Tensor polarizabilities of levels of the configurations 4f 13 6s6p and 4f 12 5d6s 2 in thulium I

The level-crossing technique with parallel electric and magnetic fields was used to measure the tensor polarizabilities of six levels of the configuration 4f ¹³ 6s6p + 4f ¹² 5d6s ² in the Tm I-spectrum. Using intermediate coupling wave functions given by Camus and the experimental values of the tensor polarizabilities, the radial integrals for electric dipole transitions from levels of the configuration 4f ¹³6s6p + 4f ¹²5d6s ² to levels of the configuration 4f ¹³ 5d6s + 4f ¹² 6s ²6p have been determined. The results areI(4f ¹³6s6p,4f ¹³5d6s)=1.98(45)ea ₀ andI(4f ¹²5d6s ²,4f ¹²6s ²6p) = 0.88(25)ea ₀. A comparison between the experimental and the calculated values of the tensor polarizabilities shows an excellent agreement, provided that these radial integrals and the radial integrals for the electric dipole transitions to the ground state configuration 4f ¹³6s ² as determined by Wallenstein from lifetime measurements are used in the calculation, instead of radial integrals computed by Camus with Hartree-Fock wave functions.     

Spectroscopic investigation on thallium 6s6p 2 configuration at electron-atom collisions: II. Excitation functions

We have measured the excitation functions of the Tl I 221.1, 258.0, and 231.6 nm lines having clearly pronounced features above the ionization potential. The nature of these features, including the resonance mechanism and postcollisional interaction with the participation of autoionizing states of the 6s6p ² configuration, has been discussed. A high-energy feature (at 12.7 eV) revealed in the excitation function of the 221.1 nm line is associated with the shape resonance formed at excitation of the autoionizing state of the configuration 6p ³.     

Tensor polarizabilities and lifetimes of levels of the configurations 4f 66s6p and 4f 55d6s2 in samarium I

Stark splittings of 7 levels of the configurations 4f ⁶6s6p and 4f ⁵5d6s² in Sm I were measured by quantum beat spectroscopy in pure electric fields, allowing the determination of tensor polarizabilities. Additionally, the lifetimes of 11 levels of these configurations were determined from time-resolved registration of the exponential decay. From these values the radial integrals I(6p,6s), I(6p,5d), and I(5d,4f) were derived by a parametric analysis. Theoretical values of tensor polarizabilities and lifetimes which were calculated using these radial integrals show good agreement with experimental data of various authors.     

Experimentally determined transition probabilities of the systems 6p2→6p6d, 6p7s, 6p8s of neutral lead

Branching ratio measurements have been performed for all of the observed transitions from eight levels in neutral lead (6p²→6p6d, 6p²→ 6p7s, 6p²→6p8s) excited in a hollow cathode discharge in the 200–730 nm spectral range. From the relative emission intensity data, a set of absolute transition probabilities is derived for 28 lines, including lines for which transition probabilities have not been previously published. The absolute scales are obtained by averaging the measured lifetimes of the ³P⁰_1,2, ¹P_1⁰(6p7s), ³F^0_2,3, ³D^0_1,2(6p6d) levels.     

Comparison of the noncoplanar 6Li(p,pd)4He reactions at 120 and 200 MeV

The ⁶Li(p, pd)⁴He reaction was studied at 200.2 MeV, at the quasi-free angle pair (θ_p, θ_d) = (54°, ?48.9°), for noncoplanarity angles φ from 0° to 28°. ⁶Li αd spectroscopic factors of 0.84 and 0.76 are deduced from our coplanar data at this energy and 120 MeV, respectively, for ground-state 2S Woods-Saxon wave functions. A recent microscopic three-body calculation predicts spectroscopic factors from 0.70 to 0.75; using the ground-state wave functions from this study, we deduce a factor of 0.76 from the 200 MeV data. DWIA calculations fit the measured integrated cross sections versus φ for spectator momenta P_α ? 100 MeV/c at both bombarding energies, but underpredict them for larger P_α. Momentum form factors were better reproduced with 1S αd cluster wave functions for a soft-core bound-state potential than with the 2S Woods-Saxon wave functions, but the former wave functions generate unphysically large (～1.25) spectroscopic factors.     

