Structural analysis of three-spin systems of photosystem II by PELDOR

The pulsed electron electron double resonance (PELDOR) pulse sequence is applied to a three-spin system consisting of three radicals (Y _D ^· , Y _Z ^· and Q _A ^? ) generated in spinach PS II. The distance between Y_Z and Q_A has been determined to be 3.4 nm with the previously derived distances of the other radical pairs, 2.9 nm for Y _D ^· -Y _Z ^· and 3.9 nm for Y _D ^· -Q _A ^? . This distance has been derived from the Y _Z ^· -Q _A ^? radical pair trapped in Y_D-less mutants ofChlamydomonas reinhardtii. Furthermore the method was applied to the Y _D ^· -Q _A ^? -Chl _Z ⁺ system to find the unknown distance between Q_A and Chl_Z. The derived distance was 3.4 nm. A triangular configuration was found in the membrane system that gives the relative positions of the electron transfer components.     

Recurrence of random walks in the Ising spins

Consider the 1/2-Ising model inZ ². Let σ _j be the spin at the site (j, 0)∈Z ² (j=0, ±1, ±2, ...). Let \(\{ X_n \} _{n = 0}^{ + \infty } \) be a random walk with the random transition probabilities such that $$P(X_{n + 1} = j \pm 1|X_n = j) = p_j^ \pm \equiv 1/2 \pm v(\sigma _j - \mu )/2$$ We show a case whereE[p _j ⁺ ≧E[p _j ^? ], but \(\mathop {\lim }\limits_{n \to \infty } X_n = - \infty \) is recurrent a.s.     

Ground-state energy of quantum liquids

The kinetic (K ₄ ⁰ (n) and K ₃ ⁰ (n)) and potential (V ₄ ⁰ (n) and V ₃ ⁰ (n)) energies of ⁴He and ³He atoms have been found from the law of corresponding states and the experimental data on the dependence of the ground-state energies E ₄ ⁰ (n) and E ₃ ⁰ (n) on the density of the isotopes ⁴He and ³He. In the approximation of structureless quantum liquid, the potential energies are equal, V ₄ ⁰ V ₃ ⁰ (n) = (n), and the kinetic energies are inversely proportional to the atomic mass, $K_4^0 (n) = \frac{3} {4}K_3^0 (n)$ . The potential energy given by the expression V ⁰ = 4E ₄ ⁰ ? 3E ₃ ⁰ to a high accuracy is linear in the density n, which is associated with nearly an absence of short-range order in liquid helium. The kinetic energy of liquid ⁴He is given by the expression K ₄ ⁰ = 3(E ₃ ⁰ ? E ₄ ⁰ ), which agrees with the experimental data on neutron scattering in liquid ⁴He. The quantities K ₄ ⁰ (n) and K ₃ ⁰ (n) determine the scale of all thermodynamic characteristics in the temperature range where the effects of the particle statistics can be neglected.     

Phenomenology of composite colored weak bosons

In composite models of quarks, leptons and weak bosons whereW-constituents are colored objects, color octet partners ofW ^± andZ ⁰ are predicted. We study in detail the phenomenology of these particles. Independent of the specific model one expects a color octet isotriplet of vector bosons (W ₈ ^± ,Z ₈ ⁰ ) with mass in the range of 100–200 GeV, and a color octet isosinglet vector bosonV ₈ ⁰ with substantially larger mass, due to mixing with the gluon. Moreover, relatively light color octet excitations of the leptons appear, while the existence of “color exotic” partners of the quarks is model dependent. These particles decay mainly into a lepton (quark) and a gluon. We construct the couplings ofW ₈ ^± ,Z ₈ ⁰ andV ₈ ⁰ to ordinary and “color exotic” fermions. The signals of color octet weak bosons in low energy weak reactions are explored in detail. The production cross section ofW ₈ ^± (Z ₈ ⁰ ) in hadron-hadron collisions is calculated for \(0.54TeV \leqq \sqrt s \leqq 20TeV\) . Various decay modes of colored weak bosons are studied. The most prominent decay signatures ofW ₈ ^± andZ ₈ ⁰ are events of the type (l ^+-: charged lepton;j: hadronic jet; : missing transverse momentum). The present CERN \(p\bar p\) collider data on such events are discussed in the light ofW ₈ ^± andZ ₈ ⁰ decays. If colored weak bosons are not found with a mass less than ～250 GeV composite model building will be strongly restricted.     

