Magnetic hyperfine field of Hg in nickel and the sign of magnetic moment of 197mAu by NMR-ON

Nuclear magnetic resonance on oriented nuclei (NMR-ON) measurements were performed on the successive decay of ^197mHg–^197mAu in Ni. The NMR-ON resonance spectra of ^197mHgNi were obtained by detecting the 134 keV γ-ray from the decay of ^197mHg and the 279 keV γ-ray from the decay of ^197mAu. The magnetic hyperfine splitting frequency of ^197mHgNi in an external magnetic field of 0.2 T has been determined as 16.55(6) MHz. With the known g-factor of ^197mHg the hyperfine field of B₈₂(^197mHgNi)= -13.53(6) T was deduced. The anisotropy of the 279 keV γ-ray (^197mAu to ¹⁹⁷Au) increased at the resonance. This phenomenon was explained using the spin inversion process including the lifetime of the isomer and the spin–lattice relaxation time. The sign of the g-factor of ^197mAu was determined to be positive. This revised version was published online in August 2006 with corrections to the Cover Date.     

The magnetic hyperfine field at181Ta impurities in the 4f-ferromagnets Ho and Er

The magnetic hyperfine fieldH _hf at¹⁸¹Ta impurities in the ferromagnetic Rare Earth metals Ho and Er has been determined by time differential perturbed angular correlation measurements at 4.2 K. The results |H _hf(TaHo)|=101(8)kG |H _hf(TaEr)|= 94(8)kG together with the previously determined values ofH _hf(TaGd) andH _hf(TaDy) show that the magnetic hyperfine field at Ta impurities in the Rare Earth metals is predominantly due to the conduction electron polarization of the hosts.     

Hyperfine structure of highly charged ions

¹⁹⁷Au Mössbauer spectra from Au/TM (TM = Fe, Co, Ni) multilayers consist mainly of two components. One component shows a large hyperfine magnetic field due to the hybridization at the interface between Au and ferromagnetic layers. The other component is nonmagnetic arising from the middle part of the Au layers. From the fractional area of the magnetic components in each spectrum, the Au atoms in 0.4 nm Au layers are perturbed by the Fe and Ni layers, and Co layers perturb 0.3 nm Au layers at the interface.     

197Au Mössbauer study of Au/Ni and Au/Fe metallic superlattices

¹⁹⁷Au Mössbauer measurements have been performed for Au/Ni and Au/Fe metallic superlattices at below 75 K. For Au/Ni superlattices, the area ratio in a spectrum between a superlattice component and that of the pure Au buffer layer has been determined at 25, 50 and 75 K. From the area ratios, it is found that the recoil-free fraction of Au in Au(10 Å)/Ni(10 Å) is larger than that of the bulk Au, suggesting the existence of the supermodulus effect in this superlattice. The¹⁹⁷Au Mössbauer spectrum obtained from Au(5 Å)/Fe(8 Å) is entirely magnetic at 16 K, suggesting the existence of a magnetic hyperfine interaction at¹⁹⁷Au nuclei through the transferred electron spin polarization.     

Spins of198Au levels from the (n, γ) reaction using polarized neutrons and polarized197Au nuclei

The¹⁹⁷Au(n, γ) reaction was studied with the aid of polarized thermal neutron beams. Two kinds of experimental data were obtained: i) circular polarization of gamma rays of high energy due to capture of polarized neutrons by unoriented¹⁹⁷Au nuclei, and ii) angular distribution of such gamma rays observed after capture of polarized neutrons by polarized¹⁹⁷Au nuclei. Spins of several levels of¹⁹⁸Au could be uniquely assigned or could be restricted. The sign of the hyperfine field of Au in AuFe has been determined to be negative.     

Hyperfine heat capacity of metallic europium and erbium

The specific heats of the Rare Earth metals Eu and Er have been measured in the temperature range 0.03 to 0.8K. The measurements yield magnetic hyperfine parameters of 13.2 mK, 5.85 mK, and 42.3 mK for ¹⁵¹Eu, ¹⁵³Eu, and ¹⁶⁷Er, respectively, corresponding to magnetic hyperfine fields of 0.26 and 7.2 MOe for Eu and Er. The nuclear quadrupole coupling constants were found to be ?0.06 mK, ?0.16 mK, and ?2.7 mK for ¹⁵¹Eu, ¹⁵³Eu and ¹⁶⁷Er.     

