Completeness of “good” Bethe ansatz solutions of a quantum-group-invariant Heisenberg model

The sl_q(2) quantum-group-invariant Heisenberg model with open boundary conditions is investigated by means of the Bethe ansatz. As is well known, quantum groups for q equal to a root of unity possess a finite number of “good” representations with non-zero q-dimension and “bad” ones with vanishing q-dimension. Correspondingly, the state space of an invariant Heisenberg chain decomposes into “good” and “bad” states. A “good” state may be described by a path of only “good” representations. It is shown that the “good” states are given by all “good” Bethe ansatz solutions with roots restricted to the first periodicity strip, i.e. only positive-parity strings (in the language of Takahashi) are allowed. Applying Bethe's string-counting technique completeness of the “good” Bethe states is proven, i.e. the same number of states is found as the number of all restricted paths on the sl_q(2) Bratteli diagram. It is the first time that a “completeness” proof for an anisotropic quantum-invariant reduced Heisenberg model is performed.     

Nucleation and growth mechanism for flame synthesis of MoO2 hollow microchannels with nanometer wall thickness

The growth and morphological evolution of molybdenum-oxide microstructures formed in the high temperature environment of a counter-flow oxy-fuel flame using molybdenum probes is studied. Experiments conducted using various probe retention times show the sequence of the morphological changes. The morphological row begins with micron size objects exhibiting polygonal cubic shape, develops into elongated channels, changes to large structures with leaf-like shape, and ends in dendritic structures. Time of probe–flame interaction is found to be a governing parameter controlling the wide variety of morphological patterns; a molecular level growth mechanism is attributed to their development. This study reveals that the structures are grown in several consecutive stages: material “evaporation and transportation”, “transformation”, “nucleation”, “initial growth”, “intermediate growth”, and “final growth”. XRD analysis shows that the chemical compositions of all structures correspond to MoO₂.     

Methane activation over Ag-exchanged ZSM-5 zeolites: A theoretical study

Methane activation catalyzed over Ag-exchanged ZSM-5 zeolites was investigated by using the density functional theory (DFT) with a cluster model. Two different pathways were taken into account in this work: the “alkyl” and the “carbenium” pathways. The activation barriers obtained are 34.09 and 66.63 kcal/mol for the “alkyl” and the “carbenium” pathway, respectively. The calculated results show that the activation barrier of the “alkyl” pathway is smaller than that of “carbenium” pathway. Consequently, the “alkyl” pathway is the preferential reaction pathway. A new mechanism of methane conversion in the presence of ethene was proposed. In the catalytic cycle, the initial step of methane activation proceeds with the “alkyl” pathway and the Ag⁺ cation acts as an acceptor of the methyl group, then ethene reacts with the Ag⁺CH₃⁻ group to form propene. In addition, it is found that the Ag⁺ cations play an important role in the methane activation, compared with the reaction of methane activation over H-ZSM-5.     

Beyond nanosizing: an approach to shape analysis of fluorescent nanostructures by SMI-microscopy

Using spatially modulated illumination (SMI) light microscopy it is possible to measure the sizes of fluorescent structures that have an extension far below the conventional optical resolution limit (“subresolution size”). Presently, the sizes are determined as the object extension along the optical axis of the SMI microscope. For this, however, “a priori” assumptions on the fluorochrome distribution (“shape”) within the examined fluorescent structure have to be made. Usually it is assumed that the fluorochrome follows a Gauss-distribution or a spherical distribution. In this report we overcome the necessity to make an assumption on the shape of the fluorochrome distribution. We introduce two new experimentally obtained parameters which allow the determination of a shape measure to describe the spatial distribution of the fluorescent dye. This becomes possible by independent measurements with different excitation wavelengths. As an example, we present shape parameter measurements on individual fluorescent microspheres with a nominal geometrical diameter (“size”) of 190 nm. In the case investigated, the experimental shape correlated well with a homogeneous fluorochrome distribution (“spherical shape”) but not with a variety of other “shapes”.     

Belting and pop, nonclassical approaches to the female middle voice: Some preliminary considerations

There is a commonly perceived difference in the sound produced in the approximate range D₄-D₅ by female singers in the western opera and concert tradition, on the one hand, and certain other styles, including rock, pop, folk, and some Broadway musicals, on the other. The term “belting” is sometimes used to refer to at least one approach to such “nonclassical” singing. In this study, based on spectrographic, electroglottographic, and sub- and supraglottal pressure measurements on representative voices of the “operatic” and “nonclassical” tradition, acoustic and laryngeal differences between the two traditions are described, and an objective, specific definition of “belting” is offered.     

