Interaction of viscous drops in a yield stress material

The interaction of Newtonian drops of various volumes moving in yield stress material is investigated experimentally. Tetrachloroethylene drops move in a rectangular reservoir filled with neutralized 0.07% w/w Carbopol gel under the action of gravity. For initially vertically aligned drop pairs, we present time evolution of separation distance, velocities during the interaction and conditions for coalescence of the drops, which depend on the volumes of the drops and the initial separation between them. For the asymmetric interaction of the pairs, we present interaction patterns, which have been used for estimation of the size of the yielded region and its shape around the leading drop.     

Techniques for generating centimetric drops in microgravity and application to cavitation studies

This paper describes the techniques and physical parameters used to produce stable centimetric water drops in microgravity, and to study single cavitation bubbles inside such drops (Parabolic Flight Campaigns, European Space Agency ESA). While the main scientific results have been presented in a previous paper, we shall herein provide the necessary technical background, with potential applications to other experiments. First, we present an original method to produce and capture large stable drops in microgravity. This technique succeeded in generating quasi-spherical water drops with volumes up to 8 ml, despite the residual g-jitter. We find that the equilibrium of the drops is essentially dictated by the ratio between the drop volume and the contact surface used to capture the drop, and formulate a simple stability criterion. In a second part, we present a setup for creating and studying single cavitation bubbles inside those drops. In addition, we analyze the influence of the bubble size and position on the drop behaviour after collapse, i.e., jets and surface perturbations.     

A rationally-based correlation of mean fragment size for drop secondary breakup

A correlation was derived for the Sauter mean diameter of fragments produced in the bag and multimode drop breakup regimes for drops having Ohnesorge numbers less than 0.1. Development of the correlation focused on the growth of capillary instabilities on the toroidal rim seen during the final stages of bag breakup. The model linked the time scale for drop breakup and the time scale associated with growth of the unstable waves. The instability scale was approximated from the results of linear stability theory for capillary waves on liquid cylinders. The drop breakup scale was based on correlations available in the literature for drops subjected to a rapid (relative to drop deformation time scales) rise in relative velocity. Though development focused on bag breakup, the resultant expression was also shown to correlate the multimode regime data reasonably well.     

Droplet production from disintegrating bubbles at water surfaces. Single vs. multiple bubbles

We experimentally determine the droplet production rate at a water surface where either single or multiple bubbles (bubbly flow) with similar mean diameters disintegrate and produce film and jet droplets. A detailed assessment of film drop production from bubbly flow is important, since most presently used correlations are based on single-bubble measurements. Moreover, jet drops––even though they contain a much larger fluid volume––are de-entrained into the water surface in most technical and geophysical applications. Detailed phase Doppler anemometry (PDA) measurements are performed in the vicinity of the water surface with long sampling times. For a considered mean diameter of approximately 3 mm, the size distribution of the non spherical bubbles is determined from photographic images. From single-bubble measurements we find, consistent with literature data, a narrow size distribution of the jet drops with a mean diameter of 477 μm. For bubbly flow, the maximum is shifted to somewhat smaller jet drop diameters (425 μm) and the production of film droplets increases significantly. We relate this increase to the coalescence of bubbles prior to their disintegration at the surface. Our results therefore show that for a fixed bubble size and gas flow rate the number of film drops entrained from a bubbly flow is underestimated, if the estimate is based on single-bubble data.     

Coalescence of viscous drops translating through a capillary tube

An experimental study of the interaction and coalescence of viscous drops moving through a cylindrical capillary tube under low Reynolds number conditions is presented. The combined pressure- and buoyancy-driven motion of drops in a Newtonian continuous phase is examined. The interaction between two drops is quantified using image analysis, and measurements of the coalescence time are reported for various drop size ratios, Bond numbers, and viscosity ratios. The time scale for coalescence in the non-axisymmetric configuration is found to be substantially larger than that for coalescence in the axisymmetric configuration. Measurements of the radius of the liquid film formed between the two drops at the instant of apparent contact are used in conjunction with a planar film drainage model to predict the dependence of the coalescence time on drop size ratio for coalescence of low viscosity-ratio drops in the axisymmetric configuration.     

Low-Reynolds-number motion of a deformable drop between two parallel plane walls

The motion of a three-dimensional deformable drop between two parallel plane walls in a low-Reynolds-number Poiseuille flow is examined using a boundary-integral algorithm that employs the Green’s function for the domain between two infinite plane walls, which incorporates the wall effects without discretization of the walls. We have developed an economical calculation scheme that allows long-time dynamical simulations, so that both transient and steady-state shapes and velocities are obtained. Results are presented for neutrally buoyant drops having various viscosity, size, deformability, and channel position. For nearly spherical drops, the decrease in translational velocity relative to the undisturbed fluid velocity at the drop center increases with drop size, proximity of the drop to one or both walls, and drop-to-medium viscosity ratio. When deformable drops are initially placed off the centerline of flow, lateral migration towards the channel center is observed, where the drops obtain steady shapes and translational velocities for subcritical capillary numbers. With increasing capillary number, the drops become more deformed and have larger steady velocities due to larger drop-to-wall clearances. Non-monotonic behavior for the lateral migration velocities with increasing viscosity ratio is observed. Simulation results for large drops with non-deformed spherical diameters exceeding the channel height are also presented.     

