共查询到20条相似文献,搜索用时 15 毫秒
1.
Christopher Glidewell John N. Low Susan A. McWilliam Janet M. S. Skakle James L. Wardell 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(2):o97-o99
In 2‐trifluoromethyl‐4‐nitroaniline, C7H5F3N2O2, (I), the molecules lie across a mirror plane in space group Pnma. The molecules are linked by paired N—H?O hydrogen bonds to form a C(8)[R(6)] chain of rings, pairs of which are linked into a molecular ladder by a single C—H?O hydrogen bond. The isomeric 3‐trifluoromethyl‐4‐nitroaniline, (II), has Z′ = 2 in space group P21/c. Each molecule is linked to four others by N—H?O hydrogen bonds to form sheets built from alternating R(12) and R(32) rings. 相似文献
2.
R. Alan Howie John N. Low James L. Wardell Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(1):o84-o86
The title compound, C7H8N2O4S, exhibits a markedly polarized molecular–electronic structure. The molecules are linked into a chain of edge‐fused (12) rings by two N—H⋯Ozdbnd;S hydrogen bonds [H⋯O = 2.10 and 2.21 Å, N⋯O = 2.900 (2) and 2.878 (2) Å, and N—H⋯O = 152 and 133°]. 相似文献
3.
Debbie Cannon John N. Low Susan A. McWilliam Janet M. S. Skakle James L. Wardell Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(5):600-603
Molecules of the title compound, C7H6N2O5S, are linked into sheets containing R22(10) and R66(42) rings by C—H?O hydrogen bonds [C?O 3.405 (3) and 3.511 (2) Å; C—H?O 159 and 169°], in which both acceptors are in the same nitro group. Comparisons are made with the hydrogen bonding in other nitrobenzenesulfenate esters. 相似文献
4.
Simon J. Garden Cíntia de A. Custdio James L. Wardell John N. Low Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(7):o408-o410
The molecules of 2‐cyano‐4‐iodoacetanilide, C9H7IN2O, are linked by N—H...N and C—H...O hydrogen bonds into chains of alternating R22(12) and R22(14) rings. 相似文献
5.
John N. Low Justo Cobo Rodrigo Abonia Jairo Quiroga Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(3):o194-o195
Molecules of the title compound, C13H16N4O2, are linked by one N—H⋯O hydrogen bond [H⋯O = 2.47 Å, N⋯O = 3.326 (2) Å and N—H⋯O = 166°] and one N—H⋯N hydrogen bond [H⋯N = 2.19 Å, N⋯N = 3.063 (2) Å and N—H⋯N = 173°] into sheets containing alternating (20) and (32) rings, both types of which are centrosymmetric. 相似文献
6.
John N. Low Justo Cobo Celeste Garcìa Manuel Melguizo Manuel Nogueras Adolfo Snchez Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(5):597-599
In the title compound, C10H9N3O5, which was formed by the reaction of 6‐amino‐2‐methoxy‐4(3H)‐pyrimidinone with dimethyl acetylenedicarboxylate, the molecules are linked by N—H?O hydrogen bonds [N?O 2.8974 (15) and 3.0300 (15) Å, and N—H?O 165 and 174°] into planar sheets built from alternating R22(8) and R66(42) rings. 相似文献
7.
Christopher Glidewell John N. Low Manuel Melguizo Antonio Quesada 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(1):o14-o18
In 2‐amino‐4,6‐dimethoxy‐5‐nitropyrimidine, C6H8N4O4, the molecules are linked by one N—H⋯N and one N—H⋯O hydrogen bond to form sheets built from alternating R(8) and R(32) rings. In isomeric 4‐amino‐2,6‐dimethoxy‐5‐nitropyrimidine, C6H8N4O4, which crystallizes with Z′ = 2 in P, the two independent molecules are linked into a dimer by two independent N—H⋯N hydrogen bonds. These dimers are linked into sheets by a combination of two‐centre C—H⋯O and three‐centre C—H⋯(O)2 hydrogen bonds, and the sheets are further linked by two independent aromatic π–π‐stacking interactions to form a three‐dimensional structure. 相似文献
8.
