<Emphasis Type="Italic">A</Emphasis><Subscript>∞</Subscript>-Algebra of an Elliptic Curve and Eisenstein Series

We compute explicitly the A _∞-structure on the algebra \({{\rm Ext}^*(\mathcal{O}_C \oplus L, \mathcal{O}_C \oplus L)}\) , where L is a line bundle of degree 1 on an elliptic curve C. The answer involves higher derivatives of Eisenstein series.     

Buchdahl–Vaidya–Tikekar model for stellar interior in pure Lovelock gravity

In the paper (Khugaev et al. in Phys Rev D94:064065. arXiv: 1603.07118, 2016), we have shown that for perfect fluid spheres the pressure isotropy equation for Buchdahl–Vaidya–Tikekar metric ansatz continues to have the same Gauss form in higher dimensions, and hence higher dimensional solutions could be obtained by redefining the space geometry characterizing Vaidya–Tikekar parameter K. In this paper we extend this analysis to pure Lovelock gravity; i.e. a \((2N+2)\)-dimensional solution with a given \(K_{2N+2}\) can be taken over to higher n-dimensional pure Lovelock solution with \(K_n=(K_{2N+2}-n+2N+2)/(n-2N-1)\) where N is degree of Lovelock action. This ansatz includes the uniform density Schwarzshild and the Finch–Skea models, and it is interesting that the two define the two ends of compactness, the former being the densest and while the latter rarest. All other models with this ansatz lie in between these two limiting distributions.     

Effect of cation substitution in Cs<Subscript>1–2<Emphasis Type="Italic">x</Emphasis></Subscript>Ba<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>H<Subscript>2</Subscript>PO<Subscript>4</Subscript> on structural properties and proton conductivity

We synthesized compounds with partial substitution of Cs⁺ cations in CsH₂PO₄ by Ba²⁺ cations. The structural, electron transport and thermodynamic properties of Cs_1–2x Ba _x H₂PO₄ (x = 0–0.15) were studied for the first time with the help of a set of physicochemical methods: infrared and impedance spectroscopy, X-ray diffraction and synchronous thermal analysis. The proton conductivity of Cs_1–2x Ba _x H₂PO₄ at 50–230°C was investigated in detail by impedance measurements. The formation of solid substitution solutions isostructural with CsH₂PO₄ (P2₁/m) is observed in the range of substitution degrees of x = 0–0.1, with a slight decrease in the unit cell parameters and some salt amorphization. The conductivity of disordered Cs_1–2x Ba _x H₂PO₄ in the low-temperature region increases by two orders of magnitude at x = 0.02 and increases with an increasing fraction of barium cations by three or four orders of magnitude at x = 0.05–0.1; the superionic phase transition practically disappears. At x = 0.15, heterophase systems based on salts are formed, showing high conductivity and a further decrease in the activation energy of conductivity to 0.63 eV. The conductivity of the high-temperature phase of Cs_1–2x Ba _x H₂PO₄ does not change with increasing fraction of the substituent.     

Synthesis,in vitro $$\alpha $$-glucosidase inhibitory activity,and in silico study of ( E)-thiosemicarbazones and ( E)-2-(2-(arylmethylene)hydrazinyl)-4-arylthiazole derivatives

This study is focused on the identification of thiazole-based inhibitors for the \(\alpha \)-glucosidase enzyme. For that purpose, (E)-2-(2-(arylmethylene)hydrazinyl)-4-arylthiazole derivatives were synthesized in two steps and characterized by various spectroscopic techniques. All derivatives and intermediates were evaluated for their in vitro \(\alpha \)-glucosidase inhibitory activity. Thiosemicarbazones 20 and 35, and cyclized thiazole derivatives 2, 5–11, 13, 15, 21–24, 27–31, and 36–37 showed significant inhibitory potential in the range of \(\hbox {IC}_{50}=6.2\pm 0.19\)–\(43.6\pm 0.23~\upmu \hbox {M}\) as compared to standard acarbose (\(\hbox {IC}_{50}=37.7\pm 0.19~\upmu \hbox {M}\)). A molecular modeling study was carried out to understand the binding interactions of compounds with the active site of enzyme.     

