Elasticity of the crystal lattice of polyethylene terephthalate

The elasticity of the crystal lattice of polyethylene terephthalate was studied along and across the axes of the polymer molecules. The elastic modulus across the chains depended on the degree of crystallinity and the interplane distances in the directions of thea and b parameters of the unit cell. The nature of the elastic deformation in the crystal lattice was analyzed, and its elastic modulus along and across the axes of the chains was calculated. On loading biaxially oriented amorphous-crystalline polymers with a tensile stress applied in the direction of one of the orientation axes of the polymer, the stresses in the crystallites oriented along and across the external applied force and the amorphous regions in series with them were equal to the stress in the sample averaged over the cross section.Deceased.Translated from Mekhanika Polimerov, No. 6, pp. 982–986, November–December, 1972.     

Structural changes in a cotton fiber under load

Mechanical tests and x-ray studies have shown that a shift of the meridional reflection towards smaller angles signifies the stretching of the crystallite lattice in the meridional direction. The shift has been used to determine the modulus of elasticity of the crystal lattice of cotton. The microdeformation (of the crystal lattice) and the macrodeformation (extension of the specimen as a whole) are compared. The modulus of elasticity of the crystal lattice is an order greater than that of the fiber itself.V. I. Lenin Tadzhik State University, Dushanbe. Translated from Mekhanika Polimerov, No. 4, pp. 594–598, July–August, 1973.     

Investigation of the modulus of elasticity of carbon fibers

A simplified analysis of the dependence of the elastic properties and electrical conductivity of a carbon fiber on its orientation index is presented. The experimentally confirmed inverse correlation between the electrical resistivity and the speed of sound makes it possible to calculate the modulus of elasticity of carbon fibers from data on the bulk resistivity.Moscow Aviation Technological Institute. Translated from Mekhanika Polimerov, No. 5, pp. 846–850, September–October, 1971.     

Some laws of the elastic properties of oriented fibrous polymers and fibers

The author considers the results of calculations of the limiting values of the elastic properties (modulus of elasticity and load-extension diagram) of the main types of chemical fibers, using a model with "ideal orientation" of the molecules and the derived laws of deformation of polymer chains. A method is proposed for calculating the elastic properties of "ideally oriented" polymers from the velocity of propagation of an elastic deformation pulse and the effective density of the "skeletons" of the polymer chains. Values of the moduli of elasticity of the amorphous regions of the structure of oriented polymers are calculated. The calculated results are compared with experimental data on the elastic properties of fibers.Mekhanika Polimerov, Vol. 2, No. 1, pp. 34–42, 1966Paper read at the XIV All-Union Conference on High-Molecular Compounds, Oriented State.     

Transverse compression of PPTA fibers

Results of single transverse compression testing of PPTA and PIPD fibers, using a novel test device, are presented and discussed. In the tests, short lengths of single fibers are compressed between two parallel, stiff platens. The fiber elastic deformation is analyzed as a Hertzian contact problem. The inelastic deformation is analyzed by elastic-plastic FE simulation and by laser-scanning confocal microscopy of the compressed fibers ex post facto. The results obtained are compared to those in the literature and to the theoretical predictions of PPTA fiber transverse elasticity based on PPTA crystal elasticity.Presented at the 11th International Conference on Mechanics of Composite Materials (Riga, June 11–15, 2000).3TEX, Inc. 109, MacKenan Drive, Cary, North Carolina 27511, USA. Published in Mekhanika Kompozitnykh Materialov, Vol. 36, No. 4, pp. 533–544, March–April, 2000.     

Method of determining the volume and shear characteristics of elastico-viscous hereditary media from uniaxial-tension (compression) experiments

A method is proposed for determining the elastic constants — instantaneous modulus of elasticity, Poisson's ratio, shear modulus, bulk modulus, and the shear and volume influence functions — the shear creep kernel, the shear creep rate kernel, and the corresponding relaxation kernels from the data of creep or relaxation tests.Moscow. Translated from Mekhanika Polimerov, No. 4, pp. 754–758, July–August, 1969.     

Elasticity of the crystal lattices of novel polyimides and fragments of polyimide chains

Conclusions 1. The elasticity modulus of the crystal lattices along the c axis, the pliancy of the repeated links, and the force f needed for stretching a single chain in the lattice by 1% were determined from the displacement of meridional x-ray reflexes produced by loading of PMPF and PMB polyimide filaments.2. Thanks to the similarity and simplicity of the conformations and chains of the polymers examined in the crystal lattice, and also thanks to the similarity of their chemical structure, the pliancies and the forces f for the various fragments of the chains could be experimentally determined. The pliancies calculated for the repeated links and their fragments agree satisfactorily with the experimental data.3. Addition of phenylene groups to the dianhydride fragment should not lead to a noticeable change of the pliancy of the chain as a whole.Institute of High-Molecular-Weight Compounds, Academy of Sciences of the USSR, Leningrad. Translated from Mekhanika Polimerov, No. 5, pp. 771–776, September–October, 1976.     

