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1.
Bahattin Yalçın Perizad A. Fatullayeva Orhan Büyükgüngör Başak Koşar Sülin Taşcıoğlu Akif I. Israfilov Zaur D. Ibayev Ajdar A. Medjidov Adnan Aydın 《Polyhedron》2007
N-(2-Hydroxybenzyl)aminopyridines (Li) react with Cu(II) and Pd(II) ions to form complexes in the compositions Cu(Li)2(CH3COO)2 · nH2O (n = 0, 2, 4), Pd(Li)2Cl2 · nC2H5OH (n = 0, 2) and Pd(L2)2Cl2 · 2H2O. In the complexes, the ligands are neutral and monodentate which coordinate through pyridinic nitrogen. Crystal data of the complexes obtained from 2-amino pyridine derivative have pointed such a coordinating route and comparison of the spectral data suggests the validity of similar complexation modes of other analog ligands. Cu(II) complex of N-(2-hydroxybenzyl)-2-aminopyridine (L1), [Cu(L1)2(CH3COO)2] has slightly distorted square planar cis-mononuclear structure which is built by two oxygen atoms of two monodentate carboxylic groups disposed in cis-position and two nitrogen atoms of two pyridine rings. The remaining two oxygen atoms of two carboxylic groups form two Cu and H bridges containing cycles which joint at same four coordinated copper(II) ion. IR and electronic spectral data and the magnetic moments as well as the thermogravimetric analyses also specify on mononuclear octahedric structure of complexes [Cu(L2)2(CH3COO)2 · 2H2O] and [Cu(L3)2(CH3COO)2 · 4H2O] where L2 and L3 are N-(2-hydroxybenzyl)-2- or 3-aminopyridines, respectively. 相似文献
2.
In the current work, two triazine‐based multidentate ligands (H2L1 and H2L2) and their homo‐dinuclear Mn (II), mononuclear Ln (III) and hetero‐dinuclear Mn (II)/Ln (III) (Where Ln: Eu or La) complexes were synthesized and characterized by spectroscopic and analytical methods. Single crystals of a homo‐dinuclear Mn (II) complex {[Mn (HL1)(CH3OH)](ClO4·CH3OH}2 ( 1 ) were obtained and the molecular structure was determined by X‐ray diffraction method. In the structure of the complex, each Mn (II) ion is seven‐coordinate and one of the phenolic oxygen bridges two Mn (II) centre forming a dimeric structure. The UV–Vis. and photoluminescence properties of synthesized ligands and their metal complexes were investigated in DMF solution and the compounds showed emission bands in the UV–Vis. region. The catecholase enzyme‐like activity of the complexes were studied for 3,5‐DTBC → 3,5‐DTBQ conversion in the presence of air oxygen. Homo‐dinuclear Mn (II) complexes ( 1 and 4 ) were found to efficiently catalyse 3,5‐DTBC → 3,5‐DTBQ conversion with the turnover numbers of 37.25 and 35.78 h?1 (kcat), respectively. Mononuclear Eu (III) and La (III) complexes did not show catecholase activity. 相似文献
3.
The complexes of 4-chloro-2-methoxybenzoic acid anion with Mn2+,
Co2+, Ni2+, Cu2+
and Zn2+ were obtained as polycrystalline solids
with general formula M(C8H6ClO3)2·nH2O and colours typical for M(II) ions (Mn – slightly pink, Co –
pink, Ni – slightly green, Cu – turquoise and Zn – white).
The results of elemental, thermal and spectral analyses suggest that compounds
of Mn(II), Cu(II) and Zn(II) are tetrahydrates whereas those of Co(II) and
Ni(II) are pentahydrates. The carboxylate groups in these complexes are monodentate.
The hydrates of 4-chloro-2-methoxybenzoates of Mn(II), Co(II), Ni(II), Cu(II)
and Zn(II) heated in air to 1273 K are dehydrated in one step in the range
of 323–411 K and form anhydrous salts which next in the range of 433–1212
K are decomposed to the following oxides: Mn3O4,
CoO, NiO and ZnO. The final products of decomposition of Cu(II) complex are
CuO and Cu. The solubility value in water at 293 K for all complexes is in
the order of 10–3 mol dm–3.