Generalized Kähler Potentials from Supergravity

We consider supersymmetric \({\mathcal{N} = 2}\) solutions with non–vanishing NS three–form. Building on worldsheet results, we reduce the problem to a single generalized Monge–Ampère equation on the generalized Kähler potential K recently interpreted geometrically by Lindström, Ro?ek, Von Unge and Zabzine. One input in the procedure is a holomorphic function w that can be thought of as the effective superpotential for a D3 brane probe. The procedure is hence likely to be useful for finding gravity duals to field theories with non–vanishing abelian superpotential, such as Leigh–Strassler theories. We indeed show that a purely NS precursor of the Lunin–Maldacena dual to the β–deformed \({\mathcal{N} = 4}\) super–Yang–Mills falls in our class.     

Mechanisms of ionization of <Emphasis Type="Italic">F</Emphasis><Subscript>2</Subscript>-centers in laser media on the basis of LiF crystals

F₂ color centers with a superhigh concentration (5000-cm^–1 absorption coefficient at 450 nm) were formed by high-density electron beams in a layer of LiF crystals of micrometer thickness. The F₂-centers excited by high-power nanosecond wide-band optical pulses (the “soft” pumping regime) efficiently amplified the laser radiation and showed high stability under these conditions. A low stability of F₂-centers to laser radiation (the “hard” excitation regime) is explained by the dissociation of (F ₂ ⁺ , F^–) pairs induced by two-step ionization of F₂-centers: (2hν > 4.5 eV) → F₂ → (F₂)* → F ₂ ⁺ + e; F + e → F^–; F ₂ ⁺ + F^– → 3F.     

Superdiffusion in the Periodic Lorentz Gas

We introduce the dynamical sine-Gordon equation in two space dimensions with parameter \({\beta}\), which is the natural dynamic associated to the usual quantum sine-Gordon model. It is shown that when \({\beta^{2} \in (0, \frac{16\pi}{3})}\) the Wick renormalised equation is well-posed. In the regime \({\beta^{2} \in (0, 4\pi)}\), the Da Prato–Debussche method [J Funct Anal 196(1):180–210, 2002; Ann Probab 31(4):1900–1916, 2003] applies, while for \({\beta^{2} \in [4\pi, \frac{16\pi}{3})}\), the solution theory is provided via the theory of regularity structures [Hairer, Invent Math 198(2):269–504, 2014]. We also show that this model arises naturally from a class of \({2 + 1}\) -dimensional equilibrium interface fluctuation models with periodic nonlinearities. The main mathematical difficulty arises in the construction of the model for the associated regularity structure where the role of the noise is played by a non-Gaussian random distribution similar to the complex multiplicative Gaussian chaos recently analysed in Lacoin et al. [Commun Math Phys 337(2):569–632, 2015].     

Existence of two types of perfect Bi<Subscript>2</Subscript>Sr<Subscript>2−<Emphasis Type="Italic">x</Emphasis></Subscript>La<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>CuO<Subscript>6+δ</Subscript> single crystals

It is found that perfect Bi₂Sr_2?x La _x CuO_6+δ single crystals with the same concentrations of lanthanum x = 0.64 and excess oxygen δ = 0.237 exist in two types. Single crystals of the first type are obtained by slow cooling (the synthesis time is 90–105 h). They have a monoclinic superlattice and exhibit no superconducting transition down to 2 K. Crystals of the second type are obtained by rapid cooling (the synthesis time is 30–40 h) and are characterized by a orthorhombic superlattice and T _c = 18 K. Thus, the superconducting transition temperature is determined not only by the concentration of carriers but also by the configuration of defects. A rhombic superlattice prevails in single crystals obtained by slow cooling in the lanthanum concentration range x = 0.3–0.5, while a monoclinic superlattice dominates in the range x = 0.75–0.85. This fact explains the high values of T _c at optimal doping (x = 0.4) and the absence of high-T _c superconductivity at p < 0.10.     

