N,N,N^{\prime },N^{\prime }-Tetrabromobenzene-1,3-disulfonamide and poly(N-bromo-N-ethylbenzene-1,3-disulfonamide) as new and efficient catalysts for the synthesis of highly substituted 1,6-dihydropyrazine-2,3-dicarbonitrile derivatives

Various mono and bis-1,6-dihydropyrazine-2,3-dicarbonitrile derivatives were efficiently synthesized by reacting 2,3-diaminomaleonitrile (DAMN), isocyanides and ketones in the presence of a catalytic amount of $N,N{,}N^{\prime }{,}N^{\prime }$ -tetrabromobenzene-1,3-disulfonamide [TBBDA] and poly( $N$ -bromo- $N$ -ethylbenzene-1,3-disulfonamide) [PBBS] in EtOH/H $_{2}$ O at ambient temperature. Graphic abstract $N,N,N^{\prime },N^{\prime }$ -Tetrabromobenzene-1,3-disulfonamide and poly( $N$ -bromo- $N$ -ethylbenzene-1,3-disulfonamide) as new and efficient catalysts for the synthesis of highly substituted 1,6-dihydropyrazine-2,3-dicarbonitrile derivatives.      

Antineutrino science in KamLAND

The primary goal of KamLAND is a search for the oscillation of \({\bar{\nu }}_\mathrm{e}\) ’s emitted from distant power reactors. The long baseline, typically 180 km, enables KamLAND to address the oscillation solution of the “solar neutrino problem” with \({\bar{\nu }}_{e} \) ’s under laboratory conditions. KamLAND found fewer reactor \({\bar{\nu }}_{e} \) events than expected from standard assumptions about \(\overline{\nu }_e\) propagation at more than 9 \(\sigma \) confidence level (C.L.). The observed energy spectrum disagrees with the expected spectral shape at more than 5 \(\sigma \) C.L., and prefers the distortion from neutrino oscillation effects. A three-flavor oscillation analysis of the data from KamLAND and KamLAND + solar neutrino experiments with CPT invariance, yields \(\Delta m_{21}^2 \) = [ \(7.54_{-0.18}^{+0.19} \times \) 10 \(^{-5}\) eV \(^{2}\) , \(7.53_{-0.18}^{+0.19} \times \) 10 \(^{-5}\) eV \(^{2}\) ], tan \(^{2}\theta _{12}\) = [ \(0.481_{-0.080}^{+0.092} \) , \(0.437_{-0.026}^{+0.029} \) ], and sin \(^{2}\theta _{13}\) = [ \(0.010_{-0.034}^{+0.033} \) , \(0.023_{-0.015}^{+0.015} \) ]. All solutions to the solar neutrino problem except for the large mixing angle region are excluded. KamLAND also demonstrated almost two cycles of the periodic feature expected from neutrino oscillation effects. KamLAND performed the first experimental study of antineutrinos from the Earth’s interior so-called geoneutrinos (geo \({\bar{\nu }}_{e} \) ’s), and succeeded in detecting geo \({\bar{\nu }}_{e} \) ’s produced by the decays of \(^{238}\) U and \(^{232}\) Th within the Earth. Assuming a chondritic Th/U mass ratio, we obtain \(116_{-27}^{+28} {\bar{\nu }}_{e}\) events from \(^{238}\) U and \(^{232}\) Th, corresponding a geo \({\bar{\nu }}_{e}\) flux of \(3.4_{-0.8}^{+0.8}\times \) 10 \(^{6}\) cm \(^{-2}\)  s \(^{-1}\) at the KamLAND location. We evaluate various bulk silicate Earth composition models using the observed geo \({\bar{\nu }}_{e} \) rate.     

Investigation of conductivity of adhesive layer including indium tin oxide particles for multi-junction solar cells

We report connection conductivity ( \(C_{\rm c}\) ) of adhesive which including \(\hbox {In}_2\hbox {O}_3\) – \(\hbox {SnO}_2\) (ITO) particles developed for fabrication of stacked-type-multi-junction solar cells. The commercial 20- \(\upmu \) m sized ITO particles were heated in vacuum at temperature ranging from 800 to 1,300  \(^{\circ }{\rm C}\) for 10 min to increase \(C_{\rm c}\) . 6.2 wt% ITO particles were dispersed in commercial Cemedine adhesive gel to form 100 samples structured with n-type Si/adhesive/n-type Si (n-Si sample) and p-type Si/adhesive/p-type Si (p-Si sample). Current density as a function of voltage (J–V) characteristics gave \(C_{\rm c}\) . It ranged from 4.3 to 1.0 S/cm \(^2\) for the n-Si sample with 800 \(^{\circ }{\rm C}\) heat-treated ITO particles. Its standard deviation was 0.59 S/cm \(^2\) . On the other hand, it ranged from 2.0 to 0.6 S/cm \(^2\) for the p-Si sample with 800  \(^{\circ }{\rm C}\) heat-treated ITO particles. Its standard deviation was 0.22 S/cm \(^2\) . The distribution of \(C_{\rm c}\) mainly resulted from contact efficiency of ITO particles to substrate. We theoretically estimated that present \(C_{\rm c}\) achieved a low loss of the power conversion efficiency ( \(E_{\rm ff}\) ) lower than 0.3 % in the application of fabrication of multi-junction solar cell with an intrinsic \(E_{\rm ff}\) of 30 % and an open circuit voltage above 1.9 V.     