Hadronic contributions to (g−2) of the leptons and to the effective fine structure constant α(M Z 2 )

The new experiment planned at Brookhaven to measure the anomalous magnetic moment of the muona _μ≡(g _μ?2)/2 will improve the present accuracy of 7 ppm by about a factor of 20. This requires a careful reconsideration of the theoretical uncertainties of theg?2 predictions, which are dominated by the error of the contribution from the light quarks to the photon vacuum polarization. This issue is cruicial also for the precise determination of the running fine structure constant at theZ-peak as LEP/SLC experiments continue to increase their precision. In this paper we present an updated analysis of the hadronic vacuum polarization using all presently availablee ⁺e^? data. This seems to be justified because previous work on the subject was based to some extent on preliminary or incomplete experimental data. Contributions from different energy ranges are presented separately forg?2 of the muon and the τ-lepton and for α(M _Z ² ). We obtain the resultsa _μ ^had* =(725±16)×10^?10 anda _τ ^had* =(351±10)×10^?8, where the asterisk indicates the dressed (renormalization group improved) value. For the effective fine structure constant atM _Z=91.1888 GeV we obtainΔα _had ⁽⁵⁾ =0.0280±0.0007 and α(M _Z ² )^?1=128.896±0.090. Further improvement in the accuracy of theoretical predictions which depend on the hadronic vacuum polarization requires more precise measurements ofe ⁺e^? cross-sections at energies below about 12 GeV in future experiments.     

MeanM-subshell fluorescence yields atZ=88, 90, 92, and 94

M x-ray —L x-ray coincidence measurements with high resolution, cooled Si(Li) x-ray detectors were made on transitions following the alpha decays of²²⁸Th,²³²U,²³⁸Pu, and²⁴⁴Cm, in order to determine the meanM-subshell fluorescence yields. The values obtained are:v ₄ ^M =0.032±0.002, andv ₅ ^M =0.024±0.002 atZ=88;v ₁ ^M =0.038±0.003,v ₄ ^M =0.042±0.002, andv ₅ ^M =0.038±0.002 atZ=90;v ₁ ^M =0.047±0.002,v ₄ ^M =0.048±0.002, andv ₅ ^M =0.044±0.002 atZ=92;v ₁ ^M =0.066±0.002,v ₄ ^M =0.062±0.002, andv ₅ ^M =0.063±0.002 atZ=94. The quantityΩ ₁ ^M +f ₁₂ ^MΩ ₂ ^M was measured as (56±10)×10^?4, (62±12)×10^?4, (99±18) ×10^?4, and (93±15)×10^?4 forZ=88, 90, 92, and 94, respectively, which agree well with the calculations of McGuire. The radiativeL ₁-L ₃ transition intensity was measured for the four atomic numbers and found to be consistently less than the calculations of Scofield by about 45 percent.     

Polarized bhabha scattering in multiboson electroweak gauge models

The general expression for the differential cross section of the reactione ⁺ e ^?→γ,Z ₁ ⁰ ,Z ₂ ⁰ , ..., →e ⁺ e ^? with an arbitrary initial polarization state is derived in the context of electroweak gauge models with more than one neutral boson. Angular distributions, azimuthal asymmetries in the case of natural polarization, and longitudinal polarization asymmetries for models of the typeSU(2)×U(1)×G (G=?(1),S?(2)) and left-right symmetric models are compared with the standard model results. For the angular distributions withe ^± having equal helicities a～10% deviation from the standard model is predicted already below 50 GeV for models of the first type withZ ₁ ⁰ masses up to 80 GeV. At energies around the firstZ ₁ ⁰ a study of azimuthal and polarization asymmetries yields the possibility of distinguishing between different models.     

