Brownian motion and correlation in particle image velocimetry

In particle image velocimetry applications involving either low velocities or small seed particles, Brownian motion can be significant. This paper addresses the effects of Brownian motion. First, general equations describing cross-correlation particle image velocimetry are derived that include Brownian motion. When light-sheet illumination particle image velocimetry (PIV) is used Brownian motion diminishes the signal strength. A parameter describing this effect is introduced, and a weighting function describing the contribution to the measured velocity as a function of position is derived. The latter is unaffected by Brownian motion. Microscopic PIV Brownian motion also diminishes the signal strength. The weighting function for microscopic PIV is found to depend on Brownian motion, thus affecting an important experimental parameter, the depth of correlation. For both light-sheet illumination and microscopic PIV, a major consequence of Brownian motion is the spreading of the correlation signal peak. Because the magnitude of the spreading is dependent on temperature, PIV can, in principle, be used to simultaneously measure velocity and temperature. The location of the signal peak provides the velocity data, while the spreading of the peak yields temperature.     

Radiation force exerted on nanometer size non-resonant Kerr particle by a tightly focused Gaussian beam

We calculate the radiation force that is exerted by a focused continuous-wave Gaussian beam of wavelength λ on a non-absorbing nonlinear particle of radius a ? 50λ/π. The refractive index of the mechanically-rigid particle is proportional to the incident intensity according to the electro-optic Kerr effect. The force consists of two components representing the contributions of the electromagnetic field gradient and the light scattered by the Kerr particle. The focused intensity distribution is determined using expressions for the six electromagnetic components that are corrected to the fifth order in the numerical aperture (NA) of the focusing objective lens. We found that for particles with a < λ/21.28, the trapping force is dominated by the gradient force and the axial trapping force is symmetric about the geometrical focus. The two contributions are comparable with larger particles and the axial trapping force becomes asymmetric with its zero location displaced away from the focus and towards the beam propagation direction. We study the trapping force behavior versus incident beam power, NA, λ, and relative refractive index between the surrounding liquid and the particle. We also examine the confinement of a Kerr particle that exhibits Brownian motion in a focused beam. Numerical results show that the Kerr effect increases the trapping force strength and significantly improves the confinement of Brownian particles.     

Hot microswimmers

Hot microswimmers are self-propelled Brownian particles that exploit local heating for their directed self-thermophoretic motion. We provide a pedagogical overview of the key physical mechanisms underlying this promising new technology. It covers the hydrodynamics of swimming, thermophoresis and -osmosis, hot Brownian motion, force-free steering, and dedicated experimental and simulation tools to analyze hot Brownian swimmers.     

Multiple light scattering from a moving layer of Brownian particles: comparison with a rigid phase screen

Abstract

The temporal fluctuations in the intensity of light scattered by a moving layer of emulsions and suspensions containing Brownian particles are investigated experimentally, and a comparison is made with light scattered by a translating phase screen. The intensity fluctuations of the scattered light are detected through an imaging system, which collects the light emanating only from a limited volume in the medium. The effect of translational motion of the particle layer on the decay rate of the autocorrelation function of intensity fluctuations depends on the illuminating form of a laser beam and on the point spread function of the imaging system. The Brownian motion of the particles causes the scattered light to fluctuate more rapidly than that arising from the translating phase screen. In the multiple-scattering regime, the influence of this diffusional motion increases with an increase of the particle concentration in the layer.     

Multiple light scattering from a moving layer of Brownian particles: comparison with a rigid phase screen

The temporal fluctuations in the intensity of light scattered by a moving layer of emulsions and suspensions containing Brownian particles are investigated experimentally, and a comparison is made with light scattered by a translating phase screen. The intensity fluctuations of the scattered light are detected through an imaging system, which collects the light emanating only from a limited volume in the medium. The effect of translational motion of the particle layer on the decay rate of the autocorrelation function of intensity fluctuations depends on the illuminating form of a laser beam and on the point spread function of the imaging system. The Brownian motion of the particles causes the scattered light to fluctuate more rapidly than that arising from the translating phase screen. In the multiple-scattering regime, the influence of this diffusional motion increases with an increase of the particle concentration in the layer.     

On aggregate structures in a rod-like haematite particle suspension by means of Brownian dynamics simulations

We have investigated aggregation phenomena in a suspension composed of rod-like haematite particles by means of Brownian dynamics simulations. The magnetic moment of the haematite particles lies normal to the particle axis direction and therefore the present Brownian dynamics method takes into account the spin rotational Brownian motion about the particle axis. We have investigated the influence of the magnetic particle–field and particle–particle interactions, the shear rate and the volumetric fraction of particles on the particle aggregation phenomena. Snapshots of aggregate structures are used for a qualitative discussion and the cluster size distribution, radial distribution function and the orientational correlation functions of the direction of particle axis and magnetic moment are the focus for a quantitative discussion. The significant formation of raft-like clusters is found to occur at a magnetic particle–particle interaction strength much larger than that required for a magnetic spherical particle suspension. This is because the rotational Brownian motion has a significant influence on the formation of clusters in a suspension of rod-like particles with a large aspect ratio. An applied magnetic field enhances the formation of raft-like clusters. A shear flow does not have a significant influence on the internal structure of the clusters, but influences the cluster size distribution of the raft-like clusters.     

