NMR enhancement factor inCuMn(Fe) spin glasses

The spin glass magnetic enhancement factor has been measured at T=1.3 K with^63/65Cu NMR spin echo technique. Alloying iron to CuMn, (H_o) shows a large range of constancy against an external field H_o, applied in and opposite to the direction of the freezing field H_c. It is supposed that the stiffness of the frozen spin glass is stabilized in this range by a subsystem of ferromagnetic iron clusters. Bound by its own crystalline anisotropy energy, the subsystem has its own stiffness. It probably behaves as a powder system consisting of ferromagnetic single domain particle spheres, having also an isotropic distribution of domain magnetization directions and giving rise to a mean ferromagnetic NMR enhancement factor.     

Lattice location of Mn in the spin glass CuMn

The lattice location of Mn in a Cu10 at.% Mn single crystal has been determined using ⁴He ion channeling and ion-induced X-rays. It is found that the Mn atoms are 100% in substitutional sites.     

Magnetic relaxation phenomena in a CuMn spin glass

Experiments on the temperature and time dependence of the response function and the field cooled magnetisation of a Cu(Mn) spin glass at temperatures below the zero field spin glass temperature are used to explore the non-equilibrium nature of the underlying spin configuration. The results imply that a certain spin configuration is imprinted on the system as the temperature is decreased at a constant cooling rate. The cooling rate governs the magnitude of the FC magnetisation ((H,T)). Any intermittent halt at a constant temperature, , imprints an extended spin configuration, a process that is reflected e.g. in a downward relaxation of . On continued cooling at the same rate, the magnitude of (T) remains at a lower level than that of a continuous cooling curve. These results are put into the context of the corresponding behaviour of the response function as observed in measurements of the relaxation of the zero field cooled magnetisation. Received 27 October 1998 and Received in final form 30 November 1998     

Susceptibility,hysteresis and magnetization states in the CuMn spin glass

AC susceptibilities have been measured at T ⪡ T_f on a quenched Cu-8.25 at% Mn sample along the hysteresis curve and especially in remanent magnetization states. Along the M(H)-curve _ϰ∥ starts to decrease already below the S-point field H_w, when dM/dM is still increasing. After reduction of the external field from H ⪢ H_w to zero ϰ_⊥ by far exceeds ϰ _∥, which itself is a little increased above its starting (ZFC) value. Reversing the external field ϰ_∥ develops distinct maxima at the step fields H_st. A model is developed considering the spin glass at M_r to consist of magnetic moments bound by different anisotropies to preferential directions which are oriented partly at random (anisotropy field H¹_w), partly along M_r (anisotropy field H H¹_st ⪡ H¹_w). The model connects both susceptibilities with characteristic parameters of the hysteresis and quantitatively explains the data.     

Ultrasound in spin glasses

The change of the sound velocity v(,T) and the damping of sound waves (,T) in spin glasses are calculated in the frame-work of an Ising model with a random distribution of exchange interactions. The calculation is based on linearized equations of motion for the spins and on an improved mean field approximation which includes the Onsager reaction field. Near to the freezing temperatureT _f and at high temperatures v(,T) and (,T) turn out to be approximately proportional to the real and the imaginary parts of the dynamical susceptibility. For the special case of infinite range interactions atT=T _f one has v(, T_f) ( )^1/2 and (, T_f) (/)^1/2 where is the relaxation time of independent spins. However, already slightly aboveT _f the frequency dependence of both quantities becomes rather small for RKKY spin glasses. At high temperatures both, v(,T) and (,T) vary asT ^–1.SFB 125 Aachen-Jülich-Köln     

Investigation of spin reorientation phenomena in ferromagnetic MnSb by NMR

A temperature dependence of wall edge and wall centre resonances of ⁵⁵Mn has been carried out in MnSb in the region 77 to 530 K. The data show that the spin reorientation occurs in the temperature region 519 to 524 K. The observed quadrupolar splitting, ν_Q, doubles across the transition. The dc resistivity measurements also show an anomoly in this transition region. It is also found that this transition occurs when the $\text{c}\text{a}$ ratio becomes 1.417 in MnSb and MnBi.     

