Telomerization of propylene with methyl propionate

Conclusions The principal products of the telomerization of propylene with methyl propionate are telomers with the structure , where n=1–4.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2534–2537, November, 1973.     

Telomerization of vinyl chloride with methyl propionate

Conclusions The teloHierization of vinyl chloride with methyl propionate was accomplished and it was shown that telomers of type are formed.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2537–2540, November, 1973.     

Telomerization of acrylonitrile and methyl acrylate with methyl dichloroacetate

Conclusions The telomerization of acrylonitrile and methyl acrylate with methyl dichloroacetate at the C-Cl bond of the latter was accomplished by initiation with iron pentacarbonyl in combination with either DMF ordimethylaniline.Translated from Izvestiya Akademii SSSR, Seriya Khimicheskaya, No. 6, pp. 1410–1412, June, 1973.     

Telomerization of propylene with methyl dichloroacetate

Conclusions The telomerization of propylene with methyl dichloroacetate includes chain transfer via the C-H and C-Cl bonds, and leads to the formation of four series of telomers, the methyl esters of chloro-substituted acids of type X[CH(CH₃)CH₂]_nCClYCO₂CH₃ (X, Y=H, Cl), and also of the telomeric esters of the higher alcohols and dichloroacetic acid.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2150–2152, September, 1977.     

Telomerization of 1-hexene by diethyl phosphite in the presence of decacarbonyldimanganese and peroxides

Conclusions An induction period, post effect and shift in the telomer homolog distribution toward T₁ were observed upon the use of Mn₂(CO)₁₀ as the initiator of the telomerization of 1-hexene with diethyl phosphite.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 218–221, January, 1987.     

Telomerization of vinyl chloride by methyl methoxyacetate

Conclusions The telomerization of vinyl chloride by methyl methoxyacetate proceeds due to cleavage of the -C-H and methoxy group C-H bonds in the telogen and is accompanied by rearrangement of the radicals with 1,5-hydrogen migration.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1914–1917, August, 1988.