Organisation of carbon nanotubes and semiconductor nanowires using lateral alumina templates

Carbon nanotubes and semiconductor nanowires have been thoroughly studied for the future replacement of silicon-based complementary metal oxide semiconductor (CMOS) devices and circuits. However, the organisation of these nanomaterials in dense transistor arrays, where each device is capable of delivering drive currents comparable with those of their silicon counterparts is still a big challenge. Here, we present a novel approach to the organisation of carbon nanotubes and semiconductor nanowires, based on the use of porous lateral alumina templates obtained by the controlled anodic oxidation of aluminium thin films. We discuss the growth of nanomaterials inside the pores of such templates and show the feasibility of our approach. Our first results point to further work on controlling the synthesis of catalyst nanoparticles at the bottom of the pores, these particles being necessary to nucleate and sustain the growth of carbon nanotubes or semiconductor nanowires. To cite this article: D. Pribat et al., C. R. Physique 10 (2009).     

Exploring the electronic band structure of individual carbon nanotubes under 60 T

Nano-sciences, and in particular nano-physics, constitute a fascinating world of investigations where the experimental challenges are to synthesize, to address (for instance optically or electrically) to explore and promote the remarkable physical properties of new nano-materials. Somehow, one of the most promising realization of nano-sciences lies in carbon-based nano-materials with sp² covalent bonds. In particular, carbon nanotubes, graphene and more recently ultra-narrow graphene nano-ribbons are envisioned as elementary bricks of the future of nano-electronics. However, prior to such an achievement, the first steps consist in understanding their fundamental electronic properties when they constitute the drain–source channel of a gated device or inter-connexion elements. In this article, we present the richness of challenging experiments combining single-object measurements with an extreme magnetic environment. We demonstrate that an applied magnetic field (B), along with a control of the electrostatic doping, drastically modifies the electronic band structure of a carbon nanotube based transistor. Several examples will be addressed in this presentation. When B is applied parallel to the tube axis, a quantum flux threading the tube induces a giant Aharonov–Bohm conductance modulation mediated by Schottky barriers whose profile is magnetic field dependent. In the perpendicular configuration, the applied magnetic field breaks the revolution symmetry along the circumference and non-conventional Landau states develop in the high field regime. By playing with a carbon nanotube based electronic Fabry–Perot resonator, the field dependence of the resonant states of the cavity reveals the onset of the first Landau state at zero energy. These experiments enlighten the outstanding efficiency of magneto-conductance experiments to probe the electronic properties of carbon based nano-materials. To cite this article: S. Nanot et al., C. R. Physique 10 (2009).     

AC transport in carbon-based devices: challenges and perspectives

Time-dependent fields are a valuable tool to control fundamental quantum phenomena in highly coherent low dimensional electron systems. Carbon nanotubes and graphene are a promising ground for these studies. Here we offer a brief overview of driven electronic transport in carbon-based materials with the main focus on carbon nanotubes. Recent results predicting control of the current and noise in nanotube based Fabry–Pérot devices are highlighted. To cite this article: L.E.F. Foa Torres, G. Cuniberti, C. R. Physique 10 (2009).     

Charge transport in carbon nanotubes based materials: a Kubo–Greenwood computational approach

In this contribution, we present a numerical study of quantum transport in carbon nanotubes based materials. After a brief presentation of the computational approach used to investigate the transport coefficient (Kubo method), the scaling properties of quantum conductance in ballistic regime as well as in the diffusive regimes are illustrated. The impact of elastic (impurities) and dynamical disorders (phonon vibrations) are analyzed separately, with the extraction of main transport length scales (mean free path and localization length), as well as the temperature dependence of the nanotube resistance. The results are found in very good agreement with both analytical results and experimental data, demonstrating the predictability efficiency of our computational strategy. To cite this article: H. Ishii et al., C. R. Physique 10 (2009).     

Helium and point defect accumulation: (ii) kinetic modelling

The main outstanding issues regarding modeling He diffusion and defect accumulation in α-iron are reviewed. During recent years, first principles calculations have provided a better understanding of defect stability and migration properties in pure α-iron, and accurate values of energetics of He migration and He-vacancy interactions. Such information has been used by several authors to study damage evolution under different irradiation conditions using both kinetic Monte Carlo and rate theory models. In this article a review of the main results is provided, in particular for He desorption. The influence of impurities such as carbon is discussed as well as the main challenges ahead for modeling. To cite this article: M.J. Caturla et al., C. R. Physique 9 (2008).     

