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1.
Theoretical investigation on near-infrared and visible absorption spectra of nanometallic aluminium
with oxide coating in nanoenergetic materials: size and shape effects 下载免费PDF全文
The effects of metal core dimension, oxide shell thickness and ellipsoid aspect ratio of Al-Al2O3 core-shell nanoparticles on the near-infrared and visible absorption spectra of nanocomposite Al-Al2O3/nitrocellulose(NC) film are investigated by numerical calculations. Both the size-dependent interband transitions and frequency-dependent free electron damping of the nanometallic aluminium are taken into account in the calculations. Oxidation effect of nanoaluminium is also analysed. It is shown that oxidation may enhance but may also reduce the optical absorption, depending on the excited light energy and initial dimension of nanoparticle. Metal core size and excited light energy dominate the absorption characteristic. The absorption ability of ellipsoidal nanoparticles is larger than that of spheroidal nanoparticles and increases by the square index as the aspect ratio increases. These calculations will provide some significant theoretical guidance for the preparation and laser ignition of nanoenergetic materials. 相似文献
2.
Influence of patterned TiO2/SiO2 dielectric multilayers for back and front mirror facetson GaN-based laser diodes 下载免费PDF全文
Ridge InGaN multi-quantum-well-structure (MQW) edge-emitting laser diodes (LDs) were grown on (0001) sapphire substrates by low-pressure metal-organic chemical vapour deposition (MOCVD). The dielectric TiO2/SiO2 front and back facet coatings as cavity mirror facets of the LDs have been deposited with electron-beam evaporation method. The reflectivity of the designed front coating is about 50% and that of the back high reflective coating is as high as 99.9%. Under pulsed current injection at room temperature, the influences of the dielectric facets were discussed. The threshold current of the ridge GaN-based LDs was decreased after the deposition of the back high reflective dielectric mirrors and decreased again after the front facets were deposited. Above the threshold, the slope efficiency of the LDs with both reflective facets was larger than those with only back facets and without any reflective facets. It is important to design the reflectivity of the front facets for improving the performance of GaN-based LDs. 相似文献
3.
Compact efficient optical parametric generator internal to a Q-switched Nd:YVO4 laser with periodically poled MgO:LiNbO3 下载免费PDF全文
This paper demonstrates a compact efficient optical parametric
generator internal to a Q-switched diode-end-pumped Nd:YVOquasi-phase-matching,
intracavity optical parametric generator, periodically poled
MgO-doped lithium niobate (PPMgLN) Project supported by the National
Natural Science Foundation of China (Grant Nos 10474071 and
60671036). 4265K, 4260F, 4270 This paper demonstrates a compact efficient optical parametric
generator internal to a Q-switched diode-end-pumped Nd:YVOquasi-phase-matching,
intracavity optical parametric generator, periodically poled
MgO-doped lithium niobate (PPMgLN) Project supported by the National
Natural Science Foundation of China (Grant Nos 10474071 and
60671036). 4265K, 4260F, 4270 This paper demonstrates a compact efficient optical parametric
generator internal to a Q-switched diode-end-pumped Nd:YVOquasi-phase-matching,
intracavity optical parametric generator, periodically poled
MgO-doped lithium niobate (PPMgLN) Project supported by the National
Natural Science Foundation of China (Grant Nos 10474071 and
60671036). 4265K, 4260F, 4270 This paper demonstrates a compact efficient optical parametric
generator internal to a Q-switched diode-end-pumped Nd:YVOquasi-phase-matching,
intracavity optical parametric generator, periodically poled
MgO-doped lithium niobate (PPMgLN) Project supported by the National
Natural Science Foundation of China (Grant Nos 10474071 and
60671036). 4265K, 4260F, 4270 This paper demonstrates a compact efficient optical parametric
generator internal to a Q-switched diode-end-pumped Nd:YVOquasi-phase-matching,
intracavity optical parametric generator, periodically poled
MgO-doped lithium niobate (PPMgLN) Project supported by the National
Natural Science Foundation of China (Grant Nos 10474071 and
60671036). 4265K, 4260F, 4270 This paper demonstrates a compact efficient optical parametric
generator internal to a Q-switched diode-end-pumped Nd:YVO$_{4}$
laser with periodically poled MgO:LiNbO3(PPMgLN). With the
Q-switch set at a repetition rate of 25kHz and the PPMgLN crystal
operated at room temperature (25\du\,), the intracavity optical
parametric generator threshold was reached as a diode pump power of
0.9\,W. A maximum signal output power of 0.34W with a pulse width
of 25\,ns and a beam quality factor of 1.4 was obtained at an
incident diode power of 3.4\,W, leading to a conversion efficiency of
10{\%} with a slope efficiency of 14.4{\%}. By varying the crystal
temperature from 25 to 200\du, the output signal wavelengths were
tuned in range of 1506--1565\,nm. Over a 30-minutes interval, the
instability of the signal power was measured to be less than 1{\%}.
