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1.
Orhan Büyükgüngr Mustafa Odabaolu idem Albayrak Peter Lnnecke 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(7):o470-o472
The title complex, 2C5H7N2+·C4H2O42−·C4H4O4, contains cyclic eight‐membered hydrogen‐bonded rings involving 2‐aminopyridinium and fumarate ions. The fumaric acid molecules and fumarate ions lie on inversion centers and are linked into zigzag chains by O—H⋯O hydrogen bonds. The dihedral angle between the pyridinium ring and the hydrogen‐bonded fumarate ion is 7.60 (4)°. The fumarate anion is linked to the pyridinium cations by intermolecular N—H⋯O hydrogen bonds. The heterocycle is fully protonated, thus enabling amine–imine tautomerization. 相似文献
2.
Jaromír Marek Dagmar Hulov Jií Dostl Radek Marek 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(10):o583-o585
The title compound [systematic name: 9,10‐dimethoxy‐2,3‐methylenedioxy‐5,6‐dihydrodibenzo[a,g]quinolizinium formate–succinic acid (1/1)], C20H18NO4+·CHO2−·C4H6O4, contains centrosymmetric pairs of almost planar berberine cations, and hydrogen‐bonded (C4H6O4⋯HCOO−)2 rings of succinic acid with formate anions, bonded by O—H⋯O hydrogen bonds with O⋯O distances of 2.4886 (15) and 2.5652 (16) Å. Pairs of cations and molecules of succinic acid are connected by non‐conventional weak C—H⋯O hydrogen bonds, with C⋯O distances of 3.082 (2) and 3.178 (2) Å. 相似文献
3.
Anwar Usman Suchada Chantrapromma Hoong‐Kun Fun Bo‐Long Poh Chatchanok Karalai 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(3):o136-o138
In the title 1/2/2 adduct, C4H12N22+·2C6H3N2O5?·2H2O, the dication lies on a crystallographic inversion centre and the asymmetric unit also has one anion and one water molecule in general positions. The 2,4‐dinitrophenolate anions and the water molecules are linked by two O—H?O and two C—H?O hydrogen bonds to form molecular ribbons, which extend along the b direction. The piperazine dication acts as a donor for bifurcated N—H?O hydrogen bonds with the phenolate O atom and with the O atom of the o‐nitro group. Six symmetry‐related molecular ribbons are linked to a piperazine dication by N—H?O and C—H?O hydrogen bonds. 相似文献
4.
Suchada Chantrapromma Anwar Usman Hoong‐Kun Fun Bo‐Long Poh Chatchanok Karalai 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(9):o589-o590
In the title ternary complex, C10H9N2+·C7H3N2O6?·C7H4N2O6, the pyridinium cation adopts the role of the donor in an intermolecular N—H?O hydrogen‐bonding interaction with the carboxylate group of the 3,5‐dinitrobenzoate anion. The molecules of the ternary complex form molecular ribbons perpendicular to the b direction, which are stabilized by one N—H?O, one O—H?O and five C—H?O intermolecular hydrogen bonds. The ribbons are further interconnected by three intermolecular C—H?O hydrogen bonds into a three‐dimensional network. 相似文献
5.
Suchada Chantrapromma Anwar Usman Hoong‐Kun Fun Bo‐Long Poh Chatchanok Karalai 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(11):o675-o677
In the title adduct, 1,3,5,7‐tetraazatricyclo[3.3.1.13,7]decane–4‐nitrobenzene‐1,2‐diol–water (1/2/1), C6H12N4·2C6H5NO4·H2O, the hexamethylenetetramine molecule acts as an acceptor of intermolecular O—H?N hydrogen‐bonding interactions from the water molecule and the hydroxy groups of one of the two symmetry‐independent 4‐nitrocatechol molecules. The structure is built from molecular layers which are stabilized by three intermolecular O—H?O, two intermolecular O—H?N and four intermolecular C—H?O hydrogen bonds. The layers are further interconnected by one additional intermolecular O—H?N and two intermolecular C—H?O hydrogen bonds. 相似文献
6.