Acoustic Analyses of Developmental Changes and Emotional Expression in the Preverbal Vocalizations of Infants

The nonverbal vocal utterances of seven normally hearing infants were studied within their first year of life with respect to age- and emotion-related changes. Supported by a multiparametric acoustic analysis it was possible to distinguish one inspiratory and eleven expiratory call types. Most of the call types appeared within the first two months; some emerged in the majority of infants not until the 5th (“laugh”) or 7th month (“babble”). Age-related changes in acoustic structure were found in only 4 call types (“discomfort cry,” “short discomfort cry,” “wail,” “moan”). The acoustic changes were characterized mainly by an increase in harmonic-to-noise ratio and homogeneity of the call, a decrease in frequency range and a downward shift of acoustic energy from higher to lower frequencies. Emotion-related differences were found in the acoustic structure of single call types as well as in the frequency of occurrence of different call types. A change from positive to negative emotional state was accompanied by an increase in call duration, frequency range, and peak frequency (frequency with the highest amplitude within the power spectrum). Negative emotions, in addition, were characterized by a significantly higher rate of “crying,” “hic” and “ingressive vocalizations” than positive emotions, while positive emotions showed a significantly higher rate of “babble,” “laugh,” and “raspberry.”     

K–K excitations on as “primary” superfields

We show that the K–K spectrum of IIB string on is described by “twisted chiral” superfields, naturally described in “harmonic superspace”, obtained by taking suitable gauge singlets polynomials of the D3-brane boundary superconformal field theory.To each p-order polynomial is associated a massive K–K short representation with states. The quadratic polynomial corresponds to the “supercurrent multiplet” describing the “massless” bulk graviton multiplet.     

Quantum interference rectifier

Electron transport in bent quantum wire in the presence of a magnetic field which is orthogonal to the system plane is considered. Possible constructions of “quantum interference switch” and “quantum interference rectifier” are suggested.     

All-Fiber Optical Signal Inversion Using Stimulated Raman Scattering

We propose a method for all-optical signal inversion by means of stimulated Raman scattering (SRS). The idea is based on the transference of energy from the logic state #x201C;1#x201D; to the second stokes and making the logic state #x201C;0#x201D; into logic state #x201C;1#x201D; by receiving energy from the pump through SRS. According to the numerical simulation, a continuous wave pump source of LOW at 1453 nm and a few hundred meters of highly nonlinear fiber are required to invert an input signal at 1555 nm. The optical signal is inverted with high on-off contrast ratio.     

Monte Carlo simulations on a rigid-rod model for a langmuir monolayer

A monolayer of amphiphilic molecules on water surface (Langmuir monolayer) at the so-called “solid” phase is studied using Monte Carlo simulations. Each molecule is considered to be a rigid rod, one end (the hydrophilic “head”) of which is assumed to be fixed on a two-dimensional lattice, while the other end (the hydrophobic “tail”) interacts with its nearest and next-nearest neighbours through the Lennard-Jones potential. With increase in temperature, the system undergoes a first-order transition from a low-tilt to a high-tilt phase. With increase in tail-length, the two-phase coexistence region decreases and the transition becomes sharper.     

On the low-frequency limit of the Schönfeld pulse 1/f law

On the basis of propositions of the common fluctuation theory, peculiarities of small fluctuations in real physical systems with limited sizes are analyzed. It is established that small fluctuations should necessarily be divided into two types of fluctuations: “small” and “very small”. It is shown that the damping process of “small” fluctuations has relaxation character, while the damping process of “very small” fluctuations is of random character, i.e., it represents a random rectangular signal. The probability density of “very small” fluctuations is shown to be Gaussian. The agreement of the obtained results with experimental data acquired from semiconductor-based devices is analyzed. A relation between the generation–recombination noise and phonon number fluctuations in semiconductors is studied. On the basis of this consideration it is shown that the Schönfeld pulse spectrum preserves its well-known 1/f form only in the range of intermediate frequencies; at lower frequencies the spectrum gets saturated. An expression for the low-frequency limit of Schönfeld pulse 1/f law is obtained.     

Divisors on elliptic Calabi-Yau 4-folds and the superpotential in F-theory — I

Each smooth elliptic Calabi-Yau 4-fold determines both a three-dimensional physical theory (a compactification of “M-theory”) and a four-dimensional physical theory (using the “F-theory” construction). A key issue in both theories is the calculation of the “superpotential” of the theory, which by a result of Witten is determined by the divisors D on the 4-fold satisfying X( _D = 1. We propose a systematic approach to identify these divisors, and derive some criteria to determine whether a given divisor indeed contributes. We then apply our techniques in explicit examples, in particular, when the base B of the elliptic fibration is a toric variety or a Fano 3-fold.

When B is Fano, we show how divisors contributing to the superpotential are always “exceptional” (in some sense) for the Calabi-Yau 4-fold X. This naturally leads to certain transitions of X, i.e., birational tranformations to a singular model (where the image of D no longer contributes) as well as certain smoothings of the singular model. The singularities which occur are “canonical”, the same type of singularities of a (singular) Weierstrass model. We work out the transitions. If a smoothing exists, then the Hodge numbers change.

