共查询到20条相似文献,搜索用时 312 毫秒
1.
D. Mohanta G.A. Ahmed A. Choudhury F. Singh D.K. Avasthi 《Journal of nanoparticle research》2006,8(5):645-652
ZnS:Mn nanoparticles of size variation 11–17 nm were synthesized by a simple and inexpensive chemical method and confirmed by transmission electron microscopy (TEM). Presuming electronic energy loss (S
e>S
n, S
n being nuclear energy loss) to be the dominant phenomenon, they were irradiated by 80-MeV energetic oxygen ions with fluence of 1011 to 1013 ions/cm2. Photoluminescence (PL) spectra revealed three major emission bands ~445 nm, ~582 nm and ~706 nm; which are ascribed to D–A pair transition, Mn emission and surface state led fluorescence activation. The recovery of Mn emission and tunable surface state emission have been observed with ion fluence variation. Infra-red (IR) spectra of irradiated samples show great extent of oscillation with respect to amplitude due to ion fluence variation however, phonon energy (~98 MeV) remains unchanged. The possible applications of these modified properties in nanophotonics are also highlighted. 相似文献
2.
W. Cassing Ye.S. Golubeva L.A. Kondratyuk 《The European Physical Journal A - Hadrons and Nuclei》2000,7(2):279-285
We study the possibility to measure the elastic ΦN (Φ≡J/ψ,ψ(2S), ψ(3770), χ2c) scattering cross section in the reaction ˉp+d→Φ+n
sp and the elastic D(ˉD)N scattering cross section in the reaction ˉp+d→D
−
D
0
p
sp. Our studies indicate that the elastic scattering cross sections can be determined for Φ momenta about 4–6 GeV/c and D/ˉD momenta 2–5 GeV/c by selecting events with p
t≥ 0.4 GeV/c for Φ's and p
t(p
sp) ≥ 0.5 GeV/c for D/ˉD-meson production.
Received: 8 November 1999 相似文献
3.
Luteolin and apigenin, extracted from Reseda luteola L., were spectrophotometrically and fluorimetrically studied. The spectra were investigated as a function of pH in methanol/water
solutions (1/2, v/v) in the 2–12 pH range. The absorption spectra markedly shifted to the red by increasing the pH. Three acid–base dissociation
steps were detected for luteolin (pK
a = 6.9; 8.6; 10.3) and two for apigenin (pK
a = 6.6; 9.3). Fluorescence emission was very weak or undetectable (Φ
F < 10−4) in acidic solution, but increased in intensity with increasing the pH. Both molecules exhibited a great propensity towards
complex formation with metal ions, with association constants on the order of 105–107 for the first complexation step; in the presence of excess Al3+ ions, multiple equilibria were detected. A marked fluorescence enhancement was observed upon complexation with Al3+ ions (Φ
F ∼ 1 for luteolin and ∼10−2 for apigenin). 相似文献
4.
V. G. Slutskii E. S. Severin L. A. Polenov 《Russian Journal of Physical Chemistry B, Focus on Physics》2010,4(3):515-516
Boron-containing (C2B4H2)
n
nanoparticles with size 6.7, 7.8, and 10.8 nm inert at room temperature were synthesized. The synthesis was performed by
the pyrolysis of gaseous carborane C2B4H6 at 1200–1280 K and the initial carborane pressure (5–25) × 10−3 MPa. An analytic dependence relating the size of nanoparticles to the temperature and initial carborane pressure was obtained. 相似文献
5.
