Three‐photon absorption properties of a novel symmetrical Carbazole derivative having terminal 1,10‐phenanthroline rings via carbon–nitrogen (C = N) double bond

Three‐photon absorption (3PA) properties of symmetric‐type carbazole derivatives show great potential for application in light‐activated therapy and optical limiting. A novel symmetrical carbazole derivative (abbreviated as POCP) with end‐groups of 1,10‐phenanthroline rings as the donor moieties, chained via carbon–nitrogen (C = N) double bond, has been synthetized and its three photon absorption properties has been also determined by using a Q‐switched Nd: YAG laser pumped with 30 ps pulses at 1064 nm in dimethylformamide. The measurement of 3PA cross‐section of this compound is performed by open aperture Z‐scan and σ_3PA is 481 × 10^–78 cm⁶ ? s²/photon² for the transition S₀ → S₁. The influence of the molecular structure of this compound on three‐photon absorption cross‐sections is discussed micromechanically by Austin model 1 and Zerner's Intermediate Neglect of Differential Overlap/S method. Copyright © 2012 John Wiley & Sons, Ltd.     

Quantum electrodynamics with “two-particle” unitarity: Charged spin-0 bosons

The spin-0 propagator in quantum electrodynamics of charged spinless bosons (“pions”) is investigated in detail via the closest approximation to the Schwinger-Dyson equation in the two-particle unitarity approximation proposed initially by Salam by replacing the photon propagator by its zero order result. The high-energy behavior (in spacelike directions) of the (renormalized) spin-0 propagator Δ(p²) is explicitly derived and a finite electromagnetic mass excitation for the “pion” is obtained. The latter follows as a result of the derived asymptotic behavior of Δ^?1(p²) (p² → ∞) that the unrenormalized mass m₀ ≡ 0. This brings us into contact with earlier work of Johnson, Landau and their collaborators. The fact that m₀² ≡ 0 and that Δ^?1(p²)/_p²=?m² = 0 (m ≠ 0) (in Nambu's sense) gives us an eigenvalue equation for the fine structure constant which may be then computed in terms of no other parameters. This eigenvalue equation is expanded in powers of the coupling constant with all the expansion coefficients being finite. The latter is computed to sixth order in the charge.     

自由电子激光的能量转换

根据Ｗｅｉｚｓａｃｋｅｒ－Ｗｉｌｌｉａｍｓ近似，把自由电子激光模拟成相对论性电子与赝光子的碰撞，而光子被散射．按照这个物理模型，研究了电子与光子的能量交换，得到了散射光子能量与碰撞前光子能量之间的关系：ε_p=4γ²ε_p⁽⁰⁾散射光子能量的放大是以电子消耗能量为代价的分析。计算了能量交换的规模，并得出自由电子激光中能量转换效率最大为５０％. 关键词：     

SUT‐NANOTEC‐SLRI beamline for X‐ray absorption spectroscopy

The SUT‐NANOTEC‐SLRI beamline was constructed in 2012 as the flagship of the SUT‐NANOTEC‐SLRI Joint Research Facility for Synchrotron Utilization, co‐established by Suranaree University of Technology (SUT), National Nanotechnology Center (NANOTEC) and Synchrotron Light Research Institute (SLRI). It is an intermediate‐energy X‐ray absorption spectroscopy (XAS) beamline at SLRI. The beamline delivers an unfocused monochromatic X‐ray beam of tunable photon energy (1.25–10 keV). The maximum normal incident beam size is 13 mm (width) × 1 mm (height) with a photon flux of 3 × 10⁸ to 2 × 10¹⁰ photons s^?1 (100 mA)^?1 varying across photon energies. Details of the beamline and XAS instrumentation are described. To demonstrate the beamline performance, K‐edge XANES spectra of MgO, Al₂O₃, S₈, FeS, FeSO₄, Cu, Cu₂O and CuO, and EXAFS spectra of Cu and CuO are presented.     

