共查询到20条相似文献,搜索用时 62 毫秒
1.
G. Lindenblatt H. Wenz W. Behmenburg 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2001,13(3):329-336
By selective optical excitation of collision pairs and observation of the reemitted fluorescence information is obtained on
the role of the molecular channels involved in inelelastic collisions. As an example case we have studied experimentally the
Li( 3
D
→ 3
P) excitation transfer in Li(3D)X systems with X
=
Ne, Ar by means of the optical collision process Li
(2
P
) +
X
+
h
ν→
LiX
(3
D
Λ) →
Li
(3
P
, 3
D
) +
X where LiX
(3
D
Λ) collision molecules dissociate into Li(3P, 3D) atoms following laser excitation h
ν of Li
(2
P
) +
X pairs. For this purpose we measured the Li 3P/3D population ratio by the fluorescence from these levels as function of the
laser detuning Δν from the Li(2P-3D) transition and the rare gas pressure, and determined from this the 3P/3D excitation ratio B
(Δν) for single collision conditions. The experiments were performed using two step cw laser excitation of gaseous mixtures Li
+
X at temperatures around 600 K in the detuning range |Δν| ? 100 cm-1. The B
(Δν) profiles obtained display strong blue-red wing asymmetries both for Li
*
Ne and Li
*
Ar. This reflects different dissociation probabilities from the 3
D
Σ or 3
D
(Π,Δ) states that are initially prepared by blue wing or red wing excitation, respectively. The results are qualitatively discussed
in terms of new ab initio potentials for the two systems.
Received 23 February 2000 and Received in final form 5 July 2000 相似文献
2.
R. Drozdowski 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,23(1):73-79
The 1
s
3
d 3D level of atomic helium cannot be excited directly by proton impact, but it is strongly populated by cascade feeding from
1snl states with l
≥ 3, if 10÷15 keV protons are used for excitation. This cascade feeding process can be analysed in detail by investigating the intensity
of the spectral line at λ(1
s
3
d
3
D- 1
s
2
p
3
P
) = 588 nm as a function of an electric field directed parallel and antiparallel to the proton beam. In this paper the intensity
functions are calculated assuming collisional excitation of parabolic singlet states | 1
s
;
n
,
n
1
,
n
2
,
m
〉 with large electric dipole moments. The theoretical results are compared with the experimental intensity function published
earlier. Excellent agreement is obtained if the excitation cross-sections σ
n
of the parabolic states scale as n-3. 相似文献
3.
Unconventional antiferromagnetic correlations of the doped Haldane gapsystem Y 2 BaNi 1 - x Zn x O 5
V. Villar R. Mélin C. Paulsen J. Souletie E. Janod C. Payen 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,25(1):39-51
We make a new proposal to describe the very low temperature susceptibility of the doped Haldane gap compound Y2BaNi1-xZnxO5. We propose a new mean field model relevant for this compound. The ground state of this mean field model is unconventional
because antiferromagnetism coexists with random dimers. We present new susceptibility experiments at very low temperature.
We obtain a Curie-Weiss susceptibility χ(
T
) ∼
C
/(Θ +
T
) as expected for antiferromagnetic correlations but we do not obtain a direct signature of antiferromagnetic long range order.
We explain how to obtain the “impurity” susceptibility
(
T
) by subtracting the Haldane gap contribution to the total susceptibility. In the temperature range [1 K, 300 K] the experimental
data are well fitted by T
(
T
) =
C
imp
1 +
T
imp
/
T
. In the temperature range [100 mK, 1 K] the experimental data are well fitted by T
(
T
) =
A
ln(
T
/
T
c
), where T
c
increases with x. This fit suggests the existence of a finite Néel temperature which is however too small to be probed directly in our experiments.
We also obtain a maximum in the temperature dependence of the ac-susceptibility
(
T
) which suggests the existence of antiferromagnetic correlations at very low temperature.
