Ozone detection by differential absorption spectroscopy at ambient pressure with a 9.6 μm pulsed quantum-cascade laser

We report direct absorption spectroscopic detection of ozone at ambient pressure with a pulsed, DFB quantum-cascade laser (QCL) tuned within 1044–1050 cm^-1 by temperature scanning. Wavelength calibration curves were derived from FTIR and CO₂ spectra and interpreted with respect to the heat transfer from the heterostructure to the sink. The laser linewidth (0.13 cm^-1 FWHM) was found to decrease with temperature, probably as a result of operation at constant current. Spurious spectral features due to baseline inaccuracies were successfully filtered out from the QCL O₃ spectra using differential absorption. Reference O₃ concentrations were obtained by applying the same method to UV spectra, simultaneously measured with a differential optical absorption spectrometer (DOAS). Column densities retrieved from QCL spectra are in fairly good agreement (±20%) with the DOAS values above 28 ppmm. The estimated QCL lowest detectable, absolute and differential absorptions, (7×10^-3 and 2×10^-3, respectively), entail effective detection limits of 14 and 25 ppmm, respectively. Ongoing improvements in the acquisition system should allow the achievement of detection limits at the level of commercial open-path DOAS systems (2 ppmm) in the near future. Our results demonstrate the applicability of the differential absorption method to QCL spectroscopy at ambient pressure, and encourage its use for open path detection. PACS 42.62.Fi; 82.80.Gk; 92.60.Sz     

Influence of Hydrothermal Temperature on Structures and Photovoltaic Properties of SnO2 Nanoparticles

Two SnO₂ nanoparticles were synthesized by hydrothermal method at 170°C and 180°C, respectively. Transmission electron microscope observations reveal that the diameters of both the nanoparticles are around 6nm. At the same time, surface photovoltage spectroscopy measurements show that the nanoparticle synthesized at 180°C has more surface electronic states at 0.3eV below the conduction band than the one synthesized at 170°C. This means that the temperatures chosen in hydrothermal synthesis have significant influence on the surface electronic characteristics of resultant SnO² nanoparticles but the effect on their sizes is not obvious. However, after being calcined at 500°C for 2h, the diameter of the nanoparticle synthesized at 180°C increased to 23nm and that of the nanoparticle synthesized at 170°C increased to 32nm as calculated from X-ray diffraction pattern.     

The influence op demagnetization,anisotropy and stress on the resonance condition of spin-wave resonance

Spin-wave resonance equations of motion, based on Valenta's model of a thin film, are derived on the basis of quantum mechanics. We start out from the Hamiltonian including Zeeman, exchange and dipolar interaction. Phenomenological terms respecting the influence of anisotropy and stress are introduced into the equations of motion and the resonance condition is derived. The influence of the above effects on the resonance condition is discussed and a comparison is made with experiment.

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Investigation of the interaction of subpicosecond KrF laser pulses with a preformed carbon plasma

The interaction of a subpicosecond KrF laser pulse with a preformed carbon plasma of various scale lengths is investigated. Two different interaction geometries are chosen. In the first one the propagation vector of the short pulse has a component along the density gradient of the preformed plasma (angle of incidence is 45°). In the second geometry the propagation direction of the short pulse is perpendicular to the density gradient of the preplasma (angle of incidence is 90°). The emitted soft X-ray spectrum in the wavelength interval from 10 to 700 is observed while changing several parameters of the experiment. It is found that the emission in the short wavelength part under 200 results from the radiation of ions created by collisional heating near the critical density region. The long wavelength part above 200 , enhanced up to a maximal factor of 20, is mainly produced by radiating particles field—ionized up to the He-like carbon state in the high-intensity laser field. The short wavelength part is missing in the case of 90° angle of incidence because there is no interaction with the critical layer that results in an insufficient collisional heating.     

