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1.
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Polycrystalline CuGaSe2 thin films on Mo-coated soda-lime glass substrates have been synthesized by coevaporation process from Cu, Ga and Se sources. Structural and electrical properties of the as-grown CuGaSe2 films strongly depend on the film composition. Stoichiometric CuGaSe2 is fabricated, as indicated by x-ray diffraction spectroscope (XRD) and x-ray fluorescence (XRF). A two-phase region is composed of CuGaSe2 and Cu2-xSe phases for Cu-rich films, and CuGaSe2 and CuGa3Se5 phases for Ga-rich films, respectively. Morphological properties are detected by scanning electron microscope (SEM) for various compositional films, the grain sizes of the CuGaSe2films decrease with the extent of deviation from stoichiometric composition. Raman spectroscopy of Cu-rich samples shows that there exist large Cu-Se particles on the film surface. The results from Hall effect measurements for typical samples indicate that CuGaSe2 films are always of p-type semiconductor from Cu-rich to Ga-rich. Stoichiometric CuGaSe2 films exhibit relatively large mobility than any other compositional films. Finally, polycrystalline CuGaSe2 thin film solar cell with a best conversion efficiency of 6.02% has been achieved under the standard air mass (AM)1.5 spectrum for 100mW/cm^2 at room temperature (aperture area, 0.24cm^2). The open circuit voltage of the CuGaSe2 solar cells is close to770 mV.  相似文献   

2.
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唐军  马军  易鸣  贾亚 《中国物理 B》2008,17(11):4100-4106
The effect of change in concentration of messenger molecule inositol1,4,5-trisphosphate (IPspiral wave, Ca$^{2 + }$,IPspiral wave, Ca$^{2 + }$,IP$_{3}$Project supported by the NationalNatural Science Foundation of China (Grant Nos 10575041 and10747005)0545The effect of change in concentration of messenger molecule inositol1,4,5-trisphosphate (IP$_{3})$ on intracellular Ca$^{2 + }$spiralpattern evolution is studied numerically. The results indicate thatwhen the IP$_{3}$ concentration decreases from 0.27,$mu $M, aphysiologically reasonable value, to different values, the spiralcentre drifts to the edge of the medium and disappears for a smallenough IP$_{3}$ concentration. The instability of spiral pattern canbe understood in terms of excitability-change controlled by theIP$_{3}$ concentration. On the other hand, when the IP$_{3}$concentration increases from 0.27,$mu $M, a homogeneous area witha high Ca$^{2 + }$ concentration emerges and competes with thespiral pattern. A high enough IP$_{3}$ concentration can lead thehomogeneous area to occupy the whole medium. The instability ofspiral pattern is ascribed to the change in stability of astationary state with a high Ca$^{2 + }$ concentration.  相似文献   

3.
侯志灵  曹茂盛  袁杰  宋维力 《中国物理 B》2010,19(1):17702-017702
This paper reports that single-phase γ-Y2Si2O7 is prepared via a sufficient blending and cold-pressed sintering technique from Y2O3 powder and SiO2 nanopowder. It studies the dielectric properties of γ-Y2Si2O7 as a function of the temperature and frequency. The γ-Y2Si2O7 exhibits low dielectric loss and non-Debye relaxation behaviour from 25 to 1400℃ in the range of 7.3-18 GHz. The mechanism for polarization relaxation of the as-prepared γ-Y2Si2O7 differing from that of SiO 2 is explained. Such particular dielectric properties could potentially make specific attraction for extensive practical applications.  相似文献   

4.
郝延明  周严  赵淼 《中国物理》2005,14(7):1449-1452
通过X-射线衍射及磁测量手段研究了Dy2AlFe13Mn3化合物的结构及磁性质。研究结果表明Dy2AlFe13Mn3化合物具有六角相的Th2Ni17型结构。通过X-射线热膨胀测定法发现Dy2AlFe13Mn3化合物在245到344K的温度范围内存在负热膨胀现象,其平均热膨胀系数为α=-1.1×10-4K-1K-1。在105到360K的温度范围内,通过比较磁性状态下的晶胞参数和由高温顺磁状态外延得到的低温顺磁状态下的晶胞参数间的差别计算了Dy2AlFe13Mn3化合物的本征磁致伸缩。结果表明Dy2AlFe13Mn3化合物的本征体磁致伸缩ωS在105到245K的温度范围内随着温度的升高而增大,由105K时的7.0×10-3 增加到245K时的9.1×10-3。随着温度的进一步升高,ωS反而减小。沿c轴方向的本征线磁致伸缩λc随着温度的升高而减小。基面内的本征线磁致伸缩λa在105到270K的温度范围内随着温度的升高而增大,从105K时的0.8×10-3增大到270K时的3.4×10-3,然后随着温度的进一步升高而减小。  相似文献   

5.
    
