Self-energy correction to momentum-density distribution of positron-electron pairs

Positron two-dimensional angular correlation of annihilation radiation (2D ACAR), i.e., the 2D projection of the electron momentum densities sampled by positron, in Si is employed to verify the prediction of the density functional theory within the local-density approximation (LDA). Carefully conducted test shows that the LDA introduces small but definite discrepancies to the 2D-ACAR anisotropies. Self-energy calculation using the GW method indicates that density-fluctuation contributes anisotropic momentum-density correction and thus improves the agreement between theory and experiment. These results provide valuable annotations to the arguments concerning the accuracy and validity of the LDA and GW schemes.     

Radiative recombination of donor-acceptor pairs in ZnTe

Lifetime of the first excited state of donor-acceptor pairs has been measured in ZnTe as a function of the donor-acceptor distance. The measured lifetime for the radiative recombinations of donor-acceptor pairs agrees well with the calculated one in which the central cell correction for the 1s state of the acceptors is taken into account. It has been found that the lifetime depends on the impurity concentration. The concentration dependence is discussed in connection with the non-exponential decay of the luminescence observed for more distant donor-acceptor pairs.     

Positronium as a probe of sorption states of vapor molecules in polymers

Positron lifetime measurements were performed for two different polymers (low density polyethylene and a polyimide 6FDA-TMPD) during sorption of various vapors (n-hexane, cyclohexane, benzene, acrylic acid, methyl acrylate). The vapor sorption affected the long-lived component (ortho-positronium component) in a systematic way regardless of the kind of vapor, i.e. for the polyethylene both the lifetime and the intensity of the long-lived component were enhanced, while for the polyimide they were decreased significantly. These different effects are interpreted in terms of the different aggregation states, i.e. rubbery for the polyethylene and glassy for the polyimide.     

The CIDNP kinetics in recombination of successive radical pairs

A theory of chemically induced dynamic nuclear polarization (CIDNP) formed in recombination of successive radical pairs (PRs) is developed. The theory is based on that of RP recombination with the spin Hamiltonian instantaneously changing in time. With kinematics approximation it is shown that general relations for CIDNP are fully expressed via the quadratures of Green functions, which characterize the molecular motion of reagents. Analytical formulae for the time dependence of CIDNP both of primary and secondary RPs have been derived in the strong magnetic field approximation (S-T₀ approximation); field dependences of stationary CIDNP effect for some model cases have been analyzed. For long-lived systems the sensitivity of secondary RP CIDNP to the singlet-triplet evolution of primary RP has been demonstrated. It is shown that sometimes the correct analysis of the effect calls for taking into account the reactivity anisotropy.     

A theoretical description of geminal recombination and radiation-pulse-induced electric conduction in polymers in the approximation of probability of survival of ionic pairs

An approximate analytical theory of geminal recombination and geminal radiation-induced electric conduction of polymers is developed. The theory is based on an ion-pair mechanism of radiolysis and the concept of dispersion of electron transport and is valid at fairly strong fields and not overly low temperatures. The proposed approach was used to perform a preliminary analysis of the published data on pulsed-radiation-induced electroconductivity of low-density polyethylene.     

Singlet-triplet splitting of geminate electron-hole pairs in conjugated polymers

The singlet-triplet splitting of geminate polaron pairs in a ladder-type conjugated polymer has been studied by the thermally stimulated luminescence technique. The energy gap separating the singlet and triplet states of the geminate pairs is measured to be in the range of 3-6 meV, depending on the polymer morphology. The results of correlated quantum-chemical calculations on a long ladder-type oligomer are fully consistent with the observed values of the geminate polaron pair singlet-triplet gap. Such low splitting values have important implications for the spin-dependent exciton formation in conjugated polymers.     

Polarizationeffects in electron-electron and positron-electron scattering

The polarization-asymmetries in the cross-sections for electron-electron and positron-electron scattering are investigated numerically in first order perturbation theory in the range from 1 keV to 10 GeV for all angles with regard to polarization-measurements.     

Positronium atom in solids

The angular distribution of annihilation 's in quartz shows that the half-width of the narrow component of the correlation curves depends on the state of aggregation (whether the substance is a single crystal, a powder, or a glass). Before annihilation, the positronium atoms may be captured by defects (vacancies, pores, or regions of reduced electron density); if this is true, the half-width of the narrow component and the long positron lifetime depend on the characteristics of the defects or traps. The sizes of the defects in certain solids (quartz glass; powdered beryllium, magnesium, and aluminum oxides; and polytetrafluoroethylene) are evaluated from the experimental half-width of the narrow component and the long positron lifetime.Translated from Izvestiya VUZ. Fizika, No. 5, pp. 59–64, May, 1971.     

Positronium atom in semiconductors

Evaluation of the lifetimes of positronium is given in relation to binding, dissociation, and annihilation within a wide internal of temperatures. At low temperatures, the overwhelming proportion of positrons becomes bound into atoms of positronium, and from such states is annihilated with the electrons of the crystal. The study of the annihilation of positrons in the semiconductors at low temperatures can give information on the parameters of the positronium atom, and, consequently, also on the exciton states.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 38–40, April, 1974.     

Positronium formation in ice

Applying a new method, based on integral measurements, we demonstrate that there is a broadening of the narrow component in the gamma angular distribution curve when positrons annihilate in ice. This broadening seems to be imputable to the existence of Bloch states and justifies the discordance between theoretical and experimental values of the magnetic quenching.     