A Perspectival Version of the Modal Interpretation of Quantum Mechanics and the Origin of Macroscopic Behavior

We study the process of observation (measurement), within the framework of a perspectival (relational, relative state) version of the modal interpretation of quantum mechanics. We show that if we assume certain features of discreteness and determinism in the operation of the measuring device (which could be a part of the observer's nerve system), this gives rise to classical characteristics of the observed properties, in the first place to spatial localization. We investigate to what extent semi-classical behavior of the object system itself (as opposed to the observational system) is needed for the emergence of classicality. Decoherence is an essential element in the mechanism of observation that we assume, but it turns out that in our approach no environment-induced decoherence on the level of the object system is required for the emergence of classical properties.     

Experimental Test of a Time-Temperature Formulation of the Uncertainty Principle Via Nanoparticle Fluorescence

No Heading The uncertainty in the measured fluorescence decay lifetimes of 30 nm particles of YAG:Cc was used to evaluate the predictions of a novel form of the Heisenberg uncertainty principle suggested by de Sabbata and Sivaram, T t h/k. The worst-case uncertainty in temperature of 4.5 °K (as derived from the relationship between temperature and lifetime) and the measured uncertainty in decay lifetime, 0.45 ns, yielded an internal estimate of T t = 2.0 × 10^–9 °K s, which is 263 times larger than /k = 7.6 × 10^–12 °K s. An external estimate of T t = 4.5 × 10¹¹ °K s (which is = 6 times /k) is derived from the independently measured uncertainty in the temperature of the sample and the experimentally determined uncertainty in lifetime. These results could be low by a factor of 5.6 if signal averaging must be taken into account. If valid, the findings are consistent with the predictions of this version of the uncertainty principle and they imply the existence of a type of thermal quantum limit.     

Spectroscopic trace-gas sensor with rapidly scanned wavelengths of a pulsed quantum cascade laser for in situ NO monitoring of industrial exhaust systems

Development of a pulsed quantum cascade laser (QCL)-based spectroscopic trace-gas sensor for sub-part-per-million detection of nitric oxide (NO) and capable of monitoring other molecular species such as CO₂, H₂O, and NH₃ in industrial combustion exhaust systems is reported. Rapid frequency modulation is applied to the QCL to minimize the influence of fluctuating non-selective absorption. A novel method utilizes only a few laser pulses within a single wavelength scan to probe an absorption spectrum at precisely selected optical frequencies. A high-temperature gas cell was used for laboratory evaluation of the NO sensor performance. A noise-equivalent sensitivity (1) of 100 ppb × m/ at room temperature and 200 ppb × m/ at 630 K was achieved by measuring the NO R(6.5) absorption doublet at 1900.075 cm^–1.     

Model for the hydrogen adsorption on carbon nanostructures

The hydrogen sorption capacity of carbon nanostructures was for several years a very controversial subject. Theoretical models have been published demonstrating a great potential for a large hydrogen sorption capacity of carbon nanostructures. Here we present a simple empirical model where condensation of hydrogen as a monolayer at the surface of nanotubes as well as bulk condensation in the cavity of the tube is assumed. The maximum potential amount of hydrogen absorbed according to the model was calculated to be 2.28×10^-3 mass%S[m²g^-1]=3.0 mass% for the adsorption of a monolayer hydrogen at the surface. The condensation of hydrogen in the cavity of the tube leads to a potential absorption for single wall nanotubes starting at 1.5 mass% and increasing with the diameter of the tubes. The experimentally measured hydrogen capacity of the nanotube samples correlates with the B.E.T. specific surface area. The slope of the linear relationship is 1.5×10^-3 mass%/m²g^-1. Therefore, the extrapolated maximum discharge capacity of a carbon sample is 2 mass%. Furthermore, it can be concluded, that the hydrogen sorption mechanism is related to the surface of the sample, i.e. a surface adsorption process. PACS 81.05.Uw; 81.07.De; 82.33.Pt     

Wetting transition on grain boundaries in Al contacting with a Sn-rich melt

The contact angle at the intersection of a grain boundary in Al bicrystals with the solid Al/liquid Al–Sn interphase boundary has been measured for two symmetric tilt <011> {001} grain boundaries with tilt angles of 32° and 38.5°. The temperature dependencies (T) present the evidence of the grain boundary wetting phase transition at T_w. The observed hysteresis is consistent with the assumption that the wetting transition is of first order. The determined discontinuity in the temperature derivative of the grain boundary energy is–5.6 J/m²K (T w1=617°C) for the boundary with a low energy (=38.5°) and –17 J/m²K (T w2=604°C) for the grain boundary with a high energy (=32°).     