The plots of χM
vs.
temperature of 4-chloro-2-methoxybenzoates of Mn(II), Co(II), Ni(II) and Cu(II)
follow the Curie–Weiss law. The magnetic moment values of Mn2+,
Co2+, Ni2+ and Cu2+
ions in these complexes were determined in the range of 76−303 K and
they change from: 5.88–6.04 μB for Mn(C8H6ClO3)2·4H2O, 3.96–4.75
μB for Co(C8H6ClO3)2·5H2O, 2.32–3.02 μB for Ni(C8H6ClO3)2·5H2O and 1.77–1.94
μB for Cu(C8H6ClO3)2·4H2O. 相似文献
4.
A highly sensitive potentiometric flow injection analysis method for the determination of manganese(II), utilizing a redox reaction with hexacyanoferrate(III) in near neutral media containing ammonium citrate is described. The analytical method is based on the detection of the change in potential of a flow-through type redox electrode detector, resulting from the composition change of an [Fe(CN)6]3−-[Fe(CN)6]4− potential buffer solution. A linear relationship between the potential change (peak height) and the concentration of manganese(II) was found. Manganese(II) in a wide concentration range from 10−4 to 10−7 M could be determined by appropriately altering the concentration of the potential buffer from 10−3 to 10−5 M. The lower detection limit of manganese(II) was determined to be 1×10−7 M. The sampling rate and relative standard deviation were 20 h−1 and 1.9% (n=8) for 6×10−6 M manganese(II), respectively. The proposed method was successfully applied to the determination of manganese(II) in actual soil samples obtained from tea fields. Analytical results obtained by the proposed method were in good agreement with those obtained by an atomic absorption spectrophotometric method. 相似文献
5.
《Journal of Inorganic and Nuclear Chemistry》1978,40(4):745-747
In bis-tris buffer, pH 7.3, ZnCl2 (1.5 × 10−3 M) increases the oxygen affinity of human adult hemoglobin (heme concentration 4 × 10−5 M) by 43%. Using an ion-exchange method involving 65Zn radioisotope, we have found that Zn(II) forms a 1:1 complex with carboxyhemoglobin: Kf = 5.0 × 105 M−1 at room temperature. This strong binding of Zn(II) to hemoglobin is in line with the effect of the metal ion on oxygenation of hemoglobin. Mn(II) increases the oxygen affinity of hemoglobin only slightly below 25% oxygen saturation, and causes a decrease in oxygen affinity above 25% saturation (by 24 at 50% saturation). The binding of this metal ion with hemoglobin is much weaker than that found for zinc ion. 相似文献
6.
Kateryna E. Gubina Oleg A. Maslov Elizaveta A. Trush Victor A. Trush Vladimir A. Ovchynnikov Svetlana V. Shishkina Vladimir M. Amirkhanov 《Polyhedron》2009,28(13):2661-2666
This paper presents examples of mixed-ligand Co(II), Cu(II), Ni(II) and Mn(II) complexes, with a distorted octahedral coordination geometry, with 2,2′-dipyridyl or 1,10-phenanthroline and phosphortriamide ligands. The complexes of the general type ML2·Lig (where M = Co(II), Cu(II), Ni(II), Mn(II); L− = {Cl3C(O)NP(O)R2}− (R = NHBz, NHCH2CHCH2, NEt2); Lig = 2,2′-dipyridyl or 1,10-phenanthroline) were synthesised and characterised by means of X-ray diffraction, IR and UV–Vis spectroscopy. The phosphortriamide ligands are coordinated via oxygen atoms of phosphoryl and carbonyl groups involved in six-membered metal cycles. The additional ligands 2,2′-dipyridyl or 1,10-phenanthroline are coordinated to the central atom, forming five-membered cycles. 相似文献
7.