Received 17 July 2001 相似文献
4.
J. Walls J. Clarke S. Cauchi G. Karkas H. Chen W.A. van Wijngaarden 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2001,14(1):9-13
Polarizabilities of several rubidium states were determined by measuring stark shifts of transitions using an electro-optically
modulated laser beam to excite an atomic beam. The voltage required for atoms excited by the laser beam in an electric field
to be simultaneously in resonance as atoms excited by a frequency sideband of the laser in a field free region was measured.
The scalar α
and tensor α
2
polarizabilities were found to be: α
(9
S
1/2
) = 103.77±0.09, α
(10
S
1/2
) = 272.54±0.16, α
(8
D
3/2
) = 230.68±0.25 and α
2
(8
D
3/2
) = 26.55±0.10, α
(8
D
5/2
) = 222.68±0.14 and α
2
(8
D
5/2
) = 51.91±0.10 MHz/(kV/cm)2. The results are 100 times more accurate than previous measurements and are within 1% of those found theoretically using
a Coulomb approximation calculation.
Received 7 September 2000 and Received in final form 6 December 2000 相似文献
5.
H. Lippert V. Stert L. Hesse C.P. Schulz W. Radloff I.V. Hertel 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(3):445-448
The H atom transfer reaction in electronically excited indole(NH
3
)
n
clusters is studied in pump-probe experiments with femtosecond laser pulses. By applying different probe photon energies
we are able to detect the dissociation products (NH
3
)
n - 1
NH
4
for n
= 1-6. Furthermore we show that the analysis of the corresponding ion signals is not distorted by contributions from larger cluster
ions due to evaporation of NH
3
molecules. The formation times of the products are ca. 140ps for n
= 2-4 and about 80ps for n
= 5, 6.
Received 30 April 2002 / Received in final form 29 May 2002 Published online 13 September 2002 相似文献
6.
M. Vogel K. Hansen A. Herlert L. Schweikhard 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,21(2):163-166
The dimer dissociation energies of gold cluster ions Au
+
n
, n
= 9, 11, 13, 15 have been determined with an extension of a recently developed model-independent method. Monomer-dimer decay
pathway branching ratios provide the energy dependent process which is needed in this method. The measured values are D
2
(
Au
+
9
) = 3.66(8)(9) eV, D
2
(
Au
+
11
) = 4.27(11)(8) eV, D
2
(
Au
+
13
) = 4.50(9)(7) eV and D
2
(
Au
+
15
) = 4.29(10)(6) eV.
Received 13 May 2002 / Received in final form 22 July 2002 Published online 24 September 2002
RID="a"
ID="a"e-mail: manuel.vogel@uni-mainz.de 相似文献
7.
P. Pellegrini O. Dulieu F. Masnou-Seeuws 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(1):77-86
This paper proposes a general method to investigate Feshbach resonances in atomic collisions similar to Cs(6
s
) + Cs(6
p
) in the thermal or cold regime. In order to compute the predissociation widths of the C
1
Π
u
(6
s
+ 5
d
) bound vibrational levels of Cs2, coupled both with the (2)
3
Σ
+
u
(6
s
+ 6
p
) continuum and with the (2)
3
Π
u
(6
s
+ 5
d
) vibrational series, a Fourier grid method is implemented, with an optical potential. A convenient way of optimizing the latter
is proposed. A large number of resonances are found and calculations of their cross-sections for stabilization into ground
state molecules show that the rate may be important. This confirms the interpretation of Lintz and Bouchiat [Phys. Rev. Lett.
80, 2570 (1998)] who observed dimer formation in cell experiments. Possible generalization to the cold regime relies on the
possibility to tune the position of a resonance to coincide with the maximum of the collisional energy distribution.
Received 14 February 2002 Published online 28 June 2002 相似文献
8.