First principles calculations in iron: structure and mobility of defect clusters and defect complexes for kinetic modelling

Predictive simulations of the defect population evolution in materials under or after irradiation can be performed in a multi-scale approach, where the atomistic properties of defects are determined by electronic structure calculations based on the Density Functional Theory and used as input for kinetic simulations covering macroscopic time and length scales. Recent advances obtained in iron are presented. The determination of the 3D migration of self-interstitial atoms instead of a fast one-dimensional glide induced an overall revision of the widely accepted picture of radiation damage predicted by previously existing empirical potentials. A coupled ab initio and mesoscopic kinetic Monte Carlo simulation provided strong evidence to clarify controversial interpretations of electrical resistivity recovery experiments concerning the mobility of vacancies, self-interstitial atoms, and their clusters. The results on the dissolution and migration properties of helium in α-Fe were used to parameterize Rate Theory models and new inter-atomic potentials, which improved the understanding of fusion reactor materials behavior. Finally, the effects of carbon, present in all steels as the principal hardening element, are also shown. To cite this article: C.C. Fu, F. Willaime, C. R. Physique 9 (2008).     

Temperature‐dependent magneto‐photoluminescence spectroscopy of carbon nanotubes: evidence for dark excitons

We review recent experimental and theoretical studies on the radiative properties of excitons in single‐walled carbon nanotubes (SWNTs) as a function of magnetic field and temperature. These studies not only provide new insight into the fundamental properties of excitons in the ultimate one‐dimensional (1D) limit but also reveal new phenomena associated with the unique crystal and electronic structure of SWNTs. During the past several years, SWNTs have emerged as one of the most ideal systems available for the systematic study of 1D excitons, which are predicted to possess a set of properties that are distinctly different from excitons in higher dimensions. In addition, their tubular nature allows them to exhibit non‐intuitive quantum phenomena when subjected to a parallel magnetic field, which breaks time reversal symmetry and adds an Aharonov‐Bohm phase to the electronic wavefunction. In particular, a series of recent experiments demonstrate that such a symmetry‐breaking magnetic field can dramatically “brighten” an optically‐inactive, or dark, exciton state at low temperature (see the title figure on the right). We show that this phenomenon, magnetic brightening, can be understood as a consequence of interplay between the strong intervalley Coulomb mixing and field‐induced lifting of valley degeneracy. Detailed temperature‐dependent photoluminescence studies of excitons in SWNTs in a varying magnetic field have thus provided one of the most critical tests for recently proposed theories of 1D excitons taking into account the strong 1D Coulomb interactions and unique band structure on an equal footing. Furthermore, results of these studies suggest the intriguing possibility of manipulating the optical properties of SWNTs by judicious symmetry control, which can lead to novel devices and applications in lasers and optoelectronics.     

Studies of chemical diffusion in La1-X SrXCoO3-δ

Recent investigations of superconductivity in carbon nanotubes have shown that a single-wall zig-zag nanotube can become superconducting at around 15?K. Theoretical studies of superconductivity in nanotubes using the traditional phonon exchange model, however, give a superconducting transition temperature T _c less than 1?K. To explain the observed higher critical temperature we explore the possibility of the plasmon exchange mechanism for superconductivity in nanotubes. We first calculate the effective interaction between electrons in a nanotube mediated by plasmon exchange and show that this interaction can become attractive. Using this attractive interaction in the modified Eliashberg theory for strong coupling superconductors, we then calculate the critical temperature T _c in a single-wall nanotube. Our theoretical results can explain the observed T _c in a single-wall nanotube. In particular, we find that T _c is sensitively dependent on the dielectric constant of the medium, the effective mass of the electrons and the radius of the nanotube. We then consider superconductivity in a bundle of single-wall nanotubes and find that bundling of nanotubes does not change the critical temperature significantly. Going beyond carbon nanotubes we show that in a metallic hollow nanowire T _c has some sort of oscillatory behaviour as a function of the surface number density of electrons.     

