准分子激光束的喇曼组束

受激喇曼散射可以将紫外准分子激光辐射频移到特定的近紫外或可见光波长,采用喇曼整形技术可以改善斯托克斯光的光束质量,本文报道喇曼组束提高喇曼整形效率的实验结果.     

蛋白质结构和功能的紫外共振喇曼光谱研究

紫外共振喇曼光谱技术是研究复杂大分子结构的有力工具。结合作者在美国Pittsburgh University期间所做的工作，介绍了用紫外共振喇曼光谱研究肽和蛋白质结构与功能的现状和进展，N-methylacetamide和glycyglycine水溶液光化学异构过程的紫外共振喇曼光谱研究，简述了紫外共振喇曼光谱实验技术要点。本文还跟踪国际最新研究成果，介绍了利用紫外共振喇曼光谱技术研究蛋白质的折叠和去折叠过程。     

单纵模Nd:YAG激光泵浦H2气中的受激喇曼散射

用单纵模Nd:YAG激光(波长1.06μm,脉宽9ns,线宽0.003cm-1)泵浦氢气中的受激喇曼散射,产生很强的后向一级斯托克斯.当泵浦能量为120mJ,压力为1.5MPaH2时,后向和前向喇曼的光子转化效率分别为66%和15%,而在4MPa时两个数值分别为46%和39%.由于后向喇曼与前向喇曼和泵浦光的传播方向相反,二者的相互竞争产生了张弛振荡,使得后向和前向喇曼的时间波形都分裂为两个峰,后向喇曼的两个峰都被压窄到1ns,使峰值功率达到了泵浦光功率的二倍,这在前向喇曼是不可能的.而且后向喇曼的光束质量要大大优于泵浦光和前向喇曼的光束质量,在4MPaH2和脉冲重复频率为10Hz时,喇曼过程的放热使前向喇曼的光束质量变坏,但对后向喇曼的光束质量影响不大.计算表明,该实验条件下受激喇曼过程没有达到稳态,所有实验结果都可以而且只能用相关的瞬态受激喇曼理论解释.     

固体中光声喇曼效应的原理特性分析

从相干喇曼放大过程出发,运用准平衡模型以及热弹理论,对固体样品中光声喇曼效应进行理论分析,导出了脉冲激光泵浦下的光声喇曼信号表达式,并做了数值估算.总结分析了固体介质中光声喇曼效应的一些特性.     

凝聚态物质中的光声喇曼效应理论

用热弹性理论系统地分析了凝聚态物质的光声喇曼效应,分别导出了连续和脉冲激光泵浦下的光声喇曼信号表达式,并做了数值估算.     

光纤喇曼放大器的特性及其在宽带通信中的应用

随着宽带业务的增长和 DWDM技术的发展 ,人们需要更宽增益带宽的全光放大器。光纤喇曼放大器由于其可放大任意波长信号的特性而得到广泛的关注和重视。介绍了喇曼放大器的特性 ,总结了国外近年来对喇曼放大器在宽带通信应用中的研究 ,并讨论了喇曼放大器的发展方向     

光纤共振和预共振喇曼光谱

在液芯光纤内产生共振和预共振喇曼效应,喇曼光谱强度可以大幅度提高,最高可达10⁹倍.本文介绍获得光纤(预)共振喇曼光谱的可行性、实验及实验结果.用远离吸收带的激光激发获得了α甲基吡啶预共振喇曼光谱.用小功率激光(0.8mW)、低浓度溶液(9.6×10¹²mol/L)还获得了β叶红素在CS₂中的共振喇曼光谱.     

