同时发射和接收纵波和横波的压电复合材料换能器

通过控制压电复合材料中压电相的分布形式，本文具有在百度模振动的１－３型压电复合材料和具有扭转模振动的拼接２－２型压电复合材料组合在一起，构成一种混俣模式压电材料，并测试了这种压电材料晶片的性能参数，使用这种晶片作的换能器可以根据使用者的要求，单独产生纵波或横波，也可同时产生这两种波。     

扭转压电复合材料及其应用

本文描述了轴向－切向连通的圆柱２－２型压电复合材料。用ＰＺＴ／环氧树脂制作的普通２－２型压电复合材料可拼接成一种具有扭转振动的压电复合材料。这种压电复合材料和为圆柱２－２型压电复合材料的近似。本文还给出两组这种拼接型压电材料晶片的参数，用这种压电材料制作了产生扭转振动的换能器，测试了换能器的波形，频谱特性和偏振特性，指出了使用适当的高通滤波器可以抑制横波中的径向模，分析了接收波列中纵波抑制较强的原     

检测超声换能器用1-3型压电PZT/环氧复合材料及换能器的研究

本文介绍了一种制做1—3型压电 PZT/环氧复合材料的新方法.此方法采用了PZT小柱非周期性均匀分布,有效地消除了由于PZT小柱周期性分布而产生的有害横向结构共振模式,获得了振动模式较单纯的1—3型压电复合材料晶片,研制出宽带(低Q)换能器及高斯型换能器.     

宏声声学器材厂生产压电陶瓷材料

河北省保定市宏声声学器材厂（原化新压电陶瓷器件厂）生产的PMN压电材料，其配方于1987年通过了由声学专家组成的省级技术鉴定．这是一种高KP，高介电常数，低Q。的压电材料，适用于接收型换能器．该厂目前已形成PMN、PZT等四大系列产品的生产能力：1．用P（ZTNU七；压电材料制造的油田声波测井YTG－l－7型高温测井压电陶瓷换能元件，测井时可发射、接收并用，从室温到20OC高温，机电转换率的变化率＜6％．2．用于接收的PMN压电材料及FTD蜂鸣片产品，适用于仪器仪表，传感器，电话机及讯响器．3．大功率发射型材料PZT－8，适…     

1-3型压电复合材料非均匀振动换能器的研究

通过调整1－3型压电复合材料换能器中压电相的分布，可以控制换能器辐射面上振动幅度和相位的分布，从而获得具有特殊性能的声场．作为辐射源表面振动速度等相位不等幅和等幅不等相位的两种典型情况，本文对边线高斯型换能器和Wesnel聚焦换能器进行了实验研究，讨论了其声场特性．     

面切变压电复合材料及其换能器

本文通过控制压电相在压电复合材料中的分布形式，把四块完全相同的等腰直角王角形2－2型压电复合材料拼接起来，四个直角顶点位于晶片的中心，相邻块压电相的极化方向相对．这种新型材料可产生面切变振动，其换能器可辐射面切变波．波列中的纵波具有伴随性且其首波位相与面切变波首波位相相反     

压电复合材料宽带横波换能器的实验研究

本文用实验方法研究了２－２压电复合材料的厚度切变特性，定性地给出了２－２压电复合材料的性能与ＰＺＴ相体积百分比，以及与共振频率牟关系。并用这种材料作为换能元件，制作出高灵敏度窄脉冲横波换能器。     

高频宽带嵌套式复合材料换能器

研制了一种嵌套式高频宽带复合材料换能器,利用1-3型压电复合材料Q值较低、频带较宽的特点,采用组合式的结构拓展换能器的工作带宽。通过切割框型压电陶瓷、灌注环氧树脂得到压电复合材料框型敏感元件,再将不同厚度的框型敏感元件沿轴向嵌套从而制成多层嵌套的压电复合材料敏感元件。建立1-3型压电复合材料中压电小柱的等效电路,根据等效电路计算出压电小柱的谐振频率,并与1-3型压电复合材料的谐振频率理论计算结果进行对比。通过ANSYS软件对敏感元件结构进行仿真,并根据仿真结果确定了敏感元件的最佳设计方案。最终制作出的换能器进行水下测试,该换能器的谐振频率为310 kHz,最大发送电压响应为188.5 dB,-3 d B带宽可达130 kHz,接收灵敏度最大可达-186.8 dB,-3 dB带宽可达90 kHz,谐振频率处-3 d B的指向性开角约为2.4°。该嵌套式敏感元件可实现换能器宽带发射与接收声波的目标。     

