Surface tension and density of liquid Bi–Pb,Bi–Sn and Bi–Pb–Sn eutectic alloys

Surface tension and density measurement of liquid Bi₅₆Pb₄₄, Bi₄₃Sn₅₇ and Bi₄₆Pb₂₉Sn₂₅ eutectic alloys was carried out by using the large drop method over the temperature range of 380–750 K. The regular solution model has been used in conjunction with Butler's equation to calculate the surface tension of binary and ternary alloys of the Bi–Pb–Sn system, while the surface tension of ternary alloys has also been predicted by using geometric models. The new experimental results were compared with the calculated values of the surface tension as well as with the data available in the literature.     

A study of Bi–Pb–Sn–Cd–Sb penta-alloys rapidly quenched from melt

Optical microscopy, X-ray diffractometry, the double bridge method, the Vickers microhardness testing and dynamic resonance techniques have been used to investigate structure, electrical resistivity, hardness, internal friction and elastic modulus of quenched Bi–Pb–Sn–Cd–Sb penta-alloys. The properties of these penta-alloys are greatly affected by rapid quenching. The intermetallic compound χ(Pb–Bi) or Bi₃Pb₇ is obtained after rapid quenching using the melt-spinning technique, and this is in agreement with reports by other authors [Marshall, T. J., Mott, G. T. and Grieverson, M. H. (1975). Br. J. Radiol., 48, 924; Kamal, M., El-Bediwi, A. B. and Karman, M. B. (1998). Structure, mechanical properties and electrical resistivity of rapidly solidified Pb–Sn–Cd and Pb–Bi–Sn–Cd alloys. J. Mater. Sci.: Mater. Electron., 9, 425; Borromêe-Gautier, C., Giessen, B. C. and Grrant, N. J. (1968). J. Chem. Phys., 48, 1905; Moon, K.-W., Boettinger, W. J., Kattner, U. R., Handwerker, C. A. and Lee, D.-J. (2001). The effect of Pb contamination on the solidification behavior of Sn–Bi solders. J. Electron. Mater., 30, 45.]. The quenched Bi_43.5Pb_44.5Cd₅Sn₂Sb₅ alloy has important properties for safety devices in fire detection and extinguishing systems.     

Transverse mass spectra of strange and multi–strange particles in Pb–Pb collisions at 158 A GeV/c

The WA97 experiment has measured the transverse mass spectra for negative hadrons () and strange particles produced at mid–rapidity in Pb–Pb collisions. The increased statistics of analysed data samples allowed us to perform a study of the spectra of , , , and as a function of the collision centrality. The data, which correspond to the most central 40% of the total inelastic cross section, have been divided into four centrality classes according to the estimated number of nucleons taking part in the collision. The spectra, analysed separately for each centrality bin, exhibit only weak ( 15%) centrality dependence. The deviation of the inverse slope from the linear dependence on the particle mass is confirmed even for the most central Pb–Pb collisions. Received: 5 January 2000 / Revised version: 28 February 2000 / Published online: 14 April 2000     

The transport and magnetic properties of La–Pb–Mg–Mn–O manganites at low temperatures

The structure, transport properties and the magnetoresistance behavior in the temperature interval 77–400 K of the perovskite-like lanthanum manganites La_0.6Pb_0.4−xMg_x+yMnO₃ (x=0, 0.1, 0.2 and y=0, 0.2) were investigated. Polycrystalline bulk samples were prepared by sol–gel self-combustion and subsequent heat treatment at 1000 °C for different times, 40, 80, 160 and 320 min. All manganites exhibit a peak in the resistivity around 200–250 K, below the ferromagnetic ordering temperature (320–330 K). An isotropic and negative magnetoresistance has been observed in all compounds. Magnetoresistance MR exhibits a peak in the temperature range 130–150 K, below SC–metal transition temperature. Magnitude of MR at the peaks was nearly 27% in the magnetic field of 2 T. At room temperature, a magnetoresistance of 9.5% for La_0.6Pb_0.2Mg_0.2MnO₃ composition was obtained. Longer heat treatment time enhanced the magnetorezistive properties.     

