Quantum corrections to the conductance of n-GaAs films in a strong magnetic field

The conductance of doped n-GaAs films is studied experimentally as a function of magnetic field and temperature in strong magnetic fields right up to the quantum limit (ħω_c = E _F). The Hall conductance G _xy is virtually independent of temperature T until the transverse conductance G _xx is quite large compared with e ²/h. In strong fields, when G _xx becomes comparable to e ²/h, G _xy starts to depend on T. The difference between the conductances G _xx at the two temperatures 4.2 and 0.35 K depends only weakly on the magnetic field H over a wide range of magnetic fields, while the conductances G _xx themselves vary strongly. The results can be explained by quantum corrections to the conductance as a result of the electron-electron interaction in the diffusion channel. The possibility of quantization of the Hall conductance as a result of the electron-electron interaction is discussed. Pis’ma Zh. éksp. Teor. Fiz. 67, No. 3, 201–206 (10 February 1998)     

E.S.R. and ENDOR of an α-chloro radical in X-irradiated 5-chlorodeoxyuridine single crystals

The most prominent radical formed from X-irradiation of the nucleic acid constituent analogue 5-chlorodeoxyuridine at room temperature is shown to be an α-chloro radical formed by hydrogen addition to C₆. The E.S.R. analysis of the ³⁵Cl hyperfine interaction combined with theoretical simulation of the spin hamiltonian yields tensor components a_xx =46·98 MHz, a_yy =-10·98 MHz and a_zz =-17·01 MHz with a quadrupole coupling constant of eqQ=72 MHz. The principal g-tensor values are g_xx =2·0012, g_yy =2·00862 and g_zz =2·00687. Three additional hyperfine interactions in the radical are observed combining E.S.R. and ENDOR spectroscopy. Besides the two nearly equivalent β-protons on C₆ with principal values of 103·39 MHz and 110·12 MHz, there is hyperfine interaction with the ¹⁴N nucleus of nitrogen N₃ (a_xx =9·81 MHz, a_yy =a_zz ? 0 MHz) and with the proton of the hydrogen bonded to N₃. The latter interaction has tensor components of 2·65 MHz, -10·80 MHz and -8·09 MHz as obtained from ENDOR data. The chlorine hyperfine coupling parameters are related to those observed in other α-chloro radicals. The mechanism of the formation of the radical in 5-chlorodeoxyuridine is discussed briefly.     

Electron spin resonance studies of chlorine centres in irradiated chlorine-doped Na2SO4 single crystals

The nature of paramagnetic centres trapped in X-irradiated Na₂SO₄ single crystals containing chlorine as impurity has been determined from E.S.R. measurements both at room and liquid nitrogen temperatures. ClO₃, ClO₂, SO₄ ^- and O₃ ^- are the paramagnetic centres identified. The g and A parameters of ClO₃ change considerably between 298 K and 77 K. Thus the parameters of ClO₃ obtained at 298 K are g_xx = 2·0123, g_yy = 2·0143, g_zz = 2·0206 G and those of the A-tensor are A_xx = 97, A_yy = 100 and A_zz = 112 G. The parameters obtained for the same centre at 77 K are g_xx = 2·0132, g_yy = 2·0173, g_zz = 2·0073 G and those of the A-tensor are A_xx = 130·6, A_yy = 146·3 and A_zz = 181·2 G. The temperature variation of the principal values are determined in the temperature range between 298 K and 77 K. These data can be interpreted on the assumption that ClO₃ undergoes libration at room temperature, which is frozen out reversibly on cooling. The structure and mechanism of these defects are discussed further.     

Anisometric molecules in dense fluids

The Kerr constant of anisometric non-polar molecules in solvents of spherical molecules is calculated using the model of an ellipsoidal cavity in an isotropic dielectric continuum. It is shown that the Kerr constants has the same form as for dilute gases:

provided that effective polarizability elements α _xx ^l * (optical) and α _xx ^s * (static) replace the vacuum values α _xx ^l and α _xx ^s in Γ*, which then reads Γ* = 1/2[(α _xx ^l * - α _yy ^l *)(α _xx ^s *) - α _yy ^s *) + circular permutation].

Each effective polarizability element α _xx * (either optical or static) is composed of two contributions, one pertaining to the anisometric solute itself and another arising from the anisotropic distortion of the polarization in the neighbouring continuum. These two contributions are of opposite signs, so that large variations of the magnitude of the Kerr effect are predicted, depending essentially upon the mean refractivity and permittivity of the solute compared with those of the solvent.     

