溅射钆钴合金薄膜的磁性

用射频溅射的方法制备得的钆钴膜具有垂直于膜面的单轴各向异性。电子衍射结果表明薄膜是非晶态的。电子探针分析证明钆和钴的“混合”是均匀的。用极向克尔效应观察了样品的磁畴,并测量了相应的磁滞迴线;发现在一定的工艺条件下,制备得的样品,在退磁状态呈现条状畴,并在一合适的外磁场作用下能转变为磁泡。     

钼酸钆晶体畴结构的同步辐射白光形貌实时研究

用同步辐射白光X射线形貌术对畴结构在温度及外加电场变化条件下的演变情况进行了研究.结果表明:在钼酸钆样品中同时存在铁电畴和铁弹畴,但这两类畴在温度高于居里温度时都消失,当施加足够外加电压时可以单畴化.     

X射线荧光分析二元合金薄膜的成份

一、引 言 随着薄膜工艺的发展,用蒸发、溅射以及外延的方法制备各种薄膜材料,如磁性薄膜、超导薄膜和半导体薄膜等的工作有了很大的发展.薄膜的成份对其物理特性有直接的影响,所以为了研究薄膜的物理特性,就需要定量地分析它们的成份.本文介绍用X射线荧光分析二元钆钴合金薄膜成份的一种方法.这种方法原则上对任何二元薄膜都适用. 用通常的化学分析方法确定钆钴膜的成份有两个缺点,一是样品的量少,化学分析结果的误差较大;二是破坏了样品.而X射线荧光分析法不仅快速、准确,而且不破坏样品. 用X射线荧光分析成份与用电子探针或离子探针定…     

准相位匹配周期极化钼酸钆制备及倍频效应

根据准相位匹配原理，对钼酸钆晶体用于准相位匹配倍频过程的周期性畴结构进行了设计，当入射基频光为l.064pm时，所需的钼酸钆晶体畴结构周期为5．54μm。利用外电场极化，当外电场为2．5kV／mm时，钼酸钆晶体的畴结构反转时间tc=500～600μs。当外电场脉冲幅值为2．5kV／mm、脉冲延续时间t=0．6～0．8tc时，在钼酸钆晶体中制备得到了周期畴结构。当Nd：YAG纳秒激光器输出准连续功率为7～10mW的l.064μm激光通过具有周期畴结构的样品时，获得了0．532μm的倍频光输出。     

晶格失配应力对单晶(BiTm)_3(GaFe)_5O_(12)膜磁畴结构的影响

利用液相外延工艺在钆镓石榴石衬底上制得了单晶(BiTm)_3(GaFe)_5O_(12)膜,研究了晶格失配应力对其磁畴结构的影响.研究发现,生长速率越快,膜的晶格常数越大;晶格失配应力可以在一定范围内调整膜的垂直各向异性;随着晶格失配应力由较大张应力逐渐转变为较大压应力,磁畴形状先由磁泡畴转变成迷宫畴,然后转变为过渡态部分弯曲的条状畴,最终转变为整齐排列的条状畴;失配应力同时对畴宽也有影响,膜受到的失配应力越大,畴宽越大.这一实验研究对基于控制晶格失配应力来调控单晶膜的各向异性和磁畴结构有指导意义.     

磁泡材料的磁滞迴线和泡阵磁畴的剩磁

本文采用一种用光电倍增管作为检测装置的技术,可以自动绘出透明磁性介质的磁滞迴线,测得了不同磁泡外延膜样品,在不同磁畴形状等条件下的磁迴线;解释了曲线的特点,并从实验上证实,具有泡阵磁畴的磁泡膜是处于一种特殊的剩磁状态。 关键词：     

PdMn/Co多层膜的磁性和磁光特性研究

用磁控溅射法制备了不同Mn含量的PdMn/Co磁性多层膜，通过x射线衍射对该多层膜系列进行结构分析；测定了不同Mn含量系列样品的磁滞回线、垂直各向异性及磁力显微镜图，分析了饱和磁化强度、磁畴和垂直各向异性变化的原因；通过测定该多层膜体系的克尔谱，简要分析了一定波长下克尔角随Mn含量增加而变化的物理机制. 关键词： 多层膜 磁性 磁光     

