Structure and chemical valence study of Sr_(n+1)Ru_nO_(3n+1)(n= 1, 2, ∞) series

Effect of structure parameter n and its coupling with the connection mode among RuO6 octahedra of Sr n+1RunO3n+1(n = 1, 2, ∞) are investigated. The gradually enhanced rotation and tilting effect with increasing n are observed in Sr n+1RunO3n+1. Besides, the chemical valence of Ru is not changed, while the one of Sr gradually varies with increasing n, which highlights the great contribution of connection mode to the chemical environment. Our results show a strong n dependence on the connection mode between octahedra in Srn+1RunO3n+1(n = 1, 2, ∞).     

Single-phase Bi2+x(Ca,Sr) n+1 Cu n O2n+4+δ, n = 0, 1, 2, 3 AND ∞, and some substitutional DERIVATIVES

The preparation, structure and properties of five members of the homologous series Bi_2+x(Ca,Sr) _n+1 Cu _n O_2n+4+δ are discussed, namely for n = 0, 1, 2, 3 and ∞. The two end members are insulating phases with a fixed oxygen stoichiometry but the members n = 1, 2 and 3 are superconducting phases with T_c depending on the calcium to strontium ratio and on oxygen stoichiometry as determined by annealing temperature and oxygen partial pressure. Maximum zero resistance T_c 's obtained are n = 1: 76 K, n = 2: 91 K and n = 3: 106 K. The effects of Pb-substitution in n = 2 and n = 3 are discussed with particular reference to the stabilisation of the latter phase. Rare-earth substitution is shown to raise T_c for n = 2 to at least 101 K without the introduction of the n = 3 phase.     

~(100)Mo(n,2n)~(99)Mo,~(96)Mo(n,p)~(96)Nb和~(92)Mo(n,α)~(89m+g)Zr反应截面测量

本文报告了在E_n=13.40—14.79MeV中子能区用活化法以~(27)Al(n,α)~(24)Na截面为中子注量标准测得的~(100)Mo(n,2n)~(99)Mo,~(96)Mo(n,p)~(96)Nb和~(92)Mo(n,α)~(89m+g)Zr的反应截面,中子能量是用铌锆截面比法测定的。文中将实验测量值与理论计算值进行了比较,还对上述三个反应的截面进行了编评,给出了推荐的激发曲线。     

~(50,48,46)Ti的(n,p)(n,α)和~(58)Ni的(n,2n)(n,p)反应截面的测量

本文叙述了从13.50 MeV到14.81 MeV中子能区用活化法相对~(21)Al(n,α)~(24)Na的反应截面,对~(50)Ti(n,α)~(47)Ca、~(48)Ti(n,p)~(48)Sc、~(46)Ti(n,p)~(46)Sc、~(58)Ni(n,2n)~(57)Ni、~(58)Ni(n,p)~(58m+g)Co五个反应截面的测量。并将所得的结果和其他作者的结果进行了比较。     

几个(n,d~*),(n,t)和(n,n′α)反应截面的测量

本文报告了En～14MeV中子以~(27)Al(n,a)~(24)Na或~(93)Nb(n,2n)~(92m)Nb反应截面为中子注量标准测得的~(92)Mo(n,d~*)~(91m)Nb,~(106)Cd(n,d~*)~(105)Ag;~(54)Fe(n,t)~(25m+g)Mn,~(58)Ni(n,t)~(56)Co;~(51)V(n,n'a)~(47)Sc和~(92)Mo(n,n'a)~(88)Zr的反应截面。文中还列举了能收集蓟的数据以作比较,中子能量是用铌锆截面比法测定的。     

快中子(n,α)和(n,p)反应的研究

快中子核反应数据,不论对反应堆和聚变堆的设计,还是对核反应机制和核结构的研究及其理论的发展均有着重要的意义．由于屏栅电离室的诸多特点,被用于快中子核反应截面、能谱及双微分截面的测量．作为系统研究的一部分,利用屏栅电离室在北京大学４．５ＭＶ静电加速器上和在４～７ＭｅＶ能区内,对４０Ｃａ、６４Ｚｎ、５８Ｎｉ、５４Ｆｅ、３９Ｋ的（ｎ,α）反应进行了成功的测量,并对５８Ｎｉ的（ｎ,ｐ）反应进行了初步的测量．实验给出了反应中出射粒子的微分能谱、角分布和反应截面．从测量结果来看,在所测能区内,角分布大致是９０°对称的,说明在此能区复合核反应机制起主要作用．The study of the charged particle emission reactions induced by 3～7 MeV fast neutrons is of considerable interest for both nuclear applications and the understanding of basic nuclear problems. For its many merits, twin gridded ionization chamber is used in the studies of (n,α) and (n,p) reactions. As a part of systematic investigation, the (n,α) reactions for some nuclei, such as 40 Ca, 64 Zn, 58 Ni, 54 Fe, 39 K have been studied. Cross sections...     

