首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 31 毫秒
1.
《Physics letters. A》2020,384(10):126215
Inspired by recent experiments on the successful synthesis of hydrofullerene C66H4 in Tian et al. (2019) [12] with two negatively curved heptagons. Based on the density functional theory and nonequilibrium Green's function method, we report the spin-dependent transport through transition-metal-atom-encapsulated C66H4 hydrofullerene, i.e., X@C66H4(X=Fe, Co, Mn, Ni), contacted by single gold atoms via semi-infinite non-magnetic Au electrodes. It is found that, Mn- and Fe-doped systems show highly spin-polarized transmission as well as considerable magnetic moments whereas Ni-doped systems show completely spin-unpolarized transmission and nonmagnetic. Interestingly, Co-doped systems show two spin states, i.e., spin-polarized and spin-unpolarized ones. Further analysis shows that, for Mn-, Fe- and Ni-doped systems, the spin-polarized/unpolarized state is caused by the finite/(nearly-)zero magnetism of the encapsulated metal atom. While the magnetism in Co-doped systems is quenched for the top hexagonal doping case, but not for the side heptagonal doping one, which induces the spin-unpolarized/spin-polarized state. And the screening effect of electrodes on the magnetism of Co is the underlying physical mechanism. Our findings would be beneficial to the design of spintronics devices.  相似文献   

2.
We have studied the development of metastable properties associated with a nearly spin-degenerate two-dimensional electron system. Application of large hydrostatic pressure significantly reduces the g-factor experienced by electrons in GaAs/AlGaAs heterostructure, and various fractional quantum Hall effect (FQHE) states are found to undergo transition to a spin-unpolarized ground state. In case of even numerator FQHE states, the spin transitions are accompanied by hysteresis and nonlinearity in the magnetotransport. These results strongly support a recent theory of quantum Hall magnetism in which competition between spin-polarized and spin-unpolarized ground states leads to an ordered phase that exhibits ferromagnetic correlation.  相似文献   

3.
We investigate the spin-dependent effective electron-electron interactions in a uniform system of two-dimensional electrons to understand the spontaneous magnetization expected to occur at very low density. For this purpose, we adopt the Kukkonen-Overhauser form for the effective interactions which are built by accurately determined local-field factors describing the charge and spin fluctuations. The critical behavior of the effective interaction for parallel spin electrons allows us to quantitatively locate the transition to the ferromagnetic state at rs≈27. When the finite width effects are approximately taken into account the transition occurs at rs≈30 in agreement with recent quantum Monte Carlo calculations.  相似文献   

4.
Ferromagnetic ordering of silver impurities in the AlN semiconductor is predicted by plane-wave ultrasoft pseudopotential and spin-polarized calculations based on density functional theory (DFT). It was found that an Ag impurity atom led to a ferromagnetic ground state in Ag0.0625Al0.9375N, with a net magnetic moment of 1.95 μB per supercell. The nitrogen neighbors at the basal plane in the AgN4 tetrahedron are found to be the main contributors to the magnetization. This magnetic behavior is different from the ones previously reported on transition metal (TM) based dilute magnetic semiconductor (DMS), where the magnetic moment of the TM atom impurity is higher than those of the anions bonded to it. The calculated electronic structure band reveals that the Ag-doped AlN is p-type ferromagnetic semiconductor with a spin-polarized impurity band in the AlN band gap. In addition, the calculated density of states reveals that the ferromagnetic ground state originates from the strong hybridization between 4d-Ag and 2p-N states. This study shows that 4d transition metals such as silver may also be considered as candidates for ferromagnetic dopants in semiconductors.  相似文献   

