采用快速升温烧结方法生长Tl-1223超导薄膜的研究

报道了在铝酸镧(00l)衬底上生长Tl-1223超导薄膜的快速升温烧结方法以及铊(Tl)源陪烧靶的配比对Tl-1223薄膜晶体结构的影响.扫描电子显微镜观测表明,采用快速升温烧结方法生长的Tl-1223超导薄膜具有致密的晶体结构.X-射线衍射等测试表明,采用合适配比的陪烧靶在氩气环境下可以制备出纯c轴取向的Tl-1223超导薄膜,充氧退火后的薄膜具有较好的电学性能,其临界转变温度T_(c onset)达到116K,临界电流密度达到1.5MA/cm~2(77 K,0 T).实验结果表明,采用这一新的烧结方法制备Tl系超导薄膜具有升降温时间和恒温时间短、生产成本低等特点.     

Oxygen nonstoichiometry and high temperature conductivity of the 2201 phase of the Bi---Sr---Cu---O superconducting oxide

The oxygen nonstoichiometry and high temperature conductivity of Bi_2.12Sr_1.86Cu_1.02O_y (2201 phase) were determined as a function of temperature (T) and oxygen partial pressure (P_O2). The dependences of conductivity on T and P_O2 were similar to those of oxygen content, and two subphases, and β, were found in such cases as 2212 and 2223 phases. From the result a close relationship was inferred between conductivity and oxygen content, and the mobility and carrier density were calculated. The carrier density of 2201 phase was smaller than those of the 2212 and 2223 phases.     

Optimization of the superconducting phase of hydrogen sulfide

The electron and phonon spectra, as well as the densities of electron and phonon states of the SH₃ phase and the stable orthorhombic structure of hydrogen sulfide SH₂, are calculated for the pressure interval 100–225 GPa. It is found that the I4/mmm phase can be responsible for the superconducting properties of metallic hydrogen sulfide along with the SH₃ phase. Sequential stages for obtaining and conservation of the SH₂ phase are proposed. The properties of two (SH₂ and SH₃) superconducting phases of hydrogen sulfide are compared.     

氢化物气相外延生长高质量GaN膜生长参数优化研究

系统研究了低温成核层生长时间、高温生长时的V/Ⅲ 比以及生长温度对氢化物气相外延生长GaN膜晶体质量的影响. 研究发现合适的低温成核层为后续高温生长提供成核中心, 并能有效降低外延膜与衬底间的界面自由能, 促进成核岛的横向生长; 优化的V/Ⅲ比和最佳生长温度有利于降低晶体缺陷密度, 促进横向生长, 增强外延膜的二维生长. 利用扫描电子显微镜、原子力显微镜、高分辨X射线衍射、 低温光致发光谱和室温拉曼光谱对优化条件下生长的GaN外延膜进行了结构和光电特性表征. 测试结果表明, 膜表面平整光滑, 呈现二维生长模式表面形貌; (002)和(102)面摇摆曲线半高宽分别为317和343 arcsec; 低温光致发光谱中近带边发射峰为3.478 eV附近的中性施主束缚激子发射峰, 存在11 meV的蓝移, 半高宽为10 meV, 并且黄带发光强度很弱;常温拉曼光谱中E₂ (high) 峰发生1.1 cm^-1蓝移.结果表明, 优化条件下生长的GaN外延膜具有良好的晶体质量和光电特性, 但GaN 膜中存在压应力. 关键词： 氮化镓 氢化物气相外延 低温成核层     

Synthesis of high transition temperature superconducting Y-Ba-Cu-Ofilms by radio-frequency plasma flash evaporation

The authors have successfully developed a novel process for the deposition of multicomponent systems, namely radio-frequency (RF) plasma flash evaporation, in which powder mixtures of constituents are continuously injected into a RF plasma and are coevaporated and codeposited onto a substrate. The Y-Ba-Cu-O films prepared by this method showed excellent superconducting properties without postannealing; a deposition rate above several hundred nm/min was achieved. The film deposited on a MgO (100) substrate at 700°C reveals c-axis-oriented, polycrystalline orthorhombic oxygen-deficient perovskite showing a superconducting transition temperature of 87 K and a critical current density on the order of 1×10⁶ A/cm² at 77 K estimated from the magnetization. The conditions of plasmas during the deposition were measured by optical emission spectroscopy     