Cui Rong Sun Zhi Min Jin 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(10):o600-o601
In the title complex, 1,4‐diazoniabicyclo[2.2.2]octane bis(hydrogen maleate), C6H14N22+·2C4H3O4?, the C4H3O4? and C6H14N22+ ions, derived from maleic acid and 1,4‐diazabicyclo[2.2.2]octane, respectively, are disordered across a mirror plane in space group Cmc21, and they are linked by two nearly linear N—H?O hydrogen bonds, with N?O distances of 2.662 (3) and 2.614 (4) Å, and N—H?O angles of 173°. The crystal structure consists of sheets with reticulations of 3.3792 (4) Å in stratum and 7.3892 (8) Å in width. The sheets are linked by C—H?O hydrogen bonds. 相似文献
7.
Krishnan Ravikumar Balasubramanian Sridhar 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(8):o478-o482
Moxifloxacin, a novel fluoroquinolone with a broad spectrum of antibacterial activity, is available as the solvated monohydrochloride salt 7‐[(S,S)‐2‐aza‐8‐azoniabicyclo[4.3.0]non‐8‐yl]‐1‐cyclopropyl‐6‐fluoro‐8‐methoxy‐4‐oxo‐1,4‐dihydroquinoline‐3‐carboxylic acid chloride–water–methanol (2/1/1), C21H25FN3O4+·Cl−·0.5H2O·0.5CH3OH. The asymmetric unit contains two cations, two chloride ions, a molecule of water and one methanol molecule. The two cations adopt conformations that differ by an almost 180° rotation with respect to the piperidinopyrrolidine side chain. The cyclopropyl ring and the methoxy group are not coplanar with the quinoline ring system. The carboxylic acid function, the protonated terminal piperidyl N atom, the water molecule, the chloride ion and the methanol molecule participate in O—H⋯O, O—H⋯Cl, N—H⋯O and N—H⋯Cl hydrogen bonding, linking the molecules into extended two‐dimensional networks. 相似文献
8.
Raymond C. Bott Graham Smith Urs D. Wermuth 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(12):1505-1506
The crystal structure determination of the molecular proton‐transfer adduct of Kemp's triacid (cis‐cis‐1,3,5‐trimethylcyclohexane‐1,3,5‐tricarboxylic acid, KTA) with 2‐aminopyridine (2‐APY), namely 2‐aminopyridinium 3,5‐dicarboxy‐1,3,5‐trimethylcyclohexanecarboxylate, 2‐APY+·KTA? or C5H7N2+·C12H17O6?, has revealed a centrosymmetric hydrogen‐bonded cyclic KTA homodimer repeating unit [O?O 2.524 (4) Å] linked into a polymer structure through the pyridinium and amino groups of the 2‐APY molecule [O?N 2.736 (4), 2.989 (4) and 2.999 (4) Å]. 相似文献
9.
Takeo Fukunaga Setsuo Kashino Hiroyuki Ishida 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(10):o718-o722
Tartronic acid forms a hydrogen‐bonded complex, C5H5NO·C3H4O5, (I), with 2‐pyridone, while it forms acid salts, namely 3‐hydroxypyridinium hydrogen tartronate, (II), and 4‐hydroxypyridinium hydrogen tartronate, (III), both C5H6NO+·C3H3O5−, with 3‐hydroxypyridine and 4‐hydroxypyridine, respectively. In (I), the pyridone molecules and the acid molecules form R(8) and R(10) hydrogen‐bonded rings, respectively, around the inversion centres. In (II) and (III), the cations and anions are linked by N—H⋯O and O—H⋯O hydrogen bonds to form a hydrogen‐bonded chain. In each of (I), (II) and (III), an intermolecular hydrogen bond is formed between a carboxyl group and the hydroxyl group attached to the central C atom, and in (I), the hydroxyl group participates in an intramolecular hydrogen bond with a carbonyl group. No intermolecular hydrogen bond is formed between the carboxyl groups in (I), or between the carboxyl and carboxylate groups in (II) and (III). 相似文献
10.