In-plane London penetration depths near the critical temperature of Tl2Ba2Ca n−1Cu n O2n+4 and (Bi,Pb)2Sr2Ca n−1 Cu n O2n+4 (n=2,3)

From isothermalM(H) curves nearT _c , measured on polycrystalline Tl₂Ba₂Ca _n–1Cu _n O_2n +4 and (Bi, Pb)₂Sr₂Ca _n–1Cu _n O_2n+4 (n=2,3) samples, we deduce the in-plane penetration depths _ab as functions of temperature. An estimate according to the BCS weak-coupling clean-limit fit, which produces the data nearT _c very well, yields _ab(0)=3100 Å, 2320 Å 2210 Å, and 1960 Å for Bi₂Sr₂CaCu₂O₈, Bi_1.6Pb_0.4Sr₂Ca₂Cu₃O₁₀, Tl₂Ba₂CaCu₂O₈, and Tl₂Ba₂Ca₂Cu₃O₁₀, respectively. A comparison between strong-coupling and weak coupling fitting curves clearly favours the weak-coupling temperature dependence of _ab nearT _c .     

~(59)Co(n,p)~(59)Fe,~(59)Co(n,α)~(56)Mn,~(59)Co(n,2n)~(58)Co反应截面的测量

本实验用活化法测量了中子能量在12.8MeV到17.8MeV的~(59)Co(n,p)~(59)Fe,~(59)Co(n,α)~(56)Mn,~(59)Co(n,2n)~(58)Co三个反应道的反应截面值,实验的测量误差在3.3％—6.9％范围内. 本文还计算了反应截面测量误差的协方差矩阵,并将实验测量值与理论计算值进行了比较.另外,还对上述三个反应道的截面进行编评,给出了推荐的激发曲线.     

几个(n,d),(n,t)和(n,n'α)反应截面的测量

本文报告了En～14MeV中子以²⁷Al(n,α)²⁴Na或⁹³Nb(n,2n)^92mNb反应截面为中子注量标准测得的⁹²Mo(n,d*)^91mNb,¹⁰⁶Cd(n,d*)¹⁰⁵Ag;⁵⁴Fe(n,t)^52m+gMn,⁵⁸Ni(n,t)⁵⁶Co;⁵¹V(n,n'α)⁴⁷Sc和⁹²Mo(n,n'α)⁸⁸Zr的反应截面.文中还列举了能收集到的数据以作比较,中子能量是用铌锆截面比法测定的.     

(n,n)-(2n, 0)碳纳米管异质结的扭转力学特性

相近直径的锯齿型和扶手椅型碳纳米管可以共轴组合形成5-7碳环交替出现的柱形对称异质结. 本文利用分子动力学方法研究了直径相近且等长锯齿型和扶手椅型碳纳米管形成的(n, n)-(2n, 0)结在扭转过程中的扭矩和轴向应力随扭转角度的变化规律以及应力传递过程. 研究发现, (n, n)-(2n, 0)结扭转应变在达弹性限度内不会产生轴向应力, 该效应对基于碳纳米管扭转特性的纳米振荡器件的设计具有重要意义.     

Cross Section Measurements for (n,d*)(n,t) and (n,n'α) Reactions

Cross sections for some (n,d*),(n,t) and (n,n'α)reactions have been measured by using the activation method relative to cross sections of ²⁷Al(n,α)²⁴Na or ⁹³Nb(n,2n)^92mNb reactions in neutron energies around 14MeV.In this paper some of the published cross section data have also been listed and compared with our results.The neutron energies were determined by the method of cross section ratios for the reactions of ⁹⁰Zr(n,2n) ^89m+gZr and ⁹³Nb(n,2n)^92mNb.     