Effect of fiber curvature on the modulus of elasticity for unidirectional glass-reinforced plastics in tension

The effect of curvature of the fibers on the modulus of elasticity of unidirectional glass-reinforced plastics (GRP) in tension has been investigated on the basis of the theory of layered reinforced media with random initial irregularities [1,2]. It is shown experimentally that relatively minor distortion of the fibers during manufacture may result in important changes in the modulus of elasticity. A model is proposed for determining the effect of fiber curvature on Young's modulus; experiments on specimens with a given regular fiber curvature indicate good agreement with the theory. The effect of prestressing the fibers on the modulus of elasticity has been studied using commercial AG-4S material and the optimum prestress has been established.Mekhanika Polimerov, Vol. 3, No. 2, pp. 243–249, 1967     

Method of investigating the extension of high-elastic polymers

A method has been developed for studying the deformation of polymers in a field with a longitudinal velocity gradient. The changes in the longitudinal viscosity and modulus of high elasticity of polyisobutylene in uniaxial tension at constant extension and strain rates are compared.Mekhanika Polimerov, Vol. 4, No. 2, pp. 343–348, 1968     

Effectiveness of using hollow fibers to improve the rigidity of glass-reinforced plastics

Calculated and experimental relations between the modulus of elasticity and rigidity of unidirectional glass-reinforced plastics (GRP) and the capillarity coefficient of the hollow fiber reinforcement are presented. It is established that in calculating the flexural rigidity ratio of hollow- and solid-fiber GRP specimens of equal weight it is not permissible to neglect the mass and modulus of elasticity of the resin. The potentialities of hollow fibers as reinforcement for GRP shells subjected to external pressure are demonstrated.All-Union Scientific-Research Institute of Glass-Reinforced Plastics and Glass Fibers, Moscow Region. Translated from Mekhanika Polimerov, Vol. 4, No. 4, pp. 672–676, July–August, 1968.     

Possibilities of a nondestructive one-parameter method of checking the strength of anisotropic glass-reinforced plastics in uniaxial compression

A nondestructive method of checking the strength of glass-reinforced plastics (GRP) in finished products is proposed. This method is based on the correlation, investigated by the authors, between the modulus of elasticity and the compressive strength determined by a standard method. Various orientations in the plane of reinforcement of glass-reinforced plastics with different ratios of the orthogonally arranged fibers are investigated. It is proposed to determine the modulus of elasticity from the propagation velocity of an ultrasonic pulse measured under conditions of one-sided access to the surface of the product."Ritm" Research-Production Association, Leningrad. Translated from Mekhanika Polimerov, No. 5, pp. 909–919, September–October, 1974.     

Determination of the elastic characteristics of compact bone tissue by investigation of the natural vibration frequency

The dynamic elastic H and shear G_dyn moduli of compact bone tissue have been determined by investigating the natural vibration frequency of specimens obtained from long tubular human bones. The modulus of elasticity E has also been determined by conducting mechanical bending tests. The value of the H modulus is found to change in the course of storage.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 1, pp. 167–172, January–February, 1971.     

Thermal deformation of a composite reinforced with hybrid cloth strips

Conclusion We tested (for mechanical and thermal effects) composites reinforced with hybrid cloth COS and VAI strips; five alternate schemes of material, which differred in terms of the content of VAI layers and layers reinforced with COS, were tested. The elasticity characteristics, tension diagrams, and CLTE of the composites were determined. It was established experimentally that variation in the relative content of the above-indicated layers makes it possible to regulate the thermal expansion of the composite in the longitudinal direction of the reinforcing strips Objectively over significant ranges; in this case, the elastic modulus varies negligibly, while the specific elastic modulus remains virtually unchanged,An alternate scheme for determining the elasticity characteristics and CLTE of laminar polymeric materials reinforced with hybrid cloth strips on the basis of component properties is developed. The model according to which the structural organization of the composite is subdivided into several levels is primarily a computational model. The stress-strain state of the repeating structural elements is evaluated by methods of the strength of materials. The proposed algorithm for computing the physicomechanical characteristics of laminar composites is implemented in the form of a computer program. The experimental elasticity characteristics and CLTE obtained for composites with a different content of COS and VAI layers are compared with those calculated in accordance with the method developed (the computed values correspond to the experimental with an accuracy acceptable for engineering applications).Translated from Mekhanika Kompozitnykh Materialov, No. 3, pp. 392–401, May–June, 1988.     

