碳纳米管复合吸波涂层微波吸收性能的模拟计算

如何利用碳纳米管复合吸波涂层的参数进行吸波性能优化是电磁屏蔽研究的热点之一.涂层参数对吸波性能影响的研究主要停留在实验探索阶段,而碳纳米管的结构参数对吸波性能影响的研究鲜有报道.因此,从微观结构层次研究涂层参数对吸波性能的影响有重要意义.基于多壁碳纳米管的等效电路,利用碳纳米管结构参数与等效电路各元件参数的关系,研究了碳纳米管损耗微波的机理,建立了碳纳米管结构参数与微波反射率的关系式.根据此关系式,利用Matlab软件模拟计算了碳纳米管管长、管径、涂层中碳纳米管的含量以及涂层厚度对微波反射率的影响.模拟计算结果表明:涂层的微波反射率随碳纳米管含量变化的模拟曲线与实验结果符合;碳纳米管含量和厚度是影响吸收峰位置和吸收强度的重要参量,而碳纳米管直径和长度是主要影响吸收峰强度的参量.     

Validity and Accuracy of Equivalent Circuit Models of Passive Inductive Meshes. Definition of a Novel Model for 2D Grids

Accuracy of equivalent circuit models of periodic grids is investigated in amplitude and phase in the visible region. The grids studied here are one-dimensional (1D) and two-dimensional (2D) inductive thin metal meshes. They are located in free space and are illuminated by a plane wave under normal incidence. The range of validity and the accuracy of conventional circuit models are defined by comparison with rigorous results obtained with the Finite-Difference Time-Domain (FDTD) method. In particular, it is shown that electrical models of 1D grids are accurate, whereas equivalent circuits of 2D grids should be used very cautiously. Then, a new formulation is proposed to overcome this major drawback. In the non-diffraction region, the agreement between our model and the FDTD results is within 2% for the power reflectivity and 1° for the phase over a very wide range of strip widths.     

Formation and structure of sphene/titania composite coatings on titanium formed by a hybrid technique of microarc oxidation and heat-treatment

Sphene/titania composite coatings were fabricated on titanium by a hybrid technique of microarc oxidation (MAO) and heat treatment. The high-applied voltages promote the formation of sphene in the MAO coatings after heat-treatment. Heat treatment could change the surface morphology of the MAO coatings such as roughness, macropores size and density and the thickness of the MAO coatings. Increasing the heat-treatment temperature decreased the atomic concentration ratios of Ti/Si and Ti/Ca of the MAO coatings. The chemical states of Ti⁴⁺, Ca²⁺, Si²⁺ and O²⁻ were observed on all the coatings. Additionally, Ti²⁺ was detected in the MAO and heat-treated MAO coatings at 600 and 700 °C. The heat-treatment has obvious effect on the chemical states of Si, Ti and O elements due to the formation of sphene and oxidation of TiO phase of the MAO coating, but did not affect that of Ca. In the heat-treated MAO coatings at 800 °C (MAO-H8), the titanium surface shows a MAO top layer and oxidized interior layer. A concentration gradient in components in the MAO layer of the MAO-H8 coating was formed.     

Cross-linked gelatin/nanoparticles composite coating on micro-arc oxidation film for corrosion and drug release

A composite coating which could control drug release and biocorrosion of magnesium alloy stent materials WE42 was prepared. This composite coating was fabricated on the surface of the micro-arc oxidation (MAO) film of the magnesium alloy, WE42, by mixing different degrees of cross-linked gelatin with well-dispersed poly(dl-lactide-co-glycolide) (PLGA) nanoparticles. The PLGA nanoparticles were prepared by emulsion solvent evaporation/extraction technique. Nano ZS laser diffraction particle size analyzer detected that the size of the nanoparticles to be 150-300 nm. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) was used to analyze the morphology of the nanoparticles and the composite coating. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) were used to evaluate the corrosion behavior of the composite coating. Drug release was determined by ultraviolet-visible (UV-vis) spectrophotometer. The corrosion resistance of the composite coating was improved by preventing the corrosive ions from diffusing to the MAO films. The drug release rate of paclitaxel (PTX) exhibited a nearly linear sustained-release profile with no significant burst releases.     

