共查询到17条相似文献,搜索用时 78 毫秒
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采用锌-柠檬酸氢二铵溶液还原体系,以偶氮苯为原料合成出氢化偶氮苯.合成反应的最佳反应条件:当偶氮苯用量是0.625 mmol时,偶氮苯与锌的物质的量之比为1:5,0.2 g/mL柠檬酸氢二铵溶液用量5.0 mL,室温,时间约3 min,平均收率90.63%. 相似文献
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应用离子交换膜法电解邻氯硝基苯合成2,2′-二氯氢化偶氮苯.讨论了电极活化条件、电流密度、电解液温度等因素对电解还原反应的影响.结果表明:在反应温度t=80℃,阴极、阳极电解液分别为10%和30%(by m ass)的NaOH溶液,电流密度4.2A/dm2条件下电解,电流效率最高,可达73%,收率为83%. 相似文献
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Pd/C催化硝基苯氢化制氢化偶氮苯的研究 总被引:6,自引:0,他引:6
在碱性甲醇溶液中 ,硝基苯在Pd/C催化作用下能高产率地选择性氢化还原为氢化偶氮苯 ,2h转化率达10 0 % ,产品收率 98.5 %以上 .通过XRD初步分析了催化作用原理 ,并提出了可能的反应机理 相似文献
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2-羟基-3-羧基-5-磺酸基苯重氮氨基偶氮苯分光光度法测定微量锌 总被引:2,自引:0,他引:2
1引言本重氮氨基偶氮苯类试剂是分析性能优良的显色剂,2-羟基-3-羧基-5-磺酸基苯重氮氨基偶氮苯(HCSDAA)是其中新近合成的一种。我们已研究了其用于微量汞、铊、铜的分光光度测定和汞、铜的流动注射分析。本文发现,HCSDAA也是锌的高灵敏显色剂,据此提出的测定锌的方法灵敏、简便、选择性好,可不经预分离或使用掩蔽剂直接测定人发和锌强化营养盐中微量锌.2实验方法移取适量锌标准溶液于10mL比色管中,依次加入1%乳化剂OP$液1。mL,0.04%HCSDAA乙醇溶液亚.8mL、0.05mol/L硼砂一Na0H缓冲溶液(pH11.0)2.5mL,用水… 相似文献
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金属镁具有较强的还原性,可以促进加氢还原、亚砜脱硫、二元醇消除、混合醚制备等反应[1],在有机合成化学上是一种常用且有效的催化剂或反应试剂.但是迄今为止,除对格氏反应研究比较透彻外,金属镁和有机底物分子的基元反应研究报道极少,这导致了金属镁在很多有机反应中的催化作用机理往往不很清楚. 相似文献
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The values of isotropic HFS constantsa
N were obtained for nitroxyl radicals (NR) of the piperidine series in hexane and water. The interrelation between rate constants for NR reduction and oxidation reactions, isotropic HFS constantsa
N, inductive constants of the piperidine substituents, and electrochemical characteristics of NR were found. The dependence of the rate constants for the reduction of NR by hydrazobenzene (HB) and its oxidation by tetranitromethane (TNM) upon the Hammett type inductive constants
EPR, obtained using HFS constantsa
N as the basis, was analyzed. The solvent effect on the reduction and oxidation reaction rate constants, the kinetic isotopic effect of the reduction reaction for a number of NR-HB systems, and alternative reaction mechanisms are considered.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1074–1079, June, 1993. 相似文献
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以廉价的4-羟基苯甲醛为原料,在温和条件下先后经硼氢化钠还原和与乙酰氯反应,合成了乙酸4-氯甲基苯酯,其结构经元素分析,IR,1H NMR和13C NMR确证。 相似文献
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A nitrogen doped mesoporous carbon matrix supported oxygen vacancies rich tungsten oxide composite material, WO3-x@NC (1 > x > 0), has been fabricated successfully with chitosan and H3PW12O40 as precursors through calcination. In this composite material, WO3-x particles with the size about 10–15 nm disperse evenly in nitrogen doped mesoporous carbon matrix. WO3-x@NC presents low overpotentials (η10) of 61 and 306 mV to reach a current density of 10 mA/cm2 for HER and OER in 1.0 M KOH, respectively. With WO3-x@NC as both cathode and anode at the same time, an electrolyzer, WO3-x@NC//WO3-x@NC was constructed for overall water splitting, which only needs a cell voltage of 1.60 V to achieve a current of 10 mA/cm2. During this process, WO3-x@NC//WO3-x@NC exhibits remarkable stability in 48 h. Moreover, besides HER and OER, WO3-x@NC also shows striking catalytic activity for reductive conversion of 4-nitrophenol to 4-aminophenol. Oxygen vacancies from WO3-x and good electron transportation property of nitrogen doped carbon matrix play important roles in overall water electrocatalytic splitting and 4-nitrophenol reductive removal. We expect WO3-x@NC will find its way as a new resource for hydrogen energy as well as a promising material in 4-nitrophenol removal from water. 相似文献
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O. G. Ganina I. S. Veselov G. V. Grishina A. Yu. Fedorov I. P. Beletskaya 《Russian Chemical Bulletin》2006,55(9):1642-1647
4-Aminocoumarins were synthesized in high yields by the reaction of 4-hydroxycoumarin trifluoromethanesulfonates with amines.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1583–1588, September, 2006. 相似文献
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ZhengBaoZHAO JingGUO YuanGuiWEI TongDaLIANG 《中国化学快报》2005,16(7):889-892
To search for a better prodrug of 4-aminosalicylic acid that is expected to deliver stably parent drug to colon against the inflammatory bowel disease, a novel 4-aminosalicylic acid derivative was designed and synthesized from 4-aminosalicylic acid. 4-Aminosalicylglycine was prepared from 4-aminosalicylic acid by protecting amino and hydroxyl groups with benzyloxycarbonyl and acetyl, respectively, then the carboxylic acid was converted to acyl chloride which was treated with glycine. After removing the protection groups, 4-aminosalicylglycine wasobtained. All the compounds were characterized by FT-IR, ^1H-NMR, ^13C-NMR spectra. In vivo experiment on rats suggested that the curative effect of 4-aminosalicylglycine was more effective than that of 4-aminosalicylic acid. 相似文献