5.
Thermally excited states of the three-dimensional electron gas in a neutralizing background are computed by path integral Monte Carlo simulation for values of the Wigner-Seitz radius within the interval 5 < r s < 15. Coulomb and exchange interactions, permutation symmetry, and spin state are treated explicitly. Variation of electron correlation functions with density and temperature is analyzed. Quantum effects suppress and enhance spatial correlation at low and high densities, respectively. Transition between the electron-gas states characterized by these opposite trends corresponds to a density of approximately 2.5 × 1021 cm?3. A transition line between liquid-like and gaslike phases is determined in the temperature-density diagram. Weak anisotropy of many-body correlations in the liquid-like state stimulates excitation of spherically symmetric collective rotational modes. The effective short-range pseudopotential exhibits strong temperature dependence due to exchange effects. For strongly correlated systems, the characteristic screening length deviates from that predicted by the Thomas-Fermi screening model ( $ \sim \sqrt {r_s } $ ), approaching a linear function of r s. The effective short-range interaction substantially differs from the Yukawa potential in mean field theory. Coulomb interaction shifts the Fermi level up by an order of magnitude or higher, and this effect becomes stronger with decreasing density.  相似文献   

6.
We have generalised our earlier work calculating the induced density of states in alkali chemisorption to include the valence np level in addition to the s level. This allows the theory to take account of the possibility of sp hybridization. Hybridization is said to be weak is the sp level separation ΔEsP exceeds twice the width of the s or pz resonance. In the converse case hybridization is strong and the induced density of states no longer reflects distinguishable s and pz resonances. We argue that ΔEsP for the chemisorbed alkali exceeds considerably that for the free alkali atom. In the case of Na on rs = 2 jellium (considered typical of the smaller alkali on rs = 2?3 substrates) hybridization is strong for the atomic value of ΔEsp but weak when a somewhat larger value is taken, making the conclusions a little indefinite. For Cs on Cu(111), we find a clear situation of weak hybridization with the atomic ΔEsP and a fortiori with a more realistic value. There should thus be a well defined 6s resonance in this system. Our estimate of the width of the 6s resonance is in good agreement with photoemission data.  相似文献   

7.
In the compound MnBi, a first-order transition from the paramagnetic to the ferromagnetic state can be triggered by an applied magnetic field and the Curie temperature increases nearly linearly with an increase in magnetic field by ∼2 K/T. Under a field of 10 T, TC increases by 20 and 22 K during heating and cooling, respectively. Under certain conditions a reversible magnetic field or temperature induced transition between the paramagnetic and ferromagnetic states can occur. A magnetic and crystallographic H-T phase diagram for MnBi is given. Magnetic properties of MnBi compound aligned in a Bi matrix have been investigated. In the low temperature phase MnBi, a spin-reorientation takes place during which the magnetic moments rotate from being parallel to the c-axis towards the basal plane at ∼90 K. A measuring Dc magnetic field applied parallel to the c-axis of MnBi suppresses partly the spin-reorientation transition. Interestingly, the fabricated magnetic field increases the temperature of spin-reorientation transition Ts and the change in magnetization for MnBi. For the sample solidified under 0.5 T, the change in magnetization is ∼70% and Ts is ∼91 K.  相似文献   

8.
The correlation energy and the Fermi momentum of an electron gas in 2-D are evaluated explicitly as functions of density. The ring diagram and first- and second-order exchange contributions are treated. In comparison with the 3-D case, the kinetic energy for the same rs is approximately one-half and the exchange and correlation energies are somewhat larger. The ground state energy plotted against rs shows a minimum at around rs = 1.65 with a minimum value of ?0.9858 Ryd. If the third-order ring contribution is added, the curve is shifted upward. The correlation energy is ?0.6258 to order e4. The third-order ringw contribution increases this value almost linearly with rs. The Fermi momentum decreases with rs due to the contribution. Different from the 3-D case, no ln rs term appears in the correlation energy within the approximation.  相似文献   