高效率,窄脉冲1 198.5 nm Ba(NO3)2喇曼激光器

利用1064nm的Nd∶YAG激光抽运振荡腔内的硝酸钡晶体,获得高效率、窄脉冲的喇曼激光输出.硝酸钡晶体由水溶液降温法生长,长度为48 mm.喇曼振荡腔由对抽运光、一阶、二阶斯托克斯光有不同反射率的双色平面镜构成.当抽运光功率达到4.5 W时,获得最高的一阶斯托克斯喇曼激光功率为1.48 W,相应的转换效率为32.9%,并测得斜率效率为40%.由于受激喇曼散射的作用,喇曼脉冲光由抽运脉冲光的19.8 ns压缩为2.4 ns,获得的喇曼激光脉冲波形具有的“上升沿陡峭、下降沿缓慢”的特性,对其形成过程作了定性分析.测得喇曼激光的波长为1 198.5 nm,半峰全宽（FWHM）为1.2 nm.     

光纤喇曼增益系数的简捷测量

基于小信号开关增益原理,采用抽运光-探测波法,利用SLD(超辐射激光二极管)作为宽带小信号探测光源,快速测量出了标准单模光纤(G.652)的频移为0.5～20 THz内的喇曼增益系数,测量结果和文献中已有的值基本吻合,所测得的光纤喇曼增益系数可用于光纤喇曼放大器的理论和实验研究,该方法同样可以对其他类型光纤的喇曼增益系数进行测量.     

喇曼光谱对血糖的半定量分析

血糖检测一般采用酶化和生化方法,但这些方法都是有损破坏性的检测方法.本文利用喇曼光谱技术来检测血糖浓度,并且建一种新的数据分析方法来分析血糖的含量,以探索一种无损、快速的血糖检测方法.以小白鼠为实验模型,麻醉的小白鼠在注射葡萄糖后半个小时开始抽取小鼠尾巴处的血液进行喇曼光谱的获取,此后每间隔15 min对小鼠尾巴进行抽血并获取血液的喇曼光谱,在每次测量小鼠血液喇曼光谱的同时用血糖仪来监测血糖浓度的变化情况以用来做参比.1 125 cm^-1是葡萄糖的喇曼特征峰,血液中的葡萄糖称为血糖,因此我们把血液光谱中的1 125 cm^-1作为血糖峰,1 549 cm^-1为血红蛋白的喇曼特征峰,人体中的血红蛋白是稳定的,所以本文以血红蛋白的峰1 549 cm^-1作为内标来研究血液喇曼光谱中血糖峰的强度.结果表明1 125 cm^-1/1 549 cm^-1的变化可以很好地与血糖变化相对应,并且具有良好的线性关系.利用喇曼光谱技术可以无损地对血糖进行半定量分析.     

受激拉曼光束净化实验中波导的长度

计算了利用受激拉曼进行光束净化实验中波导的长度，综合考虑了泵浦光的耗散，由色散和斜入射引起的增益降低，以及泵浦光相位畸变对种子光的影响等多种因素，指出最优波导长度应取所有极限波导长度的最小值。将计算值与实验做了比较，并对结果进行了讨论。     

Single-mode Raman fiber laser based on a multimode fiber

Single-mode operation of a Raman fiber laser based on a multimode fiber has been demonstrated for what is to our knowledge the first time. Single-mode operation was achieved through the beam cleanup effect of stimulated Raman scattering in multimode fibers. The Raman laser, consisting of a 50-microm-core multimode fiber and a multimode Nd:YAG laser pump, produced an output beam corresponding to the fundamental mode of the fiber.     

Open Raman Cell to Avoid Window Damage

An open Raman cell was designed to avoid the window damage in high power Raman amplifiers. The conversion efficiency and the beam quality of the Stokes pulse were measured as a function of time when Raman gases flowed out from the Raman cell. The effects of Raman gas density and diameter of Raman cell on the specification were also discussed. The results showed that this open Raman cell was useful for high power Raman system.     

