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1.
M. G. Voronkov O. G. Yarosh A. L. Kuznetsov B. Z. Shternberg V. I. Rakhlin R. G. Mirskov 《Russian Chemical Bulletin》1988,37(6):1255-1256
Conclusions The reaction of 1,2-bis(methyldimethoxysilyl)ethane and the corresponding ethylene and acetylene derivatives with bis(2-hydroxyethyl)methylamine gives 1,2-bis(2,6-dimethyl-1,3-dioxa-6-aza-2-silacyclooctyl-2)ethane and the corresponding ethylene and acetylene derivatives. Analogously, 1,2-bis(vinyldimethoxysilyl)acetylene gave 1,2-bis(2-vinyl-6-methyl-1,3-dioxa-6-aza-2-silacyclooctyl-2)acetylene.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1420–1421, June, 1988. 相似文献
2.
A. V. Aksenov D. V. Moiseev I. V. Borovlev O. N. Nadein 《Chemistry of Heterocyclic Compounds》2000,36(8):948-951
Reduction of 1-alkyl-3-(2-quinolyl)quinolinium halides with sodium borohydride leads to 1-alkyl-1,2-dihydro-2,3-biquinolyls which, except for the ethoxycarbonyl derivative, undergo rearrangement to 1-alkyl-1,4-dihydro-2,3-biquinolyls. The last can be synthesized by the alkylation of the corresponding 1,4-dihydro-2,3-biquinolyls under conditions of interphase catalysis and in the system KOH-DMSO.For Communication 7, see [1].Stavropol' State University, Stavropol' 355009, Russia; nauka@stavsu.ru. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1084–1087, August, 2000. 相似文献
3.
A. Z. Abyshev 《Chemistry of Natural Compounds》1976,10(5):581-585
Summary From a methanolic extract of the roots ofPrangos ferulacea (L) Lindl., growing in the Nakhichevan ASSR, in addition to the compounds found previously, another six substances (I–VI) have been isolated, of which (I) and (VI) have been identified as, respectively, meransin hydrate monoacetate, found for the first time in nature, and umbelliferone: and in the study of a crystalline mixture obtained from the resin of the roots of the plant under investigation collected in Armenia, two coumarins — (VII) and (VIII) — have been isolated.On the basis of a study of IR, NMR, and mass spectra and chemical properties, the structures of the six new cumarin derivatives (II–V, VII, and VIII) have been established. Compound (II) has the structure of 8-(3-methylbutenyloxy)furo-2,3:7,6-coumarin and has been called feruliden; (III) is 7-hydroxy-8-(3-hydroxy-2-senecioyloxyisopentyl) coumarin and has been called ferudiol; (IV) is 7-hydroxy-8-(3-methoxy-2-senecioyloxyisopentyl) coumarin; (V) is 5-[1-(2,3-dihydroxy-3-methylbutyroyloxy)-1-methylethyl]-4,5-dihydrofuro-2,3:7,6-coumarin and has been called lindiol; (VII) is 8-(2-hydroxy-3-methylbut-3-enyloxy)-7-methoxycoumarin and has been called ferudenol; (VIII) is 7-methoxy-8-(3-methyl-2-oxobut-3-enyl)coumarin and has been called prangone.Leningrad Sanitary-Hygenic Medical Institute. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 568–574, September–October, 1974. 相似文献
4.
Conclusions For the first time in the isoflavone series, a compound which has the structure of 5,7-dihydroxy-3,4-methylenedioxyisoflavone (3,4-methylenedioxyorobol) and two of its glucosides — 3,4-methylenedioxyorobol 7-O--D-glucoside and 3,4-methylenedioxyorobol 7-O--D-glucosylglucoside — and also a genistein C-monoglucoside, have been described. The isoflavones were isolated from the roots ofLupinus luteus L. by preparative chromatography on paper and on columns of polyamide. In addition, the previously known genistein, genistein 7-O--D-glucoside (genistin), and genistein 7-O--D-glucosylglucoside have been obtained.V. F. Kuprevich Institute of Experimental Botany, Academy of Sciences of the Belorussian SSR. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 162–166, March–April, 1974. 相似文献
5.