Hiroyuki Hosomi Shigeru Ohba Yoshikatsu Ito 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(11):e511-e511
In the title adduct, C10H6O8·2C9H9NO, benzene‐1,2,4,5‐tetracarboxylic acid has a crystallographic twofold axis parallel to b and forms a flat zigzag chain along c linked by O— H?O cyclic hydrogen bonds with cinnamamide molecules. 相似文献
11.
Hiroyuki Ishida Setsuo Kashino 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(5):e202-e204
In the crystals of two title salts of chloranilic acid (2,5‐dichloro‐3,6‐dihydroxy‐p‐benzoquinone), namely ethylammonium chloranilate, C2H8N+·C6HCl2O4?, (I), and diethylammonium chloranilate, C4H12N+·C6HCl2O4?, (II), the chloranilate ions are present as a hydrogen‐bonded dimer which has an inversion center. The ethylammonium and diethylammonium ions link the dimers through N—H?O hydrogen bonds, forming a three‐dimensional hydrogen‐bond network in (I) and a one‐dimensional chain in (II). 相似文献
12.
Colin J. Burchell George Ferguson Alan J. Lough Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(9):1126-1128
The 1:1 adduct of 1,4‐diazabicyclo[2.2.2]octane and 5‐hydroxyisophthalic acid is a salt, [H(C6H12N2)]+·[HOC6H3(COOH)COO]? or C6H13N2+·C8H5O5?. The ions are linked by three types of hydrogen bond, i.e. N—H?O, O—H?O and O—H?N, into continuous two‐dimensional (4,4) nets built from a single type of R(58) ring. Six independent sheets of this type make up the structure and these are interwoven in sets of three. 相似文献
13.
Christophe Hardouin Eric Doris Bernard Rousseau Charles Mioskowski Martine Nierlich 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(2):225-226
The crystal structure of a methanol–water solvate ofleurosine methiodide, (leurosine‐CH3)+I?·3CH3OH·2H2O (C47H59IN4O9·3CH3OH·2H2O), is described. The piperidine ring of the upper part of the molecule adopts a sofa conformation. An intramolecular hydrogen bond between the tertiary N and the hydroxyl group of the vindoline moiety of the molecule is present. 相似文献
14.
Selena L. Staun Allen G. Oliver 《Acta Crystallographica. Section C, Structural Chemistry》2012,68(2):o84-o87
4‐Hydroxypyridine and terephthalic acid cocrystallize as a hydrate, 4‐pyridone–terephthalic acid–water (2/1/2), 2C5H5NO·C8H6O4·2H2O, from a methanol–water solution. The molecules form a two‐dimensional hydrogen‐bonded network resulting in sheets of hydrogen‐bonded molecules that lie parallel to the (10) plane. In contrast, 3‐hydroxypyridine and terephthalic acid form the salt bis(3‐hydroxypyridinium) terephthalate, 2C5H6NO+·C8H4O42−, giving rise to two‐dimensional hydrogen‐bonded sheets extending through the lattice parallel to the (10) plane. 相似文献
15.
Katharine F. Bowes George Ferguson Christopher Glidewell Alan J. Lough 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(8):o467-o469
The title compound is a hydrated salt, 1,4‐diazoniabicyclo[2.2.2]octane–N‐[(hydroxyphosphinato)methyl]iminiodiacetate–water (1/1/1.5), C6H14N22+·C5H8NO7P2?·1.5H2O, in which one of the water molecules lies across a twofold rotation axis in space group P2/n. The ionic components are linked into sheets by a combination of a three‐centre N—H?(O)2 hydrogen bond and two‐centre O—H?O and N—H?O hydrogen bonds, and these sheets are pairwise linked by the water molecules into bilayers, by means of further O—H?O hydrogen bonds. 相似文献
16.