In addition, the threshold pump intensity for the intracavity optical
parametric generator is theoretically investigated, and the obtained
result is in good agreement with the experimental results. 相似文献
4.
This paper reports that a simple chemical vapour deposition method has been adopted to fabricate large scale, high density boron nanocones with thermal evaporation of B/B2O3 powders precursors in an Ar/H2 gas mixture at the synthesis temperature of 1000-1200℃. The lengths of boron nanocones are several micrometres, and the diameters of nanocone tops are in a range of 50-100 nm. transmission electron microscopy and selected area electron diffraction indicate that the nanocones are single crystalline α-tetragonal boron. The vapour liquid solid mechanism is the main formation mechanism of boron nanocones. One broad photolumineseence emission peak at the central wavelength of about 650 nm is observed under the 532 nm light excitation. Boron nanocones with good photoluminescence properties are promising candidates for applications in optical emitting devices. 相似文献
5.
This paper studies the coalescence of heteroclusters Au767 and Ag767 by using molecular dynamics with the embedded atom method, where layer atomic energy is employed to describe the potential energy variation of per atom in different layers along radial direction. The results show that the coalescence is driven by releasing the atomic energy of the coalesced zone. The deformation, which is induced by substitutional and vacancy diffusion during the coalescence, makes the coalesced cluster disorder. If the summation of the thermal energy and the released atomic energy is large enough to keep the disorder state, the clusters form a metastable liquid droplet; otherwise, the clusters coalesce into a solid cluster when the coalesced cluster reaches the equilibrium state, and the coalesced cluster experiences liquid to solid ordering changes during the coalescence of a solid Au767 with a liquid Ag767 and a liquid Au767 with a liquid Ag767. The centre of figure of the cluster system is shifted during the coalescence process, and higher coalescence temperature causes larger shift degree. 相似文献
6.
This paper reports that the large-scale single crystalline boron carbide nanobelts have been fabricated through a simple carbothermal reduction method with B/B2O3/C/Fe powder as precursors at 1100℃. Transmission electron microscopy and selected area electron diffraction characterizations show that the boron carbide nanobelt has a B4C rhomb-centred hexagonal structure with good crystallization. Electron energy loss spectroscopy analysis indicates that the nanobelt contains only B and C, and the atomic ratio of B to C is close to 4:1. High resolution transmission electron microscopy results show that the preferential growth direction of the nanobelt is [101]. A possible growth mechanism is also discussed. 相似文献
7.
This paper reports that the YBa2Cu3-xZnxO7-δ (x = 0-0.4) samples are researched by means of x-ray diffraction, calculations of binding energy, the positron experiments and variations of oxygen content. The results of simulated calculations, positron experiments and variations of oxygen content support the existence of cluster effect. Moreover, it is concluded that the cluster effect is an important factor on suppression of high-Tc cuprate superconductivity and the Tc does not depend on the density of valence electron directly. 相似文献
8.
This paper reports that high quality CuGeO3 single crystals were successfully grown by floating-zone technique and the magnetic property was studied. The temperature dependence of magnetic susceptibility below the spin-Peierls (SP) transition temperature (Tsp) under magnetic fields applying along both the a- and c-axis direction can be fitted well by a model of noninteracting dimmers. The spin gap derived from the fitting is consistent with other reports. There is a very weak anisotropy in the fitting parameters for different directions, which should be expected from a SP system. A small upturn in susceptibility at low temperature due to paramagnetic impurities and/or defects can be observed. A suppression of the upturn by magnetic field is first discovered in this system and the possible origins for this suppression are discussed. 相似文献
9.
Single output LD end-pumped passively mode-locked Nd:YVO4 laser with semiconductor saturable absorber mirror 下载免费PDF全文
A quarter-wave plate and the thin film polarizer(TFP) are used for the LD end-pumped passively mode-locked Nd:YVO4 laser with semiconductor saturable absorber mirror(SESAM) to obtain a single beam output with a total power of 4.8 W.An optical-optical efficiency is achieved to be 24% for a stable CW mode-locking operation at 1064 nm,with a pulse repetition rate of 70 MHz and pulse width of 16 ps.The multipulse in the pulse sequence is eliminated for reaching a peak power as high as 4 kW. 相似文献
10.