Open Raman Cell to Avoid Window Damage

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紫外拉曼光谱研究钇掺杂的氧化锆体系表面相变

本文用紫外拉曼 ,近可见拉曼光谱和XRD检测了不同焙烧温度下Y2 O3-ZrO2 的相变过程。紫外拉曼光谱对样品表面相变极其灵敏 ,而近可见拉曼光谱和XRD提供的主要是体相和表面的混合信息。在紫外拉曼谱图中 ,只观察到单斜相的谱峰 ,没有明显的四方晶相的信号 ,这表明样品的表面主要是单斜晶相。然而 ,XRD和近可见拉曼光谱的结果显示Y2 O3-ZrO2 体相是四方晶相。焙烧温度超过 40 0°时 ,紫外拉曼 ,近可见拉曼和XRD晶之间明显不同的结果表明Y2 O3-ZrO2 在表面区四方相很易转变为单斜相 ,体相中的四方相由于钇的添加而稳定存在。根据紫外拉曼和XRD结果 ,当升高温度时 ,在样品的表面形成一单斜相层 ,体相钇稳定的四方相 ,且由于Y2 O3的存在抑制了单斜相进一步向体相发展。     

Influence of electron beam irradiation on structural and optical properties of α-Ag2WO4 nanoparticles

The influence of 8 MeV electron beam irradiation on the structural and optical properties of silver tungstate (α-Ag₂WO₄) nanoparticles synthesized by chemical precipitation method was investigated. The dose dependent effect of electron irradiation was investigated by various characterization techniques such as, X-ray diffraction, scanning electron microscopy, UV–vis absorption spectroscopy, photoluminescence and Raman spectroscopy. Systematic studies confirm that electron beam irradiation induces non-stoichiometry, defects and particle size variation on α-Ag₂WO₄, which in turn results changes in optical band gap, photoluminescence spectra and Raman bands.     

Visible,near‐infrared,and ultraviolet laser‐excited Raman spectroscopy of the monocytes/macrophages (U937) cells

Raman spectra of the monocytes were recorded with laser excitation at 532, 785, 830, and 244 nm. The measurements of the Raman spectra of monocytes excited with visible, near‐infrared (NIR), and ultraviolet (UV) lasers lad to the following conclusions. (1) The Raman peak pattern of the monocytes can be easily distinguished from those of HeLa and yeast cells; (2) Positions of the Raman peaks of the dried cell are in coincidence with those of the monocytes in a culture cell media. However, the relative intensities of the peaks are changed: the peak centered around 1045 cm⁻¹ is strongly intensified. (3) Raman spectra of the dead monocytes are similar to those of living cells with only one exception: the Raman peak centered around 1004 cm⁻¹ associated with breathing mode of phenylalanine is strongly intensified. The Raman spectra of monocytes excited with 244‐nm UV laser were measured on cells in a cell culture medium. A peak centered at 1485 cm⁻¹ dominates the UV Raman spectra of monocytes. The ratio I₁₅₇₄/I₁₆₁₃ for monocytes is found to be around 0.71. This number reflects the ratio between proteins and DNA content inside a cell and it is found to be twice as high as that of E. coli and 5 times as high as that of gram‐positive bacteria. Copyright © 2009 John Wiley & Sons, Ltd.     

In situ diagnostics of catalytic materials using tunable confocal Raman spectroscopy

A new Raman spectroscopic setup for in situ characterization of catalytic materials based on a tunable laser system and a confocal Raman microscope is described. The laser excitation wavelength is variable over a broad range from deep ultraviolet (UV) to near‐infrared allowing for targeted use of Raman diagnostics for catalyst characterization. By utilization of resonance effects, the sensitivity of the method can be strongly increased. The potential of the setup is illustrated by new in situ Raman results on dispersed vanadium oxide catalysts obtained at 217.5 and 280 nm UV laser excitation. Copyright © 2013 John Wiley & Sons, Ltd.     

复合输出镜（Nd,Ce）：YAG拉曼频移激光器研究

报道了由部分反射凹面镜和辅助平面镜构成的复合输出镜高压ＣＨ４气体（Ｎｄ，Ｃｅ）：ＹＡＧ拉曼频移激光器的理论和实验研究结果，在１０Ｊ的输入下，获得１２ｍＪ的拉曼激光输出，并计算的基频场基模光束参数。