Evidence for a 3.6 minute isomeric 12− state of the πh 11 2/−1 vi 13 2/−1 configuration in206Tl and effective two-particle interactions

Using the²⁰⁴Hg(α, pn)-reaction andα-particles of energies 39–55 MeV, we have found an isomeric 3.6 min 12^? state in²⁰⁶Tl at 2,642.9 keV which has the two-hole configurationπh ₁₁ ^2/?1 vi ₁₃ ^2/?1 The 12^? state decays mainly by anE5 transition of energy 1,021.4 keV to a 7⁺ state at 1,621.5 keV whose main configuration isπs ₁ ^2/?1 vi ₁₃ ^2/?1 There is, in addition, evidence for a weak 565 keVM 4 branch to an 8⁺ state at 2,078 keV whose main configuration should beπh ₁₁ ^2/?1 vf ₅ ^2/?1 . The 7⁺ state decays by a stretched cascade ofγ-rays to states of the following values ofJ ^π and excitation energy: 5 _? ⁺ , 1,405.4 keV; 4^?, 952.1 keV; 2^?, 265.8 keV and 0^?, 0 keV. The main configurations of these states areπh ₁₁ ^2/?1 vp ₁ ^2/?1 ,πd ₃ ^2/?1 vf ₅ ^2/?1 ,πd ₃ ^2/?1 vp ₁ ^2/?1 andπs ₁ ^2/?1 vp ₁ ^2/?1 respectively. From the nuclear masses of²⁰⁸Pb,²⁰⁷Pb,²⁰⁷Tl, and²⁰⁶Tl and the experimental excitation energies it is possible to obtain the proton hole-neutron hole interaction in²⁰⁶Tl. This interaction is compared with the calculations of Kuo and Herling and the discrepancies are discussed. The 12^?→8⁺ M4 transition rate is reduced because of destructive interference between the protonh _11/2→d _3/2 and the neutroni _13/2→f _5/2 contributions. The magnitude of the reduction is accurately reproduced by the wave functions of Kuo and Herling. The 12^?→7⁺ E5 transition rate is about twice as large as the single-holeπh ₁₁ ^2/?1 πs ₁ ^2/?1 transition rate. This deviation is fully explained by the configuration admixtures in the 7⁺ state, given by Kuo and Herling.     

Estimation of the QED coupling constant α at\sqrt s = M_Z

LEP measurements of theZ ⁰ parameters have been used to estimate the value of QED coupling constant at theZ ⁰ mass. The estimated value α _eff ^-1 (M _Z )=128.2±0.9 _-0.4 ^+0.0 (M _top) is in good agreement with the expectation of 128.0 _?0.4 ^+0.2 from the Standard Model.     

The determination by an independent method ofP k electron capture probabilities in133Ba and139Ce decays gamma decay of133Ba

The electron capture decays of¹³³Ba (10.4 y) and¹³⁹Ce (140 d) were investigated with high resolution Ge(Li) detectors. By x-ray — γ-ray coincidences values of the quantityP _k ω _k ? _k for various transitions in the decay of¹³³Ba and¹³⁹Ce are obtained. The factor ω _k ? _k was measured independently by means ofK-conversion electron-K x-ray coincidences and was then used to determineP _k , theK-capture probability. The independent measurement of the product ω _k ? _k , together with recent accurate values of ω _k , provides a new method for the accurate calibration of semiconductor x-ray detectors. In the decay of¹³⁹Ce, a value ofP _k =0.78±0.03 is found (where the error represents twice the standard deviation) from whichQ _ec =326 _?30 ⁺⁷⁰ keV to the¹³⁹La ground-state is found by use of theory. In¹³³Ba decay, values are found ofP _k 1=0.72±0.04 for theEC transition to the 437 keV level in¹³³Cs,P _k 2=0.80±0.07 to the 384 keV level, and from an independent measurement, the ratioP _k 1/P _k 2=0.87±0.07. From these results the ground-state value ofQ _ec =522 _?10 ⁺²⁰ keV is derived from theory for¹³³Ba decay. The gamma spectrum of¹³³Ba also was remeasured. From the present gamma intensities and previous conversion electron intensities, new values forK-shell conversion coefficients are obtained. Previously reported γ-rays at 35 and 391 keV are not confirmed.     

High spin shell model excitations in149Gd

The high spin level structure of the three-neutron nucleus¹⁴⁹Gd has been investigated by in-beamγ-ray and electron spectroscopy with (α, xn) reactions. The observed levels are characterized as members of the shell model multipletsνf ₇ ^2/3 ,νh _9/2 f ₇ ^2/2 ,νf ₇ ^2/3 ×3^?,νh _9/2 f ₇ ^2/2 ×3^?, and tentativelyνf ₇ ^2/3 ×(3^?)². The energies of theν f ₇ ^2/3 states agree only moderately with those calculated using empirical two-nucleon interactions taken from¹⁴⁸Gd, which indicates the importance of long range contributions already atN=85.     