Concentration dependence of reentrant behaviour in AuFe-alloys

The temperature and concentration dependence of the hyperfine field in AuFe alloys in the concentration range of 15 to 28 at%Fe was measured by perturbed angular correlation (PAC) spectroscopy. The temperature dependence of the hyperfine field shows a slope change at T/T_C = 0.25 for concentration below 20 at%Fe, while for higher concentration a continuous behaviour is seen.Dr. H. Micklitz is acknowledged for sending the¹⁹⁷Au results prior to publication.     

Mössbauer study of197Au in Zn and Cd single crystals

The 77.3 keV Mössbauer transition of¹⁹⁷Au was used to study the hyperfine interactions and recoilfree fractions of dilute Au impurities in Zn and Cd single crystals at 4 K. Mössbauer sources were prepared by ion implantation of^197mHg/¹⁹⁷Hg at ambient temperature. From the quadrupole splittings the electric field gradients $$\begin{gathered} eq(Au\underline {Cd} ) = + 11.7(6) \times 10^{17} v/cm^2 and \hfill \\ eq(Au\underline {Zn} ) = ( + )15.0(2.5) \times 10^{17} v/cm \hfill \\ \end{gathered} $$ were determined. The electric field gradients as well as the isomer shifts are in good agreement with the systematics of other impurity host systems. The recoilfree fractions agree with estimates using the mass corrected Debye temperatures of the host lattice.     

Mössbauer study of ferromagnetic metallic glasses irradiated by swift heavy ions at temperatures 100 and 300 K

The effect of swift heavy ion irradiation on ferromagnetic metallic glasses Fe₄₀Ni₃₈Mo₄B₁₈ and Fe₇₈Si₉B₁₃ has been studied. The ion beams used are 100 MeV ¹²⁷I and 180 MeV ¹⁹⁷Au. The specimens were irradiated at fluences ranging from 3 × 10¹² to 1.5 × 10¹⁴ ions/cm². The irradiations have been carried out at temperatures 100 and 300 K. The magnetic moments are sensitive towards the irradiation conditions such as irradiation temperature and stopping power of incident ion beam. The irradiation-induced effects have been monitored, by using Mössbauer spectroscopy. The modifications in magnetic anisotropy and hyperfine magnetic field distributions, as an effect of different irradiation temperature as well as different stopping power have been discussed. After irradiation, all the samples remain amorphous and magnetic anisotropy considerably changes from its original in-plane direction. The results show enhancement in magnetic anisotropy in the specimen irradiated at 100 K, as compared to that of irradiated at 300 K. It is expected that at low temperature, the stresses produced in the material would remain un-annealed, compared to the samples irradiated at room temperature and therefore, the modification in magnetic anisotropy would be enhanced. A distribution of hyperfine magnetic field, of the samples irradiated at low temperature, show a small but distinct peak at ～?11 Tesla, indicating Fe-B pairing.     

NMR-ON on196,197m,198,198m,200mAu in Fe and Ni

The zero-field hyperfine splitting frequencies of a series of Au isotopes in Fe and Ni have been determined with nuclear magnetic resonance on oriented nuclei. The results are:. For¹⁹⁸Au(2^–) in Fe the quadrupole splitting could be resolved. The results are ¦g_NB_HF/h|=259.48 (3) MHz and e²qp/h=–2.08(4) MHz. Our measurements show that most hyperfine splittings published on these isotopes have been incorrect. The quadrupole splitting of¹⁹⁸AuFe disagrees in magnitudeand sign from the value reported by single-passage NMR on oriented nuclei. The following nuclear quantities are deduced: (^197mAu,11/2^–)=5.98(9) _N; (^198mAu, 12^–)=5.85(9) _N; (^200mAu, 12^–)=5.90(9) _N; Q(¹⁹⁸Au,2^–)/Q(¹⁹⁹Au, 3/2⁺)=1.37(3). Our measurements show further that the non-contact hyperfine field for Au in Ni is smaller than assumed previously, and that the magnetic hyperfine splitting frequency of¹⁹⁷AuFe known from NMR is inconsistent with the magnetic hyperfine splitting frequencies of^{198, 199}AuFe.     