Hyun Seok Yang 《The European Physical Journal C - Particles and Fields》2009,64(3):445-457
We map noncommutative (NC) U(1) gauge theory on ℝ
C
d
×ℝ
NC
2n
to U(N→∞) Yang–Mills theory on ℝ
C
d
, where ℝ
C
d
is a d-dimensional commutative spacetime while ℝ
NC
2n
is a 2n-dimensional NC space. The resulting U(N) Yang–Mills theory on ℝ
C
d
is equivalent to that obtained by the dimensional reduction of (d+2n)-dimensional U(N) Yang–Mills theory onto ℝ
C
d
. We show that the gauge-Higgs system (A
μ
,Φ
a
) in the U(N→∞) Yang–Mills theory on ℝ
C
d
leads to an emergent geometry in the (d+2n)-dimensional spacetime whose metric was determined by Ward a long time ago. In particular, the 10-dimensional gravity for
d=4 and n=3 corresponds to the emergent geometry arising from the 4-dimensional N=4{\mathcal{N}}=4 vector multiplet in the AdS/CFT duality. We further elucidate the emergent gravity by showing that the gauge-Higgs system
(A
μ
,Φ
a
) in half-BPS configurations describes self-dual Einstein gravity. 相似文献
6.
L. K. Neudachina E. V. Dedyukhina O. V. Evdokimova N. V. Pechishcheva E. V. Osintseva K. Yu. Shunyaev 《Journal of Applied Spectroscopy》2010,77(2):206-212
The fluorescence properties of N,N-di(2-carboxyethyl)-p-anisidine (I) in solvents of various nature and in the crystalline state have been studied at room temperature (273 K) and at the boiling
point of liquid nitrogen (77 K). Fluorescence in aqueous solutions of I with protonated (λ
ex
/λ
fl
max
= 225/290 nm) and unprotonated (λ
ex
/λ
fl
max
= 270/380 nm) amino nitrogen has been detected. On going from aqueous solutions to nonaqueous, the fluorescence band of unprotonated
I experiences a blue shift and its intensity rises. The fluorescence intensity of the band in aprotic polar solvents is higher
than that in protic solvents. A linear dependence of the fluorescence intensity of deprotonated I on Cu(II) concentration (ranging from 1.0 to 5.0 mg/dm3) in aqueous solution has been found. The fluorescence intensity of I in aqueous solutions at 77 K and pH 1–6 has been shown to increase in the presence of Zn(II) (1–170 mg/dm3) and Cd(II) (2–330 mg/dm3) although a similar dependence is not observed at 293 K. 相似文献
7.
A. I. Klyndyuk 《Physics of the Solid State》2009,51(2):270-274
The electrical resistivity ρ and the thermopower S of ceramic materials LnBaCuFeO5 + δ (Ln= La, Pr, Nd, Sm, Gd-Lu) are measured in air at temperatures in the range from 300 to 1100 K. All the studied ferrocuprates
are p-type semiconductors. The electrical resistivity ρ and the thermopower S of these compounds increase with a decrease in the radius of the Ln
3+ cation (with an increase in the number of 4f electrons n in Ln
3+). The nonmonotonic behavior of the dependences ρ=f(n) and S=f(n) indicates that the electrical properties of the layered ferrocuprates LnBaCuFeO5 + δ depend on the electronic configuration of the Ln
3+ cation. The power factors P calculated for the LnBaCuFeO5 + δ ceramic materials from the experimental values of ρ and S increase with increasing temperature and, at T = 1000 K, reach the maximum values P = 102.0 and 54.1 μW m−1 K−2 for Ln = Pr(4f
2) and Sm(4f
5), respectively, and become close to each other and equal to 30–35 μW m−1 K−2 for Ln = Gd(4f
7), Dy(4f
9), and Ho(4f
10). 相似文献
8.
0 –S1–Sm–Sn multilevel system. An Sm→S1 absorption recovery time of τS1
A=(600±100) fs is determined. The picosecond and femtosecond pulse excitation leads to S0→S1 ground-state absorption bleaching and S1→Sm first excited-state absorption bleaching. The excited-state absorption cross-sections σS1
ex(S1→Sm) and σSm
ex(Sm→Sn) are determined.
Received: 3 June 1996 相似文献
9.