E2 andE3 transition strengths in some rare-earth nuclei

Coulomb excitation byα-particles of vibrational-like states in even-mass rare-earth nuclei is used to determine the reduced transition probabilitiesB(E2; 0 _gs ⁺ →2 _γ ⁺ ),B(E2; 0 _gs ⁺ →2 _β ⁺ ),B(E2; 2 _gs ⁺ →0 _β ⁺ ) andB(E2; 0 _gs ⁺ →3 _oct ^? ) in¹⁵⁰Nd,^{152, 154}Sm,^{154, 158}Gd,¹⁶⁴Dy and¹⁶⁶Er. TheB(Eλ; 0 _gs ⁺ →I=λ)-values range from 2.4 to 6.5 single-particle units for transitions to the 2 _γ ⁺ -states, 0.8 single-particle units for the 2 _β ⁺ -states and from 14.1 to 21.7 single-particle units for the 3^?-states.     

Angular distributions of dileptons in polarized hadronic collisions: Test of electroweak gauge models

The angular distributions of high-mass dileptons with large transverse momentum produced in longitudinally polarized hadronic collisions, hadron +hadron→(γ^*,Z ₁ ⁰ ,Z ₂ ⁰ , ...)+X→l ⁺ l ^?+X, are calculated in the QCD lowest order. The formulas presented in general form, are applicable to any gauge model of underlying electroweak interactions. Numerical results are obtained for the angular distributions in \(\bar p\) p-collisions at \(\sqrt s = 540GeV\) for the Weinberg-Salam,SU(2)×U(1)×U(1)′ andSU(2)×SU(2)′×U(1) models. Clearly distinguishable signals are revealed.     

On the yrast levels in204Pb

High-spin states in²⁰⁴Pb were populated in the²⁰⁴Hg(α,4n) reaction using α-particles in the energy region 42–51 MeV. Prompt and delayedγ-rays as well as conversion electrons were studied in addition to excitation functions, angular distributions andγ-γ coincidences. In this way a stretched cascade ofγ-rays from a level at 8125.9 keV was found to feed the previously known isomeric 9^? level at 2185.7 keV. Spins and parities were established for levels up to and including a 19^? level at 6098.0 keV. The levels with c= 17^2212; and 19^? at excitation energies of 5664.3 and 6098.0 keV are likely to be due to the simplep ₁ ^2/s-1 i ₁₃ ^2/?3 andf ₅ ^2/?1 i ₁₃ ^2/?3 configurations. The agreement between calculated and experimental energies for all observed levels in the regionJ=9–19 is very good in cases where the empirical two-particle interactions used are satisfactorily well known. Above the 19^? level there are three weakly populated levels at 7402.1, 7849.2 and 8125.9 keV, which are likely to haveJ≥20. None of these energies agrees with the calculated value 7695±20 keV for the 20⁺ state of thei ₁₃ ^2/?4 configuration which has the highest angular momentum produced by the four valence neutron holes. This apparent anomaly can be understood if the yrast levels withJ≥20 have angular momentum contribution from the core. It seems likely that the states at 7402.1, 7849.2 and 8125.9 keV are due to proton core excited states of the typeπh _9/2 h ₁₁ ^2/?1 ×νp ₁ ^2/?2 i ₁₃ ^2/?2 withJ ^π=20⁺ andJ ^π=21⁺ andπh _9/2 h ₁₁ ^2/?1 ×νp ₁ ^2/?1 f ₅ ^2?1 i ₁₃ ^2/?2 withJ ^π=22⁺ or 23⁺, respectively. The state at 8126 keV has the highest energy so far directly observed in a stretched cascade ofγ-rays from the decay of a heavy nucleus produced in (α, xn) reactions.     

Mechanisms of the Reactions of Radicals with Ozone

The available experimental data (rate constants and activation energies) for the reactions of the hydrogen atom and the R^?, RO^?, RO ₂ ^? , HO^?, and HO ₂ ^? radicals with ozone are analyzed using the method of intersecting parabolas (potential curves). The conclusion is drawn that the primary event in the reactions of H^?, R^?, HO^?, and RO^? with ozone is the addition of the radical to the ozone molecule with the subsequent fast decomposition of the labile polyoxide radical formed. The classical potential barrier for this addition reaction is close to that for the addition of radicals to molecules with multiple bonds. Peroxy radicals react with ozone by the associative decomposition mechanism, RO ₂ ^? + O₃ → RO^? + 2O₂. The ozone molecule reacts with the HO ₂ ^? radical by abstracting its hydrogen atom, O₃ + HO ₂ ^? → HO ₃ ^? + O₂. The experimental data were used to determine the parameters required to calculate the activation energies for the reactions under study.     

