共查询到20条相似文献,搜索用时 15 毫秒
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联吡啶以分子水平掺入SiO2凝胶玻璃中,显示出独特的光谱性质。其发射光谱除了正常的S1→S0跃迁产生的中心位于400nm的发射峰外,还出现了中心位于454nm的激基缔合物发射峰。经200℃处理后,联吡啶分子受Si-O网络刚性约束,激基缔合发射峰消失,出现了基于S2→S0辐射跃迁产生的325nm高能级发射峰。至550℃处理后,因联吡啶分子基本进入Si-O三维网络的间隙,发射光谱中只剩下振动结构明显的高能级荧光峰。上述结果为表征有机/无机复合材料微结构演变提供了荧光探针工具。 相似文献
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联吡啶以分子水平掺入SiO2凝胶玻璃中, 显示出独特的光谱性质. 其发射光谱除了正常的S1→S0跃迁产生的中心位于400 nm的发射峰外, 还出现了中心位于454 nm的激基缔合物发射峰. 经200 ℃处理后, 联吡啶分子受Si-O网络刚性约束, 激基缔合发射峰消失, 出现了基于S2→S0辐射跃迁产生的325 nm高能级发射峰. 至550 ℃处理后, 因联吡啶分子基本进入Si-O三维网络的间隙, 发射光谱中只剩下振动结构明显的高能级荧光峰. 上述结果为表征有机/无机复合材料微结构演变提供了荧光探针工具. 相似文献
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Aldo Antognini Franz Kottmann François Biraben Paul Indelicato François Nez Randolf Pohl 《Annals of Physics》2013
The 7σ discrepancy between the proton rms charge radius from muonic hydrogen and the CODATA-2010 value from hydrogen spectroscopy and electron-scattering has caused considerable discussions. Here, we review the theory of the 2S–2P Lamb shift and 2S hyperfine splitting in muonic hydrogen combining the published contributions and theoretical approaches. The prediction of these quantities is necessary for the determination of both proton charge and Zemach radii from the two 2S–2P transition frequencies measured in muonic hydrogen; see Pohl et al. (2010) [9] and Antognini et al. (2013) [71]. 相似文献
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本文基于MOLPRO软件包使用从头算方法计算了星际分子H2S及其阳离子H2S+的势能面及光电子能谱.首先,在(U)CCSD/cc-pVQZ理论水平下获取了H2S沿法线坐标展开的势能面,势能面直观描述了不同振动模式耦合对分子能量变化的影响,S-H键的非对称伸缩振动和面内弯曲振动共同作用使得系统势能变化范围明显变大.振动多组态相互作用方法被用来计算非谐振动频率和振动光谱,计算结果显示,倍频和组合频之间出现了强烈的费米共振,使得相应波段处的红外强度显著增强.最后,使用拉曼波函数和收缩不变Krylov子空间方法首次计算了H2SΧ1A1→H2S+ X2B1的光电子能谱.此项研究有助于进一步理解星际分子的内部结构,并为实验研究及星际观测提供参考. 相似文献
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对于很多稀土激活剂来说,具有A-型稀土氧化物结构的La_2O_2S是一种有效的基质晶体。本文报导Ti~(4+)在这种基质中的光谱特性。Ti~(4+)具有d°电子能态,而不存在明显的与它通常所发射的光相对应的原子能级,因而,Ti~(4+)发射的性质和机理还不十分清楚。我们知道,为了获得Ti~(4+)的高效发光,经常需要大于10%克分子的高浓度激活剂,这比大多数过渡金属和稀土激活剂所需要的浓度大得多。Ti激活的化合物的发光仅仅在氧化条件下制备的 相似文献
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JETP Letters - The relative position of atomic planes of low-temperature monoclinic acanthite α-Ag2S and high-temperature bcc argentite β-Ag2S has been determined from X-ray and electron... 相似文献
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《Infrared Physics & Technology》2000,41(1):41-45
The IR optical transmission spectra in the 4000–1000 cm−1 (2.5–10 μm) region in the chalcogenide glasses (ChG) of the ternary Ge–Sb–S system of stoichiometric Sb2S3–GeS2 and non-stoichiometric Sb2S3–Ge2S3 compositions are studied. The compositional dependences of the measured IR spectra connected with influence of O-, H- and C-based absorbed impurites are analyzed. 相似文献
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利用在北京谱仪上获取的1.27×106ψ(2S)事例研究了末态为矢量介子与赝标量分子的ψ(2S)两体衰变过程,ψ(2S)→ρπ及KK,得到它们的衰变分支比上限在90%置信度下分别为3.6×10-5(ρπ),2.5×10-5(K+K-+C.C.)(C.C.代表电荷共轭态)及1.2×10-4(K0K0+C.C.).这些结果在新的实验灵敏度水平上证实了ψ(2S)相对于J/ψ强衰变中的反常压制现象的存在. 相似文献
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In2S3 films have been deposited by the successive ionic adsorption and reaction technique (SILAR) at room temperature. The films have been examined to evaluate the structural and optical properties. X-ray diffraction spectra have revealed the presence of both the α-In2S3 (cubic) and β-In2S3 (tetragonal) phases. The presence of the α-In2S3 phase at room temperature is attributed to the richness of In in the deposited materials. The presence of both phases is also supported by FESEM observations. The crystallinity of the material has been observed to improve with increasing thickness. Direct band gap of the deposits decreased from 2.89 to 2.37?eV with increasing thickness. 相似文献