Five benzimidazole compounds containing pyrazole group were synthesized via one-step reaction of o-phenylenediamine and 1-arylpyrazole-4-carbaldehyde in ethanol under mild conditions. The composition and structure of resultant
benzimidazole compounds were analyzed by means of elemental analysis, mass spectrometry, 1H-nuclear magnetic resonance spectroscopy and X-ray single crystal diffraction. The ultraviolet–visible light spectra and
fluorescent spectra of the products were measured. Their ground-state (S
0) equilibrium geometries and vibrational frequencies were determined based on B3LYP method, and their first excited-state
(S
1) geometries were fully optimized based on 6–31G (d, p) basis set of TD-B3LYP method. Besides, the spectroscopic properties of the products were computed based on cc-pVTZ basis
set of TD-B3LYP method and compared with corresponding experimental data. It has been found that benzimidazole compounds containing
pyrazole group can be readily synthesized in a high yield via one-step reaction of o-phenylenediamine and 1-arylpyrazole-4-carbaldehyde in ethanol solvent. The fluorescence properties of the five synthesized
compounds are closely related to their molecular structure; and their computed fluorescence spectra well correspond to their
experimental values. Moreover, they have stable structure and strong fluorescence, showing potential application in time-resolved
fluoroimmunoassay and DNA probe. 相似文献
10.
S. L. Bondarev V. N. Knyukshto S. A. Tikhomirov A. N. Pyrko 《Optics and Spectroscopy》2003,94(6):928-933
The spectral-luminescent properties and electronic-level structure of a derivative of oxotetrahydrobenzo[c]phenanthridine—3,3-dimethyl-1,2,3,4-tetrahydrobenzo[c]phenanthridine-1-one
(DTP)—in polar and nonpolar solutions are studied by the luminescence and picosecond spectroscopy techniques at 293 and 77
K. It is shown that DTP exhibits ππp* fluorescence only in polar proton-containing methanol, ethanol, and n-propanol and that this fluorescence is associated with a chromophore + alcohol complex. Solutions of DTP in n-propanol and the nonpolar mixture methylcyclohexane + toluene (6:1) at 77 K display ππp* phosphorescence with a quantum yield
ΦPh=0.1, a lifetime τPh=1.9 s, and a frequency of the 0-0 transition equal to 21550 cm−1. The fact that DTP fluorescence is absent in aprotic solvents and exists in alcohols is explained by the inversion of the
energy levels of the S
ππ* and T
n
π* states, as a result of which the energy level of the fluorescing S
ππ* state in alcohol becomes the lowest. The picosecond spectra and kinetics of the inducedS
n
(ππ*) ← S
1(π π*) and T
k
(ππ*) ← T
1(ππ*) absorption made it possible to estimate the lifetime of the S
1(ππ*) state of DTP in n-propanol at 293 K (20±10 ps) and the position of the triplet-triplet absorption peak (495 nm).
__________
Translated from Optika i Spektroskopiya, Vol. 94, No. 6, 2003, pp. 993–998.
Original Russian Text Copyright ? 2003 by Bondarev, Knyukshto, Tikhomirov, Pyrko. 相似文献
11.
Approximating the shape of the magneto-thermoelectric power (TEP) ΔS(T,H) measured in Bi2Sr2CaCu2Oy by an asymmetric linear triangle of the form ΔS(T,H)≃S
p
(H)±B
±(H)(T
c
−T) with positive B
−(H) and B
+(H) defined below and above T
c
, we observe that B
+(H) ≃2B
−(H). To account for this asymmetry, we explicitly introduce the field-dependent chemical potential μ(H) of holes into the Ginzburg-Landau theory and calculate both an average ΔS
av(T,H) and fluctuation contribution ΔS
fl(T,H) to the total magneto-TEP ΔS(T,H). As a result, we find a rather simple relationship between the field-induced variation of the chemical potential in this
material and the above-mentioned magneto-TEP data around T
c
, viz. Δ μ(H)∝S
p
(H).