Summary Dichloro complexes of PdII, [Pd(L–L)Cl2], where L–L=1-(thiomethyl)-2-(diphenylarsino)ethane (S–As) or 1-(thiomethyl)-2-(diphenylphosphino)ethane (S–P) andtrans-[PdL2Cl2], where L=diphenyl(2-phenylethyl)-phosphine (PE), diphenyl(1-naphthyl)phosphine (PN) orN-methyl-2-thiophenealdimine (SN), have been prepared and characterized. The reactions of these complexes with MeLi were investigated. The dimethyl complexes [Pd(L–L)Me2] (L–L=S–As, S–P) and [Pd(PE)Me2] were isolated and characterized. Reaction of [Pd(L–L)Me2] (L–L=S–As, S–P) with HCl affords the monomethyl derivatives [Pd(L–L)Me(Cl)]. In contrast to the Pt analogues, [Pd(L–L)Me2] and [Pd(L–L)Me(Cl)] are relatively less stable than [Pt(L–L)Me2] and [Pt(L–L)Me(Cl)]. 相似文献
6.
N. S. Prostakov I. V. Eliseeva H. Bu Habib L. M. Kirillova A. É. Aliev 《Chemistry of Heterocyclic Compounds》1986,22(6):642-646
N-Methyl (ethyl, benzoyl, trifluoroacetyl)-substituted 3-methyl-2-phenyl-5-(3-methyl-2-phenyl-3,4-dehydropiperidyl-6) pyridines and di(N-oxide) of the correspondingly substituted ,ß-dipyridyl were prepared. A method for synthesizing 2-phenyldinicotinic acid was developed. Cyclodehydration of this acid gave 4-azafluorenone-2-carboxylic acid. Transformations of this acid were carried out with respect to two functional groups.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 813–817, June, 1986. 相似文献
7.
Summary The herbSeseli tenuisectum has been found to contain — in addition to anomalin — another three coumarins (C-2, C-3, and C-4) which are derivatives of khellactone.On the basis of NMR, mass, and IR spectroscopy, the products of stepwise alkaline methanolysis and hydrolysis, and conversion into pteryxin, it has been established that two of them are isomeric monoesters of khellactone and angelic acid with the structures 3-angeloyloxy-4-hydroxy- and 4-angeloyloxy-3-hydroxy-3,4-dihydroxyseselin, respectively. They have been obtained in the individual state for the first time by thin-layer chromatography, which has enabled their IR spectra to be recorded.The lactone C-4 is a diester of khellactone with the structure 4-angeloyloxy-3-isovaleryloxy-3,4-dihydroseselin.We are the first to have found these substances in plants of the flora of the USSR.Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 38–43, January–February, 1972. 相似文献
8.
I. V. Mazere I. A. Meirovits V. A. Ozolinya O. Ya. Neiland 《Chemistry of Heterocyclic Compounds》1972,8(12):1446-1448
3,4,3,4-Tetramethyldiphenyl ether readily forms 2,2-dihalo derivatives on bromination and iodination. Heating 2,2-diiodo-4,5,4,5-tetramethyldiphenyl ether with copper powder or oxidation, of 2,2-dilithio-4,5,4,5-tetramethyldiphenyl ether gives 2,3,7,8-tetramethyldibenzofuran, the structure of which was proved by alternative synthesis from 2,2-dinitroand 2,2-diamino-4,5,4,5-tetramethyldiphenyls.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1597–1599, December, 1972. 相似文献
9.
Yu. N. Polivin R. A. Karakhanov T. S. Sheveleva B. I. Ugrak V. I. Kelarev 《Russian Chemical Bulletin》1992,41(9):1716-1718
Reaction of 2-methyl-4,5-dihydrofuran with HCl at 0°C yields 5-chloro-2-pentanone (13%) and 1-(2-methyltetrahydrofuryl-2)-5-chloro-2-pentanone (27%) and at 200° 5-chloro-2-pentanone exclusively.N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 117913 Moscow. I. M. Gubkin State Petroleum and Gas Academy, 117917 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 9, pp. 2188–2191, September, 1992. 相似文献
10.