Estimation of the Sea Level Muon Spectra at Different Zenith Angles below 10 TeV Energy

The moderate energy primary cosmic ray nucleon spectrum has been calculated from the direct measurements of Webber et al., Seo et al., and Menn et al. along with the other results surveyed by Swordy. Using these directly measured primary mass composition results all particle primary nucleon energy spectrum has been constructed using superposition model to estimate the energy spectra of muons from the decay of the cosmic ray non-prompt and prompt mesons in the atmosphere. The Z-factors have been estimated from the CERN LEBC-EHS on the Lorentz invariant cross section results on pp ^±X and pp K^±X inclusive reactions and FNAL data on ^±p ^±X reactions, and duly corrected for A--A collisions. Using these Z-factors the meson energy spectra in the atmosphere have been calculated. The sea level muon energy spectra at zenith angles 0°, 45°, 72°, and 75° have been derived from the decay of non-prompt mesons by adopting standard diffusion equation of hadronic cascades. The contribution of charmed mesons to muon spectrum has also been accounted by adapting the conventional procedure. The derived differential sea level muon energy spectra for energies 10 TeV have been found to follow the power law fits of the form N (E) const. E ^-. Our estimated muon energy spectra at zenith angles 75° have been found comparable with the global spectrograph muon flux results of MARS, DEIS, and MSU groups.     

Cross-section asymmetry for the reactions γd →pn, γd → π0 d by linearly polarized photons in the energy rangeE γ = 0·4 – 0·8 GeV

The beam asymmetryB has been measured for the reactiond pn in the energy rangeE = 0·4 ÷ 0·8 GeV and angles _p ^cm = 45 ÷ 95° and ford ⁰d at energiesE =0·5, 0·6, 0·7 GeV and angle ^cm = 130°. The results obtained are compared to existing theoretical predictions which take into account the possible contribution of dibaryon resonances.Presented at the symposium Mesons and Light Nuclei, Bechyn, Czechoslovakia, May 27–June 1, 1985.     

Damage created by high-current-density implants of phosphorus into 〈100〉 and 〈111〉 silicon wafers

The damage left by high-current-density, 9 A/cm², implants of 120 keV phosphorus into 100 and 111 silicon oriented substrates was investigated as a function of the fluence in the range 4×10¹⁵–1.5×10¹⁶/cm². The samples were analyzed by 2 MeV He⁺ channeling and transmission electron microscopy. Initially a buried amorphous layer forms at low fluences until the wafer temperature saturates at 450 °C at a fluence of 4.5×10¹⁵/cm². As the fluence is further increased ion-assisted regrowth of this initial buried amorphous layer takes place and is 2 to 2.5 times faster (with respect to ion fluence) for 100 substrates than for 111 substrates. At higher fluences, most of the residual damage is located at a depth equal to the sum of the projected range and of the straggling. In the regrown layers twins are found in both orientations, and in some cases a hexagonal silicon phase is present at high fluences. The results are compared with the ion assisted regrowth of amorphous layers at well defined temperatures in the 250°–400 °C range.     

155Gd Mössbauer investigation on (GdxNd1−x)1+εFe4B4

Tetragonal (Gd_xNd_1–x)₁₊ Fe₄B₄ alloys have been investigated for 0.2x1 by Mössbauer spectroscopy, using the 86.5 keV¹⁵⁵Gd resonance. The Gd quadrupolar interaction e²qQ=12.67(5) mm/s for x=1, nearly independent of x, is the largest observed to date in metallic compounds of Gd. A crystal field term A ₂ ⁰ =–2450±50 K/a ₀ ² is inferred. This quadrupolar interaction shows some dispersion increasing when x decreases, reflecting the quasi incommensurate nature of the (Gd,Nd) and Fe+B sublattices in the (Gd_xNd_1–x)Fe₄B₄ structure (=0.109 for x=0 and =0.139 for x=1). The hyperfine field is perpendicular to the c axis for x0, but no unique direction is obtained for x=0.     

