Investigation of the adiabatic elasticity of polystyrene in the glass-transition region

Experimental results are presented for the density, absorption coefficient, and speed of ultrasound in a morphous polystyrene at frequencies of 375, 910, and 2350 kHz on the temperature interval 15–140°C. The glass-transition temperature does not depend on frequency. The adiabatic elasticity and characteristic impedance are calculated.Kolomna Branch of the All-Union Correspondence Polytechnic Institute. Translated from Mekhanika Polimerov, No. 4, pp. 746–749, July–August, 1973.     

Birefringence and ultimate strength of butadiene-styrene rubber

The authors present data on the relation between the ultimate strength and birefringence of SKS-30 butadiene-styrene rubber. Rubber test pieces were subjected to orientational stretching in the temperature interval –45 to +120°C.Mekhanika Polimerov, Vol. 2, No. 4, pp. 550–556, 1966     

Pyroelectric effect in polarized PVC

The pyroelectric effect has been detected in polarized PVC, and the temperature dependence of the pyroelectric constant p has been measured. The latter proved to be constant and equal to 0.1 cgse/deg·cm² at –130 to +30° C. The data show that p is proportional to the piezoelectric modulus d, with the proportionality factor k=3 · 10⁶ at room temperature. As the temperature falls, k decreases.Mekhanika Polimerov, Vol. 4, No. 2, pp. 377–378, 1968     

Thermodynamic stability of crystalline polymers in the transition region

The type of phase transition can be determined from the temperature dependence of the coefficient (–P/av)_s and the stability determinant D. We have calculated these quantities for polyethylene from data on the speed of ultrasound, density, and the specific heat C_p.Krupskaya Moscow Regional Pedagogical Institute. Translated from Mekhanika Polimerov, No. 4, pp. 724–726, July–August, 1971.     

Effect of extension on the structure and thermophysical properties of kapron (nylon 6)

The effect of extension on the structure and thermal conductivity of kapron has been investigated experimentally in the temperature range +20–130° C. The thermophysical characteristics were determined via a method based on the principle of the regular regime. The structure of the kapron was investigated by infrared spectroscopy and x-ray and microstructural analysis. The mechanical loads produced important structural changes that affected the thermophysical parameters of the kapron.Mekhanika Polimerov, Vol. 4, No. 1, pp. 180–182, 1968     

A study of the physicomechanical properties of carbon fibers at high temperatures

Conclusions 1. Carbon fibers, similar to graphite materials, are heat-resistant and do not Iose their short-term tensile strength in the temperature range studied — 20 to 2000°C.2. Young's modulus of carbon fibers hardly changes in the temperature range 20 to 1200°C, but a significant decrease is observed upon a further increase in temperature.Translated from Mekhanika Polimerov, No. 4, pp. 626–630, July–August, 1977.     

Relationship between the rheological characteristics of teflon determined for different loading regimes and temperatures

Specimens of teflon investigated in the temperature range from –40 to +60°C at various strain rates and in various loading regimes are used to demonstrate the relationship between changes in the theological properties of a material at constant standard loading rates (in the =vt regime) and the rheological characteristics determined by acoustic methods.Mekhanika Polimerov, Vol. 3, No. 4, pp. 619–624, 1967Presented on 3 February 1967 at the 4-th All-Union Conference on Strength and Plasticity, Moscow.     

Automated thermomechanograph for investigating polymer microsamples

An instrument has been developed for recording the thermomechanical curves of microsamples of polymers (30 mg) by the penetration method in the continuous heating regime. The thermomechanical curves are recorded by a PDS-021 two-coordinate recorder; the effective temperature range is 20–400°C.Institute of High-Molecular Compounds, Academy of Sciences of the USSR, Leningrad. Translated from Mekhanika Polimerov, Vol. 4, No. 4, pp. 746–749, July–August, 1968.     

Measurement of the strength of plastics in high-speed compression

A previously developed [1] method of determining the strength of plastics in high-speed compression is extended to the temperature range –196° to +150°C. Dynamic strength data have been obtained for epoxy-polyester and polyvinyl butyral resins and glass-fabric reinforced plastics based on these resins in the indicated temperature range.Mekhanika Polimerov, Vol. 1, No. 5, pp. 34–38, 1965     

Temperature-time dependence of the adhesion strength for polymer — Polymer systems

The temperature — time dependence of the adhesion strength has been studied for polymer systems differing in the thermodynamic compatibility of the substrate and adhesive and in the rate of polymerization of the latter. The fracture-activation energies of these systems have been calculated. It is shown that the temperature — time dependence of the adhesion strength varies depending on whether chemical intermolecular forces are responsible for the strength of the joint.Perm Scientific-Research Institute of Polymer Materials. A. M. Gor'kii Ural State University. Translated from Mekhanika Polimerov, Vol. 4, No. 4, pp. 665–671, July–August, 1968.     

Investigation of the relaxation process in polycarbonate film

The temperature relaxation of polycarbonate film and the accompanying change in the birefringence path difference are considered. It is shown that at a temperature of about 170°C intense crystallization takes place in the film. The deformation modulus is a function of the density of the network and its degree of orientation. The variation of these parameters with the stretch ratio and temperature is determined experimentally. The creep of polycarbonate film is considered and correlated with the curves representing the fall in the number of chains of the molecular network in pure relaxation.Mendeleev All-Union Scientific-Research Institute of Metrology, Leningrad. Translated from Mekhanika Polimerov, No. 1, pp. 72–76, January–February, 1973.     