S. Sadaoui-Kacel S. Zaater N. Bensouilah S. Djebbar 《Journal of Structural Chemistry》2016,57(8):1519-1530
Novel transition metal complexes with the repaglinide ligand [2-ethoxy-4-[N-[1-(2piperidinophenyl)-3-methyl-1-1butyl] aminocarbonylmethyl]benzoic acid] (HL) are prepared from chloride salts of manganese(II), iron(III), copper(II), and zinc(II) ions in water-alcoholic media. The mononuclear and non-electrolyte [M(L)2(H2O)2]?nH2O (M = Mn2+, n = 2, M = Cu2+, n = 5 and M = Zn2+, n = 1) and [M(L)2(H2O)(OH)]?H2O (M = Fe3+) complexes are obtained with the metal:ligand ratio of 1:2 and the L-deprotonated form of repaglinide. They are characterized using the elemental and molar conductance. The infrared, 1H and 13C NMR spectra show the coordination mode of the metal ions to the repaglinide ligand. Magnetic susceptibility measurements and electronic spectra confirm the octahedral geometry around the metal center. The experimental values of FT-IR, 1H, NMR, and electronic spectra are compared with theoretical data obtained by the density functional theory (DFT) using the B3LYP method with the LANL2DZ basis set. Analytical and spectral results suggest that the HL ligand is coordinated to the metal ions via two oxygen atoms of the ethoxy and carboxyl groups. The structural parameters of the optimized geometries of the ligand and the studied complexes are evaluated by theoretical calculations. The order of complexation energies for the obtained structures is as follows: The redox behavior of repaglinide and metal complexes are studied by cyclic voltammetry revealing irreversible redox processes. The presence of repaglinide in the complexes shifts the reduction potentials of the metal ions towards more negative values.
相似文献
$$Fe(III) complex < Cu(II) complex < Zn(II) complex < Mn(II) complex.$$
8.
Summary Copper(II) salts were reacted with two diamino-dithioether ligands, i.e. 1,3-di(o-aminophenylthio)propane (abbreviated H2L1) and 1,2-di(o-aminophenylthio)xylene (abbreviated H2L2). Mixtures of copper(I) and copper(II) complexes were obtained with Cl– and ClO
4
–
counterions. The major products were the copper(I) complexes, which were obtained pure after recrystallisation from MeCN-MeOH. The ligands lose two protons from the amine functions to form copper(I) complexes of general formula [CuL]X, where X = ClO
4
–
or Cl–. The complexes were oxidised to [CuL]X2 with H2O2 in DMF. Cu(NO3)2 on the other hand gave [CuH2LNO3]NO3. 相似文献
9.
Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) 3-methylglutarates were prepared as solids with general formula MC6 H8 O4 ×n H2 O, where n =0–8. Their solubilities in water at 293 K were determined (7.0×10−2 −4.2×10−3 mol dm−3 ). The IR spectra were recorded and thermal decomposition in air was investigated. The IR spectra suggest that the carboxylate
groups are mono- or bidentate. During heating the hydrated complexes lose some water molecules in one (Mn, Co, Ni, Cu) or
two steps (Cd) and then mono- (Cu) or dihydrates (Mn, Co, Ni) decompose to oxides directly (Mn, Cu, Co) or with intermediate
formation of free metals (Co, Ni). Anhydrous Zn(II) complex decomposes directly to the oxide ZnO.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
10.
Periakaruppan Athappan Sankarapandian Sevagapandian Gurusamy Rajagopal 《Transition Metal Chemistry》1995,20(5):472-476
Summary Metal(II) chelates of Schiff bases derived from the condensation of 1,2,3,5,6,7,8,8a-octahydro-3-oxo-N,1-diphenyl-5-(phenylmethylene)-2-naphthalenecarboxamide with o-aminophenol (KAAP), o-aminothiophenol (KAAT) or o-aminobenzoic acid (KAAB) have been prepared and characterized. The complexes are of the type [M(N2X)]2 for M = CuII and M(NX)2·nH2O for M = NiII, CoII and VOII (X = phenolic oxygen, thiophenolic sulphur or carboxylic oxygen; n = 0 or 2). Conductivity data indicate that the complexes are non-ionic. The Schiff bases behave as dibasic tridentate ligands in their copper(II) complexes and as monobasic bidentate ligands in their nickel(II), cobalt(II) and vanadyl(II) complexes. The subnormal magnetic moments of the copper(II) complexes are ascribed to an antiferromagnetic exchange interaction arising from dimerization. Nickel(II) and cobalt(II) complexes are trans octahedral whereas vanadyl(II) complexes are square pyramidal 相似文献
11.
