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1.
本文讨论了SO5 SU2 SU2 U1 U1及SO5 U1 U1的VCS表示.计算了SO5 U2 U2的约化矩阵元,并利用K矩阵技术确定了SO5权的多重度. 相似文献
2.
The infrared spectra of the 2ν1, 2ν2 and 2ν3 overtones of perchloryl fluoride, FClO3, have been recorded at high resolution using monoisotopic pure samples. Four symmetric top species have been investigated: F35Cl16O3, F37Cl16O3, F35Cl18O3 and F37Cl18O3. The vi = 2, i = 1, 2, 3 vibrationally excited states are totally symmetric, so these overtones correspond to parallel bands of medium/weak intensity, centered from 2010 to 2120 cm−1 (2ν1), from 1390 to 1430 cm−1 (2ν2) and from 1070 to 1100 cm−1 (2ν3). Most of the bands are unperturbed and their analysis was straightforward. The band origins, the rotational and centrifugal molecular constants in the v1 = 2, v2 = 2 and v3 = 2 states have been determined, with standard deviations of the fits from 0.00024 to 0.00067 cm−1. The 2ν1 overtones of F35Cl16O3 and F37Cl16O3 are perturbed by an A1/E Coriolis resonance between the v1 = 2 state and one E component of the v4 = 1, v6 = 2 manifold. The 2ν2 of F37Cl18O3 is perturbed by the same kind of interaction involving the v1 = v6 = 1 (E) state, at about 1396 cm−1. In these bands the resonance is localized on rotational levels with specific J and K values. As a consequence, a few transitions of the perpendicular bands involving the interacting levels could be identified in the spectra. A simultaneous fit of the transitions assigned to the dyads has been performed and the parameters of the excited states have been determined, including the high order Coriolis interaction coefficient . The anharmonic constants x11, x22, x33 of all the studied isotopologues of FClO3, x46 of F35Cl16O3, x46 + g46 of F37Cl16O3 and x16 of F37Cl18O3, have been derived. 相似文献
3.
O.N Ulenikov O.L Petrunina E.S Bekhtereva E.A Sinitsin H BürgerW Jerzembeck 《Journal of Molecular Spectroscopy》2002,215(1):85-92
For the first time the infrared spectrum of PHD2 was recorded in the region of the PH stretching fundamental ν1 at 2324.005 cm−1 and the overtone 2ν1 at 4563.634 cm−1 with a resolution of 4.2×10−3 cm−1 and 8.8×10−3 cm−1, respectively. In the analyses about 1340 and 1020 transitions were assigned to the corresponding ν1 and 2ν1 bands, which provided 316 and 248 upper energies, respectively. Since both the bands are sufficiently isolated, a standard Watson-type Hamiltonian (A-reduction, Ir-representation) was employed. The obtained sets of spectroscopic parameters correlate very well both with each other, and with the corresponding parameters of the ground vibrational state. 相似文献
4.
The ν1 fundamental band of the ClO2 radical has been studied by means of the 10.6-μm CO2 and N2O laser Stark spectroscopy. More than 250 and 150 Stark resonances were assigned for the 35ClO2 and 37ClO2 species, respectively, and were analyzed together with the recent microwave and laser-microwave double resonance results to give molecular constants including spin-rotation interaction constants. The ν1 band origins and electric dipole moments both in the ground and ν1 states were determined accurately
35ClO2 | 37ClO2 | |||||
945.592 357(60) | 939.602 909(66) | cm?1 | ||||
μ′ | 1.788 39(13) | 1.788 46(15) | D | |||
μ″ | 1.791 95(10) | 1.792 10(13) | D | |||
δμ | ?0.003 56(18) | ?0.003 64(26) | D |
Band | B | C | ||
3533.1 | 27.0 | — | — | |
10145.79 | 22.6713 | 0.368426 | 0.361722 |
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