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1.
熊远福  徐子刚 《分析化学》1997,25(2):219-221
研究了碲(Ⅳ)和碲(Ⅵ)在DDTC-CCl4体系中的萃取和反萃取行为,并用缝管原子捕集技术结合火焰原子吸收法测定了水样中的碲(Ⅳ)和碲(Ⅵ),特征浓度为1.2g/L/1%吸收,检出限0.2μg/L,相对标准偏差1.7%,富集倍中达100%。  相似文献   

2.
催化动力学光度法测定痕量锆   总被引:4,自引:0,他引:4  
研究了在弱酸性介质中,锆(Ⅳ)催化过氧化氢氧化铬蓝黑R这一新的指示反应及其动力学条件,建立了一种高灵敏、高选择性测定痕量锆的新方法,方法检出限为3.74×10-11g/mL,线性范围0~1.1μg/25mLZr(Ⅳ).用于合金钢中痕量锆的测定,结果满意.  相似文献   

3.
用钨酸盐和耐尔蓝光度法测定痕量碲   总被引:1,自引:0,他引:1  
李祖碧  徐其亨 《分析化学》1998,26(3):283-286
报告一个简单、灵敏、快速光度测定碲的方法。聚乙烯醇(PVA)存在下,碲与钨酸盐和耐尔蓝(NB)反应形成离子缔合物。离子缔合物的最大吸收峰位于580nm;表观摩尔吸光系数ε值为3.33×10^7L·mol^-1·cm^-1。本方法允许的碲浓度范围为0 ̄6.0μg/L;对4.8μg/L碲(Ⅳ)测定的相对标准偏差为1.3%(n=11);检测限(3σ)为0.011μg/L(n=12)。考察了许多离子的影响  相似文献   

4.
催化动力学法测定痕量碲的研究   总被引:2,自引:0,他引:2  
吴建中  陈国树 《分析化学》1995,23(4):459-462
本发现以钯(Ⅱ)作催化剂,碲(Ⅳ)作活化剂,能催化加速次磷酸钠与靛红的褪色反应,建立了一种测定碲的新方法,方法检测限为3.9×10^-11gTe(Ⅳ)/ml,测定范围为0-0.5μgTe(Ⅵ)/25mL,用以测定人发中的痕量碲,获得了满意的结果。  相似文献   

5.
动力学光度法测定痕量钛的研究   总被引:9,自引:1,他引:9  
利用Ti(Ⅳ)对溴酸钾氧化酸性品红的抑制作用,建立了动力学光度法测定痕量Ti(Ⅳ)的新方法,检出限为2.9×10^-8g/L,测定范围为0~0.022g/L。用于测定人发中Ti(Ⅳ)结果满意。  相似文献   

6.
碲(IV)在0.03mol/L草酸-0.0006%次甲基蓝介质中,在电位-0.65V(vs.SCE)处,有一尖锐灵敏的导数极谐波,峰电流与浓度在1.0×10-4~1.5×10-2μg/mL之间里线性关系,检测限为4.0×10-5μg/mL.该法应用于人发及血清中痕量碲的测定,结果准确可靠.  相似文献   

7.
催化褪色光度法测定痕量钛的研究   总被引:6,自引:1,他引:6  
本发现钛(Ⅳ)在稀硫酸介质中催化孔誉绿与碘化钾、碘酸钾之间的褪色反应,建立了褪色反应速率方程式和测定痕量钛(Ⅳ)的新方法。方法检测限为3.4 ×10^-10gTi(Ⅳ)/mL,测定范围为0~1.0μg/25mLTi(Ⅳ)。用于测定人发中的微量元素钛的含量,获得了满意结果。  相似文献   

8.
催化褪色法测定痕量硒(Ⅳ)的研究   总被引:3,自引:0,他引:3  
本研究发现,在盐酸介质中,Se(Ⅳ)作活化剂,Pd~(2+)催化次磷酸钠与甲基红的褪色反应。同时研究了反应动力学条件,建立了测定痕量Se(Ⅳ)的新方法。方法检测限为4.8×10~(-5)μg/mLSe(Ⅳ),测定范围为0~0.01μg/mLSe(Ⅳ)。用于测定人发中的痕量Se(Ⅳ),获得了满意结果。  相似文献   

9.
贾丽  夏冰 《分析化学》1996,24(3):315-317
在碱性介质中,痕量锇(Ⅳ)对水杨基荧光酮(SAF)与过氧化氢的氧化还原反应有显著的催化作用。本文以此为基础,提出用分光光度催化动力学测定痕量锇(Ⅳ)的新方法。本法未加掩蔽剂时的线性范围是0.08-0.80μg/L,加入掩蔽剂后的线性范围是0.08-0.80μg/L,检出限为0.08μg/L。本法用于实际样品中Os(Ⅳ)的测定,结果良好,本实验还测定了此催伦反应的活化能和反应级数。  相似文献   

10.
催化动力学光度法测定海产品中痕量硒   总被引:24,自引:4,他引:20  
许卉  贺萍 《分析化学》1999,27(5):540-542
在硝酸介质中,硒(Ⅳ)能催化溴酸钾氧化亚甲蓝使之褪色。研究了这一催化反应的动力学条件,建立了一种动力学光度法测定痕量Se(Ⅳ)的新方法。其灵敏度为3.8×10^-7g/L Se(Ⅳ),Se(Ⅳ)的含量在0 ̄8μg/L范围内与褪色反应速率1g(A0/A)成正比。通过萃取纯化,使方法具有良好的选择性和准确度。用于多种海产品中痕量硒的测定,结果满意.  相似文献   

