A- and C-weighted sound levels as predictors of the annoyance caused by shooting sounds,for various façade attenuation types

In a previous study on the annoyance caused by a great variety of shooting sounds [J. Acoust. Soc. Am. 109, 244-253 (2001)], it was shown that the annoyance, as rated indoors with the windows closed, could be adequately predicted from the outdoor A-weighted and C-weighted sound-exposure levels [ASEL (L(AE)) and CSEL (L(CE))] of the impulse sounds. The explained variance in the mean ratings by (outdoor) ASEL was significantly increased by adding the product (L(CE) - L(AE))(L(AE)) as a second variable. In the present study it was investigated to which extent the additional contribution of the second predictor is also relevant for fa?ade attenuation types with lower and higher degrees of sound isolation than applied previously. Twenty subjects rated the indoor annoyance caused by 11 different impulse types produced by firearms ranging in caliber from 7.62 to 155 mm, at various levels and for five fa?ade attenuation conditions. The effect of fa?ade attenuation on the ratings was large and consistent. In all conditions, an optimal prediction of the annoyance was obtained with outdoor ASEL as the first, and (L(CE) - L(AE))(L(AE)) as the second predictor. The benefit of the second predictor, expressed as the increase in the explained variance, ranged from 2.5 to 55 percent points, and strongly increased with the degree of fa?ade attenuation. It was concluded that for the determination of the rating sound level, the acoustic parameters ASEL and CSEL are very powerful. In addition, the results showed that for the whole set of impulses included, the annoyance could also be predicted very well by the weighted sum of indoor ASEL and the product (L(CE) - L(AE))(L(AE)).     

Photoinduced deposition of gold nanoparticles on TiO<Subscript>2</Subscript>–WO<Subscript>3</Subscript> nanotube films as efficient photoanodes for solar water splitting

Gold-modified TiO₂–WO₃ nanotubes with different amounts of gold were obtained by two methods; photoassisted deposition and one-step electrochemical anodizing method. The morphology, crystallinity and elemental composition were studied by FE-SEM, XRD and EDX. The photoelectrochemical performance was examined under Xe light illumination in 1 M NaOH electrolyte. Characterization of the as-prepared TiO₂–WO₃ samples indicated that sodium tungstate concentration in anodizing solution significantly influenced the morphology and photoelectrochemical activity of fabricated films. Also, photoelectrochemical characterizations show that the photocatalytic activity of Au/TiO₂–WO₃ nanotubes was improved as compared with that of bare TiO₂–WO₃ nanotubes. The experimental results showed that the photocatalytic activities of Au/TiO₂–WO₃ were significantly affected by the amount of Au nanoparticles. The amount of gold nanoparticles was effectively controlled by time of photoreduction of the chloroauric acid solution. These new photoanodes showed enhanced high photocurrent density with good stability and are a highly promising photoanodes for photocatalytic hydrogen production.