Functional Properties of Hörmander’s Space of Distributions Having a Specified Wavefront Set

The space \({\mathcal{D}_\Gamma^\prime}\) of distributions having their wavefront sets in a closed cone \({\Gamma}\) has become important in physics because of its role in the formulation of quantum field theory in curved spacetime. In this paper, the topological and bornological properties of \({\mathcal{D}_\Gamma^\prime}\) and its dual \({\mathcal{E}_\Lambda^\prime}\) are investigated. It is found that \({\mathcal{D}_\Gamma^\prime}\) is a nuclear, semi-reflexive and semi-Montel complete normal space of distributions. Its strong dual \({\mathcal{E}_\Lambda^\prime}\) is a nuclear, barrelled and (ultra)bornological normal space of distributions which, however, is not even sequentially complete. Concrete rules are given to determine whether a distribution belongs to \({\mathcal{D}_\Gamma^\prime}\) , whether a sequence converges in \({\mathcal{D}_\Gamma^\prime}\) and whether a set of distributions is bounded in \({\mathcal{D}_\Gamma^\prime}\) .     

Maximal Distance Travelled by N Vicious Walkers Till Their Survival

We consider N Brownian particles moving on a line starting from initial positions \(\mathbf{{u}}\equiv \{u_1,u_2,\ldots u_N\}\) such that \(0 . Their motion gets stopped at time \(t_s\) when either two of them collide or when the particle closest to the origin hits the origin for the first time. For \(N=2\) , we study the probability distribution function \(p_1(m|\mathbf{{u}})\) and \(p_2(m|\mathbf{{u}})\) of the maximal distance travelled by the \(1^{\text {st}}\) and \(2^{\text {nd}}\) walker till \(t_s\) . For general N particles with identical diffusion constants \(D\) , we show that the probability distribution \(p_N(m|\mathbf{u})\) of the global maximum \(m_N\) , has a power law tail \(p_i(m|\mathbf{{u}}) \sim {N^2B_N\mathcal {F}_{N}(\mathbf{u})}/{m^{\nu _N}}\) with exponent \(\nu _N =N^2+1\) . We obtain explicit expressions of the function \(\mathcal {F}_{N}(\mathbf{u})\) and of the N dependent amplitude \(B_N\) which we also analyze for large N using techniques from random matrix theory. We verify our analytical results through direct numerical simulations.     

Geometric Discord of Non-X-Structured State under Decoherence Channels

We investigate the level surfaces of geometric discord under some typical kinds of decoherence channels for a class of two-qubit states with the Bloch vectors \(\overset {\rightharpoonup }{r}\) and \(\overset {\rightharpoonup }{s}\) in z and x direction respectively. The surfaces of geometric discord are composed of three interaction ”cylinders” along three orthogonal directions of \(\overset {\rightharpoonup }{c}_{1}\) , \(\overset {\rightharpoonup }{c}_{2}\) and \(\overset {\rightharpoonup }{c}_{3}\) . We study the different images corresponding to different values of geometric discord, the Bloch vectors as well as p. In the phase damping channel, the geometric discord keeps constant over a period of time, furthermore the geometric discord and the quantum discord have the same sudden change point for Non-X-structured state.     

Spin Effects in the Interaction of Antiprotons with the Deuteron at Low and Intermediate Energies

Antiproton-deuteron scattering is analyzed within the Glauber theory, accounting for the full spin dependence of the underlying \({\bar{N}N}\) amplitudes. The latter are taken from the Jülich \({\bar{N}N}\) models and from a recently published new partial-wave analysis of \({\bar{p}p}\) scattering data. Predictions for differential cross sections and the spin observables \({A_y^d}\) , \({A_y^{\bar{p}}}\) , A _xx , A _yy are presented for antiproton beam energies up to about 300 MeV. The efficiency of the polarization buildup for antiprotons in a storage ring is investigated.     