面切变压电复合材料及其换能器

本文通过控制压电相在压复合材料中的分布工，把四块完全相同的等腰直角三角形２－２型压电复合拼材料拼接起来，四个直角顶点位于晶片的中心，     

铁电/铁磁1-3型结构复合材料磁电性能分析

磁致伸缩和压电复合材料通过机械力作用可获得较大的磁电效应，由Terfenol-D粉末与树脂黏接剂构成压磁相，和压电陶瓷PZT黏结在一起，形成1-3型柱状阵列结构，可获得很大的磁电转换系数.采用有限元方法，对此结构的复合材料进行静态分析.复合材料的介电常数和磁电系数的计算结果和实验数值一致，得到样品中应力、应变和电极化分布情况及其关系，并给出进一步提高磁电转换系数的途径，该种复合方式有望成为一种新型高性能的磁电结构. 关键词： 复合材料 磁电效应 有限元     

QED effects in Cu-like Pb recombination resonances near threshold

In an electron-ion recombination study with Pb53+ dielectronic recombination resonances are found for as low as approximately 10(-3)-10(-4) eV relative energy. The resonances have been calculated by relativistic many-body perturbation theory and through comparison with experiment the Pb53+(4p(1/2)-4s(1/2)) energy splitting of approximately 118 eV is determined with an accuracy comparable to the position of the first few resonances, i.e., approximately 10(-3) eV. Such a precision provides a test of QED in a many-body environment at a level which can still not be reached in calculations.     

Low-temperature sintering and electromagnetic properties of Ba(Zn1/3Nb2/3)O3/NiCuZn ferrite composites

Dense Ba(Zn_1/3Nb_2/3)O₃/(Ni_0.37Cu_0.20Zn_0.43O)-(Fe₂O₃)_0.96 (BZN/NiCuZn) composites were prepared by the conventional solid-state reaction method and sintered at 950 °C. The phase composition and surface morphology of the composites were investigated using XRD and SEM, respectively. The dielectric and magnetic properties of the composites are also reported. In low frequency range the dielectric properties of the BZN/NiCuZn composites show Maxwell-Wagner relaxation. In high frequency range the BZN/NiCuZn composites possess high dielectric constants and permeabilities, which can be used in high-frequency communications for capacitor-inductor integrating devices such as electromagnetic interference filters and antennas.     

Modeling of micromachined silicon–polymer 2-2 composite matching layers for 15 MHz ultrasound transducers

Silicon–polymer composites fabricated by micromachining technology offer attractive properties for use as matching layers in high frequency ultrasound transducers. Understanding of the acoustic behavior of such composites is essential for using them as one of the layers in a multilayered transducer structure. This paper presents analytical and finite element models of the acoustic properties of silicon–polymer composites in 2-2 connectivity. Analytical calculations based on partial wave solutions are applied to identify the resonance modes and estimate effective acoustic material properties. Finite Element Method (FEM) simulations were used to investigate the interaction between the composite and the surrounding load medium, either a fluid or a solid, with emphasis on the acoustic impedance of the composite. Composites with lateral periods of 20, 40 and 80 μm were fabricated and used as acoustic matching layers for air-backed transducers operating at 15 MHz. These composites were characterized acoustically, and the results were compared with analytical calculations. The analytical model shows that at low to medium silicon volume fraction, the first lateral resonance in the silicon–polymer 2-2 composite is defined by the composite period, and this lateral resonant frequency is at least 1.2 times higher than that of a piezo-composite with the same polymer filler. FEM simulations showed that the effective acoustic impedance of the silicon–polymer composite varies with frequency, and that it also depends on the load material, especially whether this is a fluid or a solid. The estimated longitudinal sound velocities of the 20 and 40 μm period composites match the results from analytical calculations within 2.7% and 2.6%, respectively. The effective acoustic impedances of the 20 and 40 μm period composites were found to be 10% and 26% lower than the values from the analytical calculations. This difference is explained by the shear stiffness in the solid, which tends to even out the surface displacements of the composites.     