Czakis-Sulikowska D. Czylkowska A. Malinowska A. 《Journal of Thermal Analysis and Calorimetry》2002,67(3):667-678
New mixed-ligand complexes of general formulae Mn(4-bpy)(CCl3COO)2⋅H2O, Ni(4-bpy)2(CCl3COO)2⋅2H2O and Zn(4-bpy)2(CCl3COO)2⋅2H2O (where 4-bpy=4,4’-bipyridine) were obtained and characterized. The IR spectra, conductivity measurements and other physical properties
of these compounds were discussed. The central atoms M(II) form coordinate bonds with title ligands. The thermal behaviour
of the synthesized complexes was studied in air. During heating the complexes decompose via different intermediate products to Mn3O4, NiO and ZnO; partial volatilization of ZnCl2was observed. A coupled TG-MS system was used to the analysis of the principal volatile thermal decomposition products of
Mn(II) and Ni(II) complexes. The principal volatile mass fragments correspond to: H2O+, OH+, CO+
2, HCl+, Cl+
2, CCl+ and other.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
12.
Wiesława Ferenc Agnieszka Walków-Dziewulska Maria Wojciechowska J. Sarzyński 《Journal of Thermal Analysis and Calorimetry》2006,86(2):359-364
Physico-chemical properties of 4-chloro-2-nitrobenzoates of Co(II),
Ni(II), and Cu(II) were studied. The complexes were obtained as mono- and
trihydrates with a metal ion to ligand ratio of 1:2. All analysed 4-chloro-2-nitrobenzoates
are polycrystalline compounds with colours depending on the central ions:
pink for Co(II), green for Ni(II), and blue for Cu(II) complexes. Their thermal
decomposition was studied only in the range of 293–523 K, because it
was found that on heating in air above 523 K 4-chloro-2-nitrobenzoates decompose
explosively. Hydrated complexes lose crystallization water molecules in one
step and anhydrous compounds are formed. The final products of their decomposition
are the oxides of the respective transition metals. From the results it appears
that during dehydration process no transformation of nitro group to nitrite
takes place. The solubilities of analysed complexes in water at 293 K are
of the order of 10–4–10–2
mol dm–3. The magnetic moment values of Co2+,
Ni2+ and Cu2+ ions in
4-chloro-2-nitrobenzoates experimentally determined at 76–303 K change
from 3.89 to 4.82 μB for Co(II) complex, from 2.25
to 2.98 μB for Ni(II) 4-chloro-2-nitrobenzoate,
and from 0.27 to 1.44 μB for Cu(II) complex. 4-chloro-2-nitrobenzoates
of Co(II), and Ni(II) follow the Curie–Weiss law. Complex of Cu(II)
forms dimer. 相似文献
13.
Moamen S. Refat Ahmed Gaber Yusuf S. Althobaiti Hussain Alyami Walaa F. Alsanie Sonam Shakya Abdel Majid A. Adam Mohamed I. Kobeasy Kareem A. Asla 《Molecules (Basel, Switzerland)》2022,27(13)
New Cu(II), Ni(II), Co(II), and Mn(II) complexes of the gabapentin (Gpn) bidentate drug ligand were synthesized and studied using elemental analyses, melting temperatures, molar conductivity, UV–Vis, magnetic measurements, FTIR, and surface morphology (scanning (SEM) and transmission (TEM) electron microscopes).The gabapentin ligand was shown to form monobasic metal:ligand (1:1) stoichiometry complexes with the metal ions Cu(II), Ni(II), Co(II), and Mn(II). Molar conductance measurements in dimethyl-sulfoxide solvent with a concentration of 10−3 M correlated to a non-electrolytic character for all of the produced complexes. A deformed octahedral environment was proposed for all metal complexes. Through the nitrogen atom of the –NH2 group and the oxygen atom of the carboxylate group, the Gpn drug chelated as a bidentate ligand toward the Mn2+, Co2+, Ni2+, and Cu2+ metal ions. This coordination behavior was validated by spectroscopic, magnetic, and electronic spectra using the formulas of the [M(Gpn)(H2O)3(Cl)]·nH2O complexes (where n = 2–6).Transmission electron microscopy was used to examine the nanostructure of the produced gabapentin complexes. Molecular docking was utilized to investigate the comparative interaction between the Gpn drug and its four metal [Cu(II), Ni(II), Co(II), and Mn(II)] complexes as ligands using serotonin (6BQH) and dopamine (6CM4) receptors. AutoDock Vina results were further refined through molecular dynamics simulation, and molecular processes for receptor–ligand interactions were also studied. The B3LYP level of theory and LanL2DZ basis set was used for DFT (density functional theory) studies. The optimized geometries, along with the MEP map and HOMO → LUMO of the metal complexes, were studied. 相似文献
14.