Reaction of N-(1-pyrrolidinyl)-, N-(1-piperidinyl)-, N-(4-morpholinyl)-, and N-(1-hexahydroazepinyl)-thioureas with propiolic acid gives hetero-N-spiro-4-(2-amino-2-1,3,4-thiadizolin-4-io-5-acetates), which rearrange in acetic anhydride to 2-(N-heteryl)imino-2,3-dihydro-4H-1,3-thiazin-4-ones.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 263–265, February, 1993. 相似文献
11.
L. G. Levkovskaya I. E. Mamaeva L. A. Serochkina T. S. Safonova 《Chemistry of Heterocyclic Compounds》1993,29(4):480-483
Representatives of new heterocyclic systems were obtained — pyrido[3,25,6][1,4]thiazino[3,4-c]- and pyrimido[5,45,6][1,4]thiazino[3,4-c][1,2, 4]triazines. Hydrazides of N-(pyrid-3-yl)- and N-(pyrimid-5-yl)oxamic acids were isolated and characterized. Their acylation products were investigated.For communication 45, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 559–562, April, 1993. 相似文献
12.
Summary 1. Isoimperatorin and oxypeucedanin have been found in the roots ofPrangos tschimganica B. Fedtsch.2. A new coumarin which we have called prantschimgin, has been isolated and its structure has been established as the ester of 5-(2-hydroxyisopropyl)-4,5-dihydrofuro(2,3: 7, 6) coumarin and 2, 2-dimethylacrylic (senecioic) acid.Khimiya Prirodnykh Soedinenii, Vol. 2, No. 4, pp. 235–239, 1966 相似文献
13.
G. A. Vitovskaya N. P. Elinov I. S. Kozhina G. Z. Mamatov 《Chemistry of Natural Compounds》1972,6(1):12-15
Conclusions 1. Xanthalin has been shown to have the structure of 2, 2-dimethyl-3, 4,-diangeloyloxy-3, 4-dihydropyrano-5, 6:6, 7-coumarin on the basis of the preparation of a number of derivatives and cleavage products.2. The following products of the alkaline hydrolysis of xanthalin have been isolated and characterized for the first time: (±)-3, 4-dihydroxy-3, 4-dihydroxanthyletin (isokhellactone), C14H14O5, with mp 213–215° C and (–)-trans-3-hydroxy-4-methoxy-3, 4-dihydroxanthyletin (isomethylkhellactone, C15H16O5, with mp 136.5–138° C and []
D
20
–47.7 (ethanol).Khimiya Prirodnykh Soedinenii, Vol. 6, No. 1, pp. 14–19, 1970 相似文献
14.
Derivatives of a new heterocyclic system thieno[2,35,6]pyrimido[3,4-a]indole, were obtained by the reaction of substituted N,O-diacetylindoxyls with excess N-(2-methyl-3-ethoxycarbonyl-4-thienyl)hydrazine. The reaction of N-acetylindoxyl and 4-hydrazinouracil forms 12-amino-1,3-dioxo-2,4,6-trimethylpyrimido[5,45,6]pyrimido[3,4-a]indole.Deceased.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, 1343–1345, October, 1987. 相似文献
15.
A. K. Sheinkman T. V. Stupnikova N. A. Klyuev L. Yu. Petrovskaya V. G. Zhil'nikov 《Chemistry of Heterocyclic Compounds》1977,13(2):190-198
Indoles and pyrrole were subjected to hetarylation with imidazole and benzimidazole in the presence of aliphatic, aromatic, and heteroaromatic carboxylic acid chlorides. The resulting N,N-diacylimidazolinyl- and N,N-diacylbenzimidazolinylindoles were converted to 2-(3-indolyl)-1,3-diacylimidazolium and N,N-diacylbenzimidazolium salts by the action of trityl perchlorate.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 238–247, February, 1977. 相似文献
16.