Surface modification of pure titanium by hydroxyapatite-containing composite coatings

Micro-arc oxidation (MAO) is commonly applied to modify the surface of titanium (Ti)-based medical implants with a bioactive and porous Ti oxide (TiO₂) coating. The study reports a new method of incorporating hydroxyapatite (HA) within the TiO₂ coating by MAO and alkali heat treatment (AHT) in the solution containing Ca ion and P ion. The morphology, composition and phase composition of the coatings were analyzed with scanning electron microscopy with energy-dispersive X-ray spectrometer and X-ray diffraction. Surface topography and roughness of the coatings were investigated by atomic force microscopy operated in the tapping mode. The results showed that TiO₂-based coatings were obtained on pure Ti by MAO with an electrolyte containing Ca ion and P ion; the prepared MAO coatings were mainly composed of Ca, P, O and Ti. AHT transformed Ca and P to HA crystals. In conclusion, the TiO₂/HA composite coatings can be obtained on the surface of pure Ti by MAO and AHT, and the addition of Ca ion and P ion to the AHT solution contributed to the formation of HA.     

钛合金微弧氧化过程中电学参量的特性研究

利用自制的数据采集系统研究了恒定电压下TC4钛合金微弧氧化(MAO)过程中有关电学参量随处理时间的变化规律. 结果表明，通电回路中的阴极和阳极峰值电流随处理时间的变化明显分为4个阶段；膜厚度随处理时间的变化明显分为3个阶段；氧化膜的动态正、反向电阻和动态正、反向电阻率也随处理时间分阶段变化. MAO过程中，各时刻的动态正、反向电阻值不同，一般情况下，动态正向电阻大于反向电阻. 对不同处理时间样品的扫描电子显微镜分析表明，MAO膜呈多孔结构并随处理时间变化.     

0-3型压电复合材料覆盖层水下 吸声性能的理论研究

目前压电分流阻尼技术在振动和噪声领域的应用得到了广泛的关注. 本文尝试将压电分流阻尼技术应用于水下吸声领域, 以提高覆盖层的吸声性能. 将压电覆盖层厚度模态的机电方程和声波传播的传递矩阵相结合, 建立一维电声模型. 该模型可以用于分析多层压电和非压电水下吸声覆盖层的吸声性能. 采用该模型分析了0-3型压电复合材料覆盖层的水下吸声性能. 压电复合材料的参数是采用Furukawa的模型计算的. 研究结果表明, 采用合适的分流电阻, 负电容分流电路可以在较宽的频率范围显著提高覆盖层的吸声性能. 其原理可以从阻抗匹配的角度解释, 负电容分流电路可以调整压电覆盖层的表面声阻抗, 使之与水的特性声阻抗相匹配.     

Fabrication and characterization of rod-like nano-hydroxyapatite on MAO coating supported on Mg-Zn-Ca alloy