Phosphorus(V)corrole- Porphyrin Based Hetero Trimers: Synthesis,Spectroscopy and Photochemistry

‘Axial-bonding’-type hetero trimers have been constructed by employing a simple ‘inorganic’ reaction such as axial bond formation of main group element containing phosphorus corrole. The approach is simple and modular in nature. The architecture of these hetero trimers such that, while a phosphorus(V)corrole forms the basal scaffolding unit, either two free-base porphyrins [(H ₂ ) ₂ –PCor] or Zn^II porphyrins [(Zn) ₂ –PCor] occupy the two axial sites via an aryloxy bridge. Both hetero trimeric species have been completely characterized by mass (FAB), UV/Vis, proton nuclear magnetic resonance spectroscopies and also by the differential pulse voltammetric method. Comparison of their spectroscopic and electrochemical data of these trimers with those of the corresponding reference compounds reveal that there is no apparent ring-to-ring interactions in these ‘vertically’ linked hetero trimers. Reduced fluorescence quantum yields were observed for [(H ₂ ) ₂ –PCor] and [(Zn) ₂ –PCor] when compared to corresponding monomeric chromophores. Finally, a comparison is made between the presently reported phosphorus(V)corrole based hetero arrays and the previously reported analogous arrays based on Ge(IV)corrole with regard to their spectroscopic properties and photochemical activities.     

Study of the charge dependence of the pion–nucleon coupling constant on the basis of data on low-energy nucleon–nucleon interactions

The relation between quantities that characterize the pion–nucleon and nucleon–nucleon interactions is studied with allowance for the fact that, at low energies, nuclear forces in nucleon–nucleon systems are mediated predominantly by one-pion exchange. On the basis of the values currently recommended for the low-energy parameters of the proton–proton interaction, the charged pion–nucleon coupling constant is evaluated at g_π²±/4π = 14.55(13). This value is in perfect agreement with the experimental value of g_π²±/4π = 14.52(26) found by the Uppsala Neutron Research Group. At the same time, the value obtained for the charged pion–nucleon coupling constant differs sizably from the value of the pion–nucleon coupling constant for neutral pions, which is g_π² 0/4π = 13.55(13). This is indicative of a substantial charge dependence of the coupling constant.     

Synthesis of new chiral 1,3,4-thiadiazole-based di- and tri-arylsulfonamide residues and evaluation of in vitro anti-HIV activity and cytotoxicity

A series of new chiral 1,3,4-thiadiazole-based bis-sulfonamides 4a–4w and tri-sulfonamide analogue 5 was synthesized and evaluated as anti-HIV agents. The reaction of chiral amino acids 1 with sulfonyl chlorides 2, followed by subsequent reaction of resultant N-protected amino acids 2a–2f with thiosemicarbazide in the presence of excess phosphorous oxychloride afforded N-(1-(5-amino-1,3,4-thiadiazol-2-yl)alkyl)-4-arylsulfonamides 3a–3f. Treatment of 2a–2f with substituted sulfonyl chlorides in portions furnished the target bis-sulfonamide analogues 4a–4w in good yields, together with the unexpected 5. The new compounds were assayed against HIV-1 and HIV-2 in MT-4 cells. Compounds 4s were the most active in inhibiting HIV-1 with IC₅₀?=?9.5 μM (SI?=?6.6), suggesting to be a new lead in the development of an antiviral agent. Interestingly, compound 5 exhibited significant cytotoxicity of >?4.09 μM and could be a promising antiproliferative agent.     