Concept of a spectrometer for resonant inelastic X‐ray scattering with parallel detection in incoming and outgoing photon energies

A spectrometer for resonant inelastic X‐ray scattering (RIXS) is proposed where imaging and dispersion actions in two orthogonal planes are combined to deliver a full two‐dimensional map of RIXS intensity in one shot with parallel detection at incoming hv_in and outgoing hv_out photon energies. Preliminary ray‐tracing simulations with a typical undulator beamline demonstrate a resolving power well above 11000 with both hv_in and hv_out near 930 eV, with a vast potential for improvement. Combining this instrument – nicknamed hv² spectrometer – with an X‐ray free‐electron laser source simplifies its technical implementation and enables efficient time‐resolved RIXS experiments.     

Absolute measurement of an atomic cascade rate using a two photon coincidence technique. Application to the 4p21S0 -4s4p 1P1 -4s21S0 cascade of calcium excited by a two photon absorption

The two photon coincidence technique yields an absolute measurement of a cascade decay rate without knowing the detection efficiency of each detector. This method is applied to calcium atoms in an atomic beam excited to the 4p²¹S₀ state, and decaying via the resonant ¹P₁ state; it yields the excitation rate of the upper 4p²¹S₀ level. Since the excitation process (two photon absorption) is controlled, one can compute the excitation rate of the upper level as a function of the transition probabilities in the cascade. The lower transition is well known and we can therefore deduce the transition probability for the 4p²¹S₀ -4s4p ¹P₁, transition which previously had not been accurately determined. The preliminary measurements yield a line strength s = 0.98 ± 0.3 au in good agreement with a recent measurement of the lifetime of the 4p²¹S₀ state.     

Radiative corrections to neutral pion-pair production

We calculate the one-photon loop radiative corrections to the neutral pion-pair photoproduction process p^-g ?p^-p⁰p⁰\pi^-\gamma \ensuremath \rightarrow\pi^-\pi^0\pi^0 . At leading order this reaction is governed by the chiral pion-pion interaction. Since the chiral p⁺ \pi^{+}_{} p^- \pi^{-}_{} ? \rightarrow p⁰ \pi^{0}_{} p⁰ \pi^{0}_{} contact vertex depends only on the final-state invariant mass it factors out of all photon loop diagrams. We give analytical expressions for the multiplicative correction factor R ~ a/2p\ensuremath R\sim \alpha/2\pi arising from eight classes of contributing one-photon loop diagrams. An electromagnetic counterterm has to be included in order to cancel the ultraviolet divergences generated by the photon loops. Infrared finiteness of the virtual radiative corrections is achieved (in the standard way) by including soft photon radiation below an energy cut-off l \lambda . The radiative corrections to the total cross-section vary between +2% and -2% for center-of-mass energies from threshold up to 7m_p\ensuremath 7m_{\pi} . We study also the radiative corrections to the p⁰p⁰\ensuremath \pi^0\pi^0 mass spectrum.     

Experimental investigation of ρ<Superscript>0</Superscript> photoproduction on the pion in the H1 experiment

Experimental results on quasielastic photoproduction of the ρ⁰ meson in association with a neutron, obtained at the HERA collider, are presented. The total and differential cross sections of the γp → ρ⁰ nπ⁺ reaction at the positron–proton center-of-mass energy of √s =319 GeV are measured. The data collected with the H1 detector in 2006 and 2007 correspond to an integrated luminosity of 1.16 pb^?1. The kinematic region of the photon–proton cms energy of 20 < W _γp <100 GeV, photon virtuality of Q ² < 2 GeV², and the ρ⁰ transverse momentum below 1 GeV/c is analyzed. Secondary neutrons with energies x _L > 0.35 (in proton-energy units) and emission angles below 0.75 mrad are selected. The model of double peripheral exchange, in which the ρ⁰ is elastically produced via the photon interaction with the virtual pion from the proton–neutron vertex, is employed for interpreting the results. The cross section for the ρ⁰ elastic photoproduction on the pion, γπ⁺→ ρ⁰π⁺, is extracted in the one-pion-exchange approximation. The magnitude of the cross section suggests that the γp → ρ⁰ nπ⁺ reaction is significantly affected by absorption.     