The vortex ring velocity resulting from an impacting water drop

Experimental observations are reported on the evolution of a vortex ring for the first 70 ms after it is created by the impact of a dyed water drop upon a pool of clear water. The 2.6 mm diameter drops were released from two heights. The drops impacted the pool with Weber numbers of 23.2 and 16.6 and Froude numbers of 25.2 and 18.0. The Reynolds number of the resulting relaminarized vortex rings based on their diameter was in the range of 320 to 390. Precisely controlled multiple exposure photographs were used to measure the position and shape of the vortex ring versus time, and calculate velocity. It is proposed here that the appropriate time scale is the time it takes for the impact crater to reach its maximum depth. Excellent agreement was found when using this scaling to compare both the present data sets and that previously published for a larger drop.This work was supported by the Natural Sciences and Engineering Research Council of Canada Grant No. OGP 00 41747. Mr. B. Faulkner is thanked for help with the strobe-timing     

Calculation of motion of a spherical drop in the Bingham medium

Mathematical modeling of the experimentally observed process of approaching of two identical oil drops located in an alcohol-water solution (matrix) with an identical density is performed. It is found that the drop moves in cycles consisting of the state at rest, acceleration, and deceleration; the cycle time is about 10⁻² s. Violation of the balance of forces on the drop boundary in the state at rest is caused by the fact that the shear stresses on this boundary cannot exceed the yield stress of the matrix, and the normal stresses are determined by solving the problem of the elasticity theory, because intermolecular bonds in the quiescent matrix make it similar to a solid. The results of drop motion calculations and experimental data agree well during the entire process of drop approaching, except for the final stage, which can be attributed to the neglect of hydrodynamic interaction of the drops.     

Collision between immiscible drops with large surface tension difference: diesel oil and water

The collision outcomes of immiscible drops with large surface tension difference, namely, a water drop and a diesel oil drop, were observed experimentally. In a near head-on collision between immiscible drops with large surface tension difference, an “overlaying” action for the drop of the smaller surface tension, i.e., the diesel oil drop, to go around the surface of the drop of the larger surface tension, i.e., the water drop, occurs during the collision. This overlaying action reduces the reflex energy for head-on collisions, making reflex separation more difficult to occur. At the same time, due to the immiscibility, the liquid bridge during stretching separation becomes narrower, which makes stretching separation easier to happen. No coalescence could be observed for a collision of Weber number greater than 60. In addition, compound drops are produced frequently.     

A boundary‐only approach to the deformation of a shear‐thinning drop in extensional Newtonian flow

The influence of shear thinning on drop deformation is examined through a numerical simulation. A two‐dimensional formulation within the scope of the boundary element method (BEM) is proposed for a drop driven by the ambient flow inside a channel of a general shape, with emphasis on a convergent–divergent channel. The drop is assumed to be shear thinning, obeying the Carreau–Bird model and the suspending fluid is Newtonian. The viscosity of the drop at any time is estimated on the basis of a rate‐of‐strain averaged over the region occupied by the drop. The viscosity thus changes from one time step to the next, and it is strongly influenced by drop deformation. It is found that small drops, flowing on the axis, elongate in the convergent part of the channel, then regain their spherical form in the divergent part; thus confirming experimental observations. Newtonian drops placed off‐axis are found to rotate during the flow with the period related to the initial extension, i.e. to the drop aspect ratio. This rotation is strongly prohibited by shear thinning. The formulation is validated by monitoring the local change of viscosity along the interface between the drop and the suspending fluid. It is found that the viscosity averaged over the drop compares, generally to within a few per cent, with the exact viscosity along the interface.     

Particle-induced bridging in immiscible polymer blends

Pickering emulsions are emulsions whose drops are stabilized against coalescence by particles adsorbed at their interface. Recent research on oil/water/particle systems shows that particles can sometimes adsorb at two oil/water interfaces. Such “bridging particles” can glue together drops of oil in water or vice versa. We hypothesize that the same effect should apply in immiscible polymer blends with droplet-matrix morphologies, viz., added particles should glue together drops and give rise to particle-bridged drop clusters. We test this hypothesis in PIB-in-PDMS blends [PIB, poly(isobutylene); PDMS, poly(dimethylsiloxane)] with fumed silica particles. Direct visualization shows that the particles can indeed induce clustering of the drops, and the blends appear to show gel-like behavior. Such gel-like behavior is confirmed by dynamic oscillatory experiments. However, we are unable to conclusively attribute the gel-like behavior to droplet clustering: Association of the fumed silica particles in the bulk, which itself causes gel-like behavior, confounds the results and prevents clear analysis of the gluing effect of the particles. We conclude that PIB/PDMS/fumed silica is not a good model system, for studying particle-containing polymer blends. We instead propose that spherical monodisperse silica particles can offer a far more convenient model system, and provide direct visual evidence of gluing of PIB drops in a PDMS matrix.     

