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1.
Angle-resolved photoemission spectra from Na adlayers on Al(111) reveal features which behave like quantum well resonances although the substrate provides no confining barrier. These features are observed in a narrow photon energy range where overlayer collective excitations cause resonant enhancement of the photoemission intensity. The quantum well behavior is shown to be due to surface resonances of the Na/Al system. The resonances are observable using photoemission because of spatial confinement and dynamical enhancement of the local electric field within the Na films.  相似文献   

2.
Angle-resolved photoemission has developed into one of the leading probes of the electronic structure and associated dynamics of condensed matter systems. As with any experimental technique the ability to resolve features in the spectra is ultimately limited by the resolution of the instrumentation used in the measurement. Previously developed for sharpening astronomical images, the Lucy-Richardson deconvolution technique proves to be a useful tool for improving the photoemission spectra obtained in modern hemispherical electron spectrometers where the photoelectron spectrum is displayed as a 2D image in energy and momentum space.  相似文献   

3.
Employing high resolution photoemission spectroscopy, we studied the evolution of the spectral features in rare earth hexaboride single crystals as a function of temperature and 4f binding energy, where the variation of the 4f binding energy is obtained by changing the rare earth element. High energy resolution helped to reveal the distinct features corresponding to the various photoemission final states. Experimental results of CeB(6), a dense Kondo system, exhibit the growth of the features near the Fermi level with the decrease in temperature relative to the uncompensated local moment contributions. The valence band spectra of the antiferromagnetic compounds, PrB(6) and NdB(6), exhibit multiple features-the 4f ionization peaks (poorly screened features) appear at higher binding energies and the features in the vicinity of the Fermi level possessing significant 4f character are due to the well-screened photoemission final states. These results indicate finite hybridization between the 4f and B 2s2p conduction electronic states. Interestingly, the well-screened features in PrB(6) and NdB(6) exhibit unusual enhancement in intensity at low temperature.  相似文献   

4.
Analysis of a variety of Auger and photoemission spectra leads to the conclusion that the value given by Bearden for the MgKα1,2 X-ray energy is not the best value for use in photoemission spectroscopy. The reported value is the energy at the maximum of the X-ray spectrum. Use of this can lead to inconsistencies in measured energies. These are removed if one uses the centroid of the magnesium X-ray spectrum (1253.53 eV). Use of this value also resolves a disagreement between values reported by different laboratories for the Nels ionization energy.  相似文献   

5.
We report on the results of angle-resolved photoemission experiments on a quasi-one-dimensional (1D) MX-chain compound [Ni(chxn)2Br]Br2, which shows a gigantic nonlinear optical effect. A "band" having about 500 meV energy dispersion is found in the first half of the Brillouin zone, but disappears at kb/pi approximately 1/2. These spectral features are well reproduced by the d-p chain model with a small charge-transfer energy Delta compared with that of 1D Cu-O compounds. We propose that this smaller Delta is the origin of the absence of clear spin-charge separation in the photoemission spectra and the strong nonlinear optical effect.  相似文献   

6.
The chemisorption of ammonia on Ni(111) has been investigated using LEED, thermal desorption, and angle-resolved photoemission. For exposures at 200 K, thermal desorption shows a coverage-dependent binding energy associated with dipole-dipole interactions. A (2 × 2) LEED pattern occurs at 2–4 L exposure. Time dependence of the LEED pattern and changes in the thermal desorption induced by the LEED beam indicate that the (2 × 2) pattern is due to a stable intermediate decomposition species. Using synchrotron radiation photoemission all three valence orbitals of ammonia have been observed for the first time. The energies of the ammonia-induced features in the photoemission (?22.0, ?11.0 and ?6.7 eV below the Fermi energy) and the observed symmatries positively identify the absorbed species as molecular ammonia. Additional structure observed in the photoemission spectra after electron bombardment is associated with the stable adsorbed intermediate.  相似文献   

7.
We present the first electron energy loss data on a high-temperature superconductor. A detailed comparison with photoemission energy distribution curves and partial-yield spectra identifies the nature of the corresponding features. This analysis shows that the bulk plasmon energy is 24.6 eV, and that there are two peaks in the density of empty states, 2.3–2.5 eV and 4.3–4.6 eV above the Fermi level.  相似文献   