Magnetic phase shifter for superconducting qubits

We have designed and investigated a contactless magnetic phase shifter for flux-based superconducting qubits. The phase shifter is realized by placing a perpendicularly magnetized dot at the center of a superconducting loop. The flux generated by this magnetic dot gives rise to an additional shielding current in the loop and induces a phase shift. By modifying the parameters of the dot an arbitrary phase shift can be generated in the loop. This magnetic phase shifter can, therefore, be used as an external current source in superconducting circuits, as well as a suitable tool to study fractional Josephson vortices.     

Epitaxial growth of high-Tc superconducting Tl-Ca-Ba-Cu-O films by liquid phase epataxial process

Tl-Ca-Ba-Cu-O epitaxial films have been successfully grown on (001) MgO substrate by liquid phase epitaxial (LPE) process. The as-grown films showed an onset of superconductivity at about 140 K and zero resistance at 111 K. X-ray diffraction analysis suggests the films to be highly preferentially oriented with the c-axis perpendicular to the film surface. Observation from transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) revealed the presence of both Tl-Ca₂Ba₂Cu₃O_y and TlCa₂Ba₃Cu₄O_y phases.     

Optimization of process parameters of titanium dioxide films by response surfaces methodology

An efficient approach for determination of the optimum process parameters for titanium dioxide coatings by using second-order response surface model is presented and investigated experimentally. Thin films were prepared by electron-beam evaporation associated with ion-beam assisted deposition by using different control factors, including starting materials, working pressure, substrate temperature, deposition rate and annealing temperature. The factorial design of the experiment was established to meet the equipment conditions and to avoid affecting the results. The main effect between various factors and interactions are independent. The significant level of both the main effects and the interaction are observed by analysis of variance (ANOVA) approach. Based on the statistical analysis, the results have provided much valuable information on the relationship between various control factors and thin film properties. Besides the optimum optical constants and surface roughness of TiO₂ thin films were obtained in the range of each parameter level. The factorial prediction model for preparation parameters of thin film was also established.     

密封容器中后处理制备Tl2Ba2CaCu2Oy高温超导薄膜及其性能研究

以铝酸镧（001）单晶为基片，采用两步法制备Tl2Ba2CaCu2Oy（Tl 2212）高 温超导薄膜.首先，利用脉冲激光沉积（PLD）工艺沉积Ba2CaCu2Ox非晶前驱体薄膜；然后，前驱体薄膜在高温（720—850℃）下密封钢容器里铊化结晶形成Tl 2212薄膜.XRD结果表明Tl2212 薄膜是沿c轴方向生长的，其相组成为Tl 2212，摇摆曲线（0012）的半高宽为0.72° ，SEM图像显示其表面光滑平整，其零电阻温度为106.2K. 关键词： Tl 2212超导薄膜 脉冲激光沉积     

Polytetrafluoroethylene piezoelectrets prepared by sintering process

Polytetrafluoroethylene (PTFE) films with a void structure are prepared by a sintering process. Such void PTFE films are piezoelectric after proper corona charging. The quasi-static piezoelectric d ₃₃ coefficients up to 250 pC/N are achieved for the samples which were made of compact and biaxial-tension porous PTFE layers. Pre-ageing treatment is an effective method to further improve the thermal stability. For the samples with pre-ageing treatment, the reduction of the d ₃₃ coefficients is around 2% per day when exposed to 120 °C.     

Quantum logic gates for coupled superconducting phase qubits

Based on a quantum analysis of two capacitively coupled current-biased Josephson junctions, we propose two fundamental two-qubit quantum logic gates. Each of these gates, when supplemented by single-qubit operations, is sufficient for universal quantum computation. Numerical solutions of the time-dependent Schr?dinger equation demonstrate that these operations can be performed with good fidelity.     

Screening dependence of superconducting state parameters

Theoretical values of superconducting state parameters of a number of superconductors are presented here using linear potential with seven different forms of dielectric screening in order to exhibit the dielectric dependence of these parameters. Presently computed results on comparison with the available experimental data show that the R.P.A. screening provides the best explanation of the superconducting state in most of the metals. It has been observed that the use of a non-local pseudopotential is desirable in the case of complex metals like Al, Pb etc.     