田晓庆 《物理学报》2008,57(1):286-289
In this paper the growth mechanism of a Te/Bi$_{2}$Te$_{3}$ novelstructure is studied by textit{ab-initio} calculations. The resultsshow that the growth of Te nanorods is determined by the adsorptionenergy of Te atoms on different crystalline Te surfaces. Theadsorption energy of Te on the Te (001) surface is 3.29 eV, which isabout 0.25 eV higher than that of Te on the Te (110). This energydifference makes the preferential growth direction along the $<001>$direction. In addition, the higher surface energy ofBi$_{2}$Te$_{3}$ (110) and the lattice misfit between crystallineBi$_{2}$Te$_{3}$ and Te along $<001>$ direction are considered toexplain the growth of the Bi$_{2}$Te$_{3}$ nanoplatelets, in whichVolmer--Weber model is used. The theoretical results are inagreement with experimental observation.  相似文献   

6.
Strontium and oxygen co-doped La1.937Sr0.063CuO4+δ superconductor with Tc≈ 40K, which is obtained by oxidizing strontium-doped starting ceramic sample La1.937Sr0.063CuO4 in NaC10 solution, is annealed under different conditions to allow interstitial oxygen to redistribute. The evolution of the intrinsic superconducting property with the oxygen redistribution is studied in detail by magnetic measurements in various fields. It is found that there occurs the electronic phase separation from the single superconducting phase with Tc ≈ 40 K into two coexisting superconducting states with values of Tc: 15 and 40K or of 15 and 35 K in this system, depending on annealing condition. Our results indicate that the 15, 35 and 40 K superconducting phases associated with the excess oxygen redistribution are all thermodynamically meta-stable intrinsic states in this Sr/O co-doped cuprate.  相似文献   

7.
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张莉  罗文浪  阮文  蒋刚  朱正和 《中国物理 B》2008,17(6):2023-2026
Using the different level of methods B3P86, BLYP, B3PW91, HF, QCISD、 CASSCF (4,4) and MP2 with the various basis functions 6-311G^**, D95, cc-pVTZ and DGDZVP, the calculations of this paper confirm that the ground state is X^-3B1 with C2v group for CH2. Furthermore, the three kinds of theoretical methods, i.e. B3P86、 CCSD(T, MP4) and G2 with the same basis set cc-pVTZ only are used to recalculate the zero-point energy revision which are modified by scaling factor 0.989 for the high level based on the virial theorem, and also with the correction for basis set superposition error. These results are also contrary to X^-3∑^-g for the ground state of CH2 in reference. Based on the atomic and molecular reaction statics, this paper proves that the decomposition type (1) i.e. CH4 →CH2+H2, is forbidden and the decomposition type (2) i.e. CH4→CHa+H is allowed for CH4. This is similar to the decomposition of SiH4.  相似文献   

8.
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方志杰  石丽洁  刘永辉 《中国物理 B》2008,17(11):4279-4284
This paper studies the electronic structure and native defects in transparent conducting oxides CuScO2 and CuYO2 using the first-principle calculations. Some typical native copper-related and oxygen-related defects, such as vacancy, interstitials, and antisites in their relevant charge state are considered. The results of calculation show that, CuMO2(M = Sc, Y) is impossible to show n-type conductivity ability. It finds that copper vacancy and oxygen interstitial have relatively low formation energy and they are the relevant defects in CuScO2 and CuYO2. Copper vacancy is the most efficient acceptor, and under O-rich condition oxygen antisite also becomes important acceptor and plays an important role in p-type conductivity.  相似文献   