Zh. éksp. Teor. Fiz. 116, 257–262 (July 1999)
Published in English in the original Russian journal. Reproduced here with stylistic changes by the Translation Editor. 相似文献
12.
A. V. Voitsekhovskii V. V. Vasil’ev D. V. Grigor’ev I. V. Romanov 《Russian Physics Journal》2009,52(5):441-447
The process of reconstuction of the distribution profile of hole concentration in the p
+–n structure by the method of differential Hall measurements upon implantation of ions As+ (Е = 190 keV, D = 3.1014 cm-2, j = 0.025 μA/cm2) into epitaxial films Cd
x
Hg1–x
Te for x ~ 0.2, with the initial electron concentration and mobility n = 1014 cm-3 and μ = 2∙105 cm2∙V–1∙s–1 is numerically simulated. The dependences of degree of reconstruction of the hole-concentration distribution profile on the
depth of a shunting n-layer and magnitude of the magnetic field, at which the electrophysical parameters of the p
+–n structure are measured, are calculated. The dependence of the limiting magnetic field determining the magnetic-field range
for measurements on the n-layer depth is found. It is shown that in calculations one should use the conduction values measured
at the same magnetic fields as the Hall coefficients for determination of the holeconcentration distribution profile using
the Petritz model. 相似文献
13.
Chiral and racemic molecular ferrimagnets [MnII(HL)(H2O)][MnIII(CN)6] · 2H2O, where L = S-or R-1,2-diaminopropane for chiral samples (S-pn, R-pn) and L = rac-pn for racemic samples, are investigated by the electron spin resonance technique. It is revealed that the electron spin resonance
spectra of the chiral and racemic samples differ from each other at temperatures below the Curie temperature T
C = 21 K. The maximum in the temperature dependence of the integrated magnetic susceptibility χ(T) calculated by the double integration of the line centered at a negative field of −250 Oe for the racemic samples is broadened
as compared to the maxima in the corresponding dependences for the enantiomers of the chiral samples with “right” (R) and “left” (S) symmetry. The new compounds under investigation differ from the previously synthesized crystals by the strong spin-orbit
interaction between Mn3+ ions, which leads to a dependence of their magnetic properties on the chirality of the structure.
Original Russian Text ? R.B. Morgunov, F.B. Mushenok, M.V. Kirman, 2008, published in Fizika Tverdogo Tela, 2008, Vol. 50,
No. 7, pp. 1252–1256. 相似文献
14.
I. N. Ogorodnikov N. E. Poryvay I. N. Sedunova A. V. Tolmachev R. P. Yavetskiy 《Physics of the Solid State》2011,53(2):263-270
The thermally stimulated recombination processes and luminescence in crystals of the lithium borate family Li6(Y,Gd,Eu)(BO3)3 have been investigated. The steady-state luminescence spectra under X-ray excitation (X-ray luminescence spectra), the temperature
dependences of the X-ray luminescence intensity, and the glow curves for the Li6Gd(BO3)3, Li6Eu(BO3)3, Li6Y0.5Gd0.5(BO3)3: Eu, and Li6Gd(BO3)3: Eu compounds have been measured in the temperature range 90–500 K. In the X-ray luminescence spectra, the band at 312 nm
corresponding to the 6
P
J
→ 8
S
7/2 transitions in the Gd3+ ion and the group of lines at 580–700 nm due to the 5
D
0 → 7
F
J
transitions (J = 0–4) in the Eu3+ ion are dominant. For undoped crystals, the X-ray luminescence intensity of these bands increases by a factor of 15 with
a change in the temperature from 100 to 400 K. The possible mechanisms providing the observed temperature dependence of the
intensity and their relation to the specific features of energy transfer of electronic excitations in these crystals have
been discussed. It has been revealed that the glow curves for all the crystals under investigation exhibit the main complex
peak with the maximum at a temperature of 110–160 K and a number of weaker peaks with the composition and structure dependent
on the crystal type. The nature of shallow trapping centers responsible for the thermally stimulated luminescence in the range
below room temperature and their relation to defects in the lithium cation sublattice have been analyzed. 相似文献
15.