空穴掺杂铱氧化物Srn+1IrnO3n+1 (n=1,2)的角分辨光电子能谱研究

近年来, 与铜氧化物高温超导体具有类似电子结构的5d 轨道 Ruddlesden-Popper 类型铱氧化物由于体系中库伦排斥和自旋轨道耦合之间的合作效应被人们广泛探究. 其中, 金属绝缘体转变的关键影响因素是该方向的核心研究问题, 该结果对推进掺杂莫特绝缘体体系的研究具有重要作用. 因为铱氧化物与铜氧化物在单能带哈伯德模型的次 近 邻 跃 迁 项 具 有 不 同 符 号, 因 此 空 穴 掺 杂 铱 氧 化 物 类 比 电 子 掺 杂 铜 氧 化 物. 我 们 将 空 穴 掺 杂Ruddlesden-Popper 类型铱氧 化 物 系 统 依 据 几 种 不 同 的 掺 杂 元 素 进 行 分 类, 分 别 介 绍 其 角 分 辨 光 电 子 能 谱(ARPES) 探测到的电子结构, 对其中金属绝缘体转变类型进行了总结, 并对该领域中的未来研究方向做出了展望.     

Mössbauer spectroscopic studies of (n-C n H2n +1NH3)2SnCl6 (n=6, 8-18) complexes

Temperature-dependent Mössbauer experiments have been carried out to examine the lattice-dynamic properties of tin atoms in complexes of the type (n-C _n H_2n+1NH₃)₂SnCl₆ (6 n 12). The temperature dependence of the area intensity of Mössbauer lines for the studied complexes are correlated to the motion of long alkyl chains. Solid-solid phase transitions were clearly found in all the complexes above room temperature, accompanied by an increase in the interlayer spacing (6n 18). The transition temperature and transition entropy increase linearly with the number of carbon atoms in alkyl chains.     

Structure and stability of SiBn+ AND CBn+ (n = 1–4)

The structures and binding energies of small boron-rich clusters are studied using correlated wave functions and polarization basis sets. Carbon is the central atom in CB_n⁺, while SiB_n⁺ prefers planar boron networks with silicon as one of the edge atoms. These ground state structures can be explained by differences in the electronegativities of the component elements. The various fragmentation channels of SiB_n⁺ are also examined using binding energy differences.     

(n+1)维双Sine-Gordon方程的新精确解

给出包含第一种椭圆方程的三角函数型辅助方程及其解的叠加公式.在一般函数变换下,借助符号计算系统Mathematica,构造了(n+1)维双sine-Gordon方程新的Jacobi椭圆函数精确解.这些解包括了行波变换下的Jacobi椭圆函数精确解、精确孤立波解和三角函数解.     

~(58)Ni(n,p),~(60)Ni(n,p),~(62)Ni(n,α)和~(54)Fe(n,p)反应截面的测量与评价

本实验用活化法测量了中子能量在13.60 MeV—17.77 MeV的~(58)Ni(n,p)~(58m+g)Co,~(60)Ni(n,p)~(60)Co和~(62)Ni(n,α)~(59)Fe三个反应道的反应截面值,并计算了反应截面测量误差的协方差矩阵。实验的测量误差在3％—7％范围内。本文还对上述三个反应截面及~(54)Fe(n,p)~(54)Mn反应截面进行了编译,推荐了从阈能到20MeV能区的激发曲线。     

(n,p)和(n,α)激发函数半经验计算方法

在En≤20MeV的情况下,忽略了粒子的二次发射过程,认为复合系统的形成截面是能量相关的,得到了理论模型清晰、公式形式简单的半经验计算方法.在靶核23≤A≤209的范围内,利用大量(n,p)和(n,α)反应的截面实验数据对可调参数进行了研究,得到了参数对靶核的N和Z以及入射能量的依赖关系.对得到的参数做了定性的解释,利用普适参数对(n,p)和(n,α)反应的激发函数做了预言,预言值在其误差范围内与实验数据一致. To simplify the calculation, some assumptions are considered at present work. The preequilibrium emission is the first step in the equilibrium process, which is characterized by exciton n=3 and "never come back" are considered at the preequilibrium emission process; the proton and alpha emissions are only competed with the neutron emission, the second particle emission is neglected. A semiempirical method of the cross section for (n, p ) and (n, α) reactions were obtained on the basis of evaporatio...     

(n,2n),(n,3n)反应激发函数的系统学研究

本文用包括平衡前发射在内的蒸发模型理论研究了(n,2n),(n,3n)反应的激发函数系统学.在对实验数据分析、拟合的基础上,得到一组较好的经验参数.利用这组参数计算得到的截面和实验结果符合较好.     

用~(58)Ni(n,p)~(58m+g)Co和~(58)Ni(n,2n)~(57)Ni反应的截面比定平均中子能量

本文叙述了用两个硅半导体探测器和~(58)Ni(n,p)~(58g+m)Co与~(58)Ni(n,2n)~(57)Ni反应截面比定D-T中子的平均能量的方法,得到了该截面比与中子能量的关系曲线并与所引文献中的结果进行了比较.