The non-Arrhenius migration of interstitial defects in bcc transition metals

Thermally activated migration of defects drives microstructural evolution of materials under irradiation. In the case of vacancies, the activation energy for migration is many times the absolute temperature, and the dependence of the diffusion coefficient on temperature is well approximated by the Arrhenius law. On the other hand the activation energy for the migration of self-interstitial defects, and particularly self-interstitial atom clusters, is very low. In this case a trajectory of a defect performing Brownian motion at or above room temperature does not follow the Arrhenius-like pattern of migration involving infrequent hops separated by the relatively long intervals of time during which a defect resides at a certain point in the crystal lattice. This article reviews recent atomistic simulations of migration of individual interstitial defects, as well as clusters of interstitial defects, and rationalizes the results of simulations on the basis of solutions of the multistring Frenkel–Kontorova model. The treatment developed in the paper shows that the origin of the non-Arrhenius migration of interstitial defects and interstitial defect clusters is associated with the interaction between a defect and the classical field of thermal phonons. To cite this article: S.L. Dudarev, C. R. Physique 9 (2008).     

Effective actions of intersecting brane worlds, fluxes and gaugino condensation

In this article we will first discuss the construction of brane world models being built either by intersecting D6-branes in type IIA orientifolds or, in the T-dual mirror picture, by D3- plus D7-branes with f-flux in type IIB orientifolds. We will show how their effective action is obtained by the calculation of scattering amplitudes between open and closed string states on intersecting D6-branes respectively on D3- and D7-branes. Secondly, turning on type IIB 3-form fluxes we will compute the induced soft supersymmetry breaking terms for the matter fields, like gaugino and scalar field masses. Finally, we will discuss the generation of 3-form flux in type IIB supergravity, which can be associated to the dynamical formation of a gaugino condensate in the confining phase of the dual N=1^* gauge theory. To cite this article: D. Lüst, C. R. Physique 5 (2004).

Résumé

Dans cet article nous discutons tout d'abord la construction de modèles de monde branaires construits soit par intersection de branes D6 dans des orientifolds de type IIA ou, dans la représentation T-duale, par des branes de type D3 et D7 avec des flux f dans les orientifolds de type IIB. Nous montrons comment obtenir leurs actions effectives en calculant les amplitudes de diffusion sur des intersections de branes de D6 et aussi sur des branes de type D3 et D7. Ensuite, nous allumons des flux pour la 3-forme de type IIB et nous calculons les termes de brisure douce de la supersymétrie pour les champs de matière, comme les masses du jaugino et des champs scalaires. Enfin, nous discutons la génération de flux pour la 3-forme de type IIB en supergravité, qui peut-être associée à la dynamique de la formation de condensat de jaugino dans la phase confinante de la théorie de jauge duale N=1^*. Pour citer cet article : D. Lüst, C. R. Physique 5 (2004).     

Helium and point defect accumulation: (i) microstructure and mechanical behaviour

Ferritic/martensitic (F/M) steels are good candidate structural materials for the future fusion reactors and spallation sources. However, irradiation of steels is known to produce hardening, loss of ductility, shift in ductile to brittle transition temperature (DBTT) and reduction of fracture toughness and creep resistance starting at low doses. Helium (He), produced by transmutation during the irradiation, also impacts mechanical properties. Numerous experimental and theoretical studies on the evolution of the microstructure of steels under irradiation have been conducted until now. We review the effect of irradiation-induced point defects and in particular of He on the mechanical properties of F/M steels. To cite this article: R. Schäublin et al., C. R. Physique 9 (2008).     

Jules Horowitz Reactor: a high performance material testing reactor

The physical modelling of materials' behaviour under severe conditions is an indispensable element for developing future fission and fusion systems: screening, design, optimisation, processing, licensing, and lifetime assessment of a new generation of structure materials and fuels, which will withstand high fast neutron flux at high in-service temperatures with the production of elements like helium and hydrogen.JANNUS and other analytical experimental tools are developed for this objective. However, a purely analytical approach is not sufficient: there is a need for flexible experiments integrating higher scales and coupled phenomena and offering high quality measurements; these experiments are performed in material testing reactors (MTR). Moreover, complementary representative experiments are usually performed in prototypes or dedicated facilities such as IFMIF for fusion. Only such a consistent set of tools operating on a wide range of scales, can provide an actual prediction capability. A program such as the development of silicon carbide composites (600–1200 °C) illustrates this multiscale strategy.Facing the long term needs of experimental irradiations and the ageing of present MTRs, it was thought necessary to implement a new generation high performance MTR in Europe for supporting existing and future nuclear reactors. The Jules Horowitz Reactor (JHR) project copes with this context. It is funded by an international consortium and will start operation in 2014. JHR will provide improved performances such as high neutron flux (10¹⁵ n/cm²/s above 0.1 MeV) in representative environments (coolant, pressure, temperature) with online monitoring of experimental parameters (including stress and strain control). Experimental devices designing, such as high dpa and small thermal gradients experiments, is now a key objective requiring a broad collaboration to put together present scientific state of art, end-users requirements and advanced instrumentation. To cite this article: D. Iracane et al., C. R. Physique 9 (2008).     

