共查询到20条相似文献,搜索用时 15 毫秒
1.
A new scheme for the detection of double resonance spectra of chemical intermediates involves negligible population transfer but the detection of electric field-induced energy shifts in unpopulated levels. 相似文献
2.
Chaudhuri C Chang RY Chen WX Fang WC Cheng JP Whang TJ Tsai CC 《The journal of physical chemistry. A》2007,111(39):9764-9768
The 71Pig Rydberg state of Na2 correlating with the separated atom limit Na(3s) + Na(5p) has been observed using high-resolution cw optical-optical double resonance spectroscopy. A total of 104 identified rovibrational levels in the range v = 0-12 and 11 = J = 44 have been assigned to the 71Pig state. Dunham coefficients were determined, and the Rydberg-Klein-Rees potential curve in the range of R = 2.99-4.66 A was derived for the 71Pig state using the observed quantum levels. The important molecular properties are the potential minimum Te = 36 633.00(23) cm-1 at Re = 3.6313(29) A, omegae = 115.75(13) cm-1, and Be = 0.111 22(17) cm-1. A detailed discussion of this investigation of the 71Pig state is provided. 相似文献
3.
《Chemical physics letters》1985,122(6):612-616
Absorption and fluorescence excitation spectra of I2 have been recorded in the region 1100–2100 Å using synchrotron radiation. The strongest fluorescence is excited in the region 1730–2000 Å and is associated with the D(0u+) ion-pair state: fluorescence in the region 1320–1500 Å is assigned in part to excited atoms formed by predissociation of Rydberg states. 相似文献
4.
Absorption transients at 254 nm have been observed in O3-O2 mixtures following laser irradiation at 9.64 μm. From analysis of these transients, we are able to determine vibrational relaxation rate constants (O3-O2 λ1?1/[O2] = (2560±370) Torr?1 S?1, λ2?1/[O2] = (640±50) Torr?1 S?1, and also a v1-v3 equilibration rate constant (O3-O3) of (1.5±1.0) × 106 Torr?1 S?1. 相似文献
5.
The first order rate coefficient for the thermal decomposition of oxetane and oxetane-d2 has been investigated at two temperatures as a function of pressure. Gas phase collisional relaxation results are obtained by using RRKM theory and various energy tranfer probability models.
-d2 . , RRKM .相似文献
6.
U. Buck Ch. Lauenstein R. Sroka M. Tolle 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1988,10(2-3):303-309
Carbon dioxide clusters are generated in a supersonic molecular beam and size selected by scattering from a He beam. By analyzing the measured time-of-flight spectra as a function of the deflection angle, differential energy loss spectra for (CO2)2 — He are obtained which show a rotational rainbow structure with a maximal energy transfer of ΔE/E=0.4. This result is compatible with the slipped parallel structure of dimer but not with theT-shaped geometry. The scattering analysis is also used to derive information about the pressure dependence of cluster formation and the fragmentation by electron impact ionisation. The latter process leads preferably to the monomer product ion CO 2 + with a small but finite probability for other ionic channels. 相似文献
7.
The pressure dependence of the unimolecular rate constants for the thermal decomposition of 2-methyloxetane and 3-methyloxetane has been studied. The average energy transferred downward in gas-gas collision was determined by the application of RRKM theory and a stepladder model of energy transfer.
2- 3-. , - , .相似文献
8.
An optical-optical double resonance sub-Doppler experiment is used to measure short nonradiative lifetimes in the C (1)Sigma(+) state of LiH. These lifetimes are expected to result from the strong electronic interaction between the C (1)Sigma(+) state and the continuum of the A (1)Sigma(+) state and to vary with the vibrational quantum number, from nanoseconds to milliseconds. The experimental setup combines a molecular beam of LiH, a first cw laser beam locked to a given A-X absorption line, and a second cw laser beam scanned over C-A absorption profiles. Analysis of these absorption profiles in terms of Voigt profiles shows that their Lorentzian components significantly vary with the vibrational quantum numbers of the C state. Nonradiative decay rates deduced this way are systematically larger than the calculated ones but their variations are similar. Coherent saturation effects cannot be invoked to explain this discrepancy. 相似文献
9.