O. N. Bakharev N. Zelders H. B. Brom A. Schnepf H. Schnöckel L. Jos de Jongh 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):101-104
We present
69,71Ga-NMR experiments on
microcrystalline samples of the recently discovered
supramolecular compound Ga
84
[
N
(
SiMe
3
)
2
]
20
Li
6
Br
2
(
thf
)
20
.
2
toluene, which is composed of
ligand-coordinated Ga84 metal clusters,
packed together in a fully ordered crystalline matrix. The
compound is highly conducting and even shows superconductivity
below T
c
~ 7.2 K. Our preliminary
results between 10-300 K show a metallic-like behavior: the
nuclear spin-lattice relaxation rate T
1
-1
follows the Korringa law
69
(
T
1
T
)
-1
= 0.36 s
-1
K
-1
, but with a relaxation rate approximately three
times smaller than in bulk -Ga
metal. No quantum-size effects are observed, the Korringa law
being followed down to 10 K, whereas the quantum-gaps for
individual clusters should amount to ~
10
3
K. These results therefore suggest a transport process based on
intermolecular charge transfer, similar as in alkali-doped
fullerenes and silicon-clathrates. 相似文献
9.
A.M. Balagurov V.Yu. Pomjakushin D.V. Sheptyakov V.L. Aksenov N.A. Babushkina L.M. Belova O.Yu. Gorbenko A.R. Kaul 《The European Physical Journal B - Condensed Matter and Complex Systems》2001,19(2):215-223
The atomic structure of (
La
1 - y
Pr
y
)
0.7
Ca
0.3
MnO
3
compound with 0.5≤
y
≤1 has been systematically studied by neutron powder diffraction in the temperature range from 15 to 293 K. For composition
with y
= 0.75, the structural analysis was performed on two samples, one containing the natural mixture of oxygen isotopes and the other
one 75% enriched by
18
O. The room temperature structural characteristics of the series, including cell volume, average Mn-O bond distance, and average
Mn-O-Mn bond angle, are the linear functions of the <
r
A
>. Temperature dependencies of these parameters are quite smooth, except for the point T
=
T
FM
, where a jump like changes occur. The isotope enriched samples have been found identical in crystal and magnetic structure
down to the temperature of transition of the sample with
16
O into the metallic ferromagnetic phase. It confirms that different transport and magnetic properties of the samples with
16
O and
18
O at low temperature are driven by the different oxygen atoms dynamics solely. Temperature dependencies of the CO and AFM diffraction
peak intensities and of the peak widths for compositions close to the metal-insulator boundary ( y
≈ 0.75) indicate the macroscopically phase separated AFM-dielectric + FM-metallic state below T
FM
.
Received 28 April 2000 相似文献
10.
M.-K. Chen 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,21(1):13-18
We examine the influence of relativistic and QED effects on the existence of the 1,3P
o
H- resonances between n
= 2 and 3 hydrogen thresholds, the relativistic and QED corrections and the coupling effects between the high singlet and triplet
states are considered as first-order perturbations. We firstly obtain accurate non-relativistic resonant energies and widths
of fifteen 1P
o
resonances, and fifteen 3P
o
resonances. The fifteen 1P
o
resonances are classified to be
3
(2, 0)
-
n
( 4 ?
n
? 12) and
3
(1, 1)
+
n
( 3 ?
n
? 8). The fifteen 3P
o
resonances are classified to be
3
(2, 0)
+
n
( 3 ?
n
? 12) and
3
(1, 1)
-
n
( 4 ?
n
? 8). We found there exist six Feshbach resonances for
3
(2, 0)
-
n
(1P
o
) series, four Feshbach resonances for
3
(1, 1)
+
n
(1P
o
) series, seven Feshbach resonances for
3
(2, 0)
+
n
(3P
o
) series, and three Feshbach resonances for
3
(1, 1)
-
n
(1P
o
) series.
Received 22 February 2002 Published online 24 September 2002 相似文献
11.
12.