Elastic characteristics of ferrocement reinforced with woven meshes

Applying structural mechanics methods for composite materials, we have worked out a procedure for predicting the elasticity modulus, the shear modulus, and Poisson's ratio for ferrocement taking into account the elastic properties of the components, the wire diameter, the mesh size, and the distance between the meshes. The results make it possible to exploit the potential of such reinforcement to the fullest.Translated from Mekhanika Kompozitnykh Materialov, Vol. 30, No. 4, pp. 526–530, July–August, 1994.     

Determination of the modulus of elasticity of the amorphous regions of chemical fibers

A method of calculating the orientation index and modulus of elasticity of the elements of a two-phase fiber model is presented. The effect of orientational drawing on the variation of these characteristics has been investigated for nylon [capron] fibers.Mekhanika Polimerov, Vol. 3, No. 3, pp. 409–412, 1967     

Some relationships between the specific functions and constants of visoelastic media

It is proved that the shear, lateral creep, and relaxation functions can be expressed in an elementary way by the longitudinal creep and relaxation functions and the elasticity modulus of the bulk.I. M. Gubkin Moscow Institute of Petrochemical and Gas Industry. Translated from Mekhanika Polimerov, No. 5, pp. 810–814, September–October, 1973.     

Theory of spherofibrous composites. 2. Fundamental equations

Fundamental equations of the theory of spatially reinforced media with a matrix reinforced by spherical particles are proposed on the basis of a linearly reinforced layer and tl.e hypothesis of a longitudinal state. For an arbitrary orientation of the fibers, the generalized elasticity equation for composites was found to contain 21 elastic constants and approximate formulas were derived for their determination.Presented at the Ninth International Conference on the Mechanics of Composite Materials, Riga. Latvia (October, 1995).Communication 1. see preceding article.A. A. Blagonravov Institute of Mechanical Engineering. Russian Academy of Sciences, Moscow. Russian. Translated from Mekhanika Kompozitnykh Materialov, Vol. 32, No. 3, pp. 306–316, May–June, 1996.     

Deformative characteristics of plastics reinforced with high-modulus anisotropic fibers

The independent elastic constants of plastics unidirectionally reinforced with transversely isotropic fibers have been determined. It has been assumed that the distribution of reinforcement in a transverse section of the plastic is regularly rectangular or hexagonal. To determine the transverse elastic modulus and the shear modulus in the plane of reinforcement, a constancy-of-plane-sections hypothesis was used. Values of deformative characteristics determined by the assumed calculational dependences have been compared with the experimental ones for plastics reinforced with graphite fibers.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 4, pp. 631–639, July–August, 1972.     

Comparative analysis of the structural order and defectiveness of reinforcing fibers on the basis of normalized values of mechanical properties

Experimental data on mechanical properties referred to their limiting values for a flawless polymer crystal with long molecular chains is used in a comparative analysis of the degree of ordering of the structure (crystallinity, orientation) and the defectiveness of the reinforcing fibers. The actual elastic moduli and limiting (theoretical) elastic modulus are used to obtain coefficients that characterize the overall order of the structure of the fibers but are independent of their defectiveness. Values of true strength in tension and the limitingly attainable or theoretical strength are used to calculate conditional coefficients that depend both on the overall order and the defectiveness of the fiber structure. The difference in the coefficients makes it possible to detect dangerous local defects that lead to fiber failure. Results are presented from calculations for more than 20 types of reinforcing fibers. Despite the approximate nature of these representations, the data that is obtained permits comparisons of different types of fibers, characterization of their quality, and evaluation of the degree of perfection of the fiber production technology.Paper presented at the IX International Conference on the Mechanics of Composite Materials, Riga, October, 1995.St. Petersburg State University for Technology and design, Russia. Translated from Mekhanika Kompozitnykh Materialov, Vol. 32, No. 4, pp. 444–453, July–August, 1996.     

Effect of moisture content on the microdeformation of compact bone tissue in tension

Conclusions The x-ray diffraction results indicate the following major features for the microdeformation of bone tissue. The total deformation in the elastic region is determined by the microdeformation of the mineral bone tissue component. The large yield of the mineral component indicates its relatively low elasticity modulus. The shape of the deformation curves for both dry and moist bone tissue is a factor of the combined deformation of the mineral and organic components. While the total deformation up to fracture in dry bone tissue is determined largely by microdeformation of the crystalline mineral phase, such behavior is found for moist bone tissue only in the first segment of the curve. Deformation in the second, more curved segment of the deformation curve is a factor largely of deformation of the organic bone-tissue component.Translated from Mekhanika Kompozitnykh Materialov, No. 3, pp. 530–535, May–June, 1983.