Synthesis and anti-cancer activity of a glycosyl library of \varvec{N}-acetylglucosamine-bearing oleanolic acid

N-Acetylglucosamine-bearing triterpenoid saponins (GNTS) were reported to be a unique type of saponins with potent anti-tumor activity. In order to study the structure–activity relationship of GNTS, 24 oleanolic acid saponins with ( $1 \rightarrow 3$ )-linked, ( $1\rightarrow 4$ )-linked, ( $1\rightarrow 6$ )-linked $N$ -acetylglucosamine oligosaccharide residues were synthesized in a combinatorial and concise method. The cytotoxicity of these compounds toward the leukemia cell line HL-60 and the colorectal cancer cell line HT-29 could not be improved. Half maximal inhibition below $10\,\upmu \hbox {M}$ was achieved in one single case. The study revealed that the activity decreased following the order of $3^{\prime }>4^{\prime }>6^{\prime }$ glycosyl modifications. GNTS that incorporated (d/l)-xylose and l-arabinose at positions $3^{\prime }$ and $4^{\prime }$ were more potent than those bearing other sugars.     

Dispersion dependence of two-photon absorption transition on frequency in Si PIN photodetector

The variation of two-photon absorption (TPA) coefficient \(\beta _{\mathrm{TPA}} (\omega )\) of Si excited at difference photon energy was investigated. The TPA coefficient was measured by using a picosecond pulsed laser with the wavelength could be tuned in a wide photon-energy range. An equivalent RC circuit model was adapted to derive the TPA coefficient \(\beta _{\mathrm{TPA}} (\omega )\) . The results showed that \(\beta _{\mathrm{TPA}} (\omega )\) varied from \(4.2 \times 10^{-4}\) to \(1.17 \times 10^{-3 }\)  cm/GW in the transparent wavelength region \(1.80<\lambda <1.36\,\upmu \) m of Si. The increasing tendency of \(\beta _{\mathrm{TPA}} (\omega )\) with the incident photon energy can be qualitatively interpreted as the photon energy increases from \(E_{\mathrm{ig}}/2\) to nearly \(E_{\mathrm{ig}}\) , the electrons excited from the valance band find an increasing availability of conduction band states. Comparing with the high-energy side transitions, the TPA coefficient in low-energy side is about 10 times too small. This can be attributed that the TPA transition in low-energy side is the process of photon-assisted electron transitions from valence to conduction band occurring between different points in k-space, while is direct transition in high-energy side.     

The Isospin Mixing in the X(3872) Decay Spectrum

The large isospin symmetry breaking found in the X(3872) decay is investigated by looking into the transfer strength from the \({{c}\bar{c}}\) quarkonium to the two-meson states: \({c\bar{c} \rightarrow D^{0}\overline{D}^{*0}, D^{+} D^{*-} , J /\psi\omega, {\rm and} \, J /\psi\rho}\) . The widths of the \({\rho}\) and \({\omega}\) mesons are taken into account in the calculation. It is found that very narrow \({J /\psi\omega}\) and \({J /\psi\rho}\) peaks appear at the \({D^{0}\overline{D}^{*0}}\) threshold. These narrow peaks appear provided that the strength of the \({D^{0}\overline{D}^{*0}}\) component is large around the threshold. The large width of the \({\rho}\) meson enhances the isospin-one component in the transfer strength considerably, which reduces the ratio \({{\rm Br}(X \rightarrow J /\psi\omega)/{\rm Br}(X \rightarrow J /\psi\rho)}\) down to 2.5.     

Blow Up Dynamics for Equivariant Critical Schrödinger Maps

For the Schrödinger map equation \({u_t = u \times \triangle u \, {\rm in} \, \mathbb{R}^{2+1}}\) , with values in S ², we prove for any \({\nu > 1}\) the existence of equivariant finite time blow up solutions of the form \({u(x, t) = \phi(\lambda(t) x) + \zeta(x, t)}\) , where \({\phi}\) is a lowest energy steady state, \({\lambda(t) = t^{-1/2-\nu}}\) and \({\zeta(t)}\) is arbitrary small in \({\dot H^1 \cap \dot H^2}\) .     

