27Al+27Al重离子耗散碰撞中能量自关联函数的分析

测量了²⁷Al+²⁷Al耗散反应产物的激发函数,束流²⁷Al⁸⁺的入射能量从114MeV到127MeV变化,能量步长为200keV.探测角度覆盖了实验室系10°—57°的连续区域.用不同的理论模型分析了耗散产物的能量自关联函数.结果表明,反应所形成的中间双核系统的阻尼相干转动造成了激发函数中不可平滑的涨落结构,相干转动的阻尼来自量子混沌运动.     

27Al+27Al耗散产物反应时间的提取

用发展了的Ericson统计理论,从²⁷Al+²⁷Al碰撞的耗散产物的激发函数提取了反应的相互作用时间约4.3×10^－21s.     

27Al+27Al耗散反应截面涨落的角度关联测量

在²⁷Al+²⁷Al(E_lab≈120MeV)耗散反应激发函数涨落的实验研究中,首次在较大的角度范围内获得截面涨落的角度关联系数和角度关联函数.实验结果表明,角度关联函数的形状呈现明显的非对称性,角度相干宽度至少为40°;截面涨落在前后角区表现出明显不同的角度相关性.     

27Al+27Al耗散反应中激发函数的测量与统计性质分析

通过测量能量从114—120MeV、能量步长为200keV的重离子耗散反应²⁷Al+²⁷Al从θ(cm)=50°—90°的角分布和激发函数,在对所有宏观出射道积分的基础上,分析了重离子耗散反应中激发函数涨落的物理性质.     

19F+27Al耗散反应产物截面测量中的不重复性

在中国原子能科学研究院的HI-13串列静电加速器上完成了114MeV和118.75MeV的¹⁹F+²⁷Al耗散反应产物B, C, N, O, F, Ne, Na和Mg的微分截面测量. 条形²⁷Al同位素靶的大小尺寸为10mm×50mm, 平均 厚度约67μg/cm². 固定入射束流¹⁹F的能量, 通过移动靶位, 先后轰击了靶上20个不同的位置.实验结果表明, 在弹靶系统、入射能量以及探测系统都相同的多次独立的微分截面测量中, 截面的涨落不呈现高斯型几率分布. 截面测量的这种不重复现象难以用有限计数率的统计性质来解释.     

80.9MeV 16O+27Al能量耗散和核子交换的关系

用带ΔE-E望远镜系统的飞行时间系统测量了80.9MeV ¹⁶O+²⁷Al反应出射产物的三重微分截面d³σ/dA dZ dE.对该反应中所出现的能量耗散和核子交换的关系进行了讨论.     

形变对10.6MeV/u 84Kr+27Al反应裂变前粒子发射的影响

研究了形变效应对10.6MeV/u ⁸⁴Kr+²⁷Al反应中断前粒子发射的影响.发现通过测量的裂变前粒子多重性提取的裂变延迟时间将因此从20×10^－21s减少到5×10^－21s,表明增强的断前粒子发射有一部分来自形变效应的贡献.     

57MeV/u 64Zn+27Al反应中集体流的研究

报道了利用4π带电粒子阵列测量的57MeV/u的⁶⁴Zn轰击²⁷Al反应中的集体物质流.各事件的碰撞参数分类采用平均平行速度方法,反应平面的确定采用横向动量分析方法.实验观察到在反应平面内的集体横向动量(边流参数)随着碰撞参数和粒子产物而变化.     

19F+27Al耗散反应中双核系统的转动与形变

测量了¹⁹F+²⁷Al耗散反应产物B,C,N,O,F和Ne的激发函数,入射束流的能量从110.25MeV到118.75MeV, 能量步长为250keV. 从产物的 能量自关联函数中提取了反应中所形成的中间双核系统的转动惯量, 与相粘模型计算的刚体转动惯量相比较, 结果表明形成的双核系统有大的形变.     

23Al的β+延发质子测量

利用TOF-ΔE和0°注入探测器的方法,鉴别并测量了²³Al β⁺延发质子衰变能谱,通过精密脉冲发生器和计数器测得²³Al的半衰期T_1/2=(476±45)ms.实验中重现了能量为0.216,0.278,0.438,0.479MeV的低能衰变质子.另外,还观察到了一个新的β⁺延发衰变能级E_x=8.916MeV,并给出了它们的相对强度.     

13C-(27)Al TRAPDOR and REDOR experiments for the detection of (13)C-(27)Al dipolar interactions in solids.

We report (13)C-(27)Al double resonance experiments (REDOR and TRAPDOR) on several aluminum organic compounds with the aim of detecting (13)C-(27)Al dipolar couplings and distances in solids. The (13)C and (27)Al pulses are applied to the same probe channel because their resonance frequencies are in close proximity. The different possibilities of controlling the efficiency of the TRAPDOR approach (by varying the (27)Al RF amplitude and the MAS frequency) are investigated. The results indicate that TRAPDOR is superior to REDOR in resolving differences in (13)C-(27)Al distances when choosing the proper experimental conditions. Where known, the crystal structure data are in qualitative agreement with the distance information extracted from our experiments. The experiment should be very valuable in different fields of solid state chemistry, where the interaction of organic and inorganic sample fractions is of fundamental importance.     

高岭土与针铁矿胶结样中27Al、29Si NMR谱与其原子电荷关系

由NMR谱实验得高岭土与针铁矿胶结样中²⁷Al、²⁹Si的化学位移较单一高岭土分别正移了2.7ppm和2.33ppm.由CNDO/2方法计算得到胶结样中Al、Si原子电行比高岭土分别减少了0.0787和0.0286.胶结样中Al、Si原子电荷的减少与²⁷Al、²⁹Si NMR谱化学位移相吻合,可以认为在高岭土与外铁矿的界面上形成了氢键而呈现胶结态.     