The decay of the Bethe-Salpeter kernel inP(ϕ)2 quantum field models

We extend methods of high temperature expansions to show that for even weakly coupledP(?)₂ quantum field models the Bethe-Salpeter kernel has 4 particle decay. More precisely ifK denotes the Euclidean Bethe-Salpeter kernel $$|K(x_1 ,x_2 ,x_3 ,x_4 )| \leqq Oe^{ - m_0 (1 - \varepsilon )d_2 } ,$$ wherex=(x ⁰,x ¹),d ₂=2|x ₁ ⁰ +x ₂ ⁰ ?x ₃ ⁰ ?x ₄ ⁰ |+|x ₁ ⁰ ?x ₂ ⁰ |+|x ₃ ⁰ ?x ₄ ⁰ | and ε(λ)→0 as λ→0. Our methods apply to otherr particle irreducible kernels.     

Search for CP violation in Z0 → τ + τ − and an upper limit on the weak dipole moment of the τ lepton

An improved test of invariance in the reaction e⁺e^? τ ⁺ τ ^? on the Z0 peak is performed using the data sample recorded between 1991 and 1995 with the OPAL detector at LEP. Optimal observables, requiring the reconstruction of the τ flight direction and spin, have been used for different final state topologies. From the non-observation of violation we derive 95% confidence level upper limits on the real and imaginary parts of the weak dipole moment of the τ lepton of |Re(d _τ ^w (m _Z ² | < 5.6 × 10^?18 e cm and |Im(d _τ ^w (m _Z ² ))| < 1.5 × 10^?17 e cm, respectively.     

Isotope shifts and energies of the 1s 2p states in helium

The specific mass shift (SMS) and energies of the (1s2p)^{1, 3} P states in helium are evaluated using wave functions expressed in terms of radial “pair functions” which are obtained by numerical solution of inhomogeneous two-particle differential equations. The results obtained when including successively higher angular symmetries in the wave function indicate that the SMS converges asl _max ^?3 for the singlet state and betweenl _max ^?5 andl _max ^?6 for the triplet state. These convergence rates are considerably slower than thel _max ^?5 andl _max ^?7 behaviours found for the singlet and triplet energies. The total energies,E(2¹ P)=?2.123835 a.u. andE(2³ P)=?2.133155 a.u., are about 0.00001 a.u. above the “exact” non-relativistic results obtained with perimetric coordinates and also the SMS between³He and⁴He, SMS(2¹ P)=0.4533 cm^?1 and SMS(2³ P)=?0.6356 cm^?1, are very close to the “exact” results.     

Electroweak parameters from a high statistics neutrino nucleon scattering experiment

The final results from the WA 1/2 neutrino experiment in the 1984 CERN 160 GeV narrow band beam are presented. The ratiosR _ν and \(R_{\bar v} \) of neutral to charged current interaction rates of neutrinos and antineutrinos in iron are measured to beR _ν=0.3072±0.0033 and \(R_{\bar v} \) =0.382±0.016. A value of the electroweak parameter sin² θ _w = 1 ?m _W ² /m _Z ² is extracted fromR _ν. The result is sin² θ _w =0.228+0.013(m _c ?1.5)±0.0003 (theor.) wherem _c is the mass of the charmed quark in GeV form _t =60 GeV,M _H =100 GeV, ρ=1. CombiningR _ν and \(R_{\bar v} \) one obtains a value for ρ=0.991+0.023(m _c ?1.5)±0.020(exp.). Alternatively,R _ν and \(R_{\bar v} \) yield a precise value of the ratio of intermediate vector boson massesm _W /m _Z =0.880?0.007(m _c ?1.5)±0.002(exp.)±0.002(theor.). Comparison of these results with those from direct measurements of the vector boson masses are presented. In a model-independent analysis the left- and right-handed neutral current coupling constants,g _L ² andg _R ² , are determined.