Electric hyperfine alignment of Au nuclei in KAu(CN)2 observed by the Mössbauer effect

A large electric hyperfine alignment of ¹⁹⁷Au nuclei has been observed by Mössbauer absorption measurements of the 77.3 keV γ-transition of ¹⁹⁷Au in diamagnetic KAu(CN)₂. the measurements were extended down to 36 mK by employing a ³He/⁴He dilution refrigerator. The nuclear spin-lattice relaxation time was estimated from the time dependence of the asymmetry in Mössbauer spectra. It is shown that the spectra of oriented specimen can be used for determination of the recoilless factor of the absorber.     

Spin and temperature dependence of the magnetic hyperfine field of Cd in the rare earth-aluminum Lavesphase compounds RAl2

Perturbed angular correlation spectroscopy has been used to investigate the combined magnetic and electric hyperfine interaction of the probe nucleus ¹¹¹Cd in ferromagnetically ordered rare earth (R)-dialuminides RAl₂ as a function of temperature for the rare earth constituents R=Pr, Nd, Sm, Eu, Tb, Dy, Ho and Er. In compounds with two magnetically non-equivalent Al sites (R=Sm, Tb, Ho, Er), the magnetic hyperfine field was found to be strongly anisotropic. This anisotropy is much greater than the anisotropic dipolar fields, suggesting a contribution of the anisotropic 4f-electron density to magnetic hyperfine field at the closed-shell probe nucleus. The spin dependence of the magnetic hyperfine field reflects a decrease of the effective exchange parameter of the indirect coupling with increasing R atomic number. For the compounds with the R constituents R=Pr, Nd, Tb, Dy and Ho the parameters B₄, B₆ of the interaction of the crystal field interaction have been determined from the temperature dependence of the magnetic hyperfine field. The ¹¹¹Cd PAC spectrum of EuAl₂ at 9 K confirms the antiferromagnetic structure of this compound.     

Mössbauer and X-ray study of the Fe 65 Ni 35 invar alloy obtained by mechanical alloying

Fe₆₅Ni₃₅ samples were prepared by mechanical alloying (MA) with milling times of 5, 6, 7, 10 and 11 h, using a ball mass to powder mass ratio of 20:1 and at 280 rpm. The samples were characterized by X-ray diffraction (XRD) and transmission ⁵⁷Fe Mössbauer spectrometry. The X-ray diffraction pattern showed the coexistence of one body centered cubic (BCC) and two face centered cubic (FCC1 and FCC2) structural phases. The lattice parameters of these phases did not change significantly with the milling time (2.866 Å, 3.597 Å and 3.538 Å, respectively). After 10 h of milling, the X-ray diffraction pattern showed clearly the coexistence of these three phases. Hence, Mössbauer spectrometry measurements at low temperatures from 20 to 300 K of this sample were also carried out. The Mössbauer spectra were fitted using a model with three components: the first one is a hyperfine magnetic field distributions at high fields, related to the BCC phase; the second one is a hyperfine magnetic field distribution involving low hyperfine fields related to a FCC phase rich in Ni, and the third one is a singlet related to a FCC phase rich in Fe, with paramagnetic behavior. As proposed by some authors, the last phase is related with the antitaenite phase.     

Anomalous behaviour of the magnetic hyperfine field in the microcrystalline YFeO3-Fe2O3 mixed phase system

The magnetic hyperfine field in 120 Å YFeO₃ microcrystals just below the superparamagnetic blocking temperature, as well as at 5 K are found to be surprisingly low. In addition, the hyperfine field fails to saturate even at the lowest recorded temperature. The observed features cannot be understood in terms of either collective magnetic citations or superferromagnetism. A negative equivalent pressure arising out of decreased particle size is proposed as a plausible explanation.     