Calculations of state-selective differential cross sections for charge transfer in collisions between O3+ and H2 下载免费PDF全文
The non-dissociative charge-transfer processes in collisions between O^3+ and H2 are investigated by using the quantum-mechanical molecular-orbital coupled-channel (QMOCC) method. The adiabatic potentials and radial coupling matrix elements utilized in the QMOCC calculations are obtained with the spin-coupled valence-bond approach. Electronic and vibrational state-selective differential cross sections are presented for projectile energies of 0.1, 1.0 and 10.0eV/u in the H2 orientation angles of 45° and 89°. The electronic and the vibrational state-selective differential cross sections show similar behaviours: they decrease as the scattering angle increases, and beyond a specific angle the oscillating structures appear. Moreover, it is also found that the vibrational state-selective differential cross sections are strongly orientation-dependent, which provides a possibility to determine the orientations of molecule H2 by identifying the vibrational state-selective differential scattering processes. 相似文献
11.
Infrared-to-visible and infrared-to-violet upconversion fluorescence of rare earth doped LaF3 nanocrystals 下载免费PDF全文
This paper reports that hexagonal-phase LaF3:Yb0.20^3+,Er0.02^3+ and LaF3:Yb0.20^3+, Tm0.02^3+ nanocrystals (NCs) were synthesized via a hydrothermal method. The transmission electron microscopy, selected area electron diffraction, powder x-ray diffraction, and thermogravimetric analysis are used to characterize the NCs. Under 980 nm excitation, the Yb^3+/Er^3+ and Yb^3+/Tm^3+ codoped NCs colloidal solutions present bright green and blue upconversion fluorescence, respectively. These NCs show efficient infrared-to-violet and infrared-to-visible upconversion. The upconversion fluo- rescence mechanisms of LaF2:Yb0.20^3+, Er0.02^3+ and LaF3:Yb0.20^3+,Tm0.02^3+ NCs are investigated with a 980-nm diode laser as excitation source. 相似文献
12.
A series of Mn-doped ZnO films have been prepared in different sputtering plasmas by using the inductively coupled plasma enhanced physical vapour deposition. The films show paramagnetic behaviour when they are deposited in an argon plasma. The Hall measurement indicates that ferromagnetism cannot be realized by increasing the electron concentration. However, the room-temperature ferromagnetism is obtained when the films are deposited in a mixed argon-nitrogen plasma. The first-principles calculations reveal that antiferromagnetic ordering is favoured in the case of the substitution of Mn^2+ for Zn^2+ without additional acceptor doping. The substitution of N for O (NO^-) is necessary to induce ferromagnetic couplings in the Zn-Mn-O system. The hybridization between N 2p and Mn 3d provides an empty orbit around the Fermi level. The hopping of Mn 3d electrons through the empty orbit can induce the ferromagnetic coupling. The ferromagnetism in the N-doped Zn-Mn-O system possibly originates from the charge transfer between Mn^2+ and Mn^3+ via NO^-, The key factor is the empty orbit provided by substituting N for O, rather than the conductivity type or the carrier concentration. 相似文献
13.
Deceleration of a continuous-wave (CW) molecular beam with a single quasi-CW semi-Gaussian laser beam 下载免费PDF全文
We propose a promising scheme to decelerate a CW molecular beam by using a red-detuned quasi-cw semi-Gaussian laser beam (SGB). We study the dynamical process of the deceleration for a CW deuterated ammonia (ND3) molecular beam by Monte-Carlo simulation method. Our study shows that we can obtain a ND3 molecular beam with a relative average kinetic energy loss of about 10% and a relative output molecular number of more than 90% by using a single quasi-cw SGB with a power of 1.5kW and a maximum optical well depth of 7.33mK. 相似文献
14.
With a coupling laser locked to caesium 6S$_{1 / 2}$ $F_{\rm
g}$=4--6P$_{3 / 2}$
$F_{\rm e}$=5 cycling transition and a co-propagating probe laser
scanned across
6S$_{1 / 2}$ $F_{\rm g}$=4--6P$_{3 / 2}$ $F_{\rm e}$=3, 4 and 5 transitions, a novel scheme
for sub-Doppler spectra in Doppler-broadened V-type three-level system is
demonstrated by detecting the transmission of the coupling laser through a
caesium vapour cell. The Autler--Townes doublet in the sub-Doppler spectra of the
coupling laser is clearly observed. The effects of coupling laser intensity
on the splitting and linewidth of the Autler--Townes doublet are experimentally
investigated and the results agree well with theoretical predictions. Taking
the multiple hyperfine levels of caesium atom into account, a brief analysis
is presented. 相似文献
15.