158GeV/c的Pb–Pb碰撞中的J/ψ抑制现象研究

在Blaizot等人建立的模型基础上,我们考虑了核–核碰撞中的参与者数与核子–核子碰撞数的起伏效应对J/?ψ产生的影响,并对NA50合作组在入射动量为158GeV/c的Pb-Pb碰撞中的实验数据进行了分析,理论结果与实验数据符合的很好     

Ultrasonic semi-solid coating soldering 6061 aluminum alloys with Sn–Pb–Zn alloys

In this paper, 6061 aluminum alloys were soldered without a flux by the ultrasonic semi-solid coating soldering at a low temperature. According to the analyses, it could be obtained that the following results. The effect of ultrasound on the coating which promoted processes of metallurgical reaction between the components of the solder and 6061 aluminum alloys due to the thermal effect. Al₂Zn₃ was obtained near the interface. When the solder was in semi-solid state, the connection was completed. Ultimately, the interlayer mainly composed of three kinds of microstructure zones: α-Pb solid solution phases, β-Sn phases and Sn–Pb eutectic phases. The strength of the joints was improved significantly with the minimum shear strength approaching 101 MPa.     

Influence of pelletization pressure on magnetic susceptibility samples of ceramics Bi (Pb)–Sr–Ca–Cu–O

The influence of pelletization pressing 100–500 MPa on the quality of the samples from Bi_1.7Pb_0.3Sr₂Ca_2.5Cu_3.5O_10+δ superconducting transition was investigated. Samples which were pelletized at 100, 200, 300 MPa increased weight by an uncontrollable diffusion of elements from a filling. Obviously, these elements form additive phases on borders of grains, what is possible to conclude from the dependence χ′–T. The weight of samples pressed at pressure 400 and 500 MPa practically does not change at sintering. These samples after sintering within 250 h have a rather precise superconducting transition from a magnetic susceptibility. XRD shows that the phase structure of samples differs insignificantly—after sintering time 250 h samples consist basically of a phase 2223. The powder of the same composition annealed also within 250 h without a filling by results of XRD consists of approximately equal amounts of phases 2223 and 2212.     

Temperature-dependent thermal expansion of cast and hot-pressed LAST (Pb–Sb–Ag–Te) thermoelectric materials

The thermal expansion for two compositions of cast and hot-pressed LAST (Pb–Sb–Ag–Te) n-type thermoelectric materials has been measured between room temperature and 673 K via thermomechanical analysis (TMA). In addition, using high-temperature X-ray diffraction (HT-XRD), the thermal expansion for both cast and hot-pressed LAST materials was determined from the temperature-dependent lattice parameters measured between room temperature and 623 K. The TMA and HT-XRD determined values of the coefficient of thermal expansion (CTE) for the LAST compositions ranged between 20 × 10^?6 K^?1 and 24 × 10^?6 K^?1, which is comparable to the CTE values for other thermoelectric materials including PbTe and Bi₂Te₃. The CTE of the LAST specimens with a higher Ag content (Ag_0.86Pb₁₉Sb_1.0Te₂₀) exhibited a higher CTE value than that of the LAST material with a lower Ag content (Ag_0.43Pb₁₈Sb_1.2Te₂₀). In addition, a peak in the temperature-dependent CTE was observed between room temperature and approximately 450 K for both the cast and hot-pressed LAST with the Ag_0.86Pb₁₉Sb_1.0Te₂₀ composition, whereas the CTE of the Ag_0.43Pb₁₈Sb_1.2Te₂₀ specimen increased monotonically with temperature.     

Soldering of Bi-2223/Ag high temperature superconducting tapes with Sn–Pb–Bi–Ag alloy paste

Soldered joints of Bi-2223/Ag-sheathed high temperature superconducting multifilamentary tapes were fabricated using 63 wt.%Sn–34 wt.%Pb–1 wt.%Bi–2 wt.%Ag paste. The soldered joints were observed by scanning electron microscope (SEM) and X-ray diffraction (XRD). Moreover, the electrical properties of joints were evaluated by current–voltage curves, and the tensile strengths of the joints were also tested. The results show that the soldered joint consists of Ag sheath – Ag₃Sn compound layer – PbSn₂ and Ag₃Sn solder layer – Ag₃Sn compound layer – Ag sheath. The joints are obeyed with Ohms Law and the magnitude of the joint resistance, which deceases with the increase of the overlap length, can reach the order of 10^?8 Ω. The tensile strength of the joints with a brittle fracture mode is a little lower than that of the original tapes.     