9.
马仲发  庄奕琪  杜磊  魏珊 《中国物理》2005,14(4):808-811
Based on percolation theory and random telegraph signal (RTS) noise generation mechanism, a numerical model for RTS in deep submicron metal-oxide-semiconductor field-effect transistor (MOSFET) was presented, with which the dependence of Tc/Te (where Tc=capture time, Te=emission period ) on energy levels and trap depth with respect to the interface of traps can be simulated. Compared with experimental results, the simulated ones showed a good qualitative agreement.  相似文献   

10.
杨新波  徐军  李红军  毕群玉  程艳  苏良碧  唐强 《中国物理 B》2010,19(4):47803-047803
Recently, α-Al2O3:C crystal with highlysensitive thermoluminescence (TL) and optically stimulatedluminescence (OSL) has been successfully grown by the temperature gradienttechnique. This paper investigates the heating rate dependence of TLsensitivity, light-induced fading of TL signals and thermalstability of OSL of α-Al2O3:C crystals. As theheating rate increases, the integral TL response decreases and thedosimetric glow peak shifts to higher temperatures in α-Al2O3:C crystals. Light-induced fading of TL increaseswith the irradiation dose, and TL response decreases as the exposuretime increases, especially in the first 15 minutes. With theincreasing intensity of the exposure light, the TL fading of α-Al2O3:C crystal increases sharply. The OSL response ofas-grown α-Al2O3:C crystal is quite stable below373 K and decreases sharply for higher temperatures.  相似文献   

11.
    
赵培涛 《物理学报》2008,57(1):335-342
Lidar (Light detection and ranging) has special capabilities forremote sensing of many different behaviours of the atmosphere. Oneof the techniques which show a great deal of promise for severalapplications is Raman scattering. The detecting capability,including maximum operation range and minimum detectable gasconcentration is one of the most significant parameters for lidarremote sensing of pollutants. In this paper, based on the new methodfor evaluating the capabilities of a Raman lidar system, we presentan evaluation of detecting capability of Raman lidar for monitoringatmospheric CO$_{2}$ in Hefei. Numerical simulations about theinfluence of atmospheric conditions on lidar detecting capabilitywere carried out, and a conclusion can be drawn that the maximumdifference of the operation ranges caused by the weather conditionsalone can reach about 0.4 to 0.5km with a measuring precision within30ppmv. The range of minimum detectable concentration caused by theweather conditions alone can reach about 20 to 35 ppmv in verticaldirection for 20000 shots at a distance of 1 km on the assumptionthat other parameters are kept constant. The other correspondingparameters under different conditions are also given. The capabilityof Raman lidar operated in vertical direction was found to besuperior to that operated in horizontal direction. During practicalmeasurement with the Raman lidar whose hardware components werefixed, aerosol scattering extinction effect would be a significantfactor that influenced the capability of Raman lidar. This work maybe a valuable reference for lidar system designing, measurementaccuracy improving and data processing.  相似文献   

12.
<正>T’-phase electron-doped superconductor Pr1-xLaCexCuO4-δ(PLCCO) thin films are successfully prepared on SrTiO3(100) substrates by using the dc magnetron sputtering method.It is found that the films each have a highly oriented structure along the c-axis.For optimally doped films with x≈0.10,the superconducting transition temperature Tc is 23.5 K,which is similar to that of a single crystal.The quadratic temperature dependence of the resistivity is observed when T > Tc,which can be attributed to the two-dimensional Fermi liquid behaviour.Besides,the optimal conditions for preparing the T’-phase PLCCO thin films are also discussed in detail.  相似文献   