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Inclusive γ(1S,2S,3S) photoproduction at the future Circular-Electron-Positron-Collider(CEPC)is studied,using the non-relativistic quantum chromodynamics(NRQCD)factorization formalism.Including the contributions from both direct and resolved photons,we present different distributions for the γ(1S,2S,3S) production.Our results suggest that there will be considerable events,implying that well measurements of the T photoproduction can be performed to further study heavy quarkonium physics at electron-positron colliders,in addition to hadron colliders.This supplemental study is very important for clarifying the current situation regarding the heavy quarkonium production mechanism. 相似文献
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Dorokhov A. E. Martynenko A. P. Martynenko F. A. Sukhorukova O. S. Faustov R. N. 《Journal of Experimental and Theoretical Physics》2019,129(6):956-972
Journal of Experimental and Theoretical Physics - The interval of a large structure of energy spectrum (1S–2S) in muonic helium and hydrogen is calculated using a quasi-potential method in... 相似文献
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Technical Physics - Thin-film Cu–As2S3 and Ag–As2S3 structures obtained by successively evaporating Cu(Ag) and As2S3 in vacuum on glass substrates have been studied. Samples of these... 相似文献
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O. I. Shpotyuk E. R. Skordeva R. Ya. Golovchak V. D. Pamukchieva A. P. Kovalskii 《Journal of Applied Spectroscopy》1999,66(5):749-753
The radiative-optical properties of chalcogenide glass-like semiconductors of the As2S2−Ge2S3 system in the region of a topological 2D-3D-phase transition are investigated. It is shown that γ-irradiation of samples
by an absorbed dose of 4.4 · 106 Gy leads to a longwave shift of their optical-transmission edge in the spectrum. The effect observed depends on the structural
type of the glasses investigated and changes considerably near the 2D-3D-phase transition. Two components of the transmission-edge
shift are detected: a static component, which remains unchanged for a long time after irradiation of the samples, and a dynamic
one, which gradually fades in 2–3 months. It is suggested that the microstructural mechanism of these changes is attributable
to processes of coordination defect formation in the structural skeleton of the samples.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, pp. 657–660, September–October, 1999. 相似文献
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Qibin Li 《Molecular physics》2014,112(7):947-955
The mechanism of sulphur nucleation in S–H2S system is investigated by molecular dynamics simulation with the ReaxFF reactive force field. The results indicate that the nucleation of sulphur requires certain conditions. The nucleus of sulphur will form once the allotropes of sulphur dissolve from polysulphanes. Separate sulphur atoms aggregate into the cluster in the initial stage of nucleation according to the snowball effect. The cluster of nucleation is judged by the average distance of the neighbour sulphur atoms, which is identified as 2.8 Å through a parametric study. The sustainable process of nucleation depends on whether the cluster can overcome its critical state. The formation of the cluster may accelerate its own nucleation/coalescence and H2S decomposition. 相似文献
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