Ultra-low temperature study of the even-denominator FQHE state

We present experimental data showing unambiguously an even-denominator fractional quantum Hall effect (FQHE) state at . At a bath temperature T_b=8 mK, we observe a Hall plateau quantized to a value of 2h/5e² with an uncertainty smaller than 2 parts in 10⁶ and a vanishing R_xx (R_xx=1.7±1.7 Ω). The thermal activation energy gaps Δ at Landau level filling factors , and are 0.11, 0.10, and 0.055 K, respectively. Adding a disorder broadening (typically 2 K) to these values, we deduce that all three FQHE states have probably very similar energy gaps. The electron heating experiment shows that the 2D electrons are efficiently cooled to the bath temperature for T_b8 mK. We also explore the density dependence of the activation gap at . Preliminary results at T_b25 mK show that the state is very sensitive to disorder.     

N.M.R. study of the 125Te shielding anisotropy of tellurophene dissolved in various nematic liquid crystals

The ¹²⁵Te N.M.R. spectrum of tellurophene in three liquid crystals was recorded and analysed. The different orientational behaviour of tellurophene in the liquid crystals enabled the anisotropy of the tellurium-125 shielding tensor, σ _zz - 1/2(σ _xx + σ _yy ), and the difference σ _xx - σ _yy of the tensor elements to be determined. The resulting values are -1569 ± 21 ppm and 307 ± 26 ppm, respectively. The analysis of the ¹²⁵Te N.M.R. spectra is also discussed.     

Resistivity peak values at the transition between fractional quantum hall states

Experimental data available in the literature for peak values of the diagonal resistivity in the transitions between the fractional quantum Hall states (ρ _xx ^max ) are compared with the theoretical predictions. It is found that the majority of the peak values are close to the theoretical values for two-dimensional systems with moderate mobilities. The text was submitted by the author in English.     

Molecular orbital study of polarity and hydrogen bonding effects on the g and hyperfine tensors of site directed NO spin labelled bacteriorhodopsin

Semiempirical molecular orbital methods (PM3, INDO, ZINDO/S) have been used to calculate the effects of local electric fields and of hydrogen bonding on the g and hyperfine tensors of a nitroxide spin label model system. The results yield a linear correlation between the two principal tensor components g _xx and A ^N _zz at label sites of varying polarity. Hydrogen bonding with a single water molecule produces a constant shift of Δg _xx ? ?4 × 10^?4. These theoretical results are used to interpret recent high field (3.4 T, 95 GHz) electron paramagnetic resonance investigations on site-directed spin labelled bacteriorhodopsin. This protein reveals a close correlation between proticity and polarity at the various label sites. The slope of the g _xx versus A ^N _zz dependence is affected strongly by polarity induced structural strains of the spin label.     

ESR studies of Cl2- (VK) centre trapped in irradiated Ca(ClO3)2 . 2H2O single crystals

A Cl₂- centre has been trapped in X or γ-irradiated Ca(ClO₃)₂. 2H₂O single crystals at 298 K, when the irradiated crystals were illuminated with ultra-violet light (360 nm). This centre is formed at the expense of ClO₂ centres in this crystal. This Cl₂ ^- centre is trapped at two magnetically inequivalent sites in the crystal lattice and these sites become equivalent when the static magnetic field is parallel or perpendicular to the b axis. At many orientations this centre reveals ‘super-hyperfine’ interaction with a proton (I = 1/2) of the water of crystallization. The magnetic parameters are close to those observed in alkali chlorides and the E.S.R. spectrum has been fitted to an orthorhombic spin hamiltonian. The principal g values are g_xx = 2·035, g_yy = 2·033 and g_zz = 2·000 and those of the A values are A_xx = 15·0, A_yy = 31·0 and A_zz = 109·0 G. The shfs parameters are A _‖' = 5·0 A _⊥' = 1·0 G. The V_K centre trapped in this lattice is exceptionally stable at room temperature.     

Magnetoresistance in dilute p‐Si/SiGe in parallel and tilted magnetic fields

We report the results of an experimental study of the magnetoresistance ρ_xx and ρ_xy in two samples of p‐Si/SiGe with low carrier concentrations p = 8.2 × 10¹⁰ cm^‐2 and p = 2 × 10¹¹ cm^‐2. The research was performed in the temperature range of 0.3–2 K and in the magnetic fields of up to 18 T, parallel or tilted with respect to the two‐dimensional (2D) channel plane. The large in‐plane magnetoresistance can be explained by the influence of the in‐plane magnetic field on the orbital motion of the charge carriers in the quasi‐2D system. The measurements of ρ_xx and ρ_xy in the tilted magnetic field showed that the anomaly in ρ_xx, observed at filling factor ν = 3/2 is practically nonexistent in the conductivity σ_xx. The anomaly in σ_xx at ν = 2 might be explained by overlapping of the levels with different spins 0 ↑ and 1 ↓ when the tilt angle of the applied magnetic field is changed. The dependence of g‐factor g^*(Θ)/g^*(0⁰) on the tilt angle Θ was determined.     