The poor corrosion resistance of magnesium alloys is a dominant problem that limits their clinical application. In order to solve this challenge, micro-arc oxidation (MAO) was used to fabricate a porous coating on magnesium alloys and then electrochemical deposition (ED) was done to fabricate rod-like nano-hydroxyapatite (RNHA) on MAO coating. The cross-section morphology of the composite coatings and its corresponding energy dispersion spectroscopy (EDS) surficial scanning map of calcium revealed that HA rods were successfully deposited into the pores. The three dimensional morphology and scanning electron microscopy (SEM) image of the composite coatings showed that the distribution of the HA rods was dense and uniform. Atomic force microscope (AFM) observation of the composite coatings showed that the diameters of HA rods varied from 95 nm to 116 nm and the root mean square roughness (RMS) of the composite coatings was about 42 nm, which were favorable for cellular survival. The bonding strength between the HA film and MAO coating increased to 12.3 MPa, almost two times higher than that of the direct electrochemical deposition coating (6.3 MPa). Compared with that of the substrate, the corrosion potential of Mg-Zn-Ca alloy with composite coatings increased by 161 mV and its corrosion current density decreased from 3.36 × 10⁻⁴ A/cm² to 2.40 × 10⁻⁷ A/cm² which was due to the enhancement of bonding strength and the deposition of RNHA in the MAO pores. Immersion tests were carried out at 36.5 ± 0.5 °C in simulated body fluid (SBF). It was found that RNHA can induce the rapid precipitation of calcium orthophosphates in comparison with conventional HA coatings. Thus magnesium alloy coated with the composite coatings is a promising candidate as biodegradable bone implants.     

利用遗传算法由电阻抗计算四阶带通箱的低频响应

提出了一种基于电阻抗得到四阶带通扬声器系统低频频率响应的方法。该方法无需消声室,首先建立扬声器系统的电阻抗集中参数电路模型并测量得到电阻抗曲线,然后运用遗传算法优化模型中的元件参数值,使得由模型计算得到的阻抗曲线与测得的阻抗曲线相吻合,再根据模型计算得到低频响应曲线。测量结果表明理论曲线与实测曲线相吻合,说明基于电阻抗得到低频响应的方法是可行的和有效的。     

An electro-acoustics impedance error criterion and its application to active noise control

Characteristics of radiation impedance and its inducing variation of electrical impedance for a controllable source have been investigated. An impedance-based error criterion has been proposed and its application to active noise control is demonstrated through a coil driven loudspeaker. A general formula of radiation impedance is derived for two control strategies, according to the criterion of total acoustic power output. The radiation impedances of some commonly used sound sources are calculated. We discuss in detail the relation between variation of the input electrical impedance and radiation impedance for the two control strategies. An AC-bridge circuit is designed to measure the weak variation of electrical impedance resulted from radiation impedance. The input electrical impedance of a loudspeaker was measured and the experimental result is consistent with that of theoretical analysis. An impedance-based error criterion is proposed since the AC-bridge relative output is unique for a certain control strategy. The implementation of this criterion applied to an active control system is analyzed by simulations. An analogue control system is set up and experiments are carried out in a semi-anechoic chamber to verify the new control approach.     

引入界面耦合系数的长片型磁电层状复合材料的等效电路模型

针对长片型磁电层状复合材料,提出了一种适用于准静态和动态磁场激励的引入界面耦合系数的等效电路模型,旨在为基于长片型磁电层状复合材料的传感器、换能器等器件的设计、制作和应用提供理论指导.考虑到磁电层状复合材料实际工作过程中磁致伸缩层和压电层的应变并不相同,首先利用运动方程分别对磁致伸缩层和压电层进行建模,提出了一个从物理上反映相间应变传递的界面耦合系数表达式,然后利用一个变比恰为界面耦合系数的理想变压器将两层材料的等效电路耦合,构成改进的磁电层状复合材料的等效电路模型,得到包含界面耦合系数的磁电电压系数和最佳层合比的表达式.对12个具有不同尺寸和负载条件的样品进行实验,制作过程中承受500g砝码负载的样品的界面耦合系数为0.15,最佳层合比为0.57;承受100g砝码负载的样品的界面耦合系数为0.10,最佳层合比为0.50.磁电电压系数和最佳层合比的实验值与各自包含界面耦合系数的理论值基本符合,证明了改进的等效电路模型的合理性和正确性.     