M. Gómez Berisso P. Pedrazzini J.G. Sereni O. Trovarelli C. Geibel F. Steglich 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,30(3):343-349
We present electrical resistivity and specific heat measurements of alloys on the Rh rich side of the phase diagram of the
Ce(Rh1-xPdx)2Si2 system. We compare these results with those obtained at intermediate and low Rh concentrations. The analysis of the concentration
and temperature dependence of the entropy and of the scaling behaviour of C
el
(
T
) and ρ(
T
) clearly confirm a separation of the magnetic phase diagram into two regions: the region x
≤0.3, showing a concentration independent characteristic temperature for the 4
f-electrons with T
0
≈ 45
K, while for x
> 0.3, T0 decreases to T
0
(
x
= 1) ≈ 15
K. At low Pd-content, TN decreases very rapidly from T
N
= 36
K in pure CeRh2Si2 to T
N
= 18
K at x
= 0.1. With higher Pd concentration TN stabilizes at T
N
≈ 15
K whereas the magnitude of the anomalies in C
el
(
T
) and in the susceptibility around TN are further reduced and disappear at x
≈ 0.3. This differs from the behavior found on the Pd-rich side, where TN decreases continuously to zero with increasing Rh content. The pronounced differences observed between both phase boundaries
and the drastic effect of doping on the Rh rich side suggest an itinerant character in CeRh2 Si2, in contrast with the localized character of CePd2Si2. Further evidence for the itinerant character of CeRh2Si2 is given by the ρ(
T
) dependence observed for x
≤0.3, which scales with ρ(
T
) of the prototype itinerant compound YCo2.
Received 31 December 2001 / Received in final form 6 July 2002 Published online 19 December 2002
RID="a"
ID="a"e-mail: berisso@cab.cnea.gov.ar 相似文献
13.
H.-D. Zhou R.-K. Zheng G. Li S.-J. Feng F. Liu X.-J. Fan X.-G. Li 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(4):467-471
The transport properties of the La1-xCaxMnO3 ( 0.5 ?
x
< 1) system in magnetic fields up to 14 T were studied. We found that the relationship between the charge ordering temperature
T
CO
and Mn4+ content n
Mn4 +
obeys the formula T
CO
/
T
max
= 1 -
a
(
n
Mn4 +
-
n
0
)
2
, here n0 and a are constants and T
max
is the maximum of T
CO
. For x
= 0.65, T
CO
arrives at the maximum value of 249.5 K in zero magnetic field, while the charge ordered (CO) state is most stable around
x
= 0.75. For x
= 0.5 when H
< 6 T the resistivity displays Mott's variable-range hopping (VRH) behavior, when 6 <
H
< 12 T it is suggested that two kinds of conduction mechanism, i.e., VRH and magnetic polarons, coexist in the material, and when H
> 12 T the resistivity shows metallic-like behavior and the transport mechanism is attributed to coexistence of magnetic polarons
and free carriers. For x
= 0.95, the conduction mechanism accords with the coexistence of VRH and magnetic polarons.
Received 4 January 2002 and Received in final form 28 January 2002 相似文献
14.
M. Bokor T. Marek K. Tompa P. Gütlich A. Vértes 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1999,7(4):567-571
19
F and
11
B spin-lattice relaxation times were measured in [
Zn
(
ptz
)
6
] (
BF
4
)
2
and in the spin-crossover compound [
Fe
(
ptz
)
6
] (
BF
4
)
2
. For both compounds BF
4
-
anion reorientation is active above 50 K. For [
Zn
(
ptz
)
6
] (
BF
4
)
2
, the anion-reorientation dynamics is different in the temperature regions of 50-90 K, 90-120 K, and above 150 K; between
120 and 150 K it changes rapidly reflecting a structural change. In [
Fe
(
ptz
)
6
] (
BF
4
)
2
the mechanism for the paramagnetic relaxation involving the
19
F nuclei is found to be of the diffusion-limited type according to the theory of Lowe and Tse. The present results prove that
the spin-crossover takes place in a dynamic surrounding and not in a static crystal lattice.
