dc Josephson effect in metallic single-walled carbon nanotubes

The dc Josephson effect is investigated in a single-walled metallic carbon nanotube connected to two superconducting leads. In particular, by using the Luttinger liquid theory, we analyze the effects of the electron-electron interaction on the supercurrent. We find that in the long junction limit the strong electronic correlations of the nanotube, together with its peculiar band structure, induce oscillations in the critical current as a function of the junction length and/or the nanotube electron filling. These oscillations represent a signature of the Luttinger liquid physics of the nanotube, for they are absent if the interaction is vanishing. We show that this effect can be exploited to reverse the sign of the supercurrent, realizing a tunable π-junction.     

Neutron scattering study of the intermolecular vibrations in solid C60

We present a detailed account of an inelastic neutron scattering study of the intermolecular vibrations in solid C₆₀ above and below the structural phase transformation. Assignment of the observed phonon peaks to modes of translational and librational character is discussed on the basis of lattice dynamical calculations using phenomenological intermolecular potentials. A new bond charge model is presented which reproduces the observed phonon branches very well. However, the apparently small influence of the orientational disorder on the librational excitations remains to be understood.     

Multishell conduction in multiwalled carbon nanotubes

The full electronic complexity of multiwalled carbon nanotubes may be explored by sequentially removing individual carbon shells. This technique is employed to directly measure the number of shells contributing to conduction at room temperature, as well as the contribution of each shell to the overall conductance. By exploring the gate dependence of the conductance, the random alternation between semiconducting and metallic shells can also be observed. Received: 31 August 2001 / Accepted: 3 December 2001 / Published online: 4 March 2002     

Adjustable thermal conductivity in carbon nanotube nanofluids

Homogeneous and stable nanofluids have been produced by suspending well dispersible multi-walled carbon nanotubes (CNTs) into ethylene glycol base fluid. CNT nanofluids have enhanced thermal conductivity and the enhancement ratios increase with the nanotube loading and the temperature. Thermal conductivity enhancement was adjusted by ball milling and cutting the treated CNTs suspended in the nanofluids to relatively straight CNTs with an appropriate length distribution. Our findings indicate that the straightness ratio, aspect ratio, and aggregation have collective influence on the thermal conductivity of CNT nanofluids.     

Picosecond X-ray diffraction studies of laser-excited acoustic phonons in InSb

We have employed time-resolved X-ray diffraction with picosecond temporal resolution to measure the time-dependent rocking curves of laser-irradiated asymmetrically cut single InSb crystals. Coherent acoustic phonons were excited in the crystals by irradiation with 800-nm, 100-fs laser pulses at irradiances between 0.25 and 12 mJ/cm². The induced time-dependent strain profiles (corresponding to the coherent phonons) were monitored by diffracting collimated, monochromatic pulses of X-rays from the irradiated crystals. Recording of the diffracted radiation with a fast low-jitter X-ray streak camera resulted in an overall temporal resolution of better than 2 ps. The strain associated with the coherent phonons modifies the rocking curve of the crystal in a time-dependent manner, and the rocking curve is recorded by keeping the angle of incidence of the X-rays upon the crystal fixed, but varying the energy of the incident X-rays around a central energy of 8.453 keV (corresponding to the peak of the rocking curve of the unperturbed crystal). The observed time-dependent diffraction from the irradiated crystals is in reasonable agreement with simulations over a wide range of energies from the unperturbed rocking-curve peak. Received: 22 March 2002 / Revised version: 25 March 2002 / Published online: 6 June 2002     

Size, shape and structure dependent cohesive energy and phase stability of metallic nanocrystals

A model to account for the size, shape and structure dependent cohesive energy of metallic nanocrystals is developed in this contribution. It is predicted that the cohesive energy of nanocrystals decreases with decreasing the crystal size in specific shape, and decreases with increasing the shape factor in specific size. Furthermore, the model can be applied to predict the size and shape dependent phase stability of nanocrystal. To take Cr nanocrystal as an example, we found that there exists FCC structure for Cr crystal (the bulk structure is BCC) when the crystal size is small enough, and critical size of phase transition ranges from 249 to 824 atoms due to crystal shape variation, which is consistent with the corresponding experimental results.     

Effects of Contact Atomic Structure on Electronic Transport in Molecular Junction

Based on nonequilibrium Green＇s function and first-principles calculations, we investigate the change in molecular conductance caused by different adsorption sites with the presence of additional Au atom around the metal- molecule contact in the system that benzene sandwiched between two Au（111） leads. The motivation is the variable situations that may arise in break junction experiments. Numerical results show that the enhancement of conductance induced by the presence of additional Au is dependent on the adsorption sites of anchoring atom. When molecule is located on top site with the presence of additional Au atoms, it can increase molecular conductance remarkably and present negative differential resistance under applied bias which cannot be found in bridge and hollow sites. Furthermore, the effects of different distance between additional Au and sulfur atoms in these three adsorption sites are also discussed.     