Thermoelastic equivalent circuit for laser ultrasound

I.IntroductionItiswe11knownthatultrasonicwavecanbegenerated'bytherma1expansionwhenalaserbeamisincidentonsamples.Accordingto1incarthcory,laserultrasonicsignalcanbcderivedfromtheso1utionofthermoe1asticdifferentialcquationinwho1espacc.Asanimportantparameter,theamp1itudeofsoundwavehasbeenappliedtoquantitutivemeas.rements['-3l.Recentpapersbegintofocusonanotherconsiderablecharactcr-thctempora1profileofultrasonicsignalwhoscfrequencyandphasespectruminvolvemoreinfOrmationofmaterialproperhesl~8l.And,c…     

Mechanical and corrosion resistance of hydrophilic sphene/titania composite coatings on titanium and deposition and release of cefazolin sodium/chitosan films

The mechanical and corrosion resistance of hydrophilic sphene/titania composite coatings on titanium formed by a hybid technique of microarc oxidation (MAO) and heat-treatment were investigated. The results indicated that the heat-treatment could improve the hardness, elastic modulus, elastic recovery and corrosion resistance of the MAO coatings, and reinforce the interface bonding between MAO coatings and titanium. A cefazolin sodium/chitosan drug film was prepared on the coating surfaces. The drug load procedures such as the addition of chitosan obviously increased the sustained-release ability of drug films. In addition, the increase of cefazolin sodium concentration could increase the accumulative release concentration of cefazolin sodium. The sustaining-release ability of drug films deposited on the MAO and heat-treated MAO coatings is similar. In the interior of drug film, the physical and chemical bonding reactions such as Coulombic interactions, van der Waals force and H-bonding etc. could be produced, through the chemical group interactions such as -OH and -NH₂ groups of chitosan with -CO of cefazolin sodium.     

弯曲振动薄圆盘的共振频率和等效电路参数研究

机电等效电路是分析复合换能器常用的一种解析方法, 但对薄圆盘而言, 由于弯曲振动的复杂性, 其等效集中参数很难获得, 该方法很少被应用. 本文从分布参数系统与集中参数系统等效角度, 根据动能相等原则和势能相等原则, 给出了弯曲振动薄圆盘的集中参数: 等效质量和等效弹性系数, 得到了共振频率方程, 并用ATILA软件模拟了其振动分布情况, 可以看出解析结果与数值结果趋于一致. 最后给出了分析复合振动系统时薄圆盘集中参数模型的等效电路. 本文的结果对弯曲振动复合换能器的设计提供了理论参考.     

The electrical characterization of ceramic oxides

The Effective Specific Impedance of a composite material is derived by a straightforward extension of Maxwell's theory of the dc resistivity of such a system. The connection with the commonly used equivalent circuit model for ceramic oxides is presented. By way of illustration, some specific models incorporating porosity effects or the existence of a spectrum of conductivities in the major component are analyzed in detail.     

多层微穿孔板结构声学性能计算方法对比分析

计算多层微穿孔板结构声学特性方法传统主要用声电类比法,目前出现阻抗转移法和传递矩阵法,对比分析这三种计算方法,同时进行相应的实验验证。结果表明:阻抗转移法和传递矩阵法实质上是相同的,这两种方法计算结果与实验结果吻合良好。声电类比法在空腔较大时计算结果偏离实验值,原因是声电类比法采用集总参数分析,计算多层结构时,空腔单元只考虑声顺,忽略声质量,导致误差。阻抗转移法和传递矩阵法不存在这一误差,计算准确。     

Mg-Al layered double hydroxides (LDHs) and their derived mixed oxides grown by laser techniques

Layered double hydroxides (LDHs) have been widely studied due to their applications as multifunctional materials, catalysts, host materials, anionic exchangers, adsorbents for environmental contaminants and for the immobilization of biological materials. As thin films, LDHs are good candidates for novel applications as sensors, corrosion resistant coatings or components in electro optical devices. For these applications, lamellar orientation-controlled film has to be fabricated.In this work, the successful deposition of LDH and their derived mixed oxides thin films by laser techniques is reported. Pulsed laser deposition (PLD) and matrix assisted pulsed laser evaporation (MAPLE) were the methods used for thin films deposition. The ability of Mg-Al LDHs as a carrier for metallic particles (Ag) has been considered. Frozen targets containing 10% powder in water were used for MAPLE, while for PLD the targets consisted in dry-pressed pellets.The structure and the surface morphology of the deposited films were examined by X-ray Diffraction, Atomic Force Microscopy, Scanning Electron Microscopy and Secondary Ion Mass Spectrometry.     