Nucleation and collapse of the superconducting phase in type-I superconducting films

The phase transition between the intermediate and normal states in type-I superconducting films is investigated using magneto-optical imaging. Magnetic hysteresis with different transition fields for collapse and nucleation of superconducting domains is found. This is accompanied by topological hysteresis characterized by the collapse of circular domains and the appearance of lamellar domains. Magnetic hysteresis is shown to arise from supercooled and superheated states. Domain-shape instability resulting from long-range magnetic interaction accounts well for topological hysteresis.     

Synthesis,Mössbauer studies and superconductivity of substituted Bi 2201 phase

We report X-ray diffraction, resistivity and Mössbauer studies on several substituted 2201 Bi cuprates, Bi₂Sr₂Cu_1?xFe_xO_y(O≤x≤1) and Bi₂Sr_1.6La_0.4Cu_1?xFe_xO_y and Bi_1.6Pb_0.4Sr_1.6La_0.4Cu_1?xFe_xO_y (O≤x≤0.04). The first series is not superconducting and a new phase appears for x=1. For La substituted samples, T_c increases up to 35K and decreases strongly with x. All Mössbauer spectra were fitted well with four quadrupole doublets, with relative population depending on samples.     

Pressure coefficients of intrinsic superconducting material parameters

The pressure coefficients of the upper critical field, H_c2, the thermodynamic critical field, H_C, the Ginzburg-Landau parameter, κ, the penetration depth, λ_p, and the coherence length, ξ_GL, are calculated for strong coupling superconductors at arbitrary temperatures.     

The reaction process of the Bi-Sr-Ca-Cu-O system and the forming mechanism of the 2212 superconducting phase

The reaction process and the reaction behavior of each component in the Bi-Sr-Ca-Cu-O system are presented in this paper. It reveals that the reaction is carried out in three different stages: forming of an insulating interphase at 680°C–790°C, forming of the 2212 superconducting phase at 790°C–860°C and forming often semiconducting phases in the presence of the liquid phase at 860°C–970°C. It is also confirmed that the 2212 superconducting phase (T _c=85 K) is formed by the reaction of a trinary interphase together with CuO, SrO and CaO. A new two-step method is presented to prepare the 2212 superconducting phase by a presynthesized interphase.     

视觉电生理闪光参数测量误差研究

闪光参数准确与否对于视觉电生理检查结果有效性具有重要意义。针对视觉电生理闪光参数特点,建立了闪光测量系统等效电路模型,基于传递函数理论分析了闪光测量系统参数对闪光强度、时程和波形测量误差的影响,以氙灯和LED为实验对象研究了系统参数在测量不同类型闪光时的误差。提出了减小测量误差以及消除测量闪光强度和LED闪光时程理论误差的方法并进行了实验验证。采用所述方法在不同系统参数下测量LED闪光强度结果的标准差为0.17%,LED闪光时程结果标准差为0.07%,可认为基本不变,实验与理论分析结果吻合。     

Study of superconducting state parameters of amorphous metals by a pseudopotential theory

The theoretical computation of the superconducting state parameters (SSP) viz; electron-phonon coupling strength λ, Coulomb pseudopotential μ ^*, transition temperature T _c , isotope effect exponent α and effective interaction strength N _O V of some monovalent (Cu and Au), divalent (Ca, Sr, Ba, αHg, βHg and Ra) and polyvalent (Lu, Rh, Sc, Y, La, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Ac, Th, Hf, Ru, Os, Ir, V, Ta, Pa, Cr, Mo, U, Re, Np and Pu) amorphous metals based on the different groups of the periodic table have been carried out for the first time using the well known Ashcroft’s empty core (EMC) model pseudopotential. Herein, we have employed five different types of local field correction functions proposed by Hartree (H), Taylor (T), Ichimaru-Utsumi (IU), Farid et al. (F) and Sarkar et al. (S) to study the exchange and correlation effects on the present investigations. A very strong influence of all the exchange and correlation functions have been observed in the present study. Our results are in fair agreement with documented theoretical as well as experimental data. A strong dependency of the SSP of amorphous metals on the valency Z was found.