13.
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陈振岗  谢尊  李有成  马庆敏  刘英 《中国物理 B》2010,19(4):43102-043102
The low-energy structures and the electronic and themagnetic properties of small NiNiNi$_{m}$Ti$_{n}$ clusters, lowest-energy structure,electronic and magnetic propertiesProject supported by the NationalNatural Science Foundation of China (Grant No.~10874039), and theNatural Science Foundation of Hebei Province of China (GrantNos.~A2009000246 and 2009000243).3120A, 3640B, 2110K7/3/2009 12:00:00 AMThe low-energy structures and the electronic and themagnetic properties of small NiNiNi$_{m}$Ti$_{n}$ clusters, lowest-energy structure,electronic and magnetic propertiesProject supported by the NationalNatural Science Foundation of China (Grant No.~10874039), and theNatural Science Foundation of Hebei Province of China (GrantNos.~A2009000246 and 2009000243).3120A, 3640B, 2110K7/3/2009 12:00:00 AMThe low-energy structures and the electronic and themagnetic properties of small Ni$_{n}$Ti$_{n}$ ($n=1$--$6$) andNi$_{m}$Ti$_{n}$ ($1 le n le 4$, $1 le m le 4$, $n ne m$)clusters are investigated by performing all-electron calculationsbased on density functional theory. Ground states and severalisomers near the ground states are determined for these clusters.The results indicate that the growth of small Ni$_{m}$Ti$_{n}$clusters prefers to form rich Ti--Ni and Ti--Ti bonds. When thepercentage of titanium atoms is significantly greater than that ofnickel atoms, the nickel atoms are most frequently found abovethe surface; in contrast, the titanium atoms prefer the bridgingsites. A M\"{u}lliken spin population analysis indicates that thetotal spin of titanium-nickel clusters is not always zero.http://cpb.iphy.ac.cn/CN/10.1088/1674-1056/19/4/043102https://cpb.iphy.ac.cn/CN/article/downloadArticleFile.do?attachType=PDF&id=111644NimTin;clusters;lowest-energy;structure;electronic;and;magnetic;propertiesThe low-energy structures and the electronic and the magnetic properties of small Nin Tin(n = 1-6) and Ni m Ti n(1 ≤ n ≤ 4,1 ≤ m ≤ 4,n ≠ m) clusters are investigated by performing all-electron calculations based on density functional theory.Ground states and several isomers near the ground states are determined for these clusters.The results indicate that the growth of small Ni m Ti n clusters prefers to form rich Ti-Ni and Ti-Ti bonds.When the percentage of titanium atoms is significantly greater than that of nickel atoms,the nickel atoms are most frequently found above the surface;in contrast,the titanium atoms prefer the bridging sites.A Mu¨lliken spin population analysis indicates that the total spin of titanium-nickel clusters is not always zero.  相似文献   

14.
    
In this paper, the cosmological model of the Universe has been presented in f ( Q ) $f(Q)$ gravity and the parameters are constrained from the cosmological data sets. At the beginning, a well motivated form of f ( Q ) = α + β Q n $f(Q) = alpha + beta Q^{n}$ has been employed, where α, β, and n are model parameters. The Hubble parameter is obtained in redshift with some algebraic manipulation from the considered form of f ( Q ) $f(Q)$ . Then it is parameterized with the recent Hubble $text{Hubble}$ data and Pantheon + SHOES $text{Pantheon} + text{SHOES}$ data using Markov chain Monte Carlo analysis. The obtained model parameter values are validated with the baryon acoustic oscillation data set. A parametrization of the cosmographic parameters shows the early deceleration and late time acceleration with the transition at z t 0.75 $z_text{t}approx 0.75$ . The O m ( z ) $Om(z)$ diagnostics gives positive slope which shows that the model is in the phantom phase. Also the current age of the Universe has been obtained as, t 0 = 13.85 Gyrs $t_{0} = 13.85nobreakspace nobreakspace text{Gyrs}$ . Based on the present analysis, it indicates that the f ( Q ) $f(Q)$ gravity may provide an alternative to dark energy for addressing the current cosmic acceleration.  相似文献   

15.
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刘莉  苏雄睿 《中国物理 B》2008,17(6):2170-2174
This paper reports that single-layer and graded Au-TiO2 granular composite films with Au atom content 15%- 66% were prepared by using reactive co-sputtering technique. The third-order optical nonlinearity of single-layer and graded composite films was investigated by using s- and p-polarized Z-scans in femtosecond time scale. The nonlinear absorption coefficient βeff of single-layer Au-TiO2 films is measured to be -2.3×10^3-0.76×10^3 cm/GW with Au atom content 15%-66%. The βeff value of the 10-layer Au-TiO2 graded film is enhanced to be -2.1×10^4cm/GW calculated from p-polarized Z-scans, which is about ten times the maximum βeff of single-layer films. Broadened response in the wavelength region 730-860 nm of the enhanced optical nonlinearity of graded Au-TiO2 composite films was also investigated.  相似文献   

