共查询到20条相似文献,搜索用时 703 毫秒
1.
Ralph Sthler Wolfgang Bensch 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(11):m537-m538
Turquoise crystals of the title salt, propylammonium di‐μ‐thio‐1:2κ4S‐dithio‐2κ2S‐tris(2‐aminoethyl)amine‐1κ4N‐antimony(V)nickel(II), (C3H10N)[NiSbS4(C6H18N4)] or [PAH][Ni(tren)SbS4] [where tren is tris(2‐aminoethyl)amine and PA is propylamine], were synthesized under solvothermal conditions by reacting [Ni(tren)2]Cl2, Sb and S in a solution of PA. The NiII ion is octahedrally surrounded by four N atoms of the tetradentate tren molecule and by two S atoms of the tetrahedral [SbVS4]3? anion, thus forming the anionic [Ni(tren)SbS4]? part of the compound. Charge balance is achieved through the PAH+ cation. An extended intermolecular hydrogen‐bonding network is observed between the anion and the cation. 相似文献
2.
Xiaopeng Hu Xiaolong Feng Jiwen Cai Liangnian Ji 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(9):e388-e389
The title compound, [CoCl(tren)(dmso)](ClO4)2 [tren is tris‐(2‐aminoethyl)amine, C6H18N4; dmso is dimethyl sulfoxide, C2H6OS], is the first crystal structure reported with dmso coordinated to CoIII. It crystallizes with two independent molecules in the asymmetric unit. A localized non‐crystallographic inversion centre is observed between the two cations. 相似文献
3.
Juraj Kuchr Juraj ernk Werner Massa 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(8):m418-m420
The title compound, bis[diaquabis(ethylenediamine‐κ2N,N′)copper(II)] hexacyanoiron(II) tetrahydrate, [Cu(C2H8N2)2(H2O)1.935]2[Fe(CN)6]·4H2O, was crystallized from an aqueous reaction mixture initially containing CuSO4, K3[Fe(CN)6] and ethylenediamine (en) in a 3:2:6 molar ratio. Its structure is ionic and is built up of two crystallographically different cations, viz. [Cu(en)2(H2O)2]2+ and [Cu(en)2(H2O)1.87]2+, there being a deficiency of aqua ligands in the latter, [Fe(CN)6]4− anions and disordered solvent water molecules. All the metal atoms lie on centres of inversion. The Cu atom is octahedrally coordinated by two chelate‐bonded en molecules [mean Cu—N = 2.016 (2) Å] in the equatorial plane, and by axial aqua ligands, showing very long distances due to the Jahn–Teller effect [mean Cu—O = 2.611 (2) Å]. In one of the cations, significant underoccupation of the O‐atom site is observed, correlated with the appearance of a non‐coordinated water molecule. This is interpreted as the partial contribution of a hydrate isomer. The [Fe(CN)6]4− anions form quite regular octahedra, with a mean Fe—C distance of 1.913 (2) Å. The dominant intermolecular interactions are cation–anion O—H⋯N hydrogen bonds and these interactions form layers parallel to (001). 相似文献
4.
Il Yoon Yong Woon Shin Jineun Kim Ki‐Min Park Sung Bae Park Shim Sung Lee 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(3):m165-m166
The synthesis and crystal structure of {tris[2‐(benzylamino)ethyl]amine‐κ4N}silver(I) perchlorate, [Ag(C27H36N4)]ClO4 or [Ag(bz3tren)]ClO4 {bz3tren is tris[2‐(benzylamino)ethyl]amine or N,N′,N′′‐tribenzyltris(2‐aminoethyl)amine} are reported. The Ag atom is coordinated to four N atoms of the tren unit and is located 0.604 (3) Å out of the trigonal plane described by the three secondary amine N atoms, away from the bridgehead N atom. Edge‐to‐face π–π interactions between the aromatic end groups, and weak interactions between Ag and arene, allow the formation of a pseudo‐cage complex. 相似文献
5.