Mechanical properties of in situ consolidated nanocrystalline multi-phase Al–Pb–W alloy studied by nanoindentation

Formation of chunks of various sizes ranging between 2 and 6 mm was achieved using high-energy ball milling in Al–1at.%Pb–1at.%W alloy system at room temperature during milling itself, aiding in in situ consolidation. X-ray diffraction and transmission electron microscopy (TEM) studies indicate the formation of multi-phase structure with nanocrystalline structural features. From TEM data, an average grain size of 23 nm was obtained for Al matrix and the second-phase particles were around 5 nm. A high strain rate sensitivity (SRS) of 0.071 ± 0.004 and an activation volume of 4.71b³ were measured using nanoindentation. Modulus mapping studies were carried out using Berkovich tip in dynamic mechanical analysis mode coupled with in situ scanning probe microscopy imaging. The salient feature of this investigation is highlighting the role of different phases, their crystal structures and the resultant interfaces on the overall SRS and activation volume of a multi-phase nc material.     

Study of K~*(892)~0 and ?(1020) meson production in proton–proton and Pb–Pb collisions at ■=2.76 TeV

In this paper, we describe a study of charged particle yield as a function of pTfor K~*(892)~0 and ?(1020) mesons in proton–proton(pp) and Pb–Pb collisions at ■=?2.76 Te V in the central rapidity region of |y|0.5, in a pTrange of ?pT15 Ge V c~(-1) in pp collisions and in a pT range of 0??pT??20 Ge V c~(-1) in Pb-Pb collisions. We also investigated a very important ratio,the nuclear modification factor, to study the effects of the medium in the most central region, i.e.0%–5% centrality. For data simulation, we used the EPOS-LHC and EPOS-1.99 models. To check the validity of these models' simulations, we compared the data obtained from these Monte Carlo simulation programs with ALICE experimental data for ■=?2.76 Te V. It was concluded that the models' predictions for the ?-meson in pp and for the most central Pb-Pb collisions disagreed with the ALICE data, and that the difference increased with pT. This may be connected with the essential role of collective parton behaviors which could not have been taken into account by the models. For K~(*0) mesons, both programs gave almost the same predictions,and with pTin the interval pT??3 Ge V c~(-1), the predictions were very close to the experimental data. Both models gave higher predictions for the soft pTinterval and lower predictions for the hard interactions. The values of the RAAdistributions were lower than unity and both models were very close to the ALICE data. It is very interesting that the models were not able to describe the pTdistributions, but they gave good predictions for their ratios. This may possibly be due to parton collective behaviors. We observed some additional suppression of K~(*0) at low values of pT with respect to f-mesons, which may be related to the role of the masses of the particles in soft interactions. The rising trend for R_(AA) in the region from pT=?10 Ge V c~(-1) to 20 Ge V c~(-1) observed by the ALICE experiment was absent for the f-mesons.     

Effect of tensor correlations on Gamow–Teller states in Zr and Pb

The tensor terms of the Skyrme effective interaction are included in the self-consistent Hartree–Fock plus Random Phase Approximation (HF + RPA) model. The Gamow–Teller (GT) strength function of ⁹⁰Zr and ²⁰⁸Pb are calculated with and without the tensor terms. The main peaks are moved downwards by about 2 MeV when including the tensor contribution. About 10% of the non-energy weighted sum rule is shifted to the excitation energy region above 30 MeV by the RPA tensor correlations. The contribution of the tensor terms to the energy weighted sum rule is given analytically, and compared to the outcome of RPA.     