Calculation of Xe II line strengths and radiative lifetimes in intermediate coupling

Line strengths for 5s ² 5p ⁴ 6s?5s ² 5p ⁴ 6p transition in xenon are calculated in intermediate coupling scheme. The parametric potential method is used in calculating the radial part of the wave functions while the method of least squares fit of energy levels is applied in obtaining the angular part of the wave functions. Lifetimes of the 6p states obtained using these methods show a good agreement with data from electron-impact experiments.     

Recent hyperfine structure investigations in the configurations 4f 136s 2, 4f 136s6p,and 4f 125d6s 2 of Tm I

By use of optical hyperfine structure investigations in the Tm I spectrum theA- values of 20 levels of the configurations 4f ¹³ 6s 6p and 4f ¹² 5d 6s ² and theA-value of 4f ¹³ 6s ^{2 2} F _5/2 were determined very accurately. These data and tenA-factors from former experiments are used for theoretical calculations. 30A-factors have been interpolated from intermediate coupling wave functions using 9 effective mono-electronic parameters. The r.m.s. deviation between experimental and theoreticalA- values amounts to 0.5 10^?3 cm^?1 and represents 3/100 of the average value of the measuredA-factors.     

A study of the reactions208Pb(d,d)208Pb and208Pb(d,p)209Pb at energies above and below the Coulomb barrier

The reactions²⁰⁸Pb(d, d)²⁰⁸Pb and²⁰⁸Pb(d, p)²⁰⁹Pb have been studied in the energy region from below to above the Coulomb barrier. An optical-model analysis of the elastic scattering results has been performed to obtain parameters for a DWBA analysis. Distorted wave calculations for the direct transitions leading to single-particle states in²⁰⁹Pb have been used to extract spectroscopic factors. Only two deuteron potential sets give a good account of the stripping data throughout the energy region studied.     

Hyperfine-structure and isotope-shift measurements in the 6s 5d↔6p 5d transitions of Ba I in the far-red spectral region

Measurements of the hyperfine structures in the 6p5d ¹ D ₂,³ D ₁ and³ F _{2, 3, 4} states of¹³⁵Ba and¹³⁷Ba, and isotope-shifts in several far-red transitions between the 6s 5d and 6p 5d configurations, as well as the transition 6s ^{2 1} S ₀→6s6p ³ P ₁ at 7,911 Å have been performed using high-resolution laser spectroscopy on a collimated atomic beam of natural barium. An analysis of the magnetic-dipole interaction in the 6p 5d configuration using effective one- and two-body hyperfine operators is presented. In particular the contact interaction was studied with respect to the correlation between the two valence electrons. Effects of strong configuration interaction were found. From a King-plot analysis of the isotope shift term- andJ-dependence of the field shift have been evaluated for the transitions between the 6s 5d and 6p 5d configurations. Relativistic Hartree-Fock (RHF) calculations have been performed of electron densities at the nucleus for six different configurations in Ba I and Ba II. The RHF calculations reproduce the experimental King-plot slopes quite well, while the absolute values, of the changes in electron density at the nucleus for the studied transitions, are found to be 9% lower than the results derived from a muonic experiment.     

The quenching of Pb(6p 2 1 D 2) atoms in collisions with molecules

The collisions of metastable Pb(6p ^{2 1} D ₂) atoms with various molecules were studied by the diagnostics of radiation from a hollow cathode lamp and a laser on lead vapor. Experiments were performed for a gas flow of lead atoms with argon. The Pb(6p ^{2 1} D ₂) states were excited in a gas discharge in the presence of reagent gas molecules. The absolute rate constants for the quenching and chemical reactions of lead atoms in the ground and excited states were determined. The quantum efficiency of chemical reactions was close to one for the N₂O, CH₂Cl₂, SF₆, and CuBr molecules. Long-lived chemical compounds were formed in these reactions.     