We report the observation of the rotationally resolved spectrum of the c1A1 state of CH2 via sequential single-photon absorptions at visible and near-infrared wavelengths. Direct absorption from the lowest singlet state a1A1 to c1A1 occurs in the near UV, but it is weak because it corresponds to a two electron transition between the dominant single configuration approximations to the electronic wave functions. Some absorption lines in the c-a system were originally reported in 1966 [G. Herzberg and J. W. C. Johns, Proc. R. Soc. London, Ser. A 295, 107 (1966)], but the weak spectra could not be assigned at the time. Interest in the c1A(1) state was rekindled by recent ab initio results [S. N. Yurchenko, P. Jensen, Y. Li, R. J. Buenker, and P. R. Bunker, J. Mol. Spectrosc. 208, 136 (2001)] which prompted the present work. The new spectra provide accurate energies for rotational levels in the v2linear =11,l = 1 level of the state, and permit assignment of most of the line positions measured by Herzberg and Johns. The double-resonance technique used may be easily extended to the measurement of lower rovibrational levels in the electronic state and possibly also to access the d1A2 state which is theoretically expected to lie at similar energies but, for symmetry reasons, is not accessible from the lowest singlet state in a single electric-dipole transition. 相似文献
10.
11.
The B1A1 state of SiH2 and SiD2 was observed by the optical-optical double resonance technique for the first time. The electronic band origin of the B state of SiD2 was determined to be 27 214.11 cm(-1). A very clear exclusive behavior depending on the even/odd value of the bending vibrational quantum number was observed in the spectra, representing a quasilinear behavior of the B state. The barrier height to linearity was estimated to be approximately 125 cm(-1) by the quasilinear analysis of the bending vibrational level structure of SiD2. 相似文献
12.
Markovitsi D Onidas D Gustavsson T Talbot F Lazzarotto E 《Journal of the American Chemical Society》2005,127(49):17130-17131
Absorption of UV radiation by DNA bases is known to induce carcinogenic mutations. The lesion distribution depends on the sequence around the hotspots, suggesting cooperativity between bases. Here we show that such cooperativity may intervene at the very first step of a cascade of events by formation of Franck-Condon states delocalized over several bases and subsequent energy transfer faster than 100 fs. Our study focuses on the double helix poly(dA).poly(dT), whose fluorescence, induced by femtosecond pulses at 267 nm, is probed by the upconversion technique and time-correlated single photon counting, over a large time domain (100 fs to 100 ns). The time-resolved fluorescence decays and fluorescence anisotropy decays are discussed in relation with the steady-state absorption and fluorescence spectra in the frame of exciton theory. 相似文献
13.
Molecular beam cooled HCl was state selected by two-photon excitation of the V (1) summation operator(0(+)) [v=9,11-13,15], E (1) summation operator(0(+)) [v=0], and g (3) summation operator(-)(0(+)) [v=0] states through either the Q(0) or Q(1) lines of the respective (1,3) summation operator(0(+))<--<--X (1) summation operator(0(+)) transition. Similarly, HBr was excited to the V (1) summation operator(0(+)) [v=m+3, m+5-m+8], E (1) summation operator(0(+)) [v=0], and H (1) summation operator(0(+)) [v=0] states through the Q(0) or Q(1) lines. Following absorption of a third photon, protons were formed by three different mechanisms and detected using velocity map imaging. (1) H(*)(n=2) was formed in coincidence with (2)P(i) halogen atoms and subsequently ionized. For HCl, photodissociation into H(*)(n=2)+Cl((2)P(12)) was dominant over the formation of Cl((2)P(32)) and was attributed to parallel excitation of the repulsive [(2) (2)Pi4llambda] superexcited (Omega=0) states. For HBr, the Br((2)P(32))Br((2)P(12)) ratio decreases with increasing excitation energy. This indicates that both the [(3) (2)Pi(12)5llambda] and the [B (2) summation operator5llambda] superexcited (Omega=0) states contribute to the formation of H(*)(n=2). (2) For selected intermediate states HCl was found to dissociate into the H(+)+Cl(-) ion pair with over 20% relative yield. A mechanism is proposed by which a bound [A (2) summation operatornlsigma] (1) summation operator(0(+)) superexcited state acts as a gateway state to dissociation into the ion pair. (3) For all intermediate states, protons were formed by dissociation of HX(+)[v(+)] following a parallel, DeltaOmega=0, excitation. The quantum yield for the dissociation process was obtained using previously reported photoionization efficiency data and was found to peak at v(+)=6-7 for HCl and v(+)=12 for HBr. This is consistent with excitation of the repulsive A(2) summation operator(12) and (2) (2)Pi states of HCl(+), and the (3) (2)Pi state of HBr(+). Rotational alignment of the Omega=0(+) intermediate states is evident from the angular distribution of the excited H(*)(n=2) photofragments. This effect has been observed previously and was used here to verify the reliability of the measured spatial anisotropy parameters. 相似文献
14.