The superconducting properties of a Pb/MoTe_2/Pb heterostructure:First-principles calculations within the anisotropic Migdal–Eliashberg theory

The spin-polarized band structures of an ultrathinheterostructure are calculated via first-principles density functional theory.The electron–phonon interaction and the superconducting properties of the ultrathinheterostructure are studied by using the fully anisotropic Migdal–Eliashberg theory powered by Wannier–Fourier interpolation.Due to the complex Fermi surface in this low-dimensional system,the electron–phonon interaction and the superconducting gap display significant anisotropy.The temperature dependence of the superconducting gap can be fitted by solving numerically the Bardeen–Cooper–Schrieffer(BCS)gap equation with an adjustable parameter α,suggesting that phonon-mediated mechanism as its superconducting origin.Large Rashba spin-splitting and superconductivity coexist in this heterostructure,suggesting that this hybrid low-dimensional system will have some specific applications.     

Pb–Po系列偶偶超变形带转动惯量变化的微观机制

用处理对力的粒子数守恒方法分析了A～190区偶偶核系列晕SD带^192—198Pb(1)和¹⁹⁸Po(1)的转动惯量随角频率变化的规律.计算中同时考虑了单极对力与Y20四极对力.实验结果在计算中得到较好的重视.特别是转动惯量变化的微观机制(包括中子和质子的各大壳以及各单粒子能级的贡献)在计算中得到极为清楚的展现.J⁽²⁾的上升,主要来自高N闯入壳(中子N=7,质子N=6)的贡献,而其它大壳对J⁽²⁾的贡献,基本上不随ω而变化.     

Strangeness enhancement at midrapidity in Pb–Pb collisions at 158 A GeV/c: A comparison with VENUS and RQMD models

Recently the WA97 Collaboration has measured , , , and negative particle yields and transverse mass spectra at central rapidity in Pb–Pb and p–Pb collisions at 158 A GeV/c. These results are compared with the predictions of two of the most widely used event generators for heavy-ion collisions: VENUS 4.12 and RQMD 2.3. Both models predict that enhancements increase with the strangeness content of the particle. They fail, however, to reproduce completely the measured values of yields at central rapidity. In particular, for multistrange particles, VENUS fails to reproduce both the p–Pb and the Pb–Pb data, while RQMD works for p–Pb collisions but seems to be unable to reproduce the data in Pb–Pb collisions. Moreover, the predicted behavior for strangeness production as a function of the centrality of the collision appears to be different from the observed behavior. Received: 29 April 1999 / Published online: 14 October 1999     

Glass formation in the system Li2B4O7–Pb3O4–CuO using X-ray diffraction

X-ray diffraction was performed to construct the phase diagram for the ternary Li₂B₄O₇–Pb₃O₄–CuO glass system. Three principal regions were identified: (1) a glass-forming region observed at the composition (75 < Li₂B₄O₇ < 100) mol%, (0 < CuO < 35) mol% and (0 < Pb₃O₄ < 70) mol% in the ternary system, and (100 ? x) mol% Li₂B₄O₇–x mol% Pb₃O₄ where x = 0 up to 70, (100 ? y) mol% Li₂B₄O₇–y mol% CuO where y = 0 up to 25 in the binary system;. (2) a crystalline region: all compositions prepared from the binary system Pb₃O₄–CuO and the ternary system containing Li₂B₄O₇ up to 60 mol%; (3) a partially crystalline region formed between the glass and crystalline regions.     

Optical Absorption in (Pb0.78Sn0.22)1–x In x Te

The spectral dependences of the absorption coefficient are investigated in (Pb_0.78Sn_0.22)_1–x In _x Te at T = 300 K, with the content of indium in the mix x = 0.001–0.050. Two additional-absorption lines exhibiting sharp red margins are found in the () spectra from all the specimens examined. It is shown that they are associated with the optical ionization of the sites, whose energy levels E ₀ and E ₁are located in the forbidden band. It is established that the energy parameters of the E ₀ and E ₁ bands (position of the maxima of the state density function and the half width) do not depend on x. It is demonstrated that the E ₀ band is accounted for by indium located in the sublattice sites. It is found out that the indium concentration in the sites differs from its content in the mix. No changes testifying to the hopping conduction via the impurity states of indium are found in the energy spectrum from (Pb_0.78Sn_0.22)_1–x In _x Te.