The Baker–Akhiezer Function and Factorization of the Chebotarev–Khrapkov Matrix

A new technique is proposed for the solution of the Riemann–Hilbert problem with the Chebotarev–Khrapkov matrix coefficient \({G(t) = \alpha_{1}(t)I + \alpha_{2}(t)Q(t)}\) , \({\alpha_{1}(t), \alpha_{2}(t) \in H(L)}\) , I = diag{1, 1}, Q(t) is a \({2\times2}\) zero-trace polynomial matrix. This problem has numerous applications in elasticity and diffraction theory. The main feature of the method is the removal of essential singularities of the solution to the associated homogeneous scalar Riemann–Hilbert problem on the hyperelliptic surface of an algebraic function by means of the Baker–Akhiezer function. The consequent application of this function for the derivation of the general solution to the vector Riemann–Hilbert problem requires the finding of the \({\rho}\) zeros of the Baker–Akhiezer function ( \({\rho}\) is the genus of the surface). These zeros are recovered through the solution to the associated Jacobi problem of inversion of abelian integrals or, equivalently, the determination of the zeros of the associated degree- \({\rho}\) polynomial and solution of a certain linear algebraic system of \({\rho}\) equations.     

Neutron Pairing Correlations in an {\alpha}–{n}–{n} Three-Cluster Model of the {^{6}}He Nucleus

An \({\alpha}\)–n–n three-cluster model of the \({^6}\)He nucleus is studied by solving the Faddeev equations, where the cluster potential between \({\alpha}\) and n takes into account the Pauli exclusion correction, using the Fish-Bone Optical Model (Schmid in Z Phys A 297:105, 1980). The resulting binding energy of the ground state (\({0^+}\)) is 0.831 MeV and the resonance energy of the first excited state (\({2^+}\)), 0.60–i0.012 MeV, is extracted from the three-cluster break-up threshold. These theoretical values are in reasonable agreement with the experimental data: 0.973 MeV and 0.824–i0.056 MeV, respectively. In order to investigate the structure of these states, we calculate the angle density matrix for the \({\angle n_1 \alpha n_2}\) angle in the triangle formed by the three clusters. The angle density matrix of the ground state has two peaks and the configuration of \({0^+}\) wave function corresponding to the peaks constitutes a mixture of an acute-angled triangle structure and an obtuse-angled one. This finding is consistent with the former result from a variational approach (Hagino and Sagawa in Phys Rev C 72:044321, 2005). On the other hand, in the case of \({2^+}\) state only a single peak is obtained.     

Is the CNMSSM more credible than the CMSSM?

“Post-sphaleron baryogenesis”, a fresh and profound mechanism of baryogenesis accounts for the matter–antimatter asymmetry of our present universe in a framework of Pati–Salam symmetry. We attempt here to embed this mechanism in a non-SUSY SO(10) grand unified theory by reviving a novel symmetry breaking chain with Pati–Salam symmetry as an intermediate symmetry breaking step and as well to address post-sphaleron baryogenesis and neutron–antineutron oscillation in a rational manner. The Pati–Salam symmetry based on the gauge group \(\mathrm{SU}(2)_L \times \mathrm{SU}(2)_{R} \times \mathrm{SU}(4)_C\) is realized in our model at \(10^{5}\) – \(10^{6}\)  GeV and the mixing time for the neutron–antineutron oscillation process having \(\Delta B=2\) is found to be \(\tau _{n-\bar{n}} \simeq 10^{8}\) – \(10^{10}\)  s with the model parameters, which is within the reach of forthcoming experiments. Other novel features of the model include low scale right-handed \(W^{\pm }_R\) , \(Z_R\) gauge bosons, explanation for neutrino oscillation data via the gauged inverse (or extended) seesaw mechanism and most importantly TeV scale color sextet scalar particles responsible for an observable \(n\) – \(\bar{n}\) oscillation which may be accessible to LHC. We also look after gauge coupling unification and an estimation of the proton lifetime with and without the addition of color sextet scalars.     