16.
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阎世英 《中国物理 B》2008,17(8):2925-2931
Density functional theory (DFT) (B3P86) of Gaussian 03 has been used to optimize the structure of the Cr2 molecule, a transition metal element molecule. The result shows that the ground state for the Cr2 molecule is a 13- multiple state, indicating that there exists a spin polarization effect in the Cr2 molecule. Meanwhile, we have not found any spin pollution because the wave function of the ground state does not mingle with wave functions of higher-energy states. So the ground state for Cr2 molecule being a 13-multiple state is indicative of spin polarization effect of the Cr2 molecule among transition metal elements, that is, there are 12 parallel spin electrons in the Cr2 molecule. The number of non-conjugated electrons is greatest. These electrons occupy different spatial orbitals so that the energy of the Cr2 molecule is minimized. It can be concluded that the effect of parallel spin in the Cr2 molecule is larger than the effect of the conjugated molecule, which is obviously related to the effect of electron d delocalization. In addition, the Murrell Sorbie potential functions with the parameters for the ground state and other states of the Cr2 molecule are derived. The dissociation energy De for the ground state of the Cr2 molecule is 0.1034eV, equilibrium bond length Re is 0.3396 nm, and vibration frequency we is 73.81cm^-1. Its force constants f2, f3 and f4 are 0.0835, -0.2831 and 0.3535 aJ. nm^-4 respectively. The other spectroscopic data for the ground state of the Cr2 molecule ωeχe, Be and αe are 1.2105, 0.0562 and 7.2938 x 10^-4cm^-1 respectively.  相似文献   

17.
杨海贵  戴振文  孙志伟 《中国物理》2006,15(6):1273-1277
The luminescence of Er^3+:YAlO3 in ultraviolet visible and infrared ranges under the 518 nm excitation of the multiples ^2H11/2 have been investigated. Ultraviolet (275 nm and 318 nm), violet (405 nm and 413 nm) and blue (474 nm) upconversion and infrared downconversion luminescence has been observed. By means of measuring the fluorescence decay curves and using the theory of rate equations, the luminescence kinetics was studied in detail and the processes of energy transfer upconversion (ETU) and excitation state absorption (ESA) were proposed to explain the upconversion phenomena.  相似文献   

18.
19.
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沈俊  李养贤  王芳  王光军  张绍英 《中国物理》2004,13(7):1134-1138
Effect of Co substitution on magnetic properties and magnetic entropy changes in LaFe_{11.83}Si_{0.94}Al_{0.23} compounds has been investigated by means of magnetization measurements. X-ray diffraction shows the prepared compounds to be single phase with the cubic NaZn_{13}-type structure. Substitution of Co for Fe leads to an increase of Curie temperature of the material. The magnetic entropy changes in LaFe_{11.83}Si_{0.94}Al_{0.23} and LaFe_{11.03}Co_{0.80}Si_{0.94}Al_{0.23} compounds are 21.8J/(kg·K) to 16.9J/(kg·K) under a magnetic field change of 0-5T at Curie temperature, respectively. Giant magnetic entropy changes are attributed to the higher magnetization and the rapid change in magnetization at Curie temperature.  相似文献   

20.
张晓丹  赵杰  王永晨  金鹏 《发光学报》2002,23(2):119-123
采用光荧光谱(PL)和光调制反射谱(PR)的方法,研究了由Si3N4、SiO2电介质盖层引起的无杂质空位(IFVD)诱导的InGaAsP四元化合物半导体多量子阱(MQWs)结构的带隙蓝移。实验中Si3N4、SiO2作为电介质盖层,用来产生空位,再经过快速热退火处理(RTA)。实验结果表明:多量子阱结构带隙蓝移和退火温度、复合盖层的组合有关。带隙蓝移随退火温度的升高而加大。InP、Si3N4复合盖层产生的带隙蓝移量大于InP、SiO2复合盖层。而InGaAs、SiO2复合盖层产生的带隙蓝移量则大于InGaAs、Si3N4复合盖层。同时,光调制反射谱的测试结果与光荧光测试的结果基本一致,因此,PR谱是用于测试带隙变化的另一种方法。  相似文献   

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