We speculate that divisors contributing to the superpotential are always “exceptional” (in some sense) for X, also in M-theory. In fact we show that this is a consequence of the (log)-minimal model algorithm in dimension 4, which is still conjectural in its generality, but it has been worked out in various cases, among which are toric varieties.     

Determination of the “optical” thickness and of the filling factor of discontinuous Au films from photometric and ellipsometric measurements

The “optical” thickness of discontinuous Au films is determined from a suitable combination of photometric and ellipsometric measurements. The value of the metal filling factor which can be deduced from a comparison with the “mass” thickness is found to be in good agreement with the value directly obtained from structure studies.     

Vague concept of “reversible cleavage” in the theory of the surface tension of solids

Numerous derivations of the well-known Shuttleworth equation have been based on the unclear concept of “reversible cleavage” leading to the decisive step in any derivation - equalization of the surface free energy and surface stress. This is the key concept in contemporary surface thermodynamics of solids. But “cleavage” is not a surface process and, in this field, it cannot be a reversible operation. Besides, the “reversible cleavage” has no formal definition in the domain of the surface tension of solids that is an abnormal for any exact science. Consequently, this concept and all its corollaries including the Shuttleworth and generalized Lippmann equations have to be recognized as incorrect.     

A U(1) gauge-Higgs system with a radial degree of freedom

The phase diagram of a lattice U(1) gauge-Higgs model is derived without freezing the Higgs field length. For sufficienly small Higgs self-coupling strength, the “confinement” and “Higgs” phases are separated, in contrast to what is observed in the fixed length model.     

On the theory of temporal aberrations for cathode lenses

A new approach to the theory of temporal aberration for cathode lenses is given in the present paper. A definition of temporal aberration is given in which a certain initial energy of electron emission along the axial direction ε_z1 (0ε_z1ε_0max) is considered. A new method to calculate the temporal aberration coefficients of cathode lenses named “direct integral method” is also presented. The “direct integral method” gives new expressions of the temporal aberration coefficients which are expressed in integral forms. The difference between “direct integral method” and “τ-variation method” is that the “τ-variation method” needs to solve the differential equations for the three of temporal geometrical aberration coefficients of second order, while the “direct integral method” only needs to carry out the integral calculation for all of these temporal aberration coefficients of second order.All of the formulae of the temporal aberration coefficients deduced from “direct integral method” and “τ-variation method” have been verified by an electrostatic concentric spherical system model, and contrasted with the analytical solutions. Results show that these two methods have got identical solutions and the solutions of temporal aberration coefficients of the first and second order are the same as with the analytical solutions. Although some forms of the results seem different, but they can be transformed into the same form. Thus, it can be concluded these two methods given by us are equivalent and correct, but the “direct integral method” is related to solve integral equations, which is more convenient for computation and could be suggested for use in practical design.     

Evolution Strategy Optimization for Selective Pulses in NMR

We present a first set of improved selective pulses, obtained with a numerical technique similar to the one proposed by Geen and Freeman. The novelty is essentially a robust and efficient “evolution strategy” which consistently leads, in a matter of minutes, to “solutions” better than those published so far. The other two ingredients are a “cost function,” which includes contributions from peak and average radiofrequency power, and some understanding of the peculiar requirements of each type of pulse. For example, good solutions for self-refocusing pulses and “negative phase excitation pulses” (which yield a maximum signal well after the end of the pulse) are found, as may have been predicted, among amplitude modulated pulses with 270° tip angles. Emphasis is given to the search for solutions with low RF power for selective excitation, saturation, and inversion pulses. Experimental verification of accuracy and power requirements of the pulses has been performed with a 4.7 T Sisco imager.     

Novel comprehension of “common path” principle

The idea of “common path” has been widely applied in optical instrument design for 30 years and even today. But the meaning of “common path” has not yet been explained clearly and sometimes confusion has been created. In this paper an “adaptive principle” is proposed and recommended on optical instrument system. It suggests that the designer not only arranges the measurement system to obtain measurement signal but also sets a channel to give prediction of noise or disturbance in real time or short term. Such a recommendation is based on the recent studies on nonlinear dynamics and atmospheric disturbance by means of experiments as well as theoretical analysis.     

Changes in surface chemistry of an Ir---W mixed metal coated cathode during activation

A comparative study has been made between a mixed metal (60% Ir-40%W) coated cathode and a “B” cathode during activation and also in their respective steady states. The rate limiting factor in the activation of the coated cathode is the oxidation of the initial Ba type surface to a BaO type surface. Since on the “B” cathode Ba and O emerge together, its activation is faster than the coated cathode. In the steady state of operation, both cathodes exhibit a surface near BaO stoichiometry which is the optimum composition for the minimum work function. This work function is about 0.2 eV lower on the coated cathode than on the “B” cathode. An accelerated life test at 1575 K indicated a gradual decrease of the Ir concentration in the coating.