Jorge Trilleras Jairo Quiroga Justo Cobo Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(1):o11-o14
2‐Amino‐4‐chloro‐5‐formyl‐6‐[methyl(2‐methylphenyl)amino]pyrimidine, C13H13ClN4O, (I), and 2‐amino‐4‐chloro‐5‐formyl‐6‐[(2‐methoxyphenyl)methylamino]pyrimidine, C13H13ClN4O2, (II), are isostructural and essentially isomorphous. Although the pyrimidine rings in each compound are planar, the ring‐substituent atoms show significant displacements from this plane, and the bond distances provide evidence for polarization of the electronic structures. In each compound, a combination of N—H...N and N—H...O hydrogen bonds links the molecules into sheets built from centrosymmetric R22(8) and R66(32) rings. The significance of this study lies in its observation of the isostructural nature of (I) and (II), and in the comparison of their crystal and molecular structures with those of analogous compounds. 相似文献
9.
Cyril Odianose Usifoh 《Journal of heterocyclic chemistry》2001,38(3):597-600
Isoquinolinones were brominated using N‐bromosuccinimide in dimethylformamide at room temperature to give 4‐bromo‐3‐substituted isoquinolin‐1‐(2H)‐ones. The reaction of these isoquinolinones with propargyl bromide in the presence of anhydrous potassium carbonate yielded N and O‐alkylated products. 相似文献
10.
《Journal of heterocyclic chemistry》2018,55(5):1232-1239
The functionalized pyridine ring is a ubiquitous moiety in numerous research areas including materials, natural products, as well as agrochemicals and is a strategic synthon for heteroaromatic synthetic method development. Pyridinyl ligand scaffolds are also frequently incorporated into the study of metal complexes for pharmaceutical applications or separation science. Convergent access to advanced synthons is critical to experimentally defining structure activity relationships and improvement of molecular performance in the aforementioned areas. The current work describes an efficient catalyst/ligand combination for accessing 2‐acetyl‐ and 2‐procarbonyl substituted pyridines via Suzuki‐Miyaura cross‐coupling with various organotrifluoroborates. Twenty examples are described with carbonyl and procarbonyl functional groups which afford subsequent access to diversified unsymmetric ketones. Substrate scope and limitation in addition to a scale up experiment are reported. 相似文献
11.
Ferdinand Krner Markus Schürmann Hans Preut Wolfgang Kreiser 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(1):76-77
Esterification of a single diastereomer of 2‐(4‐methylenecyclohex‐2‐enyl)propanol, (II), with (1R,4S)‐(+)‐camphanic acid [(1R,4S)‐4,7,7‐trimethyl‐3‐oxo‐2‐oxabicyclo[2.2.1]heptane‐1‐carboxylic acid] leads to the crystalline title compound, C20H28O4. The relative configuration of the camphanate was determined by X‐ray diffraction analysis. The outcome clarifies the relative and absolute stereochemistry of the naturally occurring bisabolane sesquiterpenes β‐turmerone and β‐sesquiphellandrene, since we have converted (II) into both natural products via a stereospecific route. 相似文献
12.
Braulio Insuasty Yupanqui Caldfas Justo Cobo Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(9):o483-o486
The molecules of the title compound, C20H23N3O6, are almost completely planar, apart from the H atoms bonded to tetrahedral C atoms. A combination of five hydrogen bonds, one of the N—H...O type and two each of the C—H...O and C—H...π(arene) types, links the molecules into complex sheets. 相似文献
13.
Franois Loiseau Reinhard Neier Gaël Labat Helen Stoeckli‐Evans 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(11):o636-o638
In the title compound, C9H12Br2O3, a (tetrahydrofuran‐2‐ylidene)acetate, the double bond has the Z form. In the tetrahydrofuran group, the relative configuration of the Br atom in the 3‐position and the methyl group in the 5‐position is anti. The compound crystallizes with two independent molecules per asymmetric unit and, in the crystal structure, the individual molecules are linked to their symmetry‐equivalent molecules by C—H⋯O hydrogen bonds, so forming centrosymmetric hydrogen‐bonded dimers. 相似文献
14.