Variations on the warped deformed conifold

The warped deformed conifold background of type IIB theory is dual to the cascading SU(M(p+1))×SU(Mp) gauge theory. We show that this background realizes the (super-)Goldstone mechanism where the U(1) baryon number symmetry is broken by expectation values of baryonic operators. The resulting massless pseudo-scalar and scalar glueballs are identified in the supergravity spectrum. A D-string is then dual to a global string in the gauge theory. Upon compactification, the Goldstone mechanism turns into the Higgs mechanism, and the global strings turn into ANO strings. To cite this article: S.S. Gubser et al., C. R. Physique 5 (2004).

Résumé

La configuration de fond pour la théorie de type IIB donnée par le conifold voilé déformé est duale à la cascade de théorie de jauge SU(M(p+1))×SU(Mp). Nous montrons que cette configuration donne une réalisation du mécanisme de (super-)Goldstone où la symètrie baryonique U(1) est brisée par la valeur moyenne dans le vide des opérateurs baryoniques. Les boules de glue pseudo-scalaires et scalaires de masse nulle résultantes sont identifiées dans le spectre de supegravité. Une D-corde est alors duale à une corde globale dans la théorie de jauge. Après compactification, le mécanisme de Goldstone devient un mécanisme de Higgs, et une corde globale devient une corde ANO. Pour citer cet article : S.S. Gubser et al., C. R. Physique 5 (2004).     

Negative bending mode curvature via Robin boundary conditions

We examine the band spectrum, and associated Floquet–Bloch eigensolutions, arising in straight walled acoustic waveguides that have periodic structure along the guide. Homogeneous impedance (Robin) conditions are imposed along the guide walls and we find that in certain circumstances, negative curvature of the lowest (bending) mode can be achieved. This is unexpected, and has not been observed in a variety of physical situations examined by other authors. Further unexpected properties include the existence of the bending mode only on a subset of the Brillouin zone, as well as permitting otherwise unobtainable velocities of energy transmission. We conclude with a discussion of how such boundary conditions might be physically reproduced using effective conditions and homogenization theory, although the methodology to achieve these effective conditions is an open problem. To cite this article: S.D.M. Adams et al., C. R. Physique 10 (2009).     

Radiation aging of nonmetallic materials: specific aspects

Under irradiation, all materials experience various forms of structural evolution, from the simplest, associated with point defect creation and accumulation, to complex phase changes, either towards equilibrium or nonequilibrium structures. In nonmetallic ceramics the same processes are known or probable; however, the nature of bonding, partly ionic and partly covalent, as well as the complexity associated with the long range character of the Coulomb interaction, have long posed great difficulties in defect and aging studies under irradiation. Our aim here is to review the current state of knowledge, stressing the specific characteristics of nonmetallic materials, from primary defect creation to collective behavior, with respect to both experimental facts as well as to modeling perspectives. Given the broad field covered, we will illustrate the problem by choosing a few model materials, mostly oxides, in which the whole spectrum of phenomena has been handled. We will begin with threshold energy studies, then go to microstructure formation and evolution, radiation enhanced diffusion results, and lastly to phase changes. To cite this article: Y. Limoge, C. R. Physique 9 (2008).     