Received 09 February 1999 and Received in final form 14 June 1999 相似文献
15.
Z. Hu M. Knupfer M. Kielwein U.K. Rößler M.S. Golden J. Fink F.M.F. de Groot T. Ito K. Oka G. Kaindl 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(4):449-453
A strong anisotropic distribution of the holes in Ni 3
d and O 2
p orbitals is observed in the polarization dependent O 1
s and Ni 2
p
3/2
X-ray absorption spectroscopy of the linear-chain nickelate Y2-xCaxBaNiO5 (x
= 0, 0.05, 0.1, 0.2), which demonstrates the one-dimensional nature of the electronic state in these compounds. The holes introduced
by Ca-doping occupy both O 2
p and Ni 3
d orbitals along the NiO5 chains. By comparing the experimental Ni 2
p
3/2
absorption spectra of Y2-xCaxBaNiO5 to those from charge transfer multiplet calculations we can derive the orbital character of the additional holes to be of
∼60% O2
p and ∼40% Ni 3
d.
Received 7 January 2002 相似文献
16.
17.
H. Gayvallet J.-C. Géminard 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,30(3):369-375
We have studied the temperature dependent resistivity ρ(
T
) of La2-xSrxCuO4 epitaxial thin films in the doping range 0.045 ⩽
x
⩽ 0.25 in pulsed magnetic fields up to 50 T. The zero-field resistivity ρ(
T
) of these samples in the pseudogap regime, can be scaled onto one single universal curve in a broad temperature range by using
a linear transformation of both temperature and resistivity. The high field data ρ(
T
) reveal a metal to insulator transition (MIT) at low temperatures, well into the overdoped regime. For samples having k
F
l
< 1, with kF the Fermi wave vector and l the mean free path, this low temperature insulating behavior of the resistivity is described by the variable range hopping
conductivity (VRH). For samples with k
F
l
> 1, the divergence follows ρ(
T
) ∼
ln
(1/
T
) or a power law, depending upon the Sr-content. We further found that the residual conductivity at the minimum in ρ(
T
), appearing due to the MIT, follows a linear behavior with respect to the Sr-content. It is argued that the unusual MIT in
compounds with k
F
l
> 1, is most probably associated with the pseudogap and the behavior of charge stripes at low temperatures.
Received 4 January 2002 / Received in final form 7 May 2002 Published online 14 October 2002
RID="a"
ID="a"e-mail: liesbet.weckhuysen@fys.kuleuven.ac.be 相似文献
18.
D. Ashkenasi S. Kröger H.-D. Kronfeldt 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2000,11(2):197-205
The isotope shift (IS) and hyperfine structure (hfs) of nine levels (31720 to 38921 cm-1) assigned to the configuration 4
f
12
6
s
7
s in neutral erbium have been determined experimentally using Doppler-reduced saturation absorption spectroscopy in a gas discharge.
We performed a fine structure analysis in the SL-coupling scheme of the single configuration 4
f
12
6
s
7
s, confirming and extending the classification of even parity Er I levels. We discriminated the different hfs contributions
of the 4f12 core and the (6
s
+7
s) outer electrons of the shell in a non-relativistic JJ-coupling approach and in the relativistic effective tensor operator formalism in SL-coupling. The relativistic one-electron parameters of the hfs for 167Er were fitted to the experimental data by a least squares fit procedure: [0pt] a
01
4f
=-147(3) MHz, [0pt] a
10
6s
+
a
10
7s
=-1840(30) MHz, [0pt] b
02
4f
=6560(80) MHz. The level dependencies of the isotope shift were evaluated based on crossed second order (CSO) effects. We obtained
the following results for the CSO parameters for the isotope pairs 170-168Er: d
6s7s
=-740(30) MHz, z
4f
= 0(5) MHz, (
g
3,6s
(
f
, 6
s
)+
g
3, 7s
(
f
, 7
s
))= -24(15) MHz and for 170-166Er: d
6s7s
=-1500(50) MHz, z
4f
=0(10) MHz, (
g
3,6s
(
f
,6
s
)+
g
3,7s
(
f
+7
s
))=-50(29) MHz. The resulting parameters for the hfs are compared with those known for other configurations of the Er atom and ion.