Hong‐Xi Li Yong Zang Mei‐Ling Cheng Jian‐Ping Lang 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(2):m74-m77
The Zn atom in dichloro[(3,5‐dimethyl‐1H‐pyrazol‐1‐yl)methane]zinc(II), [ZnCl2(C11H16N4)], (I), is tetrahedrally coordinated by two N atoms from one bis(3,5‐dimethylpyrazolyl)methane ligand and two terminal Cl atoms. The molecule has no crystallographic symmetry. One H atom of the CH2 group of the bis(3,5‐dimethylpyrazolyl)methane ligand interacts with a Cl atom of an adjacent molecule to yield intermolecular C—H⋯Cl contacts, thereby forming a one‐dimensional zigzag chain extending along the b axis. On the other hand, in di‐μ‐chloro‐bis{chloro[(3,5‐dimethyl‐1H‐pyrazol‐1‐yl)methane]cadmium(II)}, [Cd2Cl4(C11H16N4)2], (II), each of the two crystallographically equivalent Cd atoms is pentacoordinated by two N atoms from one bis(3,5‐dimethylpyrazolyl)methane ligand, and by one terminal and two bridging Cl− anions. The molecule has a crystallographic centre of symmetry located at the mid‐point of the Cd⋯Cd line. One H atom of the CH2 group of the bis(3,5‐dimethylpyrazolyl)methane ligand interacts with a Cl atom of an adjacent molecule to produce pairwise intermolecular C—H⋯Cl contacts, thereby affording chains of molecules running along the c axis. 相似文献
6.
Jong‐Ha Choi Takayoshi Suzuki Md. Abdus Subhan Sumio Kaizaki Yu Chul Park 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(7):m409-m412
The crystal structure of the title compound, (C2H10N2)[Cr(C4H9N2O2)2]2Cl4·2H2O, has been determined by single‐crystal X‐ray diffraction studies at 293 and 100 K. The analyses demonstrated that the crystal consists of ethylenediammonium dications (which lie about inversion centres), bis[N‐(2‐aminoethyl)glycinato]chromium(III) monocations, Cl? anions and hydrate water molecules, in a molecular ratio of 1:2:4:2. The complex cation unit has a slightly distorted octahedrally coordinated Cr atom, with two Cr—O and four Cr—N bonds in the ranges 1.951 (1)–1.953 (1) and 2.054 (1)–2.089 (2) Å, respectively, at 293 K. The geometry of the bis[N‐(2‐aminoethyl)glycinato]chromium(III) moiety was found to be trans,cis,cis with respect to the carboxylate O atom and the primary and secondary amine N atoms. The two analyses, at 293 and 100 K, exhibited no remarkable structural differences, although the colour of the crystals did differ, being red at 293 K and orange at 100 K. 相似文献
7.
Gerard A. van Albada Ilpo Mutikainen Urho Turpeinen Jan Reedijk 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(3):m179-m181
The title mononuclear complex, [Cu(CO3)(C8H7N5)(H2O)]·2H2O, was obtained by fixation of CO2 by a mixture of copper(II) tetrafluoroborate and the ligand bis(pyrimidin‐2‐yl)amine in ethanol/water. The CuII ion of the complex has a distorted square‐pyramidal environment, with a basal plane formed by two N atoms of the ligand and two chelating O atoms of the carbonate group, while the apical position is occupied by the O atom of the coordinating water molecule. In the solid state, hydrogen‐bonding interactions are dominant, the most unusual being the Watson–Crick‐type coplanar ligand pairing through two N—H?N bonds. Lattice water molecules also participate in hydrogen bonding. 相似文献
8.
M. Ramos Silva J. A. Paixão A. Matos Beja L. Alte da Veiga 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(1):7-8
The title compound, [CuCl2(C3H7N3O2)2], is a new copper(II) complex with glycocyamine [(diaminomethyleneamino)acetic acid], the first complex ever reported with this organic molecule. It is composed of discrete centrosymmetric coordinated CuII monomers, the Cu atoms being located at inversion centers. Each metal ion is square-planar coordinated by two Cl atoms and two glycocyamine O atoms. The coordinating glycocyamine molecule exists as a zwitterion, the H atom from the carboxyl group being transferred to the guanidinium group. A three-dimensional network of hydrogen bonds links the monomers and stabilizes the structure. 相似文献
9.