Comparison of one and two-neutron transfer near the coulomb barrier for the27Al(18O,16O)29Al,27Al(180,17O)28Al and27Al(13C,12C)28Al reactions

Total reaction cross sections for the transfer reactions²⁷Al(¹⁸O,¹⁶O)²⁹Al,²⁷Al(¹⁸O,¹⁷O)²⁸Al and²⁷Al(¹³C,¹²C)²⁸Al are reported for center-of-mass energies between 13 and 20 MeV for¹⁸O projectiles and between 11 and 17.5 MeV for¹³C projectiles. The reaction products,²⁹Al and²⁸Al, beta decay to²⁹Si and²⁸Si, respectively, and the subsequentγ decays of²⁹Si and²⁸Si were measured. Due to the relatively long beta decay half lives, data were taken in a beam-off mode, resulting in very clean spectra. Total cross sections were calculated and compared with a theoretical model for barrier penetration proposed by C.Y. Wong. Differences between¹⁸O induced one and two-neutron total transfer reaction cross sections are discussed.     

Spin-triplet superconductivity in UNi(2)Al(3) revealed by the (27)Al Knight shift measurement

We report (27)Al Knight shift ( (27)K) measurement on a single-crystal UNi(2)Al(3) that reveals a coexistence of superconductivity and a spin-density-wave (SDW) type of magnetic ordering ( T(SDW) = 4.5 K). The spin part of (27)K, (27)K(s), does not change down to 50 mK across the superconducting (SC) transition temperature T(c) approximately 0.9 K. In contrast with the isostructural compound UPd(2)Al(3) ( T(c) approximately 2 K), which was identified to be a spin-singlet d-wave superconductor, the behavior of (27)K strongly supports that UNi(2)Al(3) , like UPt(3) and Sr(2)RuO(4), belongs to a class of spin-triplet SC pairing state superconductors.     

Study of the excitation functions of27Al(n, α)24Na,27Al(n,p)27Mg and28Si(n,p)28Al reactions

Cross sections for the reactions²⁷Al(n, p)²⁷Mg and²⁸Si(n,p)²⁸Al were measured by activation method between 13.40 and 14.83 MeV neutron energy. An accuracy of about 4% was achieved using the²⁷Al(n, α)²⁴Na reaction as a reference at 14.1 MeV where the relative excitation function has also been measured. Results obtained were compared to a recent compilation and that calculated by the Hauser-Feshbach model. Using the back-shifted level density formula and taking into account the contribution of the separated levels, the calculations were extended to the energy range from the threshold to 18 MeV. A structure was observed in the²⁷Al(n, α)²⁴Na reaction cross section curve around 14 MeV neutron energy.     

Three-dimensional through-bond homonuclear-heteronuclear correlation experiments for quadrupolar nuclei in solid-state NMR applied to (27)Al-O-(31)P-O-(27)Al networks

We present here the first 3D homonuclear/heteronuclear correlation experiment applied to quadrupolar nuclei and making use of the sole scalar J-coupling. This experiment, based on the 2D-Homonuclear-Heteronuclear Single Quantum Correlation (H-HSQC) experiment, uses a relayed transfer from the (27)Al central transition to neighbouring (31)P spins and to the central transition of a second (27)Al. It confirms the correlation map characterizing the two (27)Al and the (31)P NMR signatures of (27)Al-O-(31)P-O-(27)Al chemically bonded molecular motifs.     

Extraction of Nuclear Temperature in 27Al+27Al Dissipative Collision

Energy coherence widths of the dissipative products in the collision ²⁷Al+²⁷Al are extracted from measurement of the excitation functions. Then, the nuclear temperature T of the intermediate dinuclear system are determined, and discussed by using a concept of coherence rotation.     

27Al multiple-quantum MAS NMR of mechanically treated bayerite (alpha-Al(OH)3) and silica mixtures

Two-dimensional 27Al multiple-quantum magic angle spinning (MQMAS) NMR experiments are used to study mixtures of bayerite (alpha-Al(OH)3) with either silicic acid (SiO2.nH2O) or silica gel (SiO2) that have been ground together for varying lengths of time. This mechanical treatment produces changes in the 27Al MAS and MQMAS NMR spectra that correspond to the formation of new Al species. Mean values of the quadrupolar interaction (PQ) and isotropic chemical shift (deltacs) are extracted from the two-dimensional 27Al NMR spectra for each of these species. The presence of significant distributions of both 27Al quadrupolar and chemical shift parameters is demonstrated and the effect of grinding duration on the magnitudes of these distributions is discussed.     

Messung von Wirkungsquerschnitten für die Reaktionen 27Al(N,P) 27Mg, 27Al(N, α)24Na und 27Al(N, α)24MNa im Energiebereich zwischen 6,3 MeV und 8,3 MeV

Measurements of Cross Sections for the Reactions ²⁷Al(N, P) ²⁷Mg, ²⁷Al(N, α)²⁴Na and ²⁷Al(N, α)^24mNa in the Energy Region between 6,3 MeV and 8,3 MeV Using the activation method cross-sections for the reactions ²⁷Al(n, α₀)²⁴Na, ²⁷Al(n, α₁)^24mNa and ²⁷Al(n, p)²⁷Mg have been measured in the energy range 6.3 MeV to 8.3 MeV. Fast neutrons were produced at the Stuttgart University 4 MV Dynamitron via the reaction ⁹Be(α, n)¹²C irradiating 0.52 μm beryllium layers on high pressure water-cooled copper backings. The energy of the He-ions was varied between 1.86 MeV and 2.76 MeV, while the average current was 200 μAmp. The neutron flux has been measured with a 2″ × 2″ NE 213 liquid scintillator cell.