Numerical study on trapping and guiding of nanoparticles in a flow using scattering field of laser light

Optical trapping and guiding using laser have been proven to be useful for non-contact and non-invasive manipulation of small objects such as biological cells, organelles within cells, and dielectric particles. We have numerically investigated so far the motion of a Brownian particle suspended in still water under the illumination of a speckle pattern generated by the interference of coherent light scattered by a rough object. In the present study, we investigate numerically the motion of a particle in a water flow under the illumination of a speckle pattern that is at rest or in motion. Trajectory of the particle is simulated in relation with its size, flow velocity, maximum irradiance, and moving velocity of the speckle pattern to confirm the feasibility of the present method for performing optical trapping and guiding of the particle in the flow.     

Influence of the Brownian movement on the motion of nanoand micro-particles in the inhomogeneous optical field

The motion of light scattering particles of the Mie and Rayleigh micro- and nano-range type in the inhomogeneously-polarized optical field, with allowance made for the Brownian movement, is analysed in the paper. The spatial modulation of polarization in the observation plane determines the spatial modulation of the volume energy density. That is why the velocity and the resulting optical force, which cause the motion of the testing particles, change according to the degree of coherence of the interacting fields. The influence of the forces which arise in the viscous medium and cause the Brownian movement upon the mechanisms of manipulating and trapping testing particles by the optical field is studied.     

A direct method of particle sizing based on the statistical processing of scattered photons from particles executing Brownian motion

A direct method of determining the mean diameter of particles executing Brownian motion is presented. The temporal coherence of the scattered field from submicroscopic particles illuminated by laser light is a function of both the integration time and the particle diameter. The temporal degree of coherence of the time-averaged scattered intensity decreases as the integration time increases. Statistical processing of the scattered photons leads to a method of particle sizing (average diameter), which circumvents the need for digital autocor-relation or power spectral estimation.     

On the theory of Brownian motion. I. Interaction between Brownian particles

The molecular theory of the Brownian motion of heavy particles in a homogeneous solvent of light particles is extended to cover the case of interactions between the Brownian particles. This will have physical effects in the concentration dependence of the Brownian particle self-diffusion coefficient. A density expansion for the Brownian particle friction coefficient is derived, and an approximation permitting the first density correction to be calculated is suggested.This work, part of research supported by NSF Grant GP-8497, was done under the tenure of a National Science Foundation Senior Postdoctoral Fellowship, and of a sabbatical leave granted by the University of Oregon.     

Using dynamic low-coherence interferometry to image Brownian motion within highly scattering media

Dynamic low-coherence interferometry was used to measure Brownian motion of submicrometer particles within highly scattering media. Strong rejection of multiply scattered light was obtained by combination of a coherence gate with a confocal microscope, thus allowing particle characterization methods generally reserved for optically dilute materials to be applied to optically concentrated suspensions. The Brownian diffusion coefficient of highly scattering media was determined with an accuracy better than 5%. Furthermore, we show that spatial variations in the Brownian diffusion coefficient can be imaged with an axial resolution determined by the coherence length of the light source (~30 mum) . The experiments also show broadening of the power spectrum as a function of depth into the sample, most likely as a result of detecting multiply scattered light.     

Brownian dynamics simulations with spin Brownian motion on the negative magneto-rheological effect of a rod-like hematite particle suspension

We have investigated the behaviour of a suspension of magnetic rod-like hematite particles in a simple shear flow with the addition of an applied magnetic field. A significant feature of the present hematite particle suspension is the fact that the magnetic moment of the hematite particle lies normal to the particle-axis direction. From simulations, we have attempted to clarify the dependence of the negative magneto-rheological effect on the particle aggregation and orientational distribution of particles. The present Brownian dynamics method has a significant advantage in that it takes into account the spin rotational Brownian motion about the particle axis in addition to the ordinary translational and rotational Brownian motion. The net viscosity is decomposed into three components and discussed at a deeper level and in detail: these three viscosity components arise from (1) the torque due to the magnetic particle–field interaction, (2) the torque and (3) the force due to the interaction between particles. It is found that a slight change in the orientational distribution has a significant influence on the negative magneto-rheological effect. In a relatively dense suspension, the viscosity components arising from an applied magnetic field and the interaction between particles come to change rapidly for a certain strength of the magnetic particle–particle interaction, which is due to the onset of the formation of raft-like clusters.     