Asymptotic Quantum Many-Body Localization from Thermal Disorder

We consider a quantum lattice system with infinite-dimensional on-site Hilbert space, very similar to the Bose–Hubbard model. We investigate many-body localization in this model, induced by thermal fluctuations rather than disorder in the Hamiltonian. We provide evidence that the Green–Kubo conductivity κ(β), defined as the time-integrated current autocorrelation function, decays faster than any polynomial in the inverse temperature β as \({\beta \to 0}\) . More precisely, we define approximations \({\kappa_{\tau}(\beta)}\) to κ(β) by integrating the current-current autocorrelation function up to a large but finite time \({\tau}\) and we rigorously show that \({\beta^{-n}\kappa_{\beta^{-m}}(\beta)}\) vanishes as \({\beta \to 0}\) , for any \({n,m \in \mathbb{N}}\) such that m?n is sufficiently large.     

Near-Extreme Eigenvalues and the First Gap of Hermitian Random Matrices

We study the phenomenon of “crowding” near the largest eigenvalue \(\lambda _\mathrm{max}\) of random \(N \times N\) matrices belonging to the Gaussian Unitary Ensemble of random matrix theory. We focus on two distinct quantities: (i) the density of states (DOS) near \(\lambda _\mathrm{max}\) , \(\rho _\mathrm{DOS}(r,N)\) , which is the average density of eigenvalues located at a distance \(r\) from \(\lambda _\mathrm{max}\) and (ii) the probability density function of the gap between the first two largest eigenvalues, \(p_\mathrm{GAP}(r,N)\) . In the edge scaling limit where \(r = \mathcal{O}(N^{-1/6})\) , which is described by a double scaling limit of a system of unconventional orthogonal polynomials, we show that \(\rho _\mathrm{DOS}(r,N)\) and \(p_\mathrm{GAP}(r,N)\) are characterized by scaling functions which can be expressed in terms of the solution of a Lax pair associated to the Painlevé XXXIV equation. This provides an alternative and simpler expression for the gap distribution, which was recently studied by Witte et al. in Nonlinearity 26:1799, 2013. Our expressions allow to obtain precise asymptotic behaviors of these scaling functions both for small and large arguments.     

An Algebraic Construction of Boundary Quantum Field Theory

We build up local, time translation covariant Boundary Quantum Field Theory nets of von Neumann algebras ${\mathcal A_V}$ on the Minkowski half-plane M ₊ starting with a local conformal net ${\mathcal A}$ of von Neumann algebras on ${\mathbb R}$ and an element V of a unitary semigroup ${\mathcal E(\mathcal A)}$ associated with ${\mathcal A}$ . The case V?=?1 reduces to the net ${\mathcal A_+}$ considered by Rehren and one of the authors; if the vacuum character of ${\mathcal A}$ is summable, ${\mathcal A_V}$ is locally isomorphic to ${\mathcal A_+}$ . We discuss the structure of the semigroup ${\mathcal E(\mathcal A)}$ . By using a one-particle version of Borchers theorem and standard subspace analysis, we provide an abstract analog of the Beurling-Lax theorem that allows us to describe, in particular, all unitaries on the one-particle Hilbert space whose second quantization promotion belongs to ${\mathcal E(\mathcal A^{(0)})}$ with ${\mathcal A^{(0)}}$ the U(1)-current net. Each such unitary is attached to a scattering function or, more generally, to a symmetric inner function. We then obtain families of models via any Buchholz-Mack-Todorov extension of ${\mathcal A^{(0)}}$ . A further family of models comes from the Ising model.     

Self-Dual Noncommutative {\phi^4} -Theory in Four Dimensions is a Non-Perturbatively Solvable and Non-Trivial Quantum Field Theory

We study quartic matrix models with partition function \({\mathcal{Z}[E, J] = \int dM}\) exp(trace \({(JM - EM^{2} - \frac{\lambda}{4} M^4)}\) ). The integral is over the space of Hermitean \({\mathcal{N} \times \mathcal{N}}\) -matrices, the external matrix E encodes the dynamics, \({\lambda > 0}\) is a scalar coupling constant and the matrix J is used to generate correlation functions. For E not a multiple of the identity matrix, we prove a universal algebraic recursion formula which gives all higher correlation functions in terms of the 2-point function and the distinct eigenvalues of E. The 2-point function itself satisfies a closed non-linear equation which must be solved case by case for given E. These results imply that if the 2-point function of a quartic matrix model is renormalisable by mass and wavefunction renormalisation, then the entire model is renormalisable and has vanishing β-function. As the main application we prove that Euclidean \({\phi^4}\) -quantum field theory on four-dimensional Moyal space with harmonic propagation, taken at its self-duality point and in the infinite volume limit, is exactly solvable and non-trivial. This model is a quartic matrix model, where E has for \({\mathcal{N} \to \infty}\) the same spectrum as the Laplace operator in four dimensions. Using the theory of singular integral equations of Carleman type we compute (for \({\mathcal{N} \to \infty}\) and after renormalisation of \({E, \lambda}\) ) the free energy density (1/volume) log \({(\mathcal{Z}[E, J]/\mathcal{Z}[E, 0])}\) exactly in terms of the solution of a non-linear integral equation. Existence of a solution is proved via the Schauder fixed point theorem. The derivation of the non-linear integral equation relies on an assumption which in subsequent work is verified for coupling constants \({\lambda \leq 0}\) .     