Wiesława Ferenc Beata Bocian J. Sarzyński 《Journal of Thermal Analysis and Calorimetry》2006,84(2):377-383
Four new complexes of 2,3,4-trimethoxybenzoic acid
anion with manganese(II), cobalt(II), nickel(II) and copper(II) cations were
synthesized, analysed and characterized by standard chemical and physical
methods. 2,3,4-Trimethoxybenzoates of Mn(II), Co(II), Ni(II) and Cu(II) are
polycrystalline compounds with colours typical for M(II) ions. The carboxylate
group in the anhydrous complexes of Mn(II), Co(II) and Ni(II) is monodentate
and in that of Cu(II) monohydrate is bidentate bridging one. The anhydrous
complexes of Mn(II), Co(II) and Ni(II) heated in air to 1273 K are stable
up to 505–517 K. Next in the range of 505–1205 K they decompose
to the following oxides: Mn3O4,
CoO, NiO. The complex of Cu(II) is stable up to 390 K, and next in the range
of 390–443 K it loses one molecule of water. The final product of its
decomposition is CuO. The solubility in water at 293 K is of the order of
10–3 mol dm–3
for the Mn(II) complex and 10–4 mol dm–3
for Co(II), Ni(II) and Cu(II) complexes. The magnetic moment values of Mn2+,
Co2+, Ni2+ and Cu2+
ions in 2,3,4-trimethoxybenzoates experimentally determined in the range of
77–300 K change from 5.64–6.57 μB (for Mn2+),
4.73–5.17 μB (for Co2+), 3.26–3.35 μB
(for Ni2+) and 0.27–1.42 μB (for Cu2+).
2,3,4-Trimethoxybenzoates of Mn(II), Co(II) and Ni(II) follow the Curie–Weiss
law, whereas that of Cu(II) forms a dimer. 相似文献
15.
New mixed-ligand complexes with empirical formulae M(4-bpy)L2·1.5H2O (M(II)=Mn, Co), Ni(4-bpy)2L2 and Cu(4-bpy) L2·H2O (where: 4-bpy=4,4'-bipyridine, L=CC L2HCOO-) have been isolated in pure state. The complexes have been characterized by elemental analysis, ir spectroscopy, conductivity
(in methanol, dimethylformamide and dimethylsulfoxide solutions) and magnetic and x-ray diffraction measurements. The Mn(II)
and Co(II) complexes are isostructural. The way of metal-ligand coordinations discussed. the ir spectra suggest that the carboxylate
groups are bonded with metal(II) in the same way (Ni, Cu) or in different way (Mn, Co). The solubility in water is in the
order of 19.40·10-3÷1.88·10-3ł mol dm-3ł. During heating the hydrate complexes lose all water in one step. The anhydrous complexes decompose to oxides via several
intermediate compounds. A coupled TG-MS system was used to analyse the principal volatile products of obtained complexes.
The principal volatile products of thermal decomposition of complexes in air are: H2O2
+, CO2
+, HCl+, Cl2
+, NO+ and other.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
16.
Iu. Shatrava V. Ovchynnikov K. Gubina S. Shishkina O. Shishkin V. Amirkhanov 《Structural chemistry》2016,27(5):1413-1425
A series of new 3d metal complexes based on dimethyl pyridin-2-ylcarbamoylphosphoramidate (HL) was synthesized. The compounds with general formula M(HL)2Cl2·nH2O and M(L)2·nH2O (M=Co2+, Cu2+, Ni2+) were characterized by means of single-crystal X-ray analysis and IR spectroscopy. The organic ligands in all complexes are coordinated via oxygen atom of the carbonyl group and nitrogen atom of the heterocycle. The coordination environment of the central atoms is a distorted octahedron. The axial positions in the Co(II) and Ni(II) complexes with deprotonated ligands are occupied by water molecules. The Co(II) and Cu(II) complexes with phosphoryl ligands in a neutral form have different ligands in the axial positions: in the Co(II) complex, the positions are occupied by two water molecules, whereas in the Cu(II) complex, the positions are occupied by two chlorine anions. The structure of HL was experimentally and theoretically obtained by utilizing single-crystal X-ray analysis and DFT calculations. The computationally optimized geometric parameters for HL show a good agreement with the experimental results. 相似文献
17.