条形畴结构的FeCoAlON薄膜磁性的研究

用磁控射频溅射法制备了FeCoAlON薄膜, 研究了Al-O和N元素的添加对FeCo合金薄膜的软磁性的影响. 研究结果表明: 随着Al, O, N元素添加量的增加, 薄膜微结构从多晶转化到纳米晶再转化到非晶态, 薄膜表现为软磁性; 在N的含量较高时, 薄膜呈现条形畴结构, 本文对条形畴结构出现的机理和条件作了详细讨论, 并发现具有条形畴结构的薄膜的磁导率频率特性具有多峰共振的特点. 关键词： 铁钴基合金 薄膜 条形畴     

极紫外与软X射线用非晶碳膜全反射镜的研究

用高真空磁控溅射设备分别在工作气压为0.40Pa和0.67Pa下制备了非晶碳膜全反射镜样品,利用X射线掠入射反射测量了膜层厚度、粗糙度和膜层密度,用原子力显微镜测量了样品的表面粗糙度,用同步辐射测量了不同工作气压下制备的非晶碳膜全反射镜的反射率,并对测量结果进行了分析讨论.测试结果表明:在0.40Pa工作气压下制备的非晶碳膜反射镜的性能优于在0.67Pa工作气压下制备的反射镜的性能,在掠入射角小于4.5°时,非晶碳膜全反射镜在5nm以上波段有比较平坦的高反射率,在波长小于5nm波段,反射率急剧下降.     

石榴石磁泡膜中3类硬磁畴的形成方法

研究石榴石磁泡膜中硬磁畴畴壁中垂直布洛赫线的稳定性可为研制布洛赫线存储器提供有益的帮助 .3类硬磁畴的形成是研究硬磁畴稳定性的前提 .本文综述了在石榴石磁泡膜上形成硬磁畴的 2类方法———“脉冲偏场法”和“低直流偏场法” .结合文献中的典型样品 ,对用“脉冲偏场法”和“低直流偏场法”形成 3类硬磁畴的过程进行了简单介绍 .     

稠苯芳杂环及其烷基质子化学位移的计算

本文提出了予测稠苯芳杂环及其烷基链上质子化学位移的计算方法。 将稠苯芳杂环化合物用凯库勒式表示,计算式为为需考虑的苯环内的乙烯基效应。σ_mi,ci为各苯环的环流效应。σ_1,Hc为各芳杂环的屏蔽效应,对杂环上质子它就是该单独芳杂环上相应质子的δ值,对苯环上质子要将它分解为各结构因素的效应,即:σ_1,He=(1/2)^d-1δ_x=y(或σ_z)+σ_c-c·σ_m,H. σ_x-y与σ_z为杂原子或其基团的屏蔽效应,σ_c=c为存在于芳杂环中的乙烯基的效应,σ_m,Hc为芳杂环的环流效应,d为对不同质子所考虑的键数。有取代基时需考虑取代基的效应。计算环上烷基质子的公式为:δ=σ_p,CH3+ασ_c,CH3+βσ_t,CH3+σ_l,G σ_l,G为稠苯芳杂环基的某级效应。     

Structural phase transitions at clean and metal-covered Si(111) surfaces investigated by RHEED spot analysis

Structural phase transitions between various kinds of superlattice structures formed on a Si(111) surface have been investigated by spot analysis of reflection high-energy electron diffraction (RHEED). Reversible transitions induced by temperature changes and irreversible ones induced by metal depositions were observed. Detailed discussions on the dynamics of the phase transitions are made by quantitative analyses of integrated spot intensity and profile. For a phase transition of 7′7  1′1 structures on a clean Si(111) surface, a hysteresis with temperature difference of 5°C. between in heating and cooling processes was found in the spot intensity change, indicating a first-order transition. Hysteresis was hardly recognized, on the other hand, for transitions of Au-induced superstructures (5×2-Au or ×-Au)  1×1-Au. The spot profiles were found to be broadened during the transition of Si(111)-×-Au  1×1-Au, which was a signature of a continuous transition, while the profiles remained unchanged during the transitions of the 7×7  1×1 and 5×2-Au  1×1-Au phases. Structural conversions induced by In adsorption on the Si(111) surface kept at constant temperatures were also analyzed. The conversions at room temperature were totally dependent on the initial substrate surface structures; the 7×7 surface did not show any structural conversion with In adsorption, while the ×-In surface successively converted to a 2×2 and a × phase with coverage increase. The structural transitions at elevated temperatures were sensitively dependent on the temperatures. Sequences of transitions among the 7×7, 4×1, ×, 1×, and ×4 were quantitatively revealed as changes in RHEED spot intensity.     