Spectral Networks and Fenchel–Nielsen Coordinates

It is known that spectral networks naturally induce certain coordinate systems on moduli spaces of flat SL(K)-connections on surfaces, previously studied by Fock and Goncharov. We give a self-contained account of this story in the case K = 2 and explain how it can be extended to incorporate the complexified Fenchel–Nielsen coordinates. As we review, the key ingredient in the story is a procedure for passing between moduli of flat SL(2)-connections on C (equipped with a little extra structure) and moduli of equivariant GL(1)-connections over a covering \({\Sigma \to C}\); taking holonomies of the equivariant GL(1)-connections then gives the desired coordinate systems on moduli of SL(2)-connections. There are two special types of spectral network, related to ideal triangulations and pants decompositions of C; these two types of network lead to Fock–Goncharov and complexified Fenchel–Nielsen coordinate systems, respectively.     

Tuning Pt–Cu nanostructures by bromide ions and their superior electrocatalytic activities for methanol oxidation reaction

Dendritic Pt–Cu nanoparticles were synthesized by a facile one-step method with the help of surfactant Brij58 at room temperature, and we also studied the effects of different Pt–Cu ratios on the morphology and size of nanoparticles. In addition, we further tuned the morphology of the Pt–Cu nanostructures by introducing bromide ions, eventually leading to the appearance of some tripod-like structures. Compared with dendritic Pt–Cu and commercial Pt black, these tripod-like Pt–Cu nanostructures exhibited higher electrocatalytic activity and CO tolerance for catalyzing methanol oxidation.

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New Elliptic Solutions of the Yang–Baxter Equation

We consider two finite index endomorphisms \({\rho}\), \({\sigma}\) of any AFD factor M. We characterize the condition for there being a sequence \({\{ u_n\}}\) of unitaries of the factor M with \({\mathrm{Ad}u_n \circ \rho \to \sigma}\). The characterization is given by using the canonical extension of endomorphisms, which is introduced by Izumi. Our result is a generalization of the characterization of approximate innerness of endomorphisms of AFD factors, obtained by Kawahiashi–Sutherland–Takesaki and Masuda–Tomatsu. Our proof, which does not depend on the types of factors, is based on recent development on the Rohlin property of flows on von Neumann algebras.     

Stable and Unstable Vortex Knots in a Trapped Bose Condensate

The dynamics of a quantum vortex toric knot T_P,Q and other analogous knots in an atomic Bose condensate at zero temperature in the Thomas–Fermi regime is considered in the hydrodynamic approximation. The condensate has a spatially inhomogeneous equilibrium density profile ρ(z, r) due to the action of an external axisymmetric potential. It is assumed that z_*= 0, r_*= 1 is the point of maximum of function rρ(z, r), so that δ(rρ) ≈ –(α–)z²/2–(α + )(δr)²/2 for small z and δr. The geometrical configuration of a knot in the cylindrical coordinates is determined by a complex 2πP-periodic function A(?, t) = Z(?, t) + i[R(?, t))–1]. When |A| ? 1, the system can be described by relatively simple approximate equations for P rescaled functions \({W_n}(\varphi ) \propto A(2\pi n + \varphi ):i{W_{n,t}} = - ({W_{n,\varphi \varphi }} + \alpha {W_n} - \in W_n^*)/2 - \sum\nolimits_{j \ne n} {1/(W_n^* - W_j^*)} \). For = 0, examples of stable solutions of type W _n = θ _n (?–γt)exp(–iωt) with a nontrivial topology are found numerically for P = 3. In addition, the dynamics of various unsteady knots with P = 3 is modeled, and the tendency to the formation of a singularity over a finite time interval is observed in some cases. For P = 2 and small ≠ 0, configurations of type W₀–W₁ ≈ B₀exp(iζ) + C(B₀, α)exp(–iζ) + D(B₀, α)exp(3iζ), where B₀ > 0 is an arbitrary constant, ζ = k₀?–Ω₀t + ζ0, k₀ = Q/2, and Ω₀ = (–α)/2–2/B₀², which rotate about the z axis, are investigated. Wide stability regions for such solutions are detected in the space of parameters (α, B₀). In unstable zones, a vortex knot may return to a weakly excited state.