Received 16 May 1999 and Received in final form 31 January 2000 相似文献
19.
D. Hupfeld W. Schweika J. Strempfer W.A. Caliebe U. Köbler K. Mattenberger G.J. McIntyre F. Yakhou Th. Brückel 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(3):273-289
We report on an investigation of the magnetic properties of Gd
x
Eu
1 - x
S mixed crystals with compositions in the range of 0.6 <
x
< 1. For the two samples Gd
0.8
Eu
0.2
S and Gd
0.73
Eu
0.27
S a long-range antiferromagnetic order was observed at low temperatures. Element-specific measurements exhibited a different
temperature dependence of the reduced sublattice magnetisation of the two magnetic species. A model calculation and Monte
Carlo simulations revealed that the different temperature dependence is due to frustration effects. These frustration effects
lead to a breakdown of the long-range order for higher europium contents. For the Gd
0.67
Eu
0.33
S-sample we were able to observe a short-range antiferromagnetic order with correlation lengths of a few 10? with X-ray resonance exchange scattering.
Received 25 April 2001 and Received in final form 3 December 2001 相似文献
20.
P. Cacciani F. Brandi I. Velchev C. Lyngå C.-G. Wahlström W. Ubachs 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2001,15(1):47-56
Rotationally resolved spectral lines in the C
-
X
(1, 0) band of carbon monoxide are investigated under high resolution using a coherent vacuum ultraviolet laser source, continuously
tunable near 107 nm. Transition frequencies are determined by calibrating against a reference standard of iodine lines, recorded
with saturation spectroscopy in the visible range, yielding an absolute accuracy of 0.003 cm-1 in the vacuum ultraviolet. Improved molecular constants for the excited state are derived and no effects of perturbation
are found at the present level of accuracy. Line broadening measurements result in information on the excited state lifetime
of the C
1
Σ
+
,
v
= 1 state for five natural isotopomers of carbon monoxide: τ(
12
C
17
O
) = 280 ps, τ(
12
C
18
O
) = 210 ps, τ(
13
C
16
O
) = 295 ps, τ(
13
C
17
O
) = 160 ps, and τ(
13
C
18
O
) = 150 ps. Within the accuracy of the present measurements no effects of J-dependent lifetimes were observed, for neither of the isotopomers. In addition direct time domain measurements of the lifetime
of the C
1
Σ
+
,
v
= 0 and v
= 1 states of the main isotopomer are performed in a pump-probe experiment using a picosecond VUV-laser, yielding τ(
12
C
16
O
) = 1780 ps for v
= 0 and τ(
12
C
16
O
) = 625 ps for v
= 1. For C
1
Σ
+
,
v
= 0 in 12C16O and 13C16O the same lifetime is found; this lifetime matches experimental values of the oscillator strength and hence supports previous
results showing pure radiative decay in this state; the error margins however do not exclude some low level of predissociation.
The measurements indicate that the C
1
Σ
+
,
v
= 0 state of the 13C18O isotopomer is predissociated with an estimated yield of 17% (i.e. above the level of predissociation for 12C16O.) From the combined data predissociation yields upon excitation of the C
1
Σ
+
,
v
= 1 state are derived, lying in the range 0.84-0.91 for the five less abundant isotopomers; for the main 12C16O isotopomer a strongly deviating predissociation yield of 0.65 is deduced.
Received 21 December 2000 and Received in final form 26 March 2001 相似文献