ErP5O14非晶玻璃的红外量子剪裁

研究了Er_1.0P₅O₁₄铒非晶玻璃的红外量子剪裁现象. 从吸收谱和激发光谱的计算比较中肯定了Er_1.0P₅O₁₄非晶 玻璃的1537.0 nm红外荧光为多光子量子剪裁荧光. 从Er_1.0P₅O₁₄非晶玻璃的可见和红外荧光发射光谱中发现激发²H_11/2, ⁴G_11/2和⁴G_9/2能级所导致的⁴I_13/2→⁴I_15/2量子剪裁红外荧光很强;基于自发辐射速率、无辐射弛豫速率和能量传递速率等参数的计算,对其量子剪裁机理进行了分析.发现起源于基态的强下转换能量传递{²H_11/2→⁴I_9/2,⁴I_15/2→⁴I_13/2},{⁴G_11/2→⁴I_13/2, ⁴I_15/2→²H_11/2},{⁴G_9/2→⁴F_7/2,⁴I_15/2→⁴I_13/2}和{⁴G_9/2→⁴I_13/2, ⁴I_15/2→²H_11/2}是导致Er_1.0P₅O₁₄非晶玻璃具有强的三光子和四光子量子剪裁红外荧光的原因.研究结果对改善太阳能电池效率有一定意义.     

1-forms over the moduli space of irreducible connections defined by the spectrum of Dirac operators

Let (P) be the moduli space of irreducible connections of a G-principal bundle P over a closed Riemannian spin manifold M. Let D_A be the Dirac operator of M coupled to a connection A of P and f a smooth function on M. We consider a smooth variation A(u) of A with tangent vector ω and denote T_ω:= (D_A(u)−f) (u=0. The coefficients of the asymptotic expansion of trace (T_ω · e^-t(D_A−f)2) near t=0 define 1-forms a^(k)_f, K=0, 1, 2, … on (P). In this paper we calculate aa⁽⁰⁾_f, a⁽¹⁾_f, a⁽²⁾_f and study some of their properties. For instance using the 1-form a⁽²⁾_f for suitable functions f we obtain a foliation of codimension 5 of the space of G-instantons of S⁴.     

Phase formation and magnetic properties of Nd2Fe14B-type Nd16Co76B8−xCx alloys and their hydrides

An attempt is made to synthesize Nd₂Co₁₄C compound by mechanical alloying Nd₁₆Co₇₆B_8−xC_x (0x8) alloys and subsequent annealing. Phase formation and magnetic properties of Nd₂Fe₁₄B-type Nd₁₆Co₇₆B_8−xC_x alloys and their hydrides are investigated. The Nd₂Co₁₄(B,C) phase with Nd₂Fe₁₄B-type structure is formed for Nd₁₆Co₇₆B_8−xC_x (0x7) alloys, while NdCo₇C_δ phase with TbCu₇-type structure is observed in Nd₁₆Co₇₆C₈ alloy. The lattice parameter c of the Nd₂Co₁₄(B,C) phase decreases with increasing the carbon content. A limit volume of the unit cell to form the Nd₂Fe₁₄B-type structure is estimated to be 0.870 nm³. The spin-reorientation temperature T_SR increases with increasing the carbon content, due to an enhancement of magnetocrystalline anisotropy caused by carbon substitution for boron. After hydrogenation, the lattice expansion is observed for Nd₁₆Co₇₆B_8−xC_x (0x7) alloys. The spin-reorientation temperature of Nd₁₆Co₇₆B_8−xC_xH_y (0x7) is much lower than that of the host alloys. Some structural and magnetic properties of hypothetic Nd₂Co₁₄C and Nd₂Co₁₄CH_y compounds are estimated by extrapolation.