore is mainly by empirical and comparative methods. When plotted against cohesion energy per chain unit, the melting points of various series of aromatic polyesters and polyurethans fall within the same band, while those of the polyamides lie on the whole higher and those of the aliphatic polyesters, polyethers, polythioethers and polydisulfides much lower. The differences are attributed to difference of molecular flexibility arising from the presence of easily rotating O?C, S?C and S?S bonds. The low melting points of rubber and other unsaturated polymers are attributed to the fact (which can now be regarded as definitely established by independent evidence) that rotation round single bonds which are adjacent to double C? C bonds is easier than in saturated chains. Easily rotating bonds which are inclined to each other, as in cis isomers, confer greater chain flexibility than the parallel bonds in trans isomers, and thus lead to lower melting points. The marked odd-even effects in saturated molecules which run through the whole of organic chemistry (the even members always melting higher than the odd) are attributed to similar effects arising from the fact that the end bonds of an odd CH2 sequence are inclined to each other while those at the ends of an even sequence are parallel. 相似文献