9.
We studied, strongly correlated states in triangular artificial atoms. Symmetry-driven orbital degeneracy of the single particle states can give rise to an SU(4) Kondo state with entangled orbital and spin degrees of freedom, and a characteristic phase shift δ=π/4. Upon application of a Zeeman field, a purely orbital Kondo state is formed with somewhat smaller Kondo temperature and a fully polarized current through the device. The Kondo temperatures are in the measurable range. The triangular atom also provides a tool to systematically study the singlet-triplet transitions observed in recent experiments [Phys. Rev. Lett., 88 (2002) 126803, cond-mat/0208268 (2002)].  相似文献   

10.
We report on the dramatic evolution of the quantum Hall ferromagnet in the fractional quantum Hall regime at nu=2/5 filling. A large enhancement in the characteristic time scale gives rise to a dynamical transition into a novel quantized Hall state. The observed Hall state is determined to be a zero-temperature phase distinct from the spin-polarized and spin-unpolarized nu=2/5 fractional quantum Hall states. It is characterized by a strong temperature dependence and puzzling correlation between temperature and time.  相似文献   

11.
On the basis of the relaxation mode theory, quasi-Debye response in the dynamic conductivity by hopping ions is theoretically investigated in three-dimensional random lattices with a uniform distribution of activation energies. It is shown at lowest frequencies that the dynamic conductivity is approximately given by σ(ω)∼σ(0)+Aωs, s″=2−n, where n is a non-integer exponent originated from the mode diffusion length and density of states. The numerical analyses give rise to some values of s″<2, for example s″∼1.5, which behaves as s″→2 with increasing temperature.  相似文献   

12.
The ground state of a three-dimensional electron gas is theoretically investigated within the framework of the local spin density approximation with the Perdew–Zunger exchange-correlation energy. The system has been found to be in a one- or two-dimensional crystal state, when the Wigner sphere radius rs has an intermediate value. At rs=60, a triangular lattice with the lattice spacing 96.10 is the lowest energy state among fluids, 1D, 2D, and 3D crystals.  相似文献   

13.
14.
Using spin density functional theory within the framework of the local spin density approximation with Perdew-Zunger type exchange-correlation energy, ferromagnetism in a quasi-two-dimensional electron gas (Q-2DEG) is studied. The electronic and magnetic structures of a thin film are calculated as a function of film thickness and electron density. Ferromagnetism in the Q-2DEG is found to appear at a higher electron density than in the three-dimensional electron gas. Unless a film is very thin, with decreasing electron density, a magnetic phase transition occurs from a spin-unpolarized fluid to a Wigner film with surface magnetism, in which the spin polarization localizes only in the neighborhood of surfaces. Further decreasing density induces another transition to a fully spin-polarized ferromagnetic Wigner film.  相似文献   

15.
A rearrangement of the ground state of a Wannier-Mott exciton upon an increase in its momentum is considered. The phase diagram of the electron and the hole experiencing the Coulomb interaction on the magnetic momentum-external magnetic field plane is investigated. A jumplike exciton-magnetoexciton “phase” transition is observed upon an increase in the momentum in fields B weaker than a certain value B<B tr1. As momentum P increases above a certain critical value P tr(B), the ground state of the system changes from the hydrogen-like state polarized by the Lorentz force to the magnetoexciton state in which the average distance 〈 r〉 between the electron and the hole increases jumpwise in the transverse direction relative to the field. As the exciton momentum increases, its wave function is extended along the magnetic field, acquiring the shape of a strongly prolate ellipsoid. It is interesting that the momentum of the transition tends to a finite value P 0>0 even for B→0. At the point of transition, the exciton energy-momentum relation changes jumpwise from a quadratic law to a relation virtually independent of the momentum. For B<B tr1, the exciton-magnetoexciton transition becomes blurred.  相似文献   