Mondal SK Ghosh S Sahu K Mandal U Bhattacharyya K 《The Journal of chemical physics》2006,125(22):224710
Fluorescence resonance energy transfer (FRET) from coumarin 480 (C480) to fluorescein 548 (F548) in a sodium dioctyl sulfosuccinate (AOT) reverse micelle is studied by picosecond and femtosecond emission spectroscopy. In bulk water, at the low concentration of the donor (C480) and the acceptor (F548), no FRET is observed. However, when the donor (C480) and the acceptor (F548) are confined in a AOT reverse micelle very fast FRET is observed. The time constants of FRET were obtained from the rise time of the emission of the acceptor (F548). In a AOT microemulsion, FRET is found to occur in multiple time scales--3, 200, and 2700 ps. The 3 ps component is assigned to FRET in the water pool of the reverse micelle with a donor-acceptor distance, 16 A. The 200 ps component corresponds to a donor-acceptor distance of 30 A and is ascribed to the negatively charged acceptor inside the water pool and the neutral donor inside the alkyl chains of AOT. The very long 2700 ps component may arise due to FRET from a donor outside the micelle to an acceptor inside the water pool and also from diffusion of the donor from bulk heptane to the reverse micelle. With increase in the excitation wavelength from 375 to 405 nm the relative contribution of the FRET due to C480 in the AOT reverse micelle (the 3 and 200 ps components) increases. 相似文献
15.
Marcus theory of electron transfer (ET) and Fo?rster theory of excitation energy transfer (EET) rely on the Condon approximation and the theoretical availability of initial and final states of ET and EET reactions, often called diabatic states. Recently [Subotnik et al., J. Chem. Phys. 130, 234102 (2009)], diabatic states for practical calculations of ET and EET reactions were defined in terms of their interactions with the surrounding environment. However, from a purely theoretical standpoint, the definition of diabatic states must arise from the minimization of the dynamic couplings between the trial diabatic states. In this work, we show that if the Condon approximation is valid, then a minimization of the derived dynamic couplings leads to corresponding diabatic states for ET reactions taking place in solution by diagonalization of the dipole moment matrix, which is equivalent to a Boys localization algorithm; while for EET reactions in solution, diabatic states are found through the Edmiston-Ruedenberg localization algorithm. In the derivation, we find interesting expressions for the environmental contribution to the dynamic coupling of the adiabatic states in condensed-phase processes. In one of the cases considered, we find that such a contribution is trivially evaluable as a scalar product of the transition dipole moment with a quantity directly derivable from the geometry arrangement of the nuclei in the molecular environment. Possibly, this has applications in the evaluation of dynamic couplings for large scale simulations. 相似文献
16.
To clarify whether the excitation energy transfer from a donor molecule or aggregate to a remote acceptor molecule or aggregate can be caused by nonadiabatic interaction as expected in our previous studies 4 ; 5 , we carried out ab initio calculations for three donor–acceptor systems. Even when the acceptor is separated from the donor by 15 Å, it was found that nonadiabatic coupling elements have moderately large values in the nuclear configuration region where the potential energy surfaces at two excited states for the donor–acceptor system are close to each other; otherwise, the conical intersection between the two excited‐state potential energy surfaces appears. In addition, it was found that the adiabatic approximation for the donor–acceptor system holds in the nuclear configuration region in which the initial and final wave packets in the process of the excitation energy transfer lie. These findings lead to the conclusion that the excitation energy transfer between two remote molecules or aggregates can be caused by the nonadiabatic interaction. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem 94: 36–43, 2003 相似文献
17.