Spin-dependent resistivity and quantum Hall ferromagnetism in two-dimensional electrons confined to AlAs quantum wells

We observe a strong dependence of the amplitude and field position of longitudinal resistivity (ρ_xx) peaks in the spin-resolved integer quantum Hall regime on the spin orientation of the Landau level (LL) in which the Fermi energy resides. The amplitude of a given peak is maximal when the partially filled LL has the same spin as the lowest LL, and amplitude changes as large as an order of magnitude are observed as the sample is tilted in field. In addition, the field position of both the ρ_xx peaks and plateau–plateau transitions in the Hall resistance shift depending on the spin orientation of the LLs. The spin dependence of the resistivity points to a new explanation for resistivity spikes, associated with first-order quantum Hall ferromagnetic transitions, that occur at the edges of quantum Hall states.     

Analyzing powers Ayy , Axx , Axz and Ay in the dd → 3Hen reaction at 270 MeV

The data on the tensor A_yy, A_xx, A_xz and vector A_y analyzing powers in the dd → ^3Hen obtained at T _d = 270 MeV in the angular range 0^° - 110^° in the c.m. are presented. The observed negative sign of the tensor analyzing powers A_yy, A_xx and A_xz at small angles clearly demonstrate the sensitivity to the ratio of the D - and S -wave component of the ³He wave function. However, the one-nucleon exchange calculations by using the standard ³He wave functions have failed to reproduce the strong variation of the tensor analyzing powers as a function of the angle in the c.m.     

Studies of the quantum Hall to quantum Hall insulator transition in InSb-based 2DESs

The temperature dependence of ρ_xx is studied in the vicinity of the quantum Hall to quantum Hall insulator transition (ν=1→0) in InSb/InAlSb based 2DESs. ρ_xx displays a symmetric temperature dependence about the transition with on the QH side and on the insulating side. A plot of 1/T₀ for successive ν displays power-law divergence with 1/T₀∝|ν−ν_c|^−γ,² with γ=2.2±0.3. This critical behavior in addition to the behavior expected of the quantum transport regime confirms that the QH/QHI transition is indeed a good quantum phase transition.     

Effect of paramagnetic doping on an inorganic polymer triaquadipotassiumbis(malonato)zincate: spectroscopic investigation

Spectroscopic investigations on Mn(II)-doped triaquadipotassiumbis(malonato)zincate [K₂(H₂O)₃] [Zn(mal)₂], an inorganic polymer, have been carried out at room temperature using single crystal electron paramagnetic resonance (EPR), ultraviolet–visible, FT-IR and powder XRD techniques. Single crystal rotations along the three orthogonal axes show more than 30 lines of patterns in EPR spectra, indicating the presence of two sites, one with a large D value and the other with a smaller D value. The calculated spin-Hamiltonian parameters are as follows. Site 1: g _xx =2.099, g _yy =2.092, g _zz =1.988, A _xx =9.77, A _yy =9.71, A _zz =8.96 mT, D _xx =?29.09, D _yy =?11.90, D _zz =40.99 mT; Site 2: g _xx =2.040, g _yy =1.995, g _zz =1.924, A _xx =9.51, A _yy =9.09, A _zz =8.80 mT, D _xx =?11.94, D _yy =?7.51 and D _zz =19.45 mT. The direction cosines of g/A/D do not match with the direction cosines of Zn–O bonds in the host lattice for either site, suggesting that both the Mn(II) sites entered the lattice interstitially. Optical results indicate a strong covalent bonding between the metal ion and ligands, with site symmetry being primarily octahedral. The FT-IR and powder XRD data confirm the retention of the crystal structure, even after incorporating a paramagnetic probe. Various admixture coefficients, bonding and optical parameters have also been calculated.     

Radical formation in lithium trifluoromethane-sulfonate for ESR dosimetry

Lithium trifluoromethane-sulfonate (Li-TFMS:CF₃SO₃Li) irradiated by γ-rays showed an electron spin resonance (ESR) powder spectrum having the rhombicg-factor ofg _xx = 2.0259 ± 0.0005,g _yy = 2.0112 ± 0.0005 andg _zz = 2.0025 ± 0.0005 and a triplet hyperfine coupling constant ofA _xx/gβ= 0.8 ± 0.15 mT.A _yy andA _zz are not obtained because of the broadened spectrum. The energy levels,g-factor,A _xx/gβ and optical absorption spectrum of several conceivable radicals such as C^⋅F₂SO₃Li, CF₃-S-O^⋅ and CF₃-S-O-O^⋅ have been calculated by softwares MOPAC-V2 and Gaussian-98 based on ROHF (Restricted Hatree-Fock for open shell molecule). The most probable radical was ascribed to CF₃-SO^⋅ from both calculated and experimental results. The response to γ-ray dose and the thermal stability have been studied in addition to the effect of UV illumination for possible use of the signal intensity in ESR dosimetry. The obtained number of free radicals per 100 eV (G-value) was 1.23 ± 0.40.     