Electrical transport measurements on single-walled carbon nanotubes

We review transport measurements on single-walled carbon nanotubes contacted by metal electrodes. At room temperature some devices show transistor action similar to that of p-channel field effect transistors, while others behave as gate-voltage independent wires. At low temperatures transport is usually dominated by Coulomb blockade. In this regime the quantum eigenstates of the finite-length tubes can be studied. At higher temperatures power law behaviour is observed for the temperature and bias dependence of the conductance. This is consistent with tunneling into a one-dimensional Luttinger liquid in a nanotube. We also discuss recent developments in contacting nanotubes which should soon allow study of their intrinsic transport properties. Received: 17 May 1999 / Accepted 18 May 1999 / Published online: 4 August 1999     

Theoretical study of phonon spectra in ferromagnetic nanoparticles

Based on the spin-phonon model we analyze the influence of surface and size effects on the phonon properties of ferromagnetic nanoparticles. A Green's function technique in real space enables us to calculate the renormalized phonon energy and its damping depending on the temperature and the anharmonic spin-phonon interaction constants. With decreasing particle size the phonon energy can decrease or increase for different surface spin-phonon interaction constants, whereas the damping increases always. The influence of an external magnetic field is discussed, too. The theoretical results are in reasonable accordance to experimental data.     

Observation of electronic Raman scattering in metallic carbon nanotubes

We present experimental measurements of the electronic contribution to the Raman spectra of individual metallic single-walled carbon nanotubes (MSWNTs). Photoexcited carriers are inelastically scattered by a continuum of low-energy electron-hole pairs created across the graphenelike linear electronic subbands of the MSWNTs. The optical resonances in MSWNTs give rise to well-defined electronic Raman peaks. This resonant electronic Raman scattering is a unique feature of the electronic structure of these one-dimensional quasimetals.     

Fuchs-Kliewer phonon spectrum of Co3O4(110) single crystal surfaces by high resolution electron energy loss spectroscopy

The Fuchs-Kliewer phonon spectrum of single crystal Co₃O₄(110) has been analyzed by high resolution electron energy loss spectroscopy (HREELS) and the four fundamental phonon losses have been identified at 26.8, 47.5, 71.1 and 84.7 meV (216, 383, 573 and 683 cm⁻¹). This is the first HREELS study reported for an intrinsic spinel single-crystal surface with primary focus on the Fuchs-Kliewer phonon structure. The Co₃O₄ crystal is first characterized by Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS) and low-energy electron diffraction (LEED), which establish the composition, cleanliness, and order of the (110) surface. Electron scattering is then used to obtain a series of well-resolved Fuchs-Kliewer phonon spectra over 2.25-14.25 eV incident electron energy range. The variation in phonon intensity with primary beam energy is shown to agree with that predicted by dielectric theory.     

The effects of LO phonons on charge qubit

In this paper, we study the influence of LO phonon (LOP) on the charge qubit in a quantum dot (QD), and find that the eigenenergies of the ground and first excited states are reduced due to the electron-LOP interaction. At the same time, the time evolution of the electron probability density is obtained, the dependence of the oscillating period on electron-LOP coupling constant is found, the relation of between the oscillating period and the confinement length of the QD is calculated. Finally, we consider the effects of the electron-LOP coupling constant on pure dephasing factor under considering the correction of electron-LOP interaction for the wave functions. Our results suggest that electron-LOP interaction has very important effects on charge qubit.     

Effect of diffusion layers and defect layer on acoustic phonons transport through the structure consisting of different films

By using the continuum elastic approximation model and the transfer matrix method, we investigate the effect of diffusion layers and defect layer on acoustic phonons transport through the structure consisting of different films. Our work show that most acoustic phonons can easily pass the structure, but some only have much less transmission probabilities and form corresponding dips in the transmission spectrum. With the change of the structure parameters such as the width of diffusion layers and defect layer, the number of unit cell and the density of containing Al in diffusion layers and defect layer, the magnitude of the frequencies of acoustic phonons corresponding to the dips almost remain unchanged, but the transmission coefficients corresponding to the dips change at different degree, and the transmission probabilities of some frequencies are very sensitive to the variation of the above-mentioned structure parameters. These results can provide some references in controlling the transmission coefficients of acoustic phonons, devising parts of acoustic apparatus and theoretical investigation related.     

One-step preparation of copper nanorods with rectangular cross sections

Copper nanorods with rectangular cross sections have been successfully prepared in high yield via a hydrothermal reduction process at a low temperature. Ascorbic acid acts as both the complexing agent and reducer, so it plays an important role for the growth of nanorods. The highly crystalline filaments exhibit the face-centered cubic structure, growing mainly along the directions. An interesting red-shift was observed in the optical absorption measurement due to the nanorods with rectangular cross sections. XRD, SEM, TEM, electron diffraction, and UV-visible spectroscopy were used to characterize these copper nanorods.     