The deformation texture of β-tin II. Rolling texture

Measurements were made of the rolling texture of -tin which is produced by rolling the sample at a temperature of 20 °C and in the temperature interval –80°C–60 °C and –180 °C–110 °C.     

Calculation of electron-energy spectrum op the compound Co3Ti

The method of supplementary plane waves is used to calculate the electron-energy spectrum of the compound Co₃Ti. The dependence of the spectrum on the choice of electron configuration is analyzed. The possibility of separating the d band into bonding and antibonding states is considered.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 15–21, December, 1978.     

The spectrum of a quasiperiodic Schrödinger operator

The spectrum (H) of the tight binding Fibonacci Hamiltonian (H _mn= _m,n+1+ _m+1,n + _m,n v(n),v(n)= ((n–1)), 1/ is the golden number) is shown to coincide with the dynamical spectrum, the set on which an infinite subsequence of traces of transfer matrices is bounded. The point spectrum is absent for any , and (H) is a Cantor set for 4. Combining this with Casdagli's earlier result, one finds that the spectrum is singular continuous for 16.On leave from the Central Research Institute for Physics, Budapest, Hungary     

Electrical properties of GaAs layers irradiated by H4 ions

The quantities(D) and(T) are studied in n- and p-GaAs, irradiated at T = 300°K by H⁺ ions (5 MeV). It is shown that the resistance of lightly doped GaAs specimens increases from original values of ₀ to 10⁹ ·cm upon irradiation by H⁺ ions (5 MeV) to integral fluxes up to D^* – 10¹⁵ H⁺/cm². For D > D^* the layer resistance decreases from 10⁹ ·cm to 1 ·cm at 300°K. It was found that all the GaAs specimens intensely irradiated by H⁺ ions had p-type conductivity near 300°K. Isochronic annealing of radiation defects was studied in the temperature interval 20–700°C.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 39–43, January, 1982.     

Emissivity of CO2-H2O mixtures at temperatures up to 1000° K

The emissivity in the 2.7 m range is examined with a spectrometer having 25 cm^–1 for 2.5, ,7.5 cm·atm,4 8cm·atm, 400T1000° K; 150P730 mm Hg. It is found that relation (1) is obeyed to within /0.1, though the calculated transmission is usually less than the measured value. It is shown that the relation is obeyed on account of the mutual position of the CO₂ and H₂O lines in the band, i.e., one gas may be considered as unselective relative to the other.     

Implementation of comparative probability by normal states. Infinite dimensional case

Let be an infinite dimensional Hilbert space and () the set of all (orthogonal) projections on . A comparative probability on () is a linear preorder on () such thatOP1,1O and such that ifP┴R,Q┴R, thenPQP+RQ+R for allP, Q, R in (). We give a sufficient and necessary condition for to be implemented in a canonical way by a normal state onB(), the bounded linear operators on .     

Lyapunov Modes of Two-Dimensional Many-Body Systems; Soft Disks, Hard Disks, and Rotors

The dynamical instability of many-body systems can best be characterized through the local Lyapunov spectrum {}, its associated eigenvectors {}, and the time-averaged spectrum {}. Each local Lyapunov exponent describes the degree of instability associated with a well-defined direction—given by the associated unit vector —in the full many-body phase space. For a variety of hard-particle systems it is by now well-established that several of the vectors, all with relatively-small values of the time-averaged exponent , correspond to quite well-defined long-wavelength modes. We investigate soft particles from the same viewpoint here, and find no convincing evidence for corresponding modes. The situation is similar—no firm evidence for modes—in a simple two-dimensional lattice-rotor model. We believe that these differences are related to the form of the time-averaged Lyapunov spectrum near =0.