On Energy-Momentum Transfer of Quantum Fields

We prove the following theorem on bounded operators in quantum field theory: if \({\|[B,B^*(x)]\|\leqslant{\rm const}D(x)}\) , then \({\|B^k_\pm(\nu)G(P^0)\|^2\leqslant{\rm const}\int D(x - y){\rm d}|\nu|(x){\rm d}|\nu|(y)}\) , where D(x) is a function weakly decaying in spacelike directions, \({B^k_\pm}\) are creation/annihilation parts of an appropriate time derivative of B, G is any positive, bounded, non-increasing function in \({L^2(\mathbb{R})}\) , and \({\nu}\) is any finite complex Borel measure; creation/annihilation operators may be also replaced by \({B^k_t}\) with \({\check{B^k_t}(p)=|p|^k\check{B}(p)}\) . We also use the notion of energy-momentum scaling degree of B with respect to a submanifold (Steinmann-type, but in momentum space, and applied to the norm of an operator). These two tools are applied to the analysis of singularities of \({\check{B}(p)G(P^0)}\) . We prove, among others, the following statement (modulo some more specific assumptions): outside p = 0 the only allowed contributions to this functional which are concentrated on a submanifold (including the trivial one—a single point) are Dirac measures on hypersurfaces (if the decay of D is not to slow).     

Photon Asymmetries in {nd\rightarrow} 3 Hγ Using EFT({/\!\!\!\pi}) Approach

The parity-violating Lagrangian of the weak nucleon-nucleon (NN) interaction in the pionless effective field theory (EFT( \({/\!\!\!\pi}\) )) approach contains five independent unknown low-energy coupling constants (LECs). The photon asymmetry with respect to neutron polarization in \({np\rightarrow d\gamma A_\gamma^{np}}\) , the circular polarization of outgoing photon in \({np\rightarrow d\gamma P_\gamma^{np}}\) , the neutron spin rotation in hydrogen \({\frac{1}{\rho}\frac{d\phi^{np}}{dl}}\) , the neutron spin rotation in deuterium \({\frac{1}{\rho}\frac{d\phi^{nd}}{dl}}\) and the circular polarization of γ-emission in \({nd\rightarrow}\) ³ Hγ \({P^{nd}_\gamma}\) are the parity-violating observables which have been recently calculated in terms of parity-violating LECs in the EFT( \({/\!\!\!\pi}\) ) framework. We obtain the LECs by matching the parity-violating observables to the Desplanques, Donoghue, and Holstein (DDH) best value estimates. Then, we evaluate photon asymmetry with respect to the neutron polarization \({a^{nd}_\gamma}\) and the photon asymmetry in relation to deuteron polarization \({A^{nd}_\gamma}\) in \({nd\rightarrow}\) ³ Hγ process. We finally compare our EFT( \({/\!\!\!\pi}\) ) photon asymmetries results with the experimental values and the previous calculations based on the DDH model.     

{\Xi} Hypernucler States Predicted by the New Interaction Model ESC08c

The features of the new interaction model ESC08c in ${\Lambda N}$ , ${\Sigma N}$ and ${\Xi N}$ channels are demonstrated single hyperon potentials ${U_Y(Y=\Lambda, \Sigma, \Xi)}$ in nuclear matter on the basis of the G-matrix theory. (K ^?, K ⁺) productions of ${\Xi}$ hypernuclei are studied with ${\Xi}$ -nucleus folding potentials.     

Studying bi-partite entangled state representations via the integration over ket-bra operators in \mathfrak{Q}-ordering or \mathfrak{P}-ordering

For two particles＇ relative position and total momentum we have introduced the entangled state representation ｜μ〉, and its conjugate state｜ξ〉 In this work, for the first time; we study theln via the integration over ket bra operators in -ordering or -ordering, where Q-ordering means all Qs are to the left, of all Ps and -ordering means all Ps are to the left of all Qs. In this way we newly derive -ordered （or Q-ordered） expansion formulas of the two-mode squeezing operator which can show the squeezing effect on both the two-mode coordinate and momentum eigenstates. This tells that not only the integration over ket bra operators within normally ordered, but also within - ordered （or -ordered） are feasible and useful in developing quantum mechanical representation and transtbrlnation theory.