Alexander S. Lyakhov Ludmila S. Ivashkevich Vladimir L. Survilo Tatjana V. Trukhachova 《Acta Crystallographica. Section C, Structural Chemistry》2012,68(1):o33-o36
Crystals of bis(2‐ethyl‐3‐hydroxy‐6‐methylpyridinium) succinate–succinic acid (1/1), C8H12NO+·0.5C4H4O42−·0.5C4H6O4, (I), and 2‐ethyl‐3‐hydroxy‐6‐methylpyridinium hydrogen succinate, C8H12NO+·C4H5O4−, (II), were obtained by reaction of 2‐ethyl‐6‐methylpyridin‐3‐ol with succinic acid. The succinate anion and succinic acid molecule in (I) are located about centres of inversion. Intermolecular O—H...O, N—H...O and C—H...O hydrogen bonds are responsible for the formation of a three‐dimensional network in the crystal structure of (I) and a two‐dimensional network in the crystal structure of (II). Both structures are additionally stabilized by π–π interactions between symmetry‐related pyridine rings, forming a rod‐like cationic arrangement for (I) and cationic dimers for (II). 相似文献
17.
Hui‐Zhong Kou Song Gao Ru‐Ji Wang 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(6):m325-m326
A cyano‐bridged bimetallic 4f–3d complex, triaqua‐1κ3O‐μ‐cyano‐1:2κ2N:C‐pentacyano‐2κ5C‐tetrakis(2‐pyrrolidone‐1κO)chromium(III)dysprosium(III) dihydrate, [CrDy(C4H7NO)4(CN)6(H2O)3]·2H2O, has been prepared and characterized by X‐ray crystallographic analysis. The structure consists of a neutral cyano‐bridged Dy–Cr dimer. A hydrogen‐bonded three‐dimensional architecture is formed through N—H?O, O—H?N and O—H?O hydrogen bonds. 相似文献
18.
Hiroyuki Ishida Setsuo Kashino 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(4):476-479
2,5‐Dichloro‐3,6‐dihydroxy‐1,4‐benzoquinone (chloranilic acid) forms X—H?Y (X, Y = N or O) and C—H?Cl hydrogen bonds with pyrazole and imidazole to afford bis(pyrazolium) dichloroanilate and bis(imidazolium) dichloroanilate, (I) and (II), both 2C3H5N2+·C6Cl2O42?, and imidazolium chloroanilate acetonitrile solvate, C3H5N2+·C6HCl2O4?·C2H3N, (III). Their crystal structures demonstrate three novel supramolecular architectures based on supramolecular synthons to build a ladder, (I), a two‐dimensional network, (II), and a flat ribbon, (III). 相似文献
19.
M. Barboiu A. van der Lee 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(9):m366-m368
The structure of the supramolecular complex calcium–trifluoromethanesulfonate–1,3‐di‐4‐pyridylurea–methanol (1/2/2/4), Ca2+·2CF3SO3−·2C11H10N4O·4CH4O, is presented. The Ca2+ ion lies on an inversion centre and is octahedrally coordinated by four methanol molecules and two trifluoromethanesulfonate counter‐ions. The molecular packing is dominated by hydrogen‐bonded sheets in the (110) plane which contain R(32) rings; in these rings, significant π–π interactions are observed between inversion‐related 1,3‐di‐4‐pyridylurea molecules. 相似文献
20.
Kyung‐Lae Park Byoung‐Gi Moon Sang‐Hun Jung Jin‐Gyu Kim Il‐Hwan Suh 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(10):1247-1250
The title compound, (S)‐(+)‐4‐[5‐(2‐oxo‐4,5‐dihydroimidazol‐1‐ylsulfonyl)indolin‐1‐ylcarbonyl]anilinium chloride (S)‐(+)‐1‐[1‐(4‐aminobenzoyl)indoline‐5‐sulfonyl]‐4‐phenyl‐4,5‐dihydroimidazol‐2‐one, C24H23N4O4S+·Cl?·C24H22N4O4S, crystallizes in space group C2 from a CH3OH/CH2Cl2 solution. In the crystal structure, there are two different conformers with their terminal C6 aromatic rings mutually oriented at angles of 67.69 (14) and 61.16 (15)°. The distances of the terminal N atoms (of the two conformers) from the chloride ion are 3.110 (4) and 3.502 (4) Å. There are eight distinct hydrogen bonds, i.e. four N—H?Cl, three N—H?O and one N—H?N, with one N—H group involved in a bifurcated hydrogen bond with two acceptors sharing the H atom. C—H?O contacts assist in the overall hydrogen‐bonding process. 相似文献