16.
The liquid-vapor interface of a confined fluid at the condensation phase transition is studied in a combined hydrostatic/mean-field limit of classical statistical mechanics. Rigorous and numerical results are presented. The limit accounts for strongly repulsive short-range forces in terms of local thermodynamics. Weak attractive longer-range ones, like gravitational or van der Waals forces, contribute a self-consistent mean potential. Although the limit is fluctuationfree, the interface is not a sharp Gibbs interface, but its structure is resolved over the range of the attractive potential. For a fluid of hard balls with –r –6 interactions the traditional condensation phase transition with critical point is exhibited in the grand ensemble: A vapor state coexists with a liquid state. Both states are quasiuniform well inside the container, but wall-induced inhomogeneities show up close to the boundary of the container. The condensation phase transition of the grand ensemble bridges a region of negative total compressibility in the canonical ensemble which contains canonically stable proper liquid-vapor interface solutions. Embedded in this region is a new, strictly canonical phase transition between a quasiuniform vapor state and a small droplet with extended vapor atmosphere. This canonical transition, in turn, bridges a region of negative total specific heat in the microanonical ensemble. That region contains subcooled vapor states as well as superheated very small droplets which are microcanonically stable.  相似文献   

17.
A new theory of the ground state energy of a two-dimensional electron fluid is presented. It is shown that the ring diagram contribution changes its analytical behavior atr s =21/2, wherer s is the usual density parameter defined by rS = 1/a 0(π n)1/2,a 0 being the Bohr radius andn is the electron density. For smallr s , a high density series is obtained in agreement with the previous calculation. For larger s , a hitherto unknown low density series is obtained. In the low density region, the first order exchange energy is completely cancelled out by a term from the ring contribution so that the ground state energy decreases in proportion tor s ?2/3 , followed byr s /?4/3 and higher order terms. The energy is found to be minimum atr s=1.4757, the minimum value being ?0.481915 Rydbergs.  相似文献   

18.
Due to electron deficiency, the graphene-like honeycomb structure of boron is unstable. By introducing Fe atoms, it is reported that FeB2 monolayer has excellent dynamic and thermal stabilities at room temperature. Based on first-principles calculations, the spin-dependent transport of zigzag FeB2 nanoribbons (ZFeB2NRs) under ferromagnetic state (FM) is investigated. It is found that, around the Fermi level, FeB-terminated (or FeFe-terminated) ZFeB2NRs exhibit completely spin-polarized (or spin-unpolarized) transmission, and BB-terminated configurations exhibit completely unpolarized or partially polarized transmission. Further analysis shows that, the hinge dihedral angle has a switching effect on the transport channels, and the spin polarization of the transmission is determined by the symmetry of the distribution of hinge dihedral angles along the transverse direction of the ribbon, where symmetric/asymmetric distribution induces spin-unpolarized/polarized transmission. Moreover, such a symmetry effect is found to be robust to the width of the ribbon, showing great application potential. Our findings may throw light on the development of B-based spintronic devices.  相似文献   

19.
The ground state energy and the correlation energy of an electron gas are evaluated rigorously without using the smallr s expansion and the small momentum-transfer approximation in the ring diagram contribution and taking into consideration the first order and second order exchange graphs. The Fermi momentum is determined by solving the number density equation without using iteration and is compared with that obtained by iteration. The ground state energy is found to stay positive in contrast to the iterative solution which becomes negative beyond a certain value ofr s .  相似文献   

20.
We present an analytic theory of the pair distribution function and the ground-state energy in a two-dimensional (2D) electron gas with an arbitrary degree of spin polarization. Our approach involves the solution of a zero-energy scattering Schrödinger equation with an effective potential which includes a Fermi term from exchange and kinetic energy and a Bose-like term from Jastrow-Feenberg correlations. The form of the latter is assessed from an analysis of data on a 2D gas of charged bosons. We obtain excellent agreement with data from quantum Monte Carlo studies of the 2D electron gas. In particular, our results for the correlation energy show a quantum phase transition occurring at coupling strength rs≈24 from the paramagnetic to the fully spin-polarized fluid.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号