8.
The valence band (VB) electronic structures of CrSi2 were studied by synchrotron radiation photoemission. Overall features of the VB photoemission spectra measured at room temperature (RT) and 20 K by using synchrotron radiation (photon energy, =20–120 eV) were similar. Two characteristic emissions were observed corresponding to the bonding and the nonbonding Cr-d partial density of states (PDOS) in the CrSi2. The onset of the VB photoemission measured at 20 K was located at about 0.32 eV below Fermi level, due to the energy band gap of CrSi2 more than 0.32 eV.  相似文献   

9.
李智浩  曹亮  郭玉献 《物理学报》2017,66(22):224101-224101
利用基于同步辐射的近边X射线吸收精细结构谱(NEXAFS)和共振光电子谱(RPES)研究了苝四甲酸二酐分子(PTCDA)薄膜的电子结构.碳K边NEXAFS谱中能量小于290 eV的四个峰对应于PTCDA分子不同化学环境碳原子1s电子到未占据分子轨道的共振跃迁.RPES谱中观察到共振光电子发射和共振俄歇电子发射导致的共振峰结构,以及二次谐波激发的碳1s信号.根据电子动能对入射光能量的依赖性分别对三类峰结构进行了归属.同时,发现PTCDA分子轨道共振光电子峰的强度具有光子能量依赖性.这种能量选择性共振增强效应是由于PTCDA分子轨道空间分布差异导致的.共振俄歇峰主要源于高结合能(4.1 eV)分子轨道能级电子参与的退激发过程.明确RPES实验谱图中各个峰结构的起源有助于准确利用基于RPES的芯能级空穴时钟谱技术定量估算有机分子/电极异质界面处电子从分子未占据轨道到电极导带的超快转移时间.  相似文献   

10.
We describe photoemission results from pure and Sb-doped SnO2 nanoparticles deposited on gold substrates. Photoelectron spectra with synchrotron radiation were recorded for Sn 3d, Sb 3d and O 1s core levels and valence bands in the 500-1200 eV energy range. For pure SnO2 nanoparticles the surface is terminated by an oxygen rich layer with no obvious surface environment for Sn. When doped n-type with 9.1% or 16.7% Sb, dopant atoms are concentrated near the surface of the nanoparticles. The valence state of the dopant atoms is predominantly SbV. Plasmon satellite features are also observed in core level photoemission spectra and their intensity relative to the main peak increases with increasing photon energy. Received 30 November 2000  相似文献   

11.
The X-ray photoelectron spectra of the 2p levels of Mn in AgMn 20 at%, Fe in AuFe 20 at%, RhFe 25 at% and 20 at% and Co in RhCo 20 at% have been measured. The Mn and Fe spectra show features which are attributed to excitation of electrons from the 3d to higher energy states during photoemission, while the Co spectra do not.  相似文献   

12.
The electronic structure of 1 ML and 2 ML Au on Ag(111) has been studied experimentally and theoretically by spin-, angle- and energy-resolved photoemission in the highly symmetrical set-up of normally incident circularly polarized VUV radiation and normal electron emission. The measured spectra agree rather well with their relativistically calculated counterparts and can be consistently interpreted with the aid of spin- and layer-resolved densities of states. The spin polarization of spectral peaks directly reflects the double group symmetry type of the the corresponding initial states. For 1 ML (2 ML) Au on Ag(111) there are two (four) Au-derived states, which are confined to the adlayers (“film states”). For 2 ML Au, the “film-state” photoemission intensity depends strongly on the photon energy, which is understood as an interference effect. Since the agreement with the experimental photoemission spectra is improved by calculations assuming an additional Ag layer on top, and since the Au-derived experimental features are substantially broadened, an intermixing of Au and Ag is very likely.  相似文献   

13.
Model calculations of X-ray absorption, emission, and photoemission spectral lineshapes are reported for intrinsic and extrinsic core excitations in metals with final-state interactions that can be represented by a central attractive potential surrounded by an effective barrier on its periphery. Some of the calculated spectra exhibit novel features: XPS lineshapes with multi-electron shake-off sidebands and features characteristic of resonances and anti-resonances, and X-ray absorption and emission spectra with (i) edges that are apparently peaked (on a moderate energy scale) when the X-ray edge singularity causes them to be, in fact, suppressed on a fine scale, (ii) edges that are markedly rounded, and (iii) gross spectral features that are influenced greatly by the electronic structure of the iniial state of the Fermi sea, and only weakly by the final-state.  相似文献   