Alexander J. Blake Lorenzo Tei Claire Wilson Martin Schrder 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(2):m43-m45
The asymmetric unit of {[4,7‐bis(2‐aminoethyl)‐1,4,7‐triazacyclononan‐1‐yl]acetato}zinc(II) triaqua{μ‐[4,7‐bis(2‐aminoethyl)‐1,4,7‐triazacyclononan‐1‐yl]acetato}lithium(I)zinc(II) chloride diperchlorate, [Zn(C12H26N5O2)][LiZn(C12H26N5O2)(H2O)3]Cl(ClO4)2, obtained from the reaction between the lithium salt of 4,7‐bis(2‐aminoethyl)‐1,4,7‐triazacyclononane‐1‐acetate and Zn(ClO4)2, contains two ZnII complexes in which each ZnII ion is six‐coordinated by five N‐atom donors and one O‐atom donor from the ligand. One carboxylate O‐atom donor is not involved in coordination to a ZnII atom, but coordinates to an Li+ ion, the tetrahedral geometry of Li+ being completed by three water molecules. The two complexes are linked via a hydrogen bond between a primary amine N—H group and the carboxylate‐O atom not involved in coordination to a metal. 相似文献
10.
Andrey I. Buvaylo Nikolay M. Dudarenko Igor O. Fritsky Jolanta
witek‐Kozowska 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(8):m331-m333
The title compound, [Ni(C2H8N2)3][Ni(C3HN3O2)2]·H2O, appears to be a modular associate consisting of two complex counter‐ions, containing bivalent nickel as the central atom in both cases, and a solvent water molecule. The NiII ion in the complex cation lies on the C2 crystallographic axis. Its coordination environment is formed by six N atoms of three ethylenediamine (en) molecules, representing a distorted octahedral geometry. The NiII ion in the complex anion occupies a position at the center of inversion. It exhibits a distorted square‐planar coordination geometry formed by four N atoms belonging to the deprotonated oxidoimine and amide groups of the two doubly charged 2‐cyano‐2‐(oxidoimino)acetamidate anions, situated in trans positions with respect to each other. In the crystal packing, the complex anions are linked by water molecules via hydrogen bonds between the amide O atoms and water H atoms, forming chains translated along the a direction. The [Ni(en)3]2+ cations fill empty spaces between the translational chains, connecting them by hydrogen bonds between the oxime and amide O atoms of the anions and the amine H atoms of the cations, forming layers along the ac plane. The water molecules provide connection between layers through N atoms of the cations, thus forming a three‐dimensional modular structure. 相似文献
11.
Juraj ernk Khalil A. Abboud 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(3):m167-m170
Partial reduction of the CuII ions in the aqueous system CuII–en–[Ni(CN)4]2? (1/1/1) (en is 1,2‐diaminoethane) yields a novel heterobimetallic mixed‐valence compound, poly[[aquabis(1,2‐diaminoethane)copper(II)] [hexa‐μ‐cyano‐tetracyanobis(1,2‐diaminoethane)tricopper(I,II)dinickel(II)] dihydrate], [Cu(C2H8N2)2(H2O)][Ni2Cu3(CN)10(C2H8N2)2]·2H2O or [Cu(en)2(H2O)][Cu(en)2Ni2Cu2(CN)10]·2H2O. The structure is formed by a negatively charged two‐dimensional array of the cyano complex [Cu(en)2Ni2Cu2(CN)10]n2n?, [Cu(en)2(H2O)]2+ complex cations and water molecules of crystallization. These last are involved in a complicated hydrogen‐bonding system. The cyano groups act as terminal, μ2‐bridging or μ3‐bridging ligands. 相似文献
12.
Michel Fleck Ladislav Bohatý 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(9):m412-m416
In catena‐poly[[[diaquanickel(II)]‐di‐μ‐glycine] dibromide], {[Ni(C2H5NO2)2(H2O)2]Br2}n, (I), the Ni atom is located on an inversion centre. In catena‐poly[[[tetraaquamagnesium(II)]‐μ‐glycine] dichloride], {[Mg(C2H5NO2)(H2O)4]Cl2}n, (II), the Mg atom and the non‐H atoms of the glycine molecule are located on a mirror plane. All other atoms are located on general positions. The atomic arrangements of both compounds are characterized by [MO6] octahedra (M = Ni or Mg) connected by glycine molecules, with the halogenide ions in the interstices. In (I), four of the coordinating O atoms are from glycine and two are from water molecules, building layers of octahedra and organic molecules. In (II), two of the coordinating O atoms are from glycine and four are from water molecules. The octahedra and organic molecules form chains. 相似文献
13.