Number‐of‐layer,pressure, and temperature resolved bond–phonon–photon cooperative relaxation of layered black phosphorus

We systematically examined the effects of number‐of‐layer, pressure, and temperature on the bond length and energy, Debye temperature, atomic cohesive energy, and binding energy density for layered black phosphorus using bond–phonon–photon spectrometric methods. We clarified the following: (1) atomic under‐coordination shortens and stiffens the P P bond, which raises the B_2g and A_g² phonon frequency and widens the bandgap, (2) bond thermal elongation and weakening soften all phonon modes, and (3) bond mechanical compression has the opposite effect of heating on phonon frequency relaxation. The phonon and photon energy depends on the bond length and energy, which determines the relevant elasticity and thermal stability of layered structure. More broadly, the approaches and findings of this work provide both insight into and efficient tools for further exploration of unusual behaviors of other two‐dimensional substance. Copyright © 2016 John Wiley & Sons, Ltd.     

Giant Three‐Photon Absorption in Monolayer MoS2 and Its Application in Near‐Infrared Photodetection

For decades, there has been extensive research on exploring fundamental physical mechanisms for strong and fast optical nonlinearities. One of the important nonlinear‐optical mechanisms is multiphoton absorption which has a wide range of photonic applications. Herein, a theoretical model is proposed for three‐photon absorption (3PA) in monolayer MoS₂. The model shows that the 3PA coefficients are on the order of 0.1 cm³/GW². As compared to bulk semiconductors, these coefficients are enhanced by several orders of magnitude due to excitonic effects. Such exciton‐enhanced 3PA is validated by light‐intensity‐dependent photocurrent measurements on a monolayer MoS₂ photodetector with femtosecond laser pulses. These results lay both theoretical and experimental foundation for developing sensitive near‐infrared MoS₂‐based three‐photon detectors.     

Electron‐Nuclear Dynamics in Molecular Harmonic Generation Driven by a Plasmonic Nonhomogeneous Field

Electron (z)‐nuclear (R) dynamics in the molecular high‐order harmonic generation (MHHG) from H₂⁺ driven by the plasmonic nonhomogeneous field, generated by the surface plasmon polaritons in the bowtie‐shaped nanostructure, have been theoretically investigated through solving the two dimensional time‐dependent Schrödinger equation with the Non‐Bohn‐Oppenheimer approximation. It is found that (i) due to the plasmonic enhancement of the laser intensity, the harmonic cutoff can be extended when the spatial position of H₂⁺ is away from the gap center of the nanostructure. However, due to the limit of the gap size, the threshold value of the harmonic cutoff can be obtained at a given position of H₂⁺. (ii) Due to the asymmetric enhancement of the laser intensity in space, the extended higher harmonics are respectively from E(t) > 0 a.u. or E(t) < 0 a.u. for the cases of the positive and the negative spatial position of H₂⁺. As a result, the intensities of the extended higher harmonics are different and can be controlled by changing the carrier‐envelope phase and the pulse duration of the laser field. (iii) In the few‐cycle pulse duration, the MHHG mainly comes from the multi‐photon resonance ionization (MPRI), while as the pulse duration increases, the MPRI, the charge‐resonance enhanced ionization (CREI) and even the dissociative ionization (DI) are contributed to the MHHG. Moreover, as the spatial position of H₂⁺ moves, the contributions of the MHHG from the MPRI, the CERI and the DI can be controlled. (iv) The contributions of the MHHG from the two‐H nuclei have been investigated and found that when E(t) > 0 a.u., the intensities of the harmonics from the negative‐H is higher than those from the positive‐H; while when E(t) < 0 a.u., the intensities of the harmonics from the positive‐H plays the main role in the MHHG. Moreover, the multi‐minima, caused by the two‐center interference can also be found. (v) Finally, by superposing a properly selected harmonics, a single isolated attosecond pulse (SIAP) with the full width at half maximum (FWHM) of 34 as can be obtained.     

Catalysis by hydrogen chloride in the gas‐phase elimination kinetics of 2‐phenyl‐2‐propanol and 3‐methyl‐1‐buten‐3‐ol

A homogeneous, molecular, gas‐phase elimination kinetics of 2‐phenyl‐2‐propanol and 3‐methyl‐1‐ buten‐3‐ol catalyzed by hydrogen chloride in the temperature range 325–386 °C and pressure range 34–149 torr are described. The rate coefficients are given by the following Arrhenius equations: for 2‐phenyl‐2‐propanol log k₁ (s^?1) = (11.01 ± 0.31) ? (109.5 ± 2.8) kJ mol^?1 (2.303 RT)^?1 and for 3‐methyl‐1‐buten‐3‐ol log k₁ (s^?1) = (11.50 ± 0.18) ? (116.5 ± 1.4) kJ mol^?1 (2.303 RT)^?1. Electron delocalization of the CH₂?CH and C₆H₅ appears to be an important effect in the rate enhancement of acid catalyzed tertiary alcohols in the gas phase. A concerted six‐member cyclic transition state type of mechanism appears to be, as described before, a rational interpretation for the dehydration process of these substrates. Copyright © 2007 John Wiley & Sons, Ltd.     