The layered LiNi0.5Mn0.47Al0.03O2 was synthesized by wet chemical method and characterized by X-ray diffraction and analysis of magnetic measurements. The
powders adopted the α-NaFeO2 structure. This substitution of Al for Mn promotes the formation of Li(Ni0.472+Ni0.033+Mn0.474+Al0.033+)O2 structures and induces an increase in the average oxidation state of Ni, thereby leading to the shrinkage of the lattice
unit cell. The concentration of antisite defects in which Ni2+ occupies the (3a) Li lattice sites in the Wyckoff notation has been estimated from the ferromagnetic Ni2+(3a)–Mn4+(3b) pairing observed below 140 K. The substitution of 3% Al for Mn reduces the amount of antisite defects from 7% to 6.4–6.5%.
The analysis of the magnetic properties in the paramagnetic phase in the framework of the Curie–Weiss law agrees well with
the combination of Ni2+ (S = 1), Ni3+ (S = 1/2) and Mn4+ (S = 3/2) spin-only values. Delithiation has been made by the use of K2S2O8. According to this process, known to be softer than the electrochemical one, the nickel ions in the (3b) sites are converted into Ni4+ in the high spin configuration, while Ni2+(3a)–Mn4+(3b) ferromagnetic pairs remain, as the Li+(3b) ions linked to the Ni2+(3a) ions in the antisite defects are not removed. The results show that the antisite defect is surrounded by Mn4+ ions, implying the nonuniform distribution of the cations in agreement with previous NMR and neutron experiments. 相似文献
16.
Sujittra Daengsakul Charusporn Mongkolkachit Chunpen Thomas Sineenat Siri Ian Thomas Vittaya Amornkitbamrung Santi Maensiri 《Applied Physics A: Materials Science & Processing》2009,96(3):691-699
This study reports the new and simple synthesis of magnetic La0.7Sr0.3MnO3 (LSMO) nanoparticles by thermal decomposition method using acetate salts of La, Sr and Mn as starting materials. To obtain
the LSMO nanoparticles, thermal decomposition of the precursor is carried out at the temperatures of 600, 700, 800, 900, and
1000°C for 6 hours. The synthesized LSMO nanoparticles were characterized by XRD, FT-IR, TEM and SEM. Structural characterization
shows that the prepared particles consisted of two phases of LaMnO3 (LMO) and LSMO with crystallite sizes ranging from 18 to 55 nm. All the prepared samples have a perovskite structure which
changes from cubic to rhombohedral with the increase in the thermal decomposition temperature. Basic magnetic characteristics
such as saturation magnetization (M
S) and coercive field (H
C) are evaluated by sample vibrating magnetometry at room temperature (20°C). The samples show soft ferromagnetic behavior
with M
S values of ∼9–55 emu/g and H
C values of ∼8–37 Oe, depending on the crystallite size and thermal decomposition temperature. The relationship between the
crystallite size and the magnetic properties is presented and discussed. The cytotoxicity of synthesized LSMO nanoparticles
was also evaluated with NIH 3T3 cells and the result showed that the synthesized nanoparticles were not toxic to the cells
as determined from cell viability in response to the liquid extraction of LSMO nanoparticles. 相似文献
17.