Thermopower of spin glasses

We calculate the thermopowerS _d(T) of spin glasses on the basis of thesd exchange model with additional interactions between the impurity spins by means of time dependent perturbation theory. Similarly to the Kondo effect, the observed giant thermopower can only be explained if one also takes into account the spin independent interactionV between the magnetic impurities and the conduction electrons. We obtain a Kondo termS _d ⁽¹⁾ (T) (which reduces for vanishing spin interactions to the thermopower of Kondo systems) and in addition a resonance termS _d ⁽²⁾ (T) of opposite sign which vanishes for vanishing interactions. The superposition of both terms leads to an additional extremum of the total thermopower and to a change of sign at a temperatureT ₀ which depends on the Kondo temperature and on the magnetic excitations of the spin glass and therewith on the freezing temperatureT _f. We obtain at low temperatures for oscillating and relaxing spin glass modesS _d ⁽¹⁾ T² andS _d ⁽²⁾ T. At high temperaturesS _d ⁽¹⁾ (T) decreases as |lnT|^–3 andS _d ⁽²⁾ asT ^–1. A close relationship between the temperature dependent resistivity in Born approximation andS _d ⁽¹⁾ (T) is pointed out.SFB 125 Aachen-Jülich-Köln     

Superconductivity of spin glasses

The coexistence of superconducting and spin glass phases is investigated. The dependence of the phase transition temperature in the spin glass state both on the impurity concentration and the superconductivity state is given. The influence of the spin glass phase on the renormalized frequency and the order parameter of the conduction electrons is determined.     

Reentrant behaviour in spin glasses

We present the phase diagram of thed-dimensional random bond Ising model as a representative system for spin glasses. We consider nearest neighbour ferromagnetic couplingsJ with concentration 1-p and impurity couplingsaJ (|a|1) with concentrationp. It is shown that for antiferromagnetic couplings, –1<a<0, the system quite generally exhibits reentrant behaviour, i.e. two phase transitions at finite temperatures, in certain ranges of the concentrationp. It is further argued that this behaviour is a quite common feature for spin glass systems characterized by competing interactions.Dedicated to B. Mühlschlegel on the occasion of his 60th birthday     

Ordering in Heisenberg spin glasses

For five different Heisenberg spin glass systems, torque experiments were performed in applied magnetic fields up to 4 T. The Dzyaloshinski-Moriya random anisotropy strengths, the in-field torque onset temperatures, and the torque relaxation were measured. Critical exponents were estimated independently using a standard protocol. The data are strong evidence for a true spin glass ordered state which survives under high applied magnetic fields; they can be interpreted consistently in terms of a chiral ordering model with replica symmetry breaking as proposed by Kawamura and co-workers.     

Heterogeneous aging in spin glasses

We introduce a set of theoretical ideas that form the basis for an analytical framework capable of describing nonequilibrium dynamics in glassy systems. We test the resulting scenario by comparing its predictions with numerical simulations of short-range spin glasses. Local fluctuations and responses are shown to be connected by a generalized local out-of-equilibrium fluctuation-dissipation relation. Scaling relationships are uncovered for the slow evolution of heterogeneities at all time scales.     

Ultrasound in spin glasses II

General expressions are derived for the change of the sound velocity Δv(ω,T) and the damping of sound waves γ(ω,T) in spin glasses for all temperatures and without assuming a specific spin dynamics. The calculation is based on the modulation of the exchange interactions by the sound waves. Explicit results are obtained for diffusive or relaxing spin excitations.     

Sensitivity enhancement in structural measurements by solid state NMR through pulsed spin locking

Free induction decay (FID) signals in solid state NMR measurements performed with magic angle spinning can often be extended in time by factors on the order of 10 by a simple pulsed spin locking technique. The sensitivity of a structural measurement in which the structural information is contained in the dependence of the integrated FID amplitude on a preceding evolution period can therefore be enhanced substantially by pulsed spin locking in the signal detection period. We demonstrate sensitivity enhancements in a variety of solid state NMR techniques that are applicable to selectively isotopically labeled samples, including 13C-15N rotational echo double resonance (REDOR), 13C-13C dipolar recoupling measurements using the constant-time finite-pulse radio-frequency-driven recoupling (fpRFDR-CT) and constant-time double-quantum-filtered dipolar recoupling (CTDQFD) techniques, and torsion angle measurements using the double quantum chemical shift anisotropy (DQCSA) technique. Further, we demonstrate that the structural information in the solid state NMR data is not distorted by pulsed spin locking in the detection period.