First-principles study of interphase Ni3Sn in Sn--Ni alloy for anode of lithium ion battery 下载免费PDF全文
This paper investigates the mechanism of Li insertion into interphase Ni3Sn in Ni-Sn alloy for the anode of lithium ion battery by means of the first-principles plane-wave pseudopotential. Compared with other phases, it is found that the Ni3Sn has larger relative expansion ratio and lower electrochemical potential, with its specific plateaus voltage around 0.3 eV when lithium atoms are filled in all octahedral interstitial sites, and the relative expansion ratio increasing dramatically when the lithiated phase transits from octahedral interstitial sites to tetrahedral interstitial sites. So this phase is a devastating phase for whole alloy electrode materials. 相似文献
16.
Intensive blue photoluminescence (PL) was observed at room temperature from the nanocrystalline-Si/SiO2 (nc-Si/SiO2) multilayers (MLs) obtained by thermal annealing of SiO/SiO2 MLs for the first time. By controlling the size of nc-Si formed in SiO sublayer from 3.5 to 1.5 nm, the PL peak blueshifts from 457 to 411 nm. Combining the analysis of TEM, Raman and absorption measurement, this paper attributes the blue PL to multiple luminescent centres at the interface of nc-Si and SiO2. 相似文献
17.
We have performed magnetization measurements and electron spin resonance (ESR) on polycrystalline manganites of Nd0.5Sr0.5-xBaxMnO3 (x = 0.1). Phase separation and phase transitions are observed from the susceptibility and the ESR spectra data. Between 260 K (~ Tc) and 185 K (~ TN), the system coexists of the paramagnetic phase and the ferromagnetic (FM) phase. Between 185 K and 140 K, the system coexists of the FM phase and the antiferromagnetic (AFM) phase. These results indicate that the system has a very complex magnetic state due to the origin of the instability stemming from manganite Nd0.5Sr0.4Ba0.1MnO3 by partially substituting the larger Ba^2+ ions for the smaller Sr^2+ ions. 相似文献
18.
Elastic scattering of two H(^2Sg) and N(^4Su) atoms at low temperatures and accurate spectroscopic parameters of NH (X^3∑^-) radical 下载免费PDF全文
This paper reports that the interaction potential for the X3Z- state of NH radical is constructed at the CCSD(T)/ cc-PV6Z level of theory. Using this potential, this paper calculates the spectroscopic parameters (De, Re, ωe, ωeχe, αe and Be) and their values are of 3.578eV, 0.10368nm, 3286.833cm^-1, 78.433cm^-1, 0.6469cm^-1 and 16.6735cm^-1 respectively, which are in excellent agreement with the experiments. Then the total of 14 vibrational states has been found when J=0 by solving the radial Schrodinger equation of nuclear motion. For each vibrational state, the vibrational manifolds are reported for the first time. And last, the total cross sections, s-wave, p-wave and d-wave cross sections are computed for the elastic collisions between two ground-state atoms (hydrogen and nitrogen) at low temperatures. It finds that the total elastic cross sections are dominated by s-wave scattering when the collision energy is below 10^-6a.u. The pronounced shape resonance is found at energy of 6.1 × 10^-6a.u. Calculations have shown that the shape resonance comes from the p-wave contributions. 相似文献
19.
High density gas state at water/graphite interface studied by molecular dynamics simulation 下载免费PDF全文
In this paper molecular dynamics simulations are performed to study the accumulation behaviour of N2 and H2 at water/graphite interface under ambient temperature and pressure. It finds that both N2 and H2 molecules can accumulate at the interface and form one of two states according to the ratio of gas molecules number to square of graphite surface from our simulation results: gas films (pancake-like) for a larger ratio and nanobubbles for a smaller ratio. In addition, we discuss the stabilities of nanobubbles at different environment temperatures. Surprisingly, it is found that the density of both kinds of gas states can be greatly increased, even comparable with that of the liquid N2 and liquid H2. The present results are expected to be helpful for the understanding of the stable existence of gas film (pancake-like) and nanobubbles. 相似文献
20.
The electron capture timescale may be shorter than hydrodynamic timescale in inner iron core of core-collapse supernova according to a recent new idea. Based on the new idea, this paper carries out a numerical simulation on supernova explosion for the progenitor model Ws15M. The numerical result shows that the size of proto-neutron star has a significant change (decrease about 20%), which may affects the propagation of the shock wave and the final explosion energy. 相似文献