Study of the role of intermolecular interactions (hydrogen bonds) in the initial stage of orientation of polyvinyl alcohol and vinyl alcohol copolymers

The effect of hydrogen bond rupture on the process of destruction of the starting crystallite structure of polyvinyl alcohol and copolymers of vinyl alcohol and N-vinylpyrrolidone and -vinylcaprolactam has been investigated. The differential spectrum method is used to establish the frequency (3200 cm^–1) of the band corresponding to the vibrations of the bound hydroxyl groups; the temperature dependence of the optical density of the 3200 cm^–1 band has been recorded. The strength of the starting structure is calculated from the stress-strain diagram and its temperature dependence is plotted. It is concluded that the strength of the starting structure is chiefly determined by the presence of hydrogen bonds between the polymer macromolecules.Leningrad Kirov Institute of Textile and Light Industry. Translated from Mekhanika Polimerov, No. 2, pp. 327–329, March–April, 1971.     

Effect of structure on the mechanical properties of block copolymers

Experimental data are given on the transitions in three block types in styrene-butadiene copolymers; these transitions were obtained by the dynamic-mechanical method on a torsional pendulum in the –180° to +170° temperature range. Based on these data, kinetic aspects have been advanced on the nature of the transitions based on the formation and decomposition of supramolecular structures of varying type and dimensions.Voronezh Technological Institute. Translated from Mekhanika Polimerov, No. 5, pp. 774–779, September–October, 1972.     

Shrinkage of epoxy cements during hardening

The authors give the results of measurements of the densities of two types of epoxy resin binders during setting from the initial liquid to the final state at room temperature. They assess the role of thermal shrinkage in the overall shrinkage deformation. They show that the coefficient of shrinkage relative to the state of lowest density is greater than the values given in the literature.Moscow Power Institute. Translated from Mekhanika Polimerov, No. 1, pp. 178–181, January–February, 1972.     

Temperature-frequency dependence of the elastic constants of certain resins

The authors present the results of an experimental investigation of the elastic constants of certain crosslinked and linear polymers in the temperature range from –50 to +110° C and the frequency range from 10¹ to 10⁵ Hz. The elastic constants were determined by both quasi-static and dynamic methods. The range of application of the different methods are characterized with respect to a time scale. It is shown that when certain experimental conditions are observed (strain rate, frequency), the values of the constants obtained by the different methods almost coincide. On the basis of temperature measurements it is postulated that rigid epoxies have a secondary low-temperature dispersion region.Mekhanika Polimerov, Vol. 3, No. 1, pp. 60–65, 1967     

Thermal effects in a glass laminate in tension

The results of a calorimetric investigation of a glass-reinforced textolite in uniaxial tension are presented. The specimens were deformed on the interval of strain rates from 0.3 to 10.5 mm/min at test temperatures from –30 to 80°C. The thermal effects are shown to depend on strain rate and test temperature.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 4, pp. 599–604, July–August, 1971.     

Stress state of thermosensitive thick cylinders made of anisotropic composites

The class of problems on the axially symmetric stress state of thick cylinders made of anisotropic materials is considered. The problems are solved numerically. The temperature and mechanical fields in the composite cylinders are investigated taking into account the temperature dependence of the matrix and reinforcement characteristics, as well as the variability of density and angle of reinforcement across the thickness.Institute of Mechanics, Ukrainian National Academy of Sciences, Kiev, Ukraine. Translated from Mekhanika Kompozitnykh Materialov, Vol. 35, No. 3, pp. 367–374, May–June, 1999.     

Dependence of the acoustic and mechanical properties of polyethylene on temperature and cyclic cooling and heating

The low-temperature stability of polyethylene is confirmed by acoustic and mechanical investigations. Data are given on the dependence of the acoustic and mechanical properties of polyethylene on temperature and repeated cyclic cooling to –50° and heating to +60°C, together with information on the change in Poisson's ratio and volume during deformation.Mekhanika Polimerov, Vol. 1, No. 3, pp. 145–150, 1965     

Investigation of the friction of rubber under constant compressive strain conditions at low pressure

A vacuum tribometer was developed which was used to investigate the maximum friction force occurring at the initial instant of slipping in rubber-metal friction pairs under conditions of a given (from 5 to 40%) compressive strain at a low pressure in the temperature range from +100 to –100°C. Filled rubbers on a base of nitrile-butadiene rubbers were studied. Up to the glass transition temperature T_g the vacuum had practically no effect on the maximum friction frocef _m; at temperatures T_g and lower the values off _m obtained in a vacuum were 10–15% higher than those obtained in the atmosphere. It is shown that with a decrease of temperature from 20°C to the glass transition temperature T_g the slope of the dependence of the maximum friction force on the degree of deformation increases, and below T_g decreases. The effect of the slipping speed v on the maximum friction forcef _m was also studied.Laboratory of Polymer Physics, V. I. Lenin Moscow State Pedagogical Institute. Leningrad Branch, Scientific Research Institute of the Rubber Industry. Translated from Mekhanika Polimerov, No. 3, pp. 486–492, May–June, 1970.     

Effect of cycle asymmetry on the cyclic strength of polymers

Cyclic strength diagrams have been obtained for polymethyl methacrylate and kaprolon at different degrees of loading asymmetry (from a pure compression to a pure tension cycle) on the interval from –100 to +80° C at 2·10³ and 3·10⁵ cycles.M. I. Kalinin Leningrad Polytechnic Institute. Translated from Mekhanika Polimerov, Vol. 4, No. 5, pp. 948–951, September–October, 1968.