Comparison of photonic nanojets key parameters produced by nonspherical microparticles

Photonic nanojet (PNJ) phenomenon arising near transparent dielectric microparticles subject to plane wave illumination in the visible is considered. The near-field light scattering patterns produced by shaped wavelength-sized particles (hexahedron, cuboid, sphere, hemisphere, axicon, assembled particles) are numerically simulated and key PNJ parameters are analyzed. Particle shape influence on the peak intensity and spatial resolution of produced PNJ is investigated. We demonstrate that due to the reciprocal action of spherical-type and conical-type focusing of the special type of composite particles constituted of a hemisphere and an axicon can produce highly localized PNJ with peak intensity considerable higher than that for isolated regular particle (sphere, microaxicon, hemisphere).     

Band formation in mixtures of oppositely charged colloids driven by an ac electric field

We present experiments on pattern formation in a Brownian system of oppositely charged colloids driven by an ac electric field. Using confocal laser scanning microscopy we observe complete segregation of the two particle species into bands perpendicular to a field of sufficient strength when the frequency is in a well-defined range. Because of its Brownian nature the system spontaneously returns to the equilibrium mixture after the field is turned off. We show that band formation is linked to the time scale associated with collisions between particles moving in opposite directions.     

Two particles with bistable coupling on a ratchet

We study the motion of two Brownian particles coupled by a bistable potential on a periodically rocked ratchet. Bistable coupling symmetrizes the two particles and admits a richer dynamics that cannot be found with linear coupling or a single particle. Depending on the coupling strength and the equilibrium distance we find different step patterns and current reversals. We present numerical results and compare them with analytical solutions in limiting cases of adiabatically slow rocking and of rigid coupling.     

Light scattering from colloids

This paper presents a review of light scattering results on static and dynamic properties of ordered colloidal suspensions of charged polystyrene particles and fractal colloidal aggregates. Our studies on static structure factor,S(Q), of ordered monodisperse colloidal suspensions and binary mixtures of particles with different particle diameters, measured by angle-resolved Rayleigh scattering will be discussed. This will include determination of bulk modulus using gravitational compression and observation of colloidal glass (inferred from splitting of the second peak inS(Q)). Dynamic light scattering, with real time analysis of scattered intensity fluctuations, is used to get information about Brownian dynamics of the particles. Recent advances in the field of light scattering from colloidal aggregates which show fractal geometry will also be discussed.     

Physics of colloidal dispersions in nematic liquid crystals

This article reviews the physics of colloidal dispersions in nematic liquid crystals as a novel challenging type of soft matter. We first investigate the nematic environment of one particle with a radial anchoring of the director at its surface. Three possible structures are identified and discussed in detail; the dipole, the Saturn-ring and the surface-ring configuration. Secondly, we address dipolar and quadrupolar two-particle interactions with the help of a phenomenological theory. Thirdly, we calculate the anisotropic Stokes drag of a particle in a nematic environment which determines the Brownian motion of particles via the Stokes–Einstein relation. We then turn our interest towards colloidal dispersions in complex geometries where we identify the dipolar configuration and study its formation. Finally, we demonstrate that surface-induced nematic order above the nematic-isotropic phase transition results in a strongly attractive but short-range two-particle interaction. Its strength can be controlled by temperature and thereby induce flocculation in an otherwise stabilized dispersion.     

Ratchet transport of self-propelled chimeras in an asymmetric periodic structure

We studied the rectified transport of underdamped particles subject to phase lag in an asymmetric periodic structure. When the inertia effect is considered, it is possible to observe reversals of the average velocity with small self-propelled force, whereas particles always move in the positive direction with large self-propelled force. The introduction of phase lag leads particles to follow circular orbits and suppress the polar motion. In addition, this can adjust the direction of particle motion. There exists an optimal value of polar interaction strength at which the rectification is maximal. These results open the way for many application processes, such as spatial sorting of particles mixture and separation based on their physical properties.     

Ratchet motion and current reversal of coupled Brownian motors in pulsating symmetric potentials

In this study, we investigate the collective directed transport of coupled Brownian particles in spatially symmetric periodic potentials under time-periodic pulsating modulations. We find that the coupling between two particles can induce symmetry breaking and consequently collective directed motion. Moreover, the direction of motion can be reversed under certain conditions. The dependence of directed current on various parameters is systematically studied. reverse motion can be achieved by modulating the coupling free length and the phase shift of the pulsating potential. The dynamical mechanism of these transport properties is understood in terms of the effective-potential theory and the space-time transformation invariance. The directed transport of coupled Brownian motors can be manipulated and optimized by adjusting the coupling strength, pulsating frequency, or noise intensity.     

Spherical particle Brownian motion in viscous medium as non-Markovian random process

The Brownian motion of a spherical particle in an infinite medium is described by the conventional methods and integral transforms considering the entrainment of surrounding particles of the medium by the Brownian particle. It is demonstrated that fluctuations of the Brownian particle velocity represent a non-Markovian random process. The features of Brownian motion in short time intervals and in small displacements are considered.