A novel two‐dimensional network dibenzo‐18‐crown‐6 (DB18‐C6) complex: [Na (DB18‐C‐6) (H2O)2] [Na (DB18‐C‐6) (SCN)2] has been isolated and characterized by elemental, IR and X‐ray diffraction analysis. The crystal structure belongs to monoclinic, space group P21/c with cell dimensions a = 1.06178(7), b = 1.40243(8), c = 3.03496(19) nm, β = 90.4220(10)°, V = 4.5292(5) nm3, Z=4, Dcalcd =1.351 g/ cm3, F(000) = 1936, R1 = 0.0369, wR2 = 0.0821. The most interesting feature in this structure is that complex cation and complex anion form a two‐dimensional network via τ‐τ stacking interactions, hydrogen bonds and electrostatic interactions. 相似文献
15.
Chun‐Hua Diao Zhi Fan Xin Chen 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(12):o717-o719
In the title compound, C21H18ClN3O5S·C2H4O2, a combination of O—H...O, N—H...O, C—H...O and C—H...N hydrogen bonds links the components into a complex network containing alternating R44(42), R55(33) and R66(40) rings. 相似文献
16.
Stanisaw Boryczka Thomas Steiner 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(9):1139-1141
In 3‐methylthio‐4‐(propargylthio)quinolinium chloride monohydrate, C13H12NS2+·Cl?·H2O, and 3‐methylthio‐4‐(propargylthio)quinolinium trichloroacetate, C13H12NS2+·C2Cl3O2?, the terminal alkyne group forms C[triple‐bond]C—H?O hydrogen bonds of favourable geometry. The conformation of the flexible propargylthio group is different in the two structures. 相似文献
17.
Fabio Zuluaga Carlos Grande Justo Cobo Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2010,66(12):o627-o630
In the title compound, C17H32O2S3, the dodecyl chain and the trithiocarbonate unit adopt a nearly planar all‐trans conformation, while the carboxyl group is synclinal to this chain direction. The molecules are linked by pairs of inversion‐related O—H...O hydrogen bonds to form centrosymmetric dimers of R22(8) type, and dimers related by translation are linked by C—H...O hydrogen bonds to form a chain of edge‐fused rings, or a molecular ladder, containing alternating R22(8) and R44(20) rings. 相似文献
18.
Ricaurte Rodríguez Justo Cobo Manuel Nogueras John N. Low Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(9):o507-o509
In the title compound, C10H19NO6, both rings adopt almost perfect chair conformations and their mutual orientation is influenced by an intramolecular O—H...N hydrogen bond. The molecules are linked by three independent O—H...O hydrogen bonds into sheets containing equal numbers of R22(10) and R44(24) rings. 相似文献
19.
Yi He Bei Chuan Zhou Hui‐Zhong Kou Ming Xiong Ru‐Ji Wang Yadong Li 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(9):m478-m480
Using caprolactam as a ligand, the novel title cyano‐bridged yttrium(III)–ferricyanide complex, [Y(caprolactam)2(H2O)4Fe(CN)6] or [FeY(CN)6(C6H11NO)2(H2O)4], has been synthesized and structurally characterized. The Y atom is seven‐coordinate and has approximately pentagonal–bipyramidal stereochemistry, with water molecules occupying apical positions. Of the five ligands in equatorial positions, one is the N‐bound bridging cyano group, and flanking this are two O‐bound caprolactam moieties, which are markedly inclined towards the bridged ferricyanide moiety such that they partially envelop it. Water molecules occupy the remaining two equatorial positions. The Y—N—C—Fe—C—N sequence of atoms lies on a crystallographic twofold axis and is therefore perfectly linear, which has not been observed previously in cyano‐bridged bimetallic complexes. 相似文献
20.
The synthesis and characterization of 2‐i‐PrC6H4PCl2 ( 3 ), 2‐t‐BuC6H4PCl2 ( 4 ), 2‐i‐PrC6H4PH2 ( 5 ), 2‐t‐BuC6H4PH2 ( 6 ), 2‐i‐PrC6H4P(SiMe3)2 ( 7 ), and 2‐t‐BuC6H4P(SiMe3)2 ( 8 ) are described. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:265–270, 2010; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20606 相似文献