11.
用溶胶-凝胶法以磷钼酸(MPA)的镍盐溶液水解钛酸四丁酯制备了NiPMo/TiO2催化剂.使用ICP、 XRD、 TG-DTA、 IR、 TPD-MS和微反应技术研究了催化剂的化学组成、热稳定性、化学吸附性质和催化反应性能.杂多钼酸盐与TiO2通过O2-在TiO2表面发生了键合.在623 K下,杂多阴离子仍保持原有的Keggin结构.CO2在Lewis酸位Ni(Ⅱ)和Lewis碱位Ni-O-Mo的桥氧协同作用下生成CO2卧式吸附态Ni(Ⅱ)←O-(CO)←(O--Ni).丙烯有多种吸附态在催化剂上吸附.在563 K、 1 MPa和空速1500 h-1的反应条件下,丙烯的摩尔转化率为3.2%,产物MAA选择性为95%.  相似文献   

12.
In the context of the preparation of camptothecin and luotonin A analogs, the synthesis of some key keto-precursors and their use in Friedländer condensation are described. This paper also focuses on the stability of these keto intermediates and emphasizes the major differences between indolizinones and pyrroloquinazolinones series. Noteworthy is also the report of some original structures isolated as by-products of some experiments.  相似文献   

13.
The Langevin paramagnetic theory can’t describe the relation between magnetization of ferrofluids and applied magnetic field. The structuralization of ferrofluids, which is considered the main influence factor of the magnetization, is regarded. The part of magnetization works is deposited when the structure is forming. This action influences the magnetization of ferrofluids directly or indirectly. On the base of the “compressing” model, the Langevin function that usually describes the magnetization of ferrofluid is modified, and a well-fitted curve is obtained. An equation of the relation between the equivalent volume fraction after being “compressed” and the intensity of magnetic field is discovered, which approximately describes the process of magnetization. The relation between the approximate initial susceptibility and the volume fraction can be obtained from modified formula.  相似文献   

14.
The highly regioselective Buchwald–Hartwig amination at C-2 of the cheap and readily accessible reagent, 2,4-dichloropyridine with a range of anilines and heterocyclic amines is described. This new methodology is robust and provides a facile access to 4-chloro-N-phenylpyridin-2-amines on 0.25 mol scale. These intermediates undergo a further Buchwald–Hartwig amination at higher temperature to enable rapid exploration of the chemical space at C-4 and to provide a library of 2,4-bisaminopyridines.  相似文献   

15.
KMnO4-mediated oxidative CN bond cleavage of tertiary amines producing secondary amine was introduced, which was trapped by electrophiles (acyl chloride and sulfonyl chloride) to form amides and sulfonamides. The reaction could take place at mild condition, tolerating a wide range of function groups and affording products in moderate to excellent yields.  相似文献   

16.
The review contains a concise historical account and information on the most significant researches undertaken by the staff at the A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences on the Chemistry of Heterocyclic Compounds. Dedicated to Academician of the Russian Academy of Sciences B. A. Trofimov on his 70th jubilee. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1443–1502, October, 2008.  相似文献   

17.
Zhanhui Yang  Shiyi Yang  Jiaxi Xu 《Tetrahedron》2017,73(23):3240-3248
Regiospecific and direct imidation of the methyl C(sp3)–H bond of thioanisoles is realized under mild and metal-free conditions with N-fluorobis(benzenesulfonyl)imide as an oxidant and nitrogen source. Proposed mechanism suggests that thionium ion intermediates and a Pummerer-type reaction are involved. The imidation has advantages such as high step-economy, excellent functionality tolerance, and regiospecificity, giving structurally diverse imidation products.  相似文献   

18.
19.
《Tetrahedron》2014,70(21):3377-3384
The Rh(II)-catalyzed reaction of 2-carbonyl-substituted 2H-azirines with ethyl 2-cyano-2-diazoacetate or 2-diazo-3,3,3-trifluoropropionate provides an easy access to 2H-1,3-oxazines and 1H-pyrrol-3(2H)-ones. These compounds can be selectively prepared from the same starting material using temperature as the only varied parameter. The 2-azabuta-1,3-diene intermediate, a common precursor for both heterocyclic products, isomerizes into 2H-1,3-oxazine under kinetic control, while 1H-pyrrol-3(2H)-one is the sole product of the reaction at elevated temperatures. According to DFT-calculations a one-atom oxazine ring contraction involving ring-opening to a 2-azabuta-1,3-diene intermediate, followed by a 1,5- and 1,2-prototropic shift leads to the consecutive formation of imidoylketene and azomethine ylide, which then further undergo cyclization to the pyrrole derivative.  相似文献   

20.
Different approaches for the synthesis of 1-benzyloxypyrazin-2(1H)-one derivatives from simple amino acids have been investigated. A library of 33 precursors for the preparation of N-hydroxy pyrazinones was obtained in moderate to good yields.  相似文献   

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