14.
Photoemission energy distribution spectra have been scanned for photoelectrons emitted normal to two different crystal faces of tungsten, namely (100) and (110). The energy distributions and the derivative spectra show large differences between emission from the two faces. Whereas strong surface state emission is observed from the (100) face, no surface states are associated with the (110) face. The spectra show features characteristic of direct and also nondirect transitions, but these features appear very different for the two faces. Using existing band structure calculations, the spectral structure is assigned to electronic transitions between bands along the Δ axis for the (100) face and the Σ axis for the (110) face. The experiments show that directional photoemission spectra taken normal to a crystal surface make it possible to investigate electronic energy bands along symmetry directions in the Brillouin zone.  相似文献   

15.
Resonant silicon Auger KLL and 2s and 2p photoemission spectra of a porous silicon sample have been studied when excited by photons in the energy domain of the 1s edge in pure silicon and silicon oxide. Characteristic features of a resonant process could be detected. In particular, the constant initial state spectrum of the 2p state of silica behaves similarly to that encountered in systems which present a well-defined atomic level. This is due to the existence of a well-localized molecular orbital built in the SiO4 unit. The use of high-energy photons, which generate high-energy electrons, allows these photoemission experiments to be quite bulk sensitive.  相似文献   

16.
We have measured the photoemission spectra both for CO adsorbed on Ni and Pd films and for gas phase CO over a wide photon energy range. The comparison of these two sets of measurements lead to the following interpreation of the two observed electronic energy levels of molecularly adsorbed CO. The lower binding energy CO-induced level corresponds to the 1π gas phase level with some admixture of the 5σ level and the higher binding energy level corresponds to the 4σ gas phase level. The hω-dependence of the photoionization cross section is shown to play a predominant role in determining the surface sensitivity.  相似文献   

17.
The influence of translational kinetic energy of incident O2 molecules for the passive oxidation of the partially oxidized Si(0 0 1) surface has been studied by photoemission spectroscopy. The incident energy of O2 molecules was controlled up to 3 eV by a supersonic molecular beam technique. Two incident energy thresholds (1.0 and 2.6 eV) were found out in accordance with the first-principle calculations. Si 2p and O 1s photoemission spectra measured at representative incident energies showed the incident energy induced oxidation at the backbonds of the dimer and the second layer (subsurface) Si atoms. Moreover, the difference of oxygen chemical bonds was found out to be as the low and the high binding energy components in the O 1s photoemission spectra. They were assigned to bridge sites oxygen and dangling bond sites oxygen, respectively.  相似文献   

18.
The effect of an ultrathin Pb film deposited on the surface of Bi2Se3 and Sb2Te3 compounds on the electronic state structure of topological insulators is studied experimentally by the angle-resolved photoemission spectroscopy (ARPES) technique. The following features are revealed: formation of two-dimensional quantum-well states in the near-surface region, an increase in the binding energy of the Dirac cone and the core levels, and a simultaneous electronic states intensity redistribution in the system in photoemission spectra. The results obtained show that topological states may coexist at the interface between studied materials and a superconductor, which seems to be promising for application in quantum computers.  相似文献   

19.
Resonant Auger spectra of O2 clusters excited at the O1s edge are reported. After excitation to the repulsive 1s-1* state, the resulting resonant Auger spectrum displays features that remain constant in kinetic energy as the photon energy is detuned. The shift between known atomic fragment features and these features is consistent with that observed for atoms and clusters in singly charged states in direct photoemission. These findings are strong evidence for the existence of molecular ultrafast dissociation processes within the clusters or on their surface.  相似文献   

20.
Core hole screening effects at organic/metal interfaces were studied by core level X-ray photoemission spectroscopy (XPS), X-ray excited Auger electron spectroscopy (XAES), and valence band ultraviolet photoemission spectroscopy (UPS). The comparison of energetic shifts in XPS and XAES enables the estimation of electronic relaxation energy (screening ability). Magnesium phthalocyanine (MgPc) and zinc phthalocyanine (ZnPc) evaporated on single crystalline Au(100) were used as model molecules. Two different features in the Mg KLL spectra can be clearly separated for (sub-)monolayer coverages, while only minor changes of the shape of Mg 1s are observed. Applying a dielectric continuum model, the major screening mechanism cannot be described sufficiently by polarization screening due to mirror charges, significant contributions by charge transfer screening have to be considered. In contrast, small screening effects in the bulk material can be explained by surface polarization.  相似文献   

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