Phase-shift, refraction and focusing based on the metamaterial technologies

We address the problem of positive phase-shifting, negative refraction and focusing via a flat lens on the basis of the metamaterial technologies. With this aim, three examples are considered which differ by the technology employed and the operating frequency. The first one concerns negative-zero-positive refraction by using a prism-shaped electromagnetic metamaterial which consists of omega-type inclusion arrays operating at microwaves. The experimental verification was done in this case by angle-resolved transmission measurements. Second, we report on the phase-shift properties of a negative index transmission line which operates at Terahertz frequencies. In order to experimentally demonstrate the left-handed character of the propagation along the line, resulting in a phase advance, we used time domain experiments. At last, focusing by double refraction in a flat negative index lens was demonstrated by the theoretical and experimental mapping of the intensity of the electric field. Such a mapping of the E-field was carried out at near infrared (1.5 μm) by analysis in the time domain and scanning by near field optical microscopy. To cite this article: D. Lippens, C. R. Physique 10 (2009).     

Parametric generation of twin photons in vertical triple microcavities

We report the realization of a monolithic vertical-cavity, surface emitting micro-optical parametric conversion nanostructure, triply resonant with the parametric frequencies, allowing parametric oscillation with ultra-low pump power threshold. The photonic phase-space naturally provides triple resonance for the parametric frequencies, together with built-in cavity phase-matching for the pump wave at normal incidence. Parametric oscillation is observed in both the strong and weak exciton–photon coupling regime, allowing a high operating temperature. Signal and idler beams can be collected at 0° or at finite angles. The OPO threshold is low enough to envisage the realization of an all-semiconductor electrically-pumped micro-parametric oscillator. To cite this article: C. Diederichs et al., C. R. Physique 8 (2007).     

Carbon nanotube chemistry and assembly for electronic devices

Carbon nanotubes (CNTs) have exceptional physical properties that make them one of the most promising building blocks for future nanotechnologies. They may in particular play an important role in the development of innovative electronic devices in the fields of flexible electronics, ultra-high sensitivity sensors, high frequency electronics, opto-electronics, energy sources and nano-electromechanical systems (NEMS). Proofs of concept of several high performance devices already exist, usually at the single device level, but there remain many serious scientific issues to be solved before the viability of such routes can be evaluated. In particular, the main concern regards the controlled synthesis and positioning of nanotubes. In our opinion, truly innovative use of these nano-objects will come from: (i) the combination of some of their complementary physical properties, such as combining their electrical and mechanical properties; (ii) the combination of their properties with additional benefits coming from other molecules grafted on the nanotubes (this route being particularly relevant for gas- and bio-sensors, opto-electronic devices and energy sources); and (iii) the use of chemically- or bio-directed self-assembly processes to allow the efficient combination of several devices into functional arrays or circuits. In this article, we review our recent results concerning nanotube chemistry and assembly and their use to develop electronic devices. In particular, we present carbon nanotube field effect transistors and their chemical optimization, high frequency nanotube transistors, nanotube-based opto-electronic devices with memory capabilities and nanotube-based nano-electromechanical systems (NEMS). The impact of chemical functionalization on the electronic properties of CNTs is analyzed on the basis of theoretical calculations. To cite this article: V. Derycke et al., C. R. Physique 10 (2009).     

Basic results in vacuum statistics

This is a review of recent work on constructing and finding statistics of string theory vacua, done in collaboration with Frederik Denef, Bogdan Florea, Bernard Shiffman and Steve Zelditch. To cite this article: M.R. Douglas, C. R. Physique 5 (2004).

Résumé

Cet article est une revue de travaux récents sur la construction et découverte de statistiques des vides de théories des cordes, réalisée en collaboration avec Frederik Denef, Bogdan Florea, Bernard Shiffman et Steve Zelditch. Pour citer cet article : M.R. Douglas, C. R. Physique 5 (2004).     

Discrete dislocation dynamics: an important recent break-through in the modelling of dislocation collective behaviour

Recent results obtained by 3D discrete Dislocation Dynamics (DD) simulations are reviewed. Firstly, in the case of fatigued AISI 316L stainless steel, it is shown how DD simulations can both explain the formation of persistent slip bands and give a criterion for crack initiation. The same study is performed in the case of precipitate hardened metals where the precipitate size plays a crucial role. Secondly, we show how molecular dynamics (MD) simulations can feed the DD simulations for two applications. The first concerns the modelling of BCC Fe for which the dislocation mobility is derived from MD simulations. The second considers the modelling of irradiated stainless steels (FCC), where MD is used to define the local rules of interactions between dislocations and Frank loops. To cite this article: M.C. Fivel, C. R. Physique 9 (2008).