Gross structure in excitation functions for207Pb(p,p′)207Pb in the region of overlapping isobaric analogue resonances

Prominent resonances in the reaction²⁰⁷Pb(p, p′)²⁰⁷Pb leading to the low-lying states in²⁰⁷Pb(1/2^? g.s., 5/2^? 0.57 MeV, 3/2^? 0.89 MeV, 7/2^? 2.33 MeV) are observed betweenE _p =16 and 18 MeV. The structures in the excitation functions are interpreted as being due to analogues of states in²⁰⁸Pb which are mixtures of neutron particle-hole configurations.     

Electron momentum distribution in multiply-ionized neon atoms

We present momentum-space properties of multiply ionized neon atoms as a function of the degree of ionization of the atom. In particular, we have calculated the Compton profiles of all possible ionized states of neon atoms with electronic configurations 1s^m2sⁿ2p^q, m=1-2, n=0-2, q=0-6. The radial single-electron radial wave functions, obtained from the Hartree-Fock atomic model, were converted into momentum space wave functions by applying appropriate Fourier transformation. The values of the Compton profiles from the present calculation can be used to interpret experimental cross sections of variously ionized neon atoms colliding with other atoms. Compton profiles of neutral neon atoms, available in the literature, are in excellent agreement with the present calculation.     

A study of particle-vibration multiplets in 203Tl using the 205Tl(p,t)203Tl, 208Pb(p,t)206Pb and 206Pb(p,t)204Pb reactions

The ²⁰⁵Tl(p, t)²⁰³Tl reaction has been used at 26.2 MeV to obtain additional information on the particle-vibration multiplets in ²⁰³Tl. Enhancement factors for the L = 0 and L = 2 transitions to the lower excited states of ²⁰³Tl were well accounted for by using enhancement factors from the ²⁰⁶Pb(p, t)²⁰⁴Pb reaction and the wave functions from the intermediate coupling calculations of Covello and Sartoris. Additional data on the ²⁰⁸Pb(p, t)²⁰⁶Pb reaction at 26.2 MeV were used along with data at other energies to examine the energy dependence of the zero-range enhancement factors.     

The effect of correlation on the excitation probability Kr 4p 6→Rb+ 4p 5 5p following β-decay

Using a multi-configuration Hartree-Fock (MCHF) approximation for the stationary states, the effect of correlation on the excitation probability, Kr 4p ^{6 1} S→ Rb⁺ 4p ⁵ 5p ¹ S is studied. It is shown that the MCHF approximation equivalent to a nonorthogonal Hartree-Fock approximation, is the most important correction to the Hartree-Fock total wave function, and that the remaining correlation, though significant, has a much smaller effect.     

Hyperfine structure in the 6p5d configuration and isotope shifts in transitions between the 6s5d and the 6p5d configurations in Ba I

High-resolution laser fluorescence spectroscopy, using a single-mode dye laser acting on a collimated atomic beam, has been performed to determine the hyperfine-structure (hfs) constants in six states of the 6p 5d configuration of¹³⁵Ba and¹³⁷Ba. Isotope shifts (IS) for eleven transitions between the 6s 5d and the 6p 5d configurations have also been measured. From an analysis of the energy levels, intermediate angular wavefunctions have been deduced. The wavefunctions are used to evaluate experimental hyperfine parameters from the experimental hfs constants. The parameters are, for the magnetic-dipole interaction compared with theoretical values, and for the electricquadrupole interaction used to estimate the nuclear quadrupole moments for the odd isotopes. The IS in the measured transitions are analysed using a King-plot, with the first resonance line in Ba II as the reference. Specific mass and field shifts are evaluated for the measured transitions. The field shifts have been used to determine the change in mean-square radius between the natural abundant Ba-isotopes.     

Hyperfine structure of the 4s4p1P1-state of67Zn by level crossing spectroscopy

The magnetic dipole coupling constantA of the 4s 4p¹P₁ state of⁶⁷Zn was measured in a level crossing experiment. The result is A(4s4p¹P₁ ⁶⁷Zn)= 17.7(5) MHz. In a modified Breit-Wills theory thisA factor leads to a parameter λ_P= 0.71(3), which describes the difference in the radial wave functions of thep-electron in 4s4p¹P₁ and³P₁ states respectively. The lifetime of the 4s4p¹P₁ state was remeasured by Hanle-effect experiments. The result τ=1.41± 0.04 nsec is in good agreement with other measurements.