Persistent current and transmission probability in the Aharonov-Bohm ring with an embedded quantum dot

Persistent current and transmission probability in the Aharonov-Bohm (AB) ring with an embedded quantum dot (QD) are studied using the technique of the scattering matrix. For the first time, we find that the persistent current can arise in the absence of magnetic flux in the ring with an embedded QD. The persistent current and the transmission probability are sensitive to the lead-ring coupling and the short-range potential barrier. It is shown that increasing the lead-ring coupling or the short-range potential barrier causes the suppression of the persistent current and the increasing resonance width of the transmission probability. The effect of the potential barrier on the number of the transmission peaks is also investigated. The dependence of the persistent current and the transmission probability on the magnetic flux exhibits a periodic property with period of the flux quantum.     

Shot Noise in Aharonov-Casher Rings

We investigate the shot noise of electron transport through an Aharonov-Casher ring subject to the Rashba spin-orbit coupling （SOC）. Analytic expressions for the coefficients of reflection and transmission are derived by using the Griffith boundary conditions. For this kind of SOC, the ballistic transport of electrons can be analyzed as two independent spin channels, and both of them have the same transmission and reflection coefficients. The dependences of shot noise and Landauer-Biittiker conductance on controllable factors, including the strength of Rashba SOC, the asymmetrical angle of lead-connection positions, the radius of the rings, and the wave vector （or energy） of the incident Fermi electrons, are explicitly described by some new combined parameters. The ways that the shot noise and conductance vary with Rashba SOC and with asymmetrical angle are demonstrated by numerical simulations, respectively. It is revealed that the shot noise reaches its maximum for the particular situation of half transmission and half reflection and zero shot noise occurs at conductance maxima.     

High Field Electrical Conduction in Pre-Formed A1-ZnS-AI Thin Films in Metal-Insulator-Metal Devices

The high field electrical conduction mechanism for the widely used ZnS thin films in the microelectronic industry is investigated. Experimental data on the dc conduction as a function of the applied bias for the A1-ZnS-A1 devices is carefully compared with the theoretical equations given by Schottky and Poole-Freukel. The resu/ts yield the value of the coefficient of the barrier lowering compatible with the Schottky theory rather than the Poole-Frenkel theory, which are also in agreement with the results reported earlier by Maekawa [Phys. Rev. Lett. 24 （1970） 1175]     

Polaron formation and hopping conductivity in the Holstein-Hubbard model

On the basis of the Holstein-Hubbard model the formation of polarons at finite densities is investigated by means of a variational approach appropriate for describing squeezing and correlation effects. An effective Hubbard model for the polarons is derived, where the correlations are treated within the slave-boson saddlepoint approximation. For low enough phonon frequencies, with increasing coupling an abrupt self-trapping transition from light to heavy polarons is found. With increasing density the squeezing effect increases, and the transition is shifted to higher couplings. In the case of an effective Coulomb repulsion, the self-trapping transition is shifted to lower couplings with increasing Hubbard interaction, and the effective polaron mass below the transition is enhanced. In the heavy polaron regime, the frequency-dependent polaron hopping conductivity is calculated. There occur qualitative finite-density and correlation effects on the zero-temperature absorption spectrum which are discussed with respect to their possible relevance to the midinfrared absorption in high-T _c superconductors.     

Electron transport in carbon nanotube quantum dots in an axial magnetic field

The quantum conductance of the quantum dots (QDs) made of two kinds of primary carbon nanotubes (CNTs), i.e., armchair and zigzag CNTs, threaded by an axial magnetic field, has been studied by using the tight binding approximation and constant interaction model. It is found that under increasing axial magnetic field, each conductance shell of the zigzag CNT-QDs could split into two groups with each group of two peaks moving up or down, respectively. And the up- and down-moving two peaks would re-group with other two peaks, down- and up-moving, in the neighboring shell, forming a new four-peak shell, and then re-splitting, re-grouping again due to the Aharonov-Bohm effect, which is in agreement with those of experiments. But, in contrast, the conductance shells of the armchair CNT-QDs do not split by the magnetic field. Our subsequent theoretical studies show further that the above phenomena, i.e., the conductance shell-splitting, re-grouping, and re-splitting again with increasing the magnetic field exist in all the CNT-QDs except for the armchair one.     

Laser heating method for estimation of carbon nanotube purity

A new method of a carbon nanotube purity estimation has been developed on the basis of Raman spectroscopy. The spectra of carbon soot containing different amounts of nanotubes were registered under heating from a probing laser beam with a step-by-step increased power density. The material temperature in the laser spot was estimated from a position of the tangential Raman mode demonstrating a linear thermal shift (-0.012 cm^-1/K) from the position 1592 cm^-1 (at room temperature). The rate of the material temperature rise versus the laser power density (determining the slope of a corresponding graph) appeared to correlate strongly with the nanotube content in the soot. The influence of the experimental conditions on the slope value has been excluded via a simultaneous measurement of a reference sample with a high nanotube content (95 vol. %). After the calibration (done by a comparison of the Raman and the transmission electron microscopy data for the nanotube percentage in the same samples) the Raman-based method is able to provide a quantitative purity estimation for any nanotube-containing material. Received: 11 December 2001 / Accepted: 12 December 2001 / Published online: 4 March 2002