M. Melmer H. Neudeck K. Schlögl A. Werner 《Monatshefte für Chemie / Chemical Monthly》1995,126(8-9):933-943
Summary All optically active title compounds were obtained from the 4,4-diacetyl-spiro compound2; (+)- and (–)-2 were accessible by chromatography on triacetyl cellulose in ethanol. The enantiomeric purities were established from chromatographic data. The chirality (–)-(2R) was deduced for all new compounds on the basis of the CD spectra of (–)-2 and (–)-2,2-spirobi-(5,6,7,8-tetrahydrobenzo[f]indane). From the molar rotations of these 4,4-disubstituted 2,2-spirobiindanes (empirical) ligand parameters were determined (using the so-called shortened approach). Generally, the values of in these compounds are higher than those of the analogous tetrahydrobenzoindane derivatives.
Herrn Prof. Dr.F. Sauter mit besten Wünschen zum 65. Geburtstag gewidmet 相似文献
17.
E. E. Sirotkina N. V. Moskalev I. G. Shabotkin 《Chemistry of Heterocyclic Compounds》1984,20(5):512-514
It is shown that the trifluoroacetylation of 9-methylcarbazole proceeds regio-specifically in the 3 position of the ring. 1,1,1-Tris(9-methyl-3-carbazolyl)-2,2,2-trifluoroethane and 1,1,1,1-tetrakis(9-methyl-3-carbazolyl)-2,2,2,2,2,-2-hexafluorodiethyl ether were also isolated from the reaction mixture. Bis(trifluoroacetyl) derivatives were not detected. Only a 3-trifluoroacetyl derivative is formed when the reaction is carried out by heating in the presence of pyridine.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 640–642, May, 1984. 相似文献
18.
Syntheses are reported for monomers and oligomers of dipropyl and di(propen-1-yl) (cis,cis and cis, trans isomers) ethers of 2-(4 -hydroxy-3, 5 -diethynylphenyl)- 2-(4-hydroxyphenyl)propane.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1668–1670, July, 1991. 相似文献
19.
A. V. Fokin E. B. Bogachuk N. P. Vorob'eva N. I. Raevskii Yu. A. Borisov A. F. Kolomiets 《Russian Chemical Bulletin》1991,40(1):86-89
The MNDO method has been used to calculate the electronic and geometric structure of 3,3,4,4-tetraehloroazoxybenzene (TCAOB), 3,3,4,4-tetrachloro-6-hydroxyazobenzene (TCHAB), and 2,3,7,8-tetrachlorodibenzofuran (TCDF). The TCAOB exists in the gas phase in the form of two configurations, one nonplanar and one nearly planar. The latter is approximately 4 kcal/mole less stable than the first. The oxidation of 3,3,4,4-tetrachloroazobenzene (TCAB) to TCAOB is endothermic only in the case of the acton of hydrogen peroxide, not molecular oxygen. The isomerization of TCAOB to TCHAB proceeds with a gain in energy (–62 kcal/mole); however, the reaction from the ground state of the TCAOB molecule is symmetry-forbidden and is possible only from an excited state of the TCAOB. The process of oxidation of TCAOB and TCHAB by molecular oxygen to form TCDF or 2,3,7,8-tetrachlorobenzo-p-dioxin is energy-favorable; this is important in judging the biological action of TCAOB.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 101–105, January, 1991. 相似文献
20.
Yuldashev M. P. Batirov É. Kh. Vdovin A. D. Malikov V. M. Yagudaev M. R. 《Chemistry of Natural Compounds》1989,25(3):303-308
From the epigeal part ofThermopsis alterniflora Rgl.et Schmalh. (Fabaceae), in addition to formononetin, ononin, cynaroside, and rothindin, two new acylated flavone glycosides have been isolated and, on the basis of chemical transformations and spectral characteristics, their structures have been established as 4,5,7-trihydroxy-3-methoxyflavone 7-O-(6-O-crotonoyl--D-glucopyranoside) and 4,5,7-trihydroxyflavone 7-O-(6-O-crotonoyl--D-glucopyranoside).Institute of the Chemistry of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 352–359, May–June, 1989. 相似文献