Involvement of weak C?H···X hydrogen bonds in metal‐to‐semiconductor regime change in one‐dimensional organic conductors (o‐DMTTF)2X (X = Cl,Br, and I): combined IR and Raman studies

We report on the infrared (IR) and Raman studies of the three isostructural quasi‐one‐dimensional cation radical salts of 3,4‐dimethyl‐tetrathiafulvalene (o‐DMTTF)₂X (X = Cl, Br, and I), which all exhibit metallic properties at room temperature and undergo transitions to a semiconducting state in two steps: a soft metal‐to‐semiconductor regime change in the temperature region T_ρ = 5–200 K and then a sharp phase transition at about T_MI = 50 K. Polarized IR reflectance spectra (700–16 000 cm⁻¹) and Raman spectra (50–3500 cm⁻¹, excitation λ = 632.8 nm) of single crystals were measured as a function of temperature (T = 5–300 K) to assess the eventual formation of a charge‐ordered state below 50 K. Additionally, the temperature dependence of the IR absorption spectra of powdered crystals in KBr discs was also studied. The Raman spectra and especially the bands related to the CC stretching vibration of o‐DMTTF provide unambiguous evidence of uniform charge distribution on o‐DMTTF down to the lowest temperatures, without any modification below 50 K. However, the temperature dependence of Raman spectra indicates a regime change below about 200 K. Temperature dependence of both electronic dispersion and vibrational features observed in the IR spectra also clearly confirms the regime change below about 200 K and shows the involvement of C H···X hydrogen bonds in the electronic localization; some spectral changes can be also related with the phase transition at 50 K. Additionally, using density functional theory methods, the normal vibrational modes of the neutral o‐DMTTF⁰ and cationic o‐DMTTF⁺ species, as well as their theoretical IR and Raman spectra, were calculated. The theoretical data were compared with the experimental IR and Raman spectra of neutral o‐DMTTF molecule. Copyright © 2011 John Wiley & Sons, Ltd.     

Measurement of photons via conversion pairs in $\sqrt{s_{NN}}$ =200 GeV Au+Au collisions with the PHENIX experiment at RHIC

Thermal photons can provide information on the temperature of the new state of matter created at RHIC. In the p_T region of 1–3 GeV/c thermal photons are expected to be the dominant direct photon source. Therefore, a possible excess compared to a pure decay photon signal due to a thermal photon contribution should be seen in the double ratio (γ/γ(π⁰))_Measured/(γ/γ(π⁰))_Simulated, if sufficient accuracy can be reached. We present a method to reconstruct direct photons by measuring e⁺e^--pairs from external photon conversions.     

Resonant inelastic x‐ray scattering from highly correlated dysprosium compounds

Dy₂O₃ and Dy metal's resonant inelastic x‐ray scattering (RIXS) spectra were measured in the Beijing Synchrotron Radiation Facility. As a bulk sensitive probe and two‐photon process, RIXS provides more information on the electronic structure of matter. In this full RIXS experiment, the 2p⁶4fⁿ→ 2p⁵4fⁿ5d¹ (2p⁵4f^{n + 1}5d⁰) → 2p⁶3d⁹4fⁿ5d¹ (2p⁶3d⁹4f^{n + 1}5d⁰) channel of two samples (Dy₂O₃ and Dy metal) was studied. Further comparison shows that there are many differences in the RIXS spectra. Dy metal has only a single resonance and its 5d band is broader than that of Dy₂O₃. In the resonant regime, it has a lower final state energy, whereas in the non‐resonant regime it exceeds Dy₂O₃. This causes a broader bandwidth of the main final state B and a narrower bandwidth in the resonant and non‐resonant regime. The pre‐edge structure in Dy L₃ absorption spectra was also resolved using RIXS, which cannot be seen in conventional XAS owing to 2p core hole lifetime broadening. Copyright © 2005 John Wiley & Sons, Ltd.     