A simplified approach for computing the electronic coupling of nonradiative excitation-energy transfer is proposed by following Scholes et al.’s construction on the initial and final states [G.D. Scholes, R.D. Harcourt, K.P. Ghiggino, J. Chem. Phys. 102 (1995) 9574]. The simplification is realized through defining a set of orthogonalized localized MOs, which include the polarization effect of the charge densities. The method allows calculating the coupling of both the singlet-to-singlet and triplet-to-triplet energy transfer. Numerical tests are performed for a few of dimers with different intermolecular orientations, and the results demonstrate that Coulomb term are the major contribution to the coupling of singlet-to-singlet energy transfer whereas in the case of triplet-to-triplet energy transfer, the dominant effect is arisen from the intermolecular charge-transfer states. The present application is on the Hartree-Fock level. However, the correlated wavefunctions which are normally expanded in terms of the determinant wavefunctions can be employed in the similar way. 相似文献
18.
M. L. Strekalov 《Journal of mathematical chemistry》2013,51(1):108-116
Collisional energy transfer between highly vibrationally excited molecules and bath gas is considered with a statistical kernel, describing energy exchange in complex-forming collisions. Knowledge of the bilinear formula for the Laguerre polynomials offers a means for determining eigenvalues and eigenfunctions of the kernel. An exact solution to master equation for the conditional probability is given as an expansion in terms of these eigenfunctions. The bulk averages of internal energy moments and energy transfer moments are calculated analytically. 相似文献
19.
Collision-induced state-to-state molecular energy transfer between rovibrational states in the 12,700 cm(-1) 4nu(CH) manifold of the electronic ground state X of acetylene (C(2)H(2)) is monitored by time-resolved infrared-ultraviolet double resonance (IR-UV DR) spectroscopy. Rotational J-states associated with the (nu(1) + 3nu(3)) or (1 0 3 0 0)(0) vibrational combination level, initially prepared by an IR pulse, are probed at approximately 299, approximately 296, or approximately 323 nm with UV laser-induced fluorescence via the Alpha electronic state. The rovibrational J-states of interest belong to a congested manifold that is affected by anharmonic, l-resonance, and Coriolis couplings, yielding complex intramolecular dynamics. Consequently, collision-induced rovibrational satellites observed by IR-UV DR comprise not only regular even-DeltaJ features but also supposedly forbidden odd-DeltaJ features. A preceding paper (J. Phys. Chem. A 2003, 107, 10759) focused on low-J-value rovibrational levels of the 4nu(CH) manifold (particularly those with J = 0 and J = 1) whereas this paper examines locally perturbed states at higher values of J (particularly J = 17 and 18, which display anomalous doublet structure in IR-absorption spectra). Three complementary forms of IR-UV DR experiments (IR-scanned, UV-scanned, and kinetic) are used to address the extent to which intramolecular perturbations influence the efficiency of J-resolved collision-induced energy transfer with both even and odd DeltaJ. 相似文献
20.
Excitation energy transfer (EET) is a process where the electronically excitation is transferred from a donor to an acceptor. EET is widely seen in both natural and in artificial systems, such as light‐harvesting in photosynthesis, the fluorescence resonance energy transfer technique, and the design of light‐emitting molecular devices. In this work, we outline the theories describing both singlet and triplet EET (SEET and TEET) rates, with a focus on the physical nature and computational methods for the electronic coupling factor, an important parameter in predicting EET rates. The SEET coupling is dominated by the Coulomb coupling, and the remaining short‐range coupling is very similar to the TEET coupling. The magnitude of the Coulomb coupling in SEET can vary much, but the contribution of short‐range coupling has been found to be similar across different excited states in naphthalene. The exchange coupling has been believed to be the major physical contribution to the short‐range coupling, but it has been pointed out that other contribution, such as the orbital overlap effect is similar or even larger in strength. The computational aspects and the subsequent physical implication for both SEET and TEET coupling values are summarized in this work. © 2013 The Authors. International Journal of Quantum Chemistry Published by Wiley Periodicals, Inc. 相似文献