《Journal of Coordination Chemistry》2012,65(3):251-259
Abstract The stepwise complex formation between 2-amino-2-hydroxymethyl-1,3-propanediol (TRIS) with Co(II) and Mn(II) was studied by potentiometry at constant ionic strength 2.0 M (NaClO4) and T = (25.0 ± 0.1)°C, from pH measurements. Data of average ligand number (Bjerrum's function) were obtained from such measurements followed by integration to obtain Leden's function, F 0(L). Graphical treatment and matrix solution of simultaneous equations have shown two overall stability constants of mononuclear stepwise complexes for the Mn(II)/TRIS system (β1 = (5.04 ± 0.02) M?1 and β2 = (5.4 ± 0.5) M?2) and three for the Co(II)/TRIS system (β1 = (1.67 ± 0.02) × 102 M?1, β2 = (7.01 ± 0.05) × 103 M?2 and β3 = (2.4 ± 0.4) × 104 M?3). Slow spontaneous oxidation of Co(II) solutions by dissolved oxygen, accelerated by S(IV), occurs in a buffer solution TRIS/HTRIS+ 0.010/0.030 M, with a synergistic effect of Mn(II). 相似文献
18.
《Journal of Coordination Chemistry》2012,65(13):1099-1123
Heteronuclear complexes containing oxorhenium(V), with Fe(III), Co(II), Ni(II), Cu(II), Cd(II) and UO2(VI) ions were prepared by the reaction of the complex ligands [ReO(HL1)(PPh3)(OH2)Cl]Cl (a) and/or [ReO(H2L2)(PPh3)(OH2)Cl]Cl (b), where H2L1?=?1-(2-hydroxyphenyl)butane-1,3-dione-3-(5,6-diphenyl-1,2,4-triazine-3-ylhydrazone) and H3L2?=?1-(2-hydroxyphenyl)butane-1,3-dione-3-(1H-benzimidazol-2-ylhydrazone), with transition and actinide salts. Heterodinuclear complexes of ReO(V) with Fe(III), Co(II), Ni(II), Cu(II) and Cd(II) were obtained using a 1?:?1 mole ratio of the complex ligand and the metal salt. Heterotrinuclear complexes were obtained containing ReO(V) with UO2(VI) and Cu(II) using 2?:?1 mole ratios of the complex ligand and the metal salts. The complex ligands a and b coordinate with the heterometal ion via a nitrogen of the heterocyclic ring and the nitrogen atom of the C=N7 group. All transition metal cations in the heteronuclear complexes have octahedral configurations, while UO2(VI)?complexes have distorted dodecahedral geometry. The structures of the complexes were elucidated by IR, ESR, electronic and 1H NMR spectra, magnetic moments, conductance and TG-DSC measurements. The antifungal activities of the complex ligands and their heteronuclear complexes towards Alternaria alternata and Aspergillus niger showed comparable behavior with some well-known antibiotics. 相似文献
19.
Copper(II) and cobalt(II) salt complexes with 2,6-dimethyl-3.5-pyridinedicarboxylic acid dihydrazide
E. Yu. Nesterova E. S. Kositsyna L. P. Tsyganok A. B. Vishnikin 《Russian Journal of Inorganic Chemistry》2012,57(3):350-357
Complexes of 2,6-dimethyl-3,5-pyridinedicarboxylic acid dihydrazide (DH) with copper(II) and cobalt(II) nitrates and sulfates
have been studied by IR and UV spectroscopy, DTA, and X-ray crystallography. The complexation results in polynuclear compounds
of the {[M(DH)(ROH)
n
]An
m
}
z
composition (M = Cu2+, Co2+; An = SO42−, NO3−; R = H, i-Pr; n = 0.5–4, m = 1.2, z ≥ 4) containing bidentate DH bridges coordinated to the metal through the carbonyl oxygen atom and the amino group nitrogen
atom of the hydrazide moiety. 相似文献
20.
Using the pulse saturation method the spin-lattice relaxation rate T1−1 for Cu(II) in Zn(II)-bis(diethyl-diselenocarbamate) was measured in the temperature range 1.5 < T < 33 K. From the T-dependence of T1−1 the Debye temperature of the host crystal was obtained. The angular dependence of T1−1 as well as the influence of the hyperfine interaction on T1−1 are discussed. 相似文献