Exchange interaction effects in the crossing of spin-polarized Landau levels in a silicon-germanium heterostructure: transition into a ferromagnetic state

The crossing of spin-split Landau levels in a Si/SiGe heterostructure is investigated by means of magneto-transport experiments in tilted magnetic fields. We observe a transition from a paramagnetic into a fully spin polarized state. During the transition strongly enhanced maxima in the transverse resistivity ρ_xx appear when the parallel field component is oriented along the Hall bar. We assign this effect to an energy level structure strongly modified by exchange interaction effects between different Landau levels. Surprisingly the maximum in ρ_xx totally disappears when the parallel field component is perpendicular to the Hall bar.     

Quantized Hall effect in disordered GaAs layers with 3D spectrum in tilted magnetic fields

The quantum Hall effect structure in the transverse magnetoresistance R _xx and the Hall resistance R _xy of heavily doped GaAs layers with a three-dimensional spectrum of the charge carriers is investigated for different field orientations. The characteristic structures (minima in R _xx and plateaus in R _xy ) shift much more slowly to higher fields and are suppressed much more rapidly in comparison with the expected angular dependence for a two-dimensional system. The results are discussed in terms of the anisotropic change of the three-dimensional conductivity tensor with magnetic field rotation. Pis’ma Zh. éksp. Teor. Fiz. 68, No. 4, 305–308 (25 August 1998)     

Single-crystal EPR investigation of Mn(II)-doped biomineral cobalt ammonium phosphate hexahydrate: a case of multiple substitutions

Single-crystal electron paramagnetic resonance (EPR) study of Mn(II)-doped cobalt ammonium phosphate hexahydrate has been carried out at room temperature. The impurity shows more than 30 line pattern EPR spectra along the three crystallographic axes, suggesting the existence of more than one type of impurity ion in the host lattice. The spin Hamiltonian parameters, estimated from the three mutually orthogonal crystal rotations, are: site 1: g _xx =1.989, g _yy =1.994, g _zz =1.999; A _xx =?8.97, A _yy =?9.52, A _zz =?9.71 mT; D _xx =?8.09 mT, D _yy =?6.05 mT, D _zz =14.14 mT; site 2: g _xx =1.988, g _yy =2.009, g _zz =2.019; A _xx =?9.11 mT, A _yy =?9.58 mT, A _zz =?9.93 mT; D _xx =?6.61 mT, D _yy =?6.11 mT, D _zz =12.72 mT. The angular variation studies further reveal that the Mn(II) impurities enter the lattice substitutionally. The other Mn(II) sites which are at interstitial locations are difficult to follow due to their low intensity. The variation of zero-field splitting parameter with temperature indicates no phase transition. The observation of well-resolved Mn(II) spectrum at room temperature has been interpreted in terms of ‘host spin-lattice relaxation narrowing’ mechanism.     

Some remarks on variable range hopping—in particular in the quantum Hall regime

An expression for the heat conductivity _xx is derived in the effective medium approximation. Mott type formulas are obtained for _xx and the Peltier coefficient _xx . Using percolation theory in a three-dimensional system the Wiedemann-Franz ratio was found to depend on the temperature like . The Mott type formulas were evaluated in a similar way for a two-dimensional system in the quantum Hall regime within the high-field percolation model. In contrast to previous calculations of the high field hopping conductivity _xx , the results are fully consistent with the experimental data on _xx and the density of states at the Fermi level. Finally, _xx is estimated which together with _xx and _xy =ie ²/h(i=0,1,2,...), determines both thermopower coefficients _xx and _xy .Dedicated to Professor W. Brenig on the occasion of his 60th birthday     

Theoretical studies of the local structures and electron paramagnetic resonance parameters for Cu2+ center in Zn(C3H3O4)2(H2O)2 single crystal

The electron paramagnetic resonance (EPR) parameters (g factors g_xx, g_yy, g_zz and hyperfine structure constants A_xx, A_yy, A_zz) are interpreted by taking account of the admixture of d-orbitals in the ground state wave function of the Cu²⁺ ion in a Zn(C₃H₃O₄)₂(H₂O)₂ (DABMZ) single crystal. Based on the calculation, local structural parameters of the impurity Cu²⁺ center were obtained (i.e. R_a≈1.92 Å, R_b≈1.96 Å, R_c≈1.99 Å). The theoretical EPR parameters based on the above Cu²⁺?O^2? bond lengths in the DABMZ crystal show good agreement with the observed values and some improvements have been made as compared with those in the previous studies.