The influence of small magnetic fields on the Mössbauer relaxation spectra of Au: Yb alloys

The influence of an external magnetic field on the hyperfine structure of the Γ₇ CEF ground state of dilute Yb impurities in Au is investigated through the Mössbauer effect. Strong changes in the shape of the hyperfine spectra are observed when small magnetic fields (?1 kG) are applied. The dependence of the hyperfine structure on applied magnetic fields is shown through a Breit-Rabi diagram. The electronic relaxation rate for this system is found to be independent of the fields applied. The nature of polarized radiation emitted by such sources is discussed.     

The temperature dependence of the magnetic hyperfine field of tantalum in dysprosium

The temperature dependence of the magnetic and electric hyperfine interactions at the site of ¹⁸¹Ta impurities in polycrystalline Dy has been measured between 4.2 and 178 K using the time differential perturbed angular correlation technique. The value of the magnetic hyperfine field at 4.2 K is: |H_hf(TaDy)| = 212(9) kG The temperature dependence of the magnetic hyperfine field follows closely the prediction of the molecular field model.     

The magnetic hyperfine field at Hg impurities in ferromagnetic Gd

The magnetic hyperfine field at dilute Hg impurities in Gd has been investigated by the conversion electron (e ^–)--time differential perturbed angular correlation (TDPAC) technique. The radioactivities^197m Hg and¹⁹⁹Tl were implanted into Gd foils by means of an isotope separator. TDPAC measurements were performed with the 165 keV-L-conversion electron—134 keV--cascade of¹⁹⁷Hg at different temperatures and with the 334 keV--158 keV-K-conversion electron cascade of¹⁹⁹Hg at 200 K.The regular site occupation probabilities were found to be 15(3)% for an annealed^197m HgGd sample and 29(5)% in unannealed¹⁹⁹TlGd samples.From the magnetic hyperfine interaction frequencies measured for the regular sites at 200 K the magnetic hyperfine fields |H _hf(¹⁹⁷HgGd; 200 K)|=256(13) kG and |H _hf(¹⁹⁹HgGd; 200 K)|=267(7) kG were deduced.On leave from the University of Lisboa, Portugal     

Temperature Dependence of the Magnetic Hyperfine Field at 140Ce on Gd Sites in GdAg Compound

Perturbed gamma–gamma angular correlation technique was used to measure the magnetic hyperfine field at Gd sites in the intermetallic compound GdAg using the ¹⁴⁰La→¹⁴⁰Ce nuclear probe. A major and well-defined magnetic interaction is observed at ¹⁴⁰Ce substituting Gd sites in GdAg below 130 K, corresponding to a ferromagnetic ordering of Gd moments. The temperature dependence of magnetic hyperfine field, however, shows a sharp deviation from an expected Brillouin-like behavior for temperatures below 75 K. This additional magnetic interaction is believed to result from the polarization of Ce spin moments induced by the magnetic field from Gd atoms.     

Mössbauer determination of the E2/M1 mixing ratio of the 77 keV transition in197Au and of the sign of the electric field gradient in KAu(CN)2

A Mössbauer measurement of the E2/M1 mixing ratio of the 77 KeV transition in¹⁹⁷Au yielded δ=?0.352±0.005. With this result, Mössbauer absorption spectra of KAu(CN)₂ single crystals show that the electric field gradient at¹⁹⁷Au in this compound is negative. This implies that the field gradient is mainly produced by 6p_z electrons. The data also indicate a large vibrational anisotropy of Au in KAu(CN)₂.     

Saturated absorption experiments using a free running CW dye laser

The hyperfine structure of some new iodine lines has been observed over the tuning range of Rhodamine 6G (5800–6200 Å), using a free running, single mode cw dye laser. The resolution obtained in this experiment allowed to calculate the hyperfine constants of the excited state (³π₀⁺) of iodine with an accuracy of 2% for the quadrupole coupling constant and 50% for the magnetic one.