碳纳米管掺杂对聚合物聚(2-甲氧基-5-辛氧基)对苯乙炔-PbSe量子点复合材料性能的影响

基于碳纳米管的良好导电性、激子传输性能和量子点聚合物复合材料高的光电转换性能, 采用原位缩合法制备了聚合物聚(2-甲氧基-5-辛氧基)-对苯乙炔(MOPPV)功能化碳纳米管(SWNT)-PbSe量子点复合材料, 通过对复合材料的X射线衍射、透射电子显微镜和紫外可见吸收光谱研究, 发现MOPPV, SWNT与PbSe量子点可以有效地复合, 且SWNT与MOPPV形成网状结构; PbSe量子点尺寸为5.75 nm, 其可均匀地分散在MOPPV-SWNT基体中形成包覆或镶嵌结构, 并发生了光诱导电荷转移.通过对复合材料的光电性能研究发现, 当MOPPV, SWNT, PbSe三者的质量比为1: 0.3 : 1 时其光电性能最好, 开路电压为0.556 V, 短路电流为2.133 mA, 填充因子为34.48%, 转换效率为0.452%, 与聚合物MOPPV-PbSe量子点复合材料材料相比, 光电性能提高了2–3倍. 关键词： 量子点 碳纳米管 复合材料 转换效率     

Optimal design of resonant piezoelectric buzzer from a perspective of vibration-absorber theory

In this paper, an optimization technique is presented for the design of piezoelectric buzzers. This design technique aims at finding the optimal configuration of the coupled cavity and diaphragm structure to maximize the sound pressure output. Instead of measuring the material constants of the piezoelectric ceramic and the metal diaphragm, an "added-mass method" is developed to estimate the equivalent electromechanical parameters of the system on which an analogous circuit can be established. The electrical impedance and on-axis sound pressure level of the piezoelectric buzzer can be simulated by solving the loop equations of the electromechanoacoustical analogous circuit. An interesting finding of this research is that the nature of the piezoelectric buzzer bears remarkable resemblance to that in the dynamic vibration absorber theory. Much physical insight can be gained by exploiting this resemblance in search of the optimal configuration. According to the system characteristic equation, a design chart was devised to "lock" the critical frequency at which the system delivers the maximal output. On the basis of the analogous circuit and the vibration absorber theory, an optimal design was found with constrained optimization formalism. Experiments were conducted to justify the optimal design. The results showed that the performance was significantly improved using the optimal design over the original design. Design guidelines for the piezoelectric buzzers are summarized.     

采用系统函数分析换能器阻抗测量方法的性能

在分析传统三电压法测量阻抗优缺点的基础上,提出了一种发射换能器阻抗测量方法,以解决海上单模激发现场检修发射相控阵一致性的难题。该方法仍利用三电压法电路结构,但修改了测量参数。首先介绍了基于系统函数的换能器阻抗测量方法的原理,然后报道了当串联电阻选取不同数值时换能器阻抗测量的结果以及它们与高精度阻抗分析仪测量结果的比较,最后进行误差分析和测量曲线的等效电路参数拟合。通过对它的性能分析可以看到,在保证采样精度条件下,选择阻值相对换能器阻抗偏小的电阻值,其测量精度完全能达到高精度阻抗分析仪的精度。最后,通过对实验测量阻抗曲线的等效电路参数的最小二乘拟合表明,其拟合电参数准确,能应用到换能器匹配网络的设计。