Positronium diffusion in crystals

The temperature dependence of the diffusion coefficient is analyzed for the two cases of localized and delocalized positronium in a crystal. The diffusion coefficient for the localized positronium is calculated from the Kubo formula, while that for the free positronium is calculated in the relaxation-time approximation. The temperature dependence of the tunneling diffusion coefficient for positronium is specified by analogy with impuritons in a quantum crystal.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 25–28, July, 1981.     

The theory of diffusion-limited recombination of donor—acceptor pairs

The asymptotics of the quasi-steady kinetics of diffusion-limited recombination of donor-acceptor (DA) pairs has been developed. The theory is based on the probability of DA pair recombination according to the relation w₀ exp [-(r/r_B)], where w₀ is constant, r is the separation between defects and r_B is the half Bohr radius of the more diffuse wavefunction. The reaction rate equation (for the thermal activation mechanism) includes the reaction constant as follows: k = 4πr_B[E_a/kT + ln (w₀r^2_B/D₀) + 1.54 + 2 K₀ (α)], α = 2r₀(w₀/D)$\text{1}\text{2}\text{,}$ where E_a is the activation energy, and K₀, I₀ are the modified Bessel functions. The quasi-steady recombination radius is introduced. The theory developed has been compared with the zone one. The interpretation of the activation energy and frequency factor have been presented for the diffusion model. An extension of the theory developed by taking into account Coulomb interaction between defects has also been presented. The applicability of the theory to the recombination of V_k centers with electronics centers is alkali halides has been shown. It is assumed that the theory is applicable to other centers of hole nature (H, proton, low symmetry exciton i.e. V_k + electron).     

Positronium in molecular substances

The progress of research into the behavior of the positronium in molecular substances in the last several years is reviewed. The Ps atom can be treated as a solute in a liquid. The repulsive exchange force is the dominant force which reacts against the van der Waals attractive force. One of the most useful general relationships found is the one between the pick-off quenching rate and the surface tension of the liquid. The pick-off quenching rate is found, in general, to be an additive property of the functional groups of a molecule. The quenching of theo-Ps atom by an active quenching agent in an inert solvent has been found to be primarily diffusion controlled. Some deviations from the simple Arrhenius equation have been found. For gases, more theoretical work on the collision problems of Ps with atoms or molecules is needed. For amorphous molecular solids, it is likely that the property of pick-off quenching ofo-Ps is similar to that in liquids. However, in crystalline molecular solids, the situation is quite different. A few definite cases have been found where a Ps atom does not form or exist. Further work in this area should be very interesting. The foregoing leads us to believe that positronium or positron annihilation can be useful in the study of fundamental properties of molecular liquids and solids.     

Interfacial region in blends of linear polymers formed in situ

Blends of linear polyurethane and poly(methyl methacrylate) were obtained by the simultaneous curing of the mixture of two monomers. It was shown that the blends obtained in situ are two-phase systems in which two phases enriched in one of the blend components are separated by an intermediate region, the interphase. From the DSC data the compositions of two phases were estimated. It was observed that introduction of a filler leads to the appearance of an additional temperature transition lying between glass transition temperatures of the two phases. The fraction of the interphase was calculated from the calorimetric data. The introduction of a filler increases this fraction. This may be considered as some improving of compatibility of the two components in the presence of a filler.     

Geminate recombination of long-lived electron-hole pairs in doped carbazole-containing amorphous molecular semiconductors

This paper reports an investigation into the features of geminate recombination of long-lived electron-hole pairs in films of poly(N-epoxypropylcarbazole) (PEPC) containing intramolecular charge transfer compounds as centers of photogeneration of charge carriers carried out by measuring the attenuation kinetics of isothermal recombination luminescence over a wide range of temperatures (4.2–300 K) for times t>1 s, along with the kinetics of photoinduced EPR signals. A study is made of how the presence of a potential barrier to the reverse transition of carriers to the recombination center and the initial triplet state of the charged pairs affects the geminate recombination. It is established that the kinetics of isothermal recombintation luminescence attenuation follow the law I(t)∝t ^−m for the times under study, where m takes values from 0.65 to 1.05. The first observations of a nonmonotonic change in m with temperature are reported (m passes through a minimum at a certain temperature), and a mechanism is proposed for recombination of charged pairs in PEPC containing intramolecular charge-transfer compounds as an explanation for this phenomenon. Fiz. Tverd. Tela (St. Petersburg) 39, 1183–1187 (July 1997)     

Positronium formation in Debye plasma

Positronium (Ps) formation during positron-hydrogen collisions in Debye plasma has been studied in detail by using the second-order distorted-wave approximation with the inclusion of the adiabatic dipole polarization potential. Reliable results have been reported at several incident positron energies in the range from the Ps formation threshold to 500 eV for different values of the Debye screening parameter μ. Resonances for S-, P- and D-wave partial Ps formation cross sections appear to exist for 0.03 ≤ μ ≤ 0.3. Interesting structures in the differential cross sections are displayed in the surface plots. It is reported here for the first time that there is a huge probability of Ps formation in dense plasma corresponding to Debye screening parameter μ ≥ 0.3.     

Positronium interactions in atomic physics

The role of positronium in the investigation of fundamental aspects of atomic physics is discussed. The recently developed technique of timed positronium beam production and the characterisation of the beam constituents in the energy range 7–41 eV are outlined. Examples of positronium atoms as probes in atomic scattering interactions are given.