Neil F. Curtis Rebekah Pawley Ward T. Robinson 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(8):m352-m354
The title compound, [NiCl(C12H32N6)(H2O)]Cl3·3H2O, has the bis(diamine)‐substituted cyclic tetraamine in a planar coordination to triplet ground‐state NiII [average Ni—N = 2.068 (3) Å], with a chloride ion [Ni—Cl = 2.4520 (5) Å] and a water molecule [Ni—O = 2.177 (2) Å] coordinated in the axial sites. The amine substituents are protonated and equatorially oriented. The amine groups, ammonium groups, water molecules and chloride ions are linked by an extensive hydrogen‐bonding network. 相似文献
14.
Kristin Kirschbaum Olaf Conrad Dean M. Giolando 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(12):e541-e541
Amido complexes of titanium are useful reagents in a variety of syntheses and as precursors for chemical vapour deposition of TiN. The title compound, dichlorobis(dimethylamido)(dimethylamine)titanium(IV), [TiCl2(C2H6N)2(C2H7N)], crystallizes with one molecule in the asymmetric unit. The neutral complex shows an unusual fivefold coordination of the titanium centre with a distorted trigonal–bipyramidal geometry and the dimethylamine molecule occupying an axial position. 相似文献
15.
Lars Engelke Christian Näther Phillipp Leisner Wolfgang Bensch Prof. Dr. 《无机化学与普通化学杂志》2008,634(15):2959-2965
The three new thioantimonates(V) [Ni(chxn)3]3(SbS4)2·4H2O ( I ), [Co(chxn)3]3(SbS4)2·4H2O ( II ) (chxn is trans‐1,2‐diaminocyclohexane) and [Co(dien)2][Co(tren)SbS4]2·4H2O ( III ) (dien is diethylenetriamine and tren is tris(2‐aminoethyl)amine) were synthesized under solvothermal conditions. Compounds I and II are isostructural crystallizing in space group C2/c. The structures are composed of isolated [M(chxn)3]2+ complexes (M = Ni, Co), [SbS4]3? anions and crystal water molecules. Short S···N/S···O/O···O separations indicate hydrogen bonding interactions between the different constituents. Compound III crystallizes in space group and is composed of [Co(dien)2]2+ and [Co(tren)SbS4]? anions and crystal water molecules. In the cationic complex the Co2+ ion is in an octahedral environment of two dien ligands whereas in [Co(tren)SbS4]? the Co2+ ion is in a trigonal bipyramidal coordination of four N atoms of tren and one S atom of the [SbS4]3? anion, i.e., two different coordination polyhedra around Co2+ coexist in this compound. Like in the former compounds an extended hydrogen bonding network connects the complexes and the water molecules into a three‐dimensional network. 相似文献
16.
Graham King Philip Coppens Milan Gembicky 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(7):m329-m332
Two new salts of the cation [CuI(dmp)2]+ (dmp is 2,9‐dimethyl‐1,10‐phenanthroline, C14H12N2), namely bis[bis(2,9‐dimethyl‐1,10‐phenanthroline‐κ2N,N′)copper(I)] bis(hexafluorophosphate) hemi[bis(4‐pyridylmethylidene)hydrazine] acetonitrile solvate, [Cu(C14H12N2)2]2(PF6)2·0.5C12H10N4·C2H3N or [Cu(dmp)2]2(PF6)2·0.5(bpmh)·CH3CN [bpmh is bis(4‐pyridylmethylidene)hydrazine, C12H10N4], (I), and bis(2,9‐dimethyl‐1,10‐phenanthroline‐κ2N,N′)copper(I) dicyanamide, [Cu(C14H12N2)2](C2N3) or [Cu(dmp)2][N(CN)2], (II), are reported. The Cu—N bond lengths and the distortion from idealized tetrahedral geometry of the dmp ligands are discussed and compared with related compounds. The bpmh molecule in (I) is π–π stacked with a dmp ligand at a distance of 3.4 Å, rather than coordinated to the metal atom. The molecule lies across an inversion center in the crystal. In (II), the normally coordinated dicyanamide molecule is present as an uncoordinated counter‐ion. 相似文献
17.
