共查询到20条相似文献,搜索用时 10 毫秒
1.
2.
3.
4.
《Tetrahedron》1988,44(10):2969-2975
The kinetics of the oxidation of number of aryl methyl, alkyl phenyl, dialkyl and diphenyl sulphides by permanganate ion to yield the sulphoxides, have been studied. The reaction is first order with respect to the sulphide and permanganate and is independent of hydrogen ion concentration. The reaction exhibited negative polar reaction constants and a small degree of steric hindrance. The lack of solvent isotope effect and the observed solvent effect ( m = 0.39 for McSPh) are explained by an electrophilic attack of permanganate-oxygen on the sulphide yielding a polar transition state. A moderate anchimeric assistance was observed in the oxidation ofo-C00Me ando-C00H substituted methyl phenyl sulphide. A mechanism involving a one-step electrophilic oxygen transfer from permanganate ion to the sulphide and a polar product-like transition state, has been proposed. 相似文献
5.
The electronic structure of the azide ion is investigated using the SCF Xα scattered wave method. Calculated ionization energies are compared with values determined by electron spectroscopy. Transition state calculations for πg → π*u, σu → π*u and σg → π*u single electron transitions yield excitation energies near 5.7, 11.0, and 12.0 eV respectively. 相似文献
6.
The kinetics and mechanism of permanganate ion oxidation of acetylacetone (Acac) was studied in acidic and alkaline media. The rate constants for keto, enol, and enolate anions were determined and discussed. Delocalization of the π‐electrons of the double bond by conjugation results in a slower oxidation rate of enol than can be usually observed for unsaturated compounds. In the case of the keto form, the acid‐catalyzed nucleophilic attack of permanganate ion occurs on the carbonyl‐C atom. For enolate anion a mechanism with basis‐catalyzed electron abstraction is suggested. © 2006 Wiley Periodicals, Inc. Int J Chem Kinet 38: 444–450, 2006 相似文献
7.
A series of limited configuration interaction calculations based upon an extended basis set is presented for the permanganate ion. The configurations have been selected so that they describe initial and final states equally well, and the size of the expansion has been increased until a reasonable convergence in the results has been assured. Both singlet and triplet states have been treated. Electron density changes occurring at the so-called charge-transfer transitions have been studied, and relaxation turns out to play an important role. The agreement with experimental spectra is satisfactory. 相似文献
8.
The kinetics of the permanganate‐hypophosphite redox reaction has been studied over a wide range of pH by using a stopped‐flow technique. It has been found that the reaction leads to the formation of phosphite and orthophosphate, and that the molar ratio of the final products depends on pH. The proposed mechanism of the process was based on the assumption that the first step in the oxidation of hypophosphite is a fast reversible reaction in which an intermediate complex (O3MnOH2PO2)2− is formed. The observed dependence of the reaction rate on pH was attributed to the influence of hydrogen and hydroxyl ions on the decomposition of this complex. The rate constants and the equilibrium constants of elementary reactions are given. © 1999 John Wiley & Sons, Inc. Int J Chem Kinet 31: 737–743, 1999 相似文献
9.
10.
K. Tennakone 《Journal of solid state chemistry》1984,51(1):131-132
Water molecules present as an interstitial impurity are found to induce electronic conduction in solid KMnO4 with an activation energy of ? 0.28 eV. It is suggested that when ionic sites are surrounded by water molecules the high dielectric constant of the water lowers the activation energy associated with transfer of electrons between the donor-acceptor states involved in the hopping conduction. 相似文献
11.
12.
Electronic structure and normal vibrations of the 1-ethyl-3-methylimidazolium ethyl sulfate ion pair
Electronic and structural properties of the ion pair 1-ethyl-3-methylimidazolium ethyl sulfate are studied using density functional methods. Three locally stable conformers of the ion pair complex are considered to analyze molecular interactions between its cation and anion. Manifestations of these interactions in the vibrational spectra are discussed and compared with experimental IR and Raman spectroscopy data. NBO analysis and difference electron density coupled with molecular electron density topography are used to interpret the frequency shifts of the normal vibrations of the ion pair, compared to the free anion and cation. Excitation energies of low-lying singlet excited states of the conformers are also studied. The density functional theory results are found to be in a reasonable agreement with experimental UV/vis absorption spectra. 相似文献
13.
14.
Melvyn H. Wood 《Theoretical chemistry accounts》1975,36(4):309-315
The results of ab-initio self-consistent field calculations for the ground state and configuration interaction calculations for the excited states of the permanganate ion are presented and discussed. The calculations were performed using two large basis sets of contracted gaussian functions, and singly excited configurations were used in the calculations of the excited states. Fair agreement is obtained between these results and the experimental absorption spectra. 相似文献
15.