High-Resolution Study of the Mid-Infrared Region of FNO(2)

Of the gas-phase IR spectrum of nitrylfluoride, FNO(2), between 1200 and 1900 cm(-1), the bands nu(4), 2nu(6), nu(2) + nu(3), and nu(1) have been studied at a resolution of ca. 0.003 cm(-1). Improved ground state rotational and centrifugal distortion constants have been obtained from a simultaneous analysis of the data from F. Hegelund, H. Bürger, and G. Pawelke [J. Mol. Spectrosc. 184, 350-361 (1997)] and the present data from nu(4) and nu(1). The nu(4) and 2nu(6) bands are free from local perturbations, and upper state spectroscopic constants have been obtained from the conventional Watson Hamiltonian. The bands nu(1) and nu(2) + nu(3) are strongly perturbed by Coriolis interactions with the nearby dark levels nu(5) + nu(6), nu(3) + nu(6), and nu(2) + nu(5). Upper state constants for nu(1) and nu(2) + nu(3) are obtained from triad and tetrad models, respectively, including Coriolis resonances within this system. In addition Coriolis interaction parameters and the vibrational energies for the three dark states together with some of their rotational constants are determined from the observed perturbation effects on nu(1) and nu(2) + nu(3). Copyright 2000 Academic Press.     

Prediction of the properties of two-phase composites with a piezoactive component

The effective dielectric, piezoelectric, and elastic constants of two-phase macroscopically piezoactive 3-0 and 3-3 composites are calculated. It is assumed that one of the components is a polarized ferroelectric ceramic material and the other is an inactive material with variable elastic properties. The limiting case when the elastic compliances of the inactive material tend to infinity (porous ferroelectric ceramics) is considered. The adequacy of this model to production technologies of piezoelectric composites is discussed. Computational results are compared with experimental data.     

Anharmonic analysis of the vibrational states of pyrimidine by the density functional method

The quartic force field of pyrimidine is calculated in the approximation of the hybrid density functional B3LYP/6-31G(d). On the basis of this force field, the IR spectrum of pyrimidine in the range 250–3800 cm^?1 is interpreted. The Darling-Dennison and Fermi resonances are taken into account and their spectral manifestations are analyzed. A combined method for the anharmonic analysis of the vibrational states of polyatomic molecules that employs the theoretical anharmonicity constants and experimental frequencies is proposed. The method ensures a higher prediction accuracy.     

On meson resonances and chiral symmetry

We study meson resonances with quantum numbers J^P=1⁺ in terms of the chiral SU(3) Lagrangian. At leading order a parameter-free prediction is obtained for the scattering of Goldstone bosons off vector mesons with J^P=1⁻ once we insist on approximate crossing symmetry of the unitarized scattering amplitude. A resonance spectrum arises that is remarkably close to the empirical pattern. In particular, we find that the strangeness-zero resonances h₁(1380), f₁(1285) and b₁(1235) are formed due to strong and channels. This leads to large coupling constants of those resonances to the latter states.     

Photoproduction of η and η' mesons off nucleons close to threshold

The importance of Born terms and resonance exchange for η and η' photoproduction off both the proton and neutron within U(3) baryon chiral perturbation theory is investigated. Low-lying resonances such as the vector mesons and J ^P = 1/2⁺, 1/2^- baryon resonances are included explicitly and their contributions together with the Born terms are calculated. The coupling constants of the resonances are determined from strong and radiative decays. We obtain reasonable agreement with experimental data near threshold. Received: 17 March 2000 / Accepted: 8 September 2000     

First High-Resolution Infrared Observation of the Symmetry-Forbidden nu(5) Band of (10)B(2)H(6)

Spectra of (10)B monoisotopic diborane, B(2)H(6), have been recorded at high resolution (2-3 x 10(-3) cm(-1)) by means of Fourier transform spectroscopy in the region 700-1300 cm(-1). A thorough analysis of the nu(18) a-type, nu(14) c-type, and nu(5) symmetry-forbidden band has been performed. Of particular interest are the results concerning the nu(5) symmetry-forbidden band, which is observed only because it borrows intensity through an a-type Coriolis interaction with the very strong nu(18) infrared band located approximately 350 cm(-1) higher in wavenumber. The nu(5) band has been observed around 833 cm(-1) and consists of a well-resolved Q branch accompanied by weaker P- and R-branch lines. Very anomalous line intensities are seen, with the low K(a) transitions being vanishingly weak, and Raman-like selection rules observed. The determination of the upper state Hamiltonian constants proved to be difficult since the corresponding energy levels of each of the bands are strongly perturbed by nearby dark states. To account for these strong localized resonances, it was necessary to introduce the relevant interacting terms in the Hamiltonian. As a result the upper state energy levels were calculated satisfactorily, and precise vibrational energies and rotational and coupling constants were determined. In particular the following band centers were derived: nu(0) (nu(5)) = 832.8496(70) cm(-1), nu(0) (nu(14)) = 977.57843(70) cm(-1), and nu(0) (nu(18)) = 1178.6346(40) cm(-1). (Type A standard uncertainties (1varsigma) are given in parentheses.) Copyright 2000 Academic Press.