The magnetic properties of complex oxides Ln
2Mn2/3Mo4/3O7 (Ln=Sm, Gd, Tb, or Y) with a pyrochlore-type structure are studied in the temperature range 2–300 K. For all compounds in the
paramagnetic state, the temperature dependence of the magnetic susceptibility is described by a generalized Curie-Weiss law
with a temperature-independent component of ∼10−6 cm3/g and with a Weiss constant Θ<0 and |Θ|<16 K. At low temperatures (T<10–12 K), the compounds have spin-glass properties; they exhibit magnetic and temperature hysteresis and the typical dependences
of the imaginary and real parts of the dynamic magnetic susceptibility on temperature and the frequency of an ac magnetic
field in a wide range of magnetization relaxation times. The data obtained suggest that d electrons are responsible for the formation of frustrated exchange interactions in the compounds and that 4f electrons in the compounds with Sm or Tb provide strong magnetic-anisotropy effects.
__________
Translated from Fizika Tverdogo Tela, Vol. 46, No. 2, 2004, pp. 287–295.
Original Russian Text Copyright ? 2004 by Korolev, Bazuev. 相似文献
18.
E. S. Itskevich 《Journal of Experimental and Theoretical Physics》1998,86(4):805-810
A study is made of the properties of the homologous series of mercury HTSC-cuprates HgBa2Can−1CunO2n
+2+δ with n=1–8. Experiments are conducted under pressure for samples with n=1–5. The Hg-1223 and Hg-1234 phases were synthesized using a controlled high pressure chamber. The oxygen content of an initial
mixture corresponding to the Hg-1234 phase was varied by changing the composition of the initial BaO/BaO2 oxides. The dependence of the superconducting transition temperature T
c
on the lattice constant a (and, therefore, on the oxygen content) and of T
c
max
and dT
c
max
/dp on n are convex upward up to n=4, 5. The maximum values always correspond to the Hg-1223 phase. Experimental T
c
max
(n) curves for the phases with n=1–6 and dT
c
max
/dp curves for n=1–5 are compared with Anderson’s theory (the so-called RVB model). A general analysis of these results indicates that the
mercury cuprates have an ideal structure for HTSC. The Hg-1223 phase is the “champion” in this ideal structure and the critical
temperature corresponding to this phase (T
c
=135 K) is the highest at atmospheric pressure.
Zh. éksp. Teor. Fiz. 113, 1474–1483 (April 1998) 相似文献
19.
The crystallization and glass transition kinetics using differential scanning calorimetry (DSC) in 50AgI–33.33Ag2O–16.67[(V2O5)1−x
–(MoO3)
x
] superionic glassy system is discussed. Thermal stability of glass, studied using various criteria, does not vary significantly
with glass former variation. However, the activation energies for structural relaxation (E
s) at glass transition temperature and crystallization (E
c) obtained using Moynihan and Kissinger, Matusita-Sakka formulations found to exhibit interesting trends with MoO3 substitution in the glass matrix. It is noticed that the electrical conductivity (σ)–temperature (T) cycles obtained at a typical heating rate of 1 °C/min do exhibit significant thermal events. The conductivity after first
heating cycle at room temperature is found to be increasing with MoO3 content and maximum for x = 0.3 (~10−3 Ω−1 cm−1 at 30 °C) which is comparable to that of the host 50AgI–33.33Ag2O–16.67V2O5 glassy system. The parameters obtained from σ–T plots and DSC scans do complement each other in a particular range of composition. 相似文献
20.
Explicit expressions have been derived for the volume dependence of electron-phonon coupling strength (λ) and the Coulomb pseudopotential (μ*) considering the variation of Fermi momentum (κ
F) and Debye temperature (θ
D) with volume. Ashcroft’s model pseudopotential and RPA form of dielectric screening have been used for obtaining pressure
dependence of transition temperature (T
C) and the logarithmic volume derivative (Φ) of the effective interaction strength (N
0
V) for metallic glass superconductor Mg70Zn30. It has been observed that T
C of the metallic glass Mg70Zn30 decreases rapidly with increase of pressure and the superconducting phase disappears at about 30% decrease of volume, for
which the μ* curve shows a minimum and an elbow is formed in the Φ graph. 相似文献