A. Gueddi B. Mernari M. Giorgi M. Pierrot 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(10):e426-e428
The reaction of the diazine ligand 3,5‐bis(2‐pyridinyl)‐1,3,4‐oxadiazole (pod, C12H8N4O), with Cu(CF3SO3)2 or Ni(ClO4)2 afforded the title complexes diaquabis[3,5‐bis(2‐pyridinyl)‐1,3,4‐oxadiazole‐N2,N3]copper(II) bis(trifluoromethanesulfonate), [Cu(pod)2(H2O)2](CF3SO3)2, and diaquabis[3,5‐bis(2‐pyridinyl)‐1,3,4‐oxadiazole‐N2,N3]nickel(II) diperchlorate, [Ni(pod)2(H2O)2](ClO4)2. Both complexes present a crystallographically centrosymmetric mononuclear cation structure which consists of a six‐coordinated CuII or NiII ion with two pod molecules acting as bidentate ligands and two axially coordinated water molecules. 相似文献
18.
Natalia V. Kuratieva Marina I. Naumova Dmitry Yu. Naumov 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(9):i129-i131
The title compounds, hexaaquacobalt(II) bis(hypophosphite), [Co(H2O)6](H2PO2)2, and hexaaquacobalt(II)/nickel(II) bis(hypophosphite), [Co0.5Ni0.5(H2O)6](H2PO2)2, are shown to adopt the same structure as hexaaquamagnesium(II) bis(hypophosphite). The packing of the Co(Ni) and P atoms is the same as in the structure of CaF2. The CoII(NiII) atoms have a pseudo‐face‐centred cubic cell, with a = b~ 10.3 Å, and the P atoms occupy the tetrahedral cavities. The central metal cation has a slightly distorted octahedral coordination sphere. The geometry of the hypophosphite anion in the structure is very close to ideal, with point symmetry mm2. Each O atom of the hypophosphite anion is hydrogen bonded to three water molecules from different cation complexes, and each H atom of the hypophosphite anion is surrounded by three water molecules from further different cation complexes. 相似文献
19.
María Gabriela Ballinas‐Lpez Itzia I. Padilla‐Martínez Francisco J. Martínez‐Martínez Herbert Hpfl Efrn V. García‐Bez 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(4):m132-m135
The isomorphous complexes bis[hydrotris(pyrazolyl)borato]magnesium(II) chloroform disolvate, [Mg(C9H10BN6)2]·2CHCl3, and bis[hydrotris(pyrazolyl)borato]calcium(II) chloroform disolvate, [Ca(C9H10BN6)2]·2CHCl3, crystallize in the cubic space group Pa with Z = 4. The metal atoms occupy sites of symmetry, and their coordination is very similar to that found for the unsolvated Mg[HB(Pz)3]2 and Ca[HB(Pz)3]2 complexes (Pz is pyrazole). The inclusion of chloroform molecules on threefold rotation axes not only leads to high‐symmetry crystal structures but also plays an important role in stabilizing the three‐dimensional supramolecular architecture through facial Pz⋯Cl⋯Pz interactions. 相似文献
20.
Liang Shen Zhi Min Jing 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(12):m591-m592
The title complex, {[Ni(C2H8N2)3][Na(NCS)3(H2O)]}n, consists of discrete [Ni(en)3]2+ dications (en is ethylenediamine) and polymeric [(H2O)0.5Na(NCS)3(H2O)0.5]n2n? anions. The compound crystallizes in space group Pc1. The NiII atom lies on a threefold axis and has a distorted octahedral coordination geometry. The Na+ cation also lies on a site with imposed crystallographic threefold symmetry and is coordinated by the thiocyanate N atoms (the thiocyanates are in general positions), by one water molecule with crystallographically imposed 32 symmetry and by a second water molecule with crystallographically imposed symmetry. The unique Na atom thus has trigonal–bipyramidal coordination. The O atoms of the water molecules bridge the Na+ cations to form one‐dimensional polymeric chains in the crystal structure. The [Ni(en)3]2+ dications are distributed around and between the chains and are linked to them via N—H?S hydrogen bonds. 相似文献