Interaction between two consecutive axisymmetric Taylor drops flowing in a heavier liquid in a vertical tube

A study regarding the interaction between two consecutive Taylor drops flowing in a heavier liquid in a vertical tube is reported. Under certain conditions, due to the wake of the leading drop, the trailing drop accelerates, leading to coalescence of the two drops. This study was developed using a numerical model based in the Volume of Fluid method in an axisymmetric geometry. The simulations reported in the present work had to fulfill two conditions: axisymmetry (due to the numerical model) and a high enough drop Reynolds number (which is related to the disturbances in the wake of an isolated drop, and thus to the tendency to drop interaction). Relevant dimensionless numbers are used to assess the effect of the acting forces. Detailed flow patterns and drop shapes are provided. Furthermore, the approaching velocity acquired by the trailing drop is analyzed and velocity profiles between the leading and the trailing drop are also reported. In general, the trailing drop shows an accelerating region, followed by a deceleration near the leading drop. The increase of Eotvos number promotes higher accelerations, while the increase in Morton number and viscosity ratio has the opposite effect. By comparison to literature gas-liquid studies, it was also found that interfacial forces promote the shape stability of the drops.     

Mass transfer from a pulsating drop

The primary difficulty in solving the problem of mass transport through an isolated drop (or bubble) moving in a fluid medium at high Reynolds numbers lies in the extreme complexity of the hydrodynamic pattern of the phenomenon. For sufficiently high velocities a separation of the external flow will occur in the rear portion of the drops and bubbles, which leads to the appearance of a turbulent wake and a sharp increase of the hydrodynamic resistance. Beginning with those dimensions for which the resistance force acting per unit surface of the drop or bubble from the external medium becomes greater than the capillary pressure, the surface of the drops and bubbles begins to deform and pulsate. The local variations of the surface tension, resulting either from the process of convective diffusion or from adsorption of surface-active substances, have a large effect on the hydrodynamics of drops and bubbles (particularly on the deformation of their surface) [1, 2], The presence of vortical, and possibly even turbulent, motion within the drops and bubbles may, under certain conditions [1], lead to their fractionation.Naturally, at the present time such complex hydrodynamics cannot be described by exact quantitative relations. Several authors have attempted to solve this problem approximately within the framework of certain assumptions. In particular [3–6], a theory was developed for the boundary layer on the surface of spherical and ellipsoidal gaseous bubbles moving in a liquid, studies were made [7, 8] of the hydrodynamics of drops located in a gas flow and the conditions were found for which fractionation of such drops takes place. Of considerable practical interest is the development of the theory of mass transfer in pulsating drops and bubbles and finding in explicit form the dependence of the mass transfer coefficients on the hydrodynamic characteristics of these systems. Until this relationship is established, every theory which ignores the effect of hydrodynamics on the mass transfer rate from an individual drop or bubble cannot be considered in any way well-founded. This relates particularly to the theories [9, 10] which consider mass transfer in systems with concentrated streams of drops and bubbles. The present paper is devoted to the study of mass transport through the surface of an isolated drop in an irrotational gas or liquid stream for large Peclet numbers P.In conclusion the authors wish to thank V. G. Levich for his helpful discussions.     

Creation, transportation, and coalescence of liquid drops by means of a light beam

A novel principle of manipulation of discrete drops using concentration-capillary forces controlled by the thermal action of a light beam is proposed. The drops are created by the light beam in a thin layer of absorbing solution and in a film of that solution beneath an air bubble in the cell. The possibility of transporting both a single drop and a drop in an air bubble by means of a light beam is demonstrated. For the first time two drops are made to coalesce on a solid substrate by bringing them into contact by means of a light beam.     