We present a comparison between experimental and calculated soft X-ray spectra of DNA's nucleobases, adenine (A), guanine (G), cytosine (C), and thymine (T) using X-ray absorption spectroscopy (XAS) and soft X-ray emission spectroscopy (XES). Spectra of the 1s thresholds of carbon, nitrogen, and oxygen give a complete picture of the occupied and unoccupied partial density of states of the nucleobases. A combination of both Hartree-Fock and density functional theory calculations are used in the comparison to experimental results. Most experimental results agree well with our theoretical calculations for the XAS and XES of all bases. All spectral features are assigned. A comparison of the experimental highest occupied molecular orbital-lowest unoccupied molecular orbital energy gaps is made to the diverse values predicted in the literature. 相似文献
16.
The UV absorption spectrum of the permanganate anion is a prototype transition-metal complex spectrum. Despite this being a simple d0 Td system, for which a beautiful spectrum with detailed vibrational structure has been available since 1967, the assignment of the second and third bands is still very controversial. The issue can be resolved only by an elucidation of the intricate vibronic structure of the spectrum. We investigate the vibronic coupling by means of linear-response time-dependent density functional calculations. By means of a diabatizing scheme that employs the transition densities obtained in the TDDFT calculations in many geometries around Re, we construct a Taylor series expansion in the normal coordinates of a diabatic potential energy matrix, coupling 24 excited states. The simulated vibronic structure is in good agreement with the experimental absorption spectrum after the adjustment of some of the calculated vertical excitation energies. The peculiar blurred vibronic structure of the second band, which is a very distinctive feature of the experimental spectrum, is fully reproduced in the calculations. It is caused by the double-well shape of the adiabatic energy surface along the Jahn-Teller active e mode of the allowed 1E state arising from the second 1T2 state, which exhibits a Jahn-Teller splitting into 1B2 and 1E states. We trace the double-well shape to an avoided crossing between two diabatic states with different orbital-excitation character. The crossing can be explained at the molecular orbital level from the Jahn-Teller splitting of the set of 7t2{3d(xy), 3d(xz), 3d(yz)} orbitals (the LUMO + 1), to which the excitations characterizing the diabatic states take place. In contrast to its character in the two well regions, at Re the 2(1)T2 state is not predominantly an excitation to the LUMO + 1, but has more HOMO - 1 --> LUMO (2e = {3d(x2-y2), 3d(z2)}) character. The changing character of the 2(1)T2 - 1E state along the e mode implies that the assignment of the experimental bands to single orbital transitions is too simplistic intrinsically. This spectrum, and notably the blurring of the vibronic structure in the second band, can be understood only from the extensive configurational mixing and vibronic coupling between the excited states. This solves the long-standing assignment problem of these bands. 相似文献
17.
A simple,fast,sensitive,highly selective and eco-friendly analytical method for the determination of catecholamines in human urine by ion chromatography(IC) with chemiluminescence(CL) detection was described in this paper.Using 12 mmol/L H2SO4 without any organic additive as eluent,three catecholamines including epinephrine(EP),norepinephrine(NE) and dopamine(DA) were well separated on a cation-exchange column.The CL detection was based on the reaction of analytes with acidic potassium permanganate in the presence of formaldehyde as an enhancer.The absence of methanol and acetonitrile in eluent made the proposed method more sensitive and eco-friendly.Under the optimal conditions,the linear range of the proposed method was in the range of 0.02-0.5μg/mL.The limit of detection(LOD) was in the range of 0.6 and 5.1μg/L.The relative standard deviations (RSD) for 0.1μg/mL mixed standard solution were in the range of 0.8-1.9%(n = 11).The method has been applied to the determination of catecholamines in human urine successfully.Excellent spiked recoveries were achieved for catecholamines ranged from 91.2%to 112.7%. 相似文献
18.
Pronin A. F. Kharchenko V. G. Bagatur'yants A. A. 《Chemistry of Heterocyclic Compounds》1977,13(7):808-808
Chemistry of Heterocyclic Compounds - 相似文献
19.
The Raman spectra of aqueous and solid sodium dithionite have been recorded. Differences in the location, intensity, and number of observed bands are attributed to conformational changes in the dithionite ion. The structure of the aqueous ion is non-planar with a C2h symmetry with an SS bond distance estimated to be 0.220–0.226 nm, as opposed to the dithionite structure in the Na2S2O4·2H2O salt which is known to have C2ν structure with a bond distance of 0.2389 nm. The Raman spectra of aqueous dithionite are assigned to Ag (SO) = 997 cm?1; Bg (SO) at 912 cm?1, Bg SO2 twist at 324 cm?1. The remaining bands are a strong Ag, the SO2 wag, the SO2 scissor, and the SS stretch at 584, 461, and 232 cm?1, respectively, but due to coupling all three motions are expected to exhibit substantial SS character. The variation of the spectra of the solid and aqueous sodium dithionite indicate strong environmental effect on the structure of the anion. 相似文献