Twisted electrostatic waves in a self‐gravitating dusty plasma

A generalized response (dielectric) function for twisted electrostatic waves is derived for an un‐magnetized self‐gravitating thermal dusty plasma, whose constituents are the Boltzmann‐distributed electrons and positive ions in the presence of negatively charged micrometre‐sized massive dust particulates. For this purpose, a set of Vlasov–Poisson coupled equations is solved along with the perturbed Laguerre–Gauss distribution function, as well as the electrostatic and gravitational potentials in the limit of paraxial approximation. For plane wave solution, the wavefronts of the dust‐acoustic (DA ) wave are assumed to have a constant phase with electric and gravitational field lines propagating straight along the propagation axis. On the other hand, non‐planar wave solutions show helical (twisted) wavefronts, in which field lines spiral around the propagation axis owing to the azimuthal velocity component to account for the finite orbital angular momentum (OAM ) states. The dispersion relation and damping rate for twisted DA waves are studied both analytically and numerically. It is shown that finite OAM states, the dust to electron temperature ratio, and dust self‐gravitation effects significantly affect the linear dispersion and Landau damping frequencies. In particular, the phase speed of twisted DA waves is reduced with the variation of the twist parameter η (= k /lq_ϕ ), dust concentration δ (= n_{d 0}/n_{i 0}), and dust self‐gravitation α (= ω_Jd /ω_pd ). The relevance of our findings to interstellar dust clouds is also discussed for micrometre‐sized massive dust grains.     

First-principles calculations of optical properties of Mg2Pb

Based on the density functional theory(DFT),the electronic structures and optical properties of Mg2Pb are calculated by using the local density approximation(LDA)and plane wave pseudo-potential method.The calculation results show that the indirect band gap width of Mg2Pb is 0.02796 eV.The optical properties of Mg2Pb have isotropic characteristics,the static dielectric function of Mg2Pb is1(0)=10.33 and the refractive index is n0=3.5075.The maximum absorption coefficient is 4.8060×105cm 1.The absorption in the photon energy range of 25–40 eV approaches to zero,shows the optical colorless and transparent behaviors.     

Measurements of the (γ, n0) reaction on 12C and 16O and the investigation of the reaction mechanism

Differential (γ, n₀) cross sections on ¹²C and ¹⁶O have been measured for photon energies 60 MeV ? E_γ ? 160 MeV. These results combined with the corresponding (γ, p₀) cross sections support an absorption mechanism of the photon by neutron-proton pairs.     

Neon 3p-excitation by proton impact (100 keV-1 MeV): Cross sections and line polarization

The excitation of all ten levels of the neon 2p ⁵3p configuration by proton impact (100 keV-1 MeV) has been investigated by the spectral analysis of photon emission. Absolute emission cross sections have been obtained by calibration with a standard light source. Cascade effects are shown to be very important especially in the case ofJ=1 levels. For the 3p(¹ S ₀) level, which we studied additionally for electron impact excitation (100 eV-1 keV), our experimental cross sections are compared with the first Born approximation. Furthermore the polarization of sixteen 3p—3s emission lines has been measured as a function of impact energy. The energy dependence of the line polarization is characterized by theJ quantum numbers of the atomic states involved in the respective transition. An anomalous polarization of all lines originating from the decay ofJ=1 levels has been found and is referred to dominant cascade effects.     

Nd1.85Ce0.15CuO4－δ单晶c-轴方向电阻的低场行为

采用自助熔剂缓冷法成功地生长出了Nd_1.85Ce_{0. 15}CuO_4-δ单晶，其零场下零电阻温度约为21K. 在0—0.5T范围内分别测量了磁场平行和垂直样品表面的电阻转变曲线以及0.5T不同角度下的电阻转变曲线. 结果显示磁场平行和垂直样品表面时的转变温度T_p随磁场的变化均服从H=H₀(1-T_p(h)/T_p(0))²关系. 0.5T 关键词： 1.85Ce_0.15CuO_4-δ单晶')" href="#">Nd_1.85Ce_0.15CuO_4-δ单晶 输运性质