Numerical simulation of drop migration in channell flow under zero-gravity

The migration of deformable drops in the channel flow neglecting the gravity influence is investigated numerically by solving the incompressible Navier-Stokes equations using the finitedifference method coupled with the front-tracking technique. The objectives of this study are to examine the effectiveness of the present approach for predicting the migration of drops in a shear flow and to investigate the behavior of the drop migration in the channel flow under zero-gravity. To validate the present calculation, some typical results are compared with available computational and theoretical data, which confirms that the present approach is reliable in predicting the drop migration. With respect to the drop migration in the channel flow at finite Reynolds numbers, the drops either move to an equilibrium lateral position or undergo an oscillatory motion under different conditions. The effects of some typical parameters, e.g., the Reynolds number, the Weber number, the viscosity ratio and the density ratio of the drop fluid to the suspending medium, and the drop size, on the migration of drops are discussed and analyzed. The project supported by the National Natural Science Foundation of China (10125210) and the Hundred-Talent Programme of the Chinese Academy of Sciences     

A boundary integral method for two-dimensional (non)-Newtonian drops in slow viscous flow

A boundary integral method for the simulation of the time-dependent deformation of Newtonian or non-Newtonian drops suspended in a Newtonian fluid is developed. The boundary integral formulation for Stokes flow is used and the non-Newtonian stress is treated as a source term which yields an extra integral over the domain of the drop. The implementation of the boundary conditions is facilitated by rewriting the domain integral by means of the Gauss divergence theorem. To apply the divergence theorem smoothness assumptions are made concerning the non-Newtonian stress tensor. The correctness of these assumptions in actual simulations is checked with a numerical validation procedure. The method appears mathematically correct and the numerical algorithm is second order accurate. Besides this validation we present simulation results for a Newtonian drop and a drop consisting of an Oldroyd-B fluid. The results for Newtonian and non-Newtonian drops in two dimensions indicate that the steady state deformation is quite independent of the drop-fluid. The deformation process, however, appears to be strongly dependent on the drop-fluid. For the non-Newtonian drop a mechanical model is developed to describe the time-dependent deformation of the cylinder for small capillary numbers.     

Diffusional interaction of drops in a liquid

The method of combining asymptotic expansions (with respect to a large Peclet number) is used to investigate the three-dimensional problem of steady-state convective diffusion to the surface of drops, around which flows a laminar stream of a viscous incompressible liquid whose velocity field is assumed to be known from the solution of the corresponding hydrodynamic problem. It is shown that for large Peclet numbers the heat and mass transfer between drops is completely determined by the mutual arrangement of special (starting or ending at the surface of a drop) lines of flow; under these circumstances, in the flow there are chains of drops which have no mutual diffusional effect on one another, and the total diffusional flow to a drop is determined by diffusion to particles located upstream in the same chain. For the case where the distance between the drops in the chain is much leas than P^1/2 (P is the Peclet number), formulas for the distribution of the concentration and the total diffusional flow to the surface of each drop are obtained. It is shown that the total diffusional flow to the surface of a drop approaches zero in inverse proportion to its order number in a chain, which generalizes [1], in which the axisymmetric case is considered. A solution of the diffusional case is obtained for the case where there are critical lines at the surface of the drop. The problem is solved to the end if the singular flow lines are not closed and depart to infinity. With the presence of a region of closed circulation behind the drops, the problem is reduced to an integral equation.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika, Zhidkosti i Gaza, No. 2, pp. 44–56, March–April, 1978.The author thanks Yu. P. Gupalo and Yu. S. Ryazantsev for their interest in the work.     

具有弱夹层的封闭油藏中的瞬态渗流

多层油藏分为层间无窜流的油藏和层间有窜流的油藏。本文研究了层间有弱渗透夹层的两层油藏中两种情形的瞬态渗流,包括单层打开的瞬态渗流和一层注入、一层采出的两层油藏的瞬态渗流。用面积平均方法求出了弱渗透夹层封闭油藏中瞬态渗流的平均压降。分析表明:在渗流前期,层间窜流量逐渐增大,在后期层间窜流量趋于稳定;在单层开采的情况下:初期两层压降不同,非打开层的压降有滞后现象,并且隔层渗透率越小,油井工作强度越弱,滞后时间越长;后期两层压降趋于一致,可以作为一层油藏处理。在一注一采的油藏中,当注采量相同时,两层压降在后期趋于不同的稳定值;当注采量不同时,两层压降在后期趋于一致,但不能达到稳定。     

Evaporation and explosion of liquid drops on a heated surface

The literature pertinent to various aspects of drop evaporation on a heated surface is reviewed. Both the laser shadowgraphic and direct photographic methods are employed to study thermal stability and flow structures in evaporating drops in all heating regimes. It is revealed that four flow regions exist in stable and unstable type drops at low liquid-film type vaporization regime. As the surface temperature is raised, the flow regions reduce to two. In the nucleate-boiling type vaporization regime, the interfacial flow structure changes due to a reduction in the Marangoni number as well as the dielectric constant of the liquid. An evidence of bubble growth in the drops is disclosed. The micro explosion of drops is found to occur in the transition-boiling type heating range. No drop explosion takes place in the spheriodal vaporization regime except when the drop rolls on to a microscratch on the heating surface. It is concluded that the mechanisms for triggering drop explosion include the spontaneous nucleation and growth phenomena and the destabilization of film boiling.