共查询到15条相似文献,搜索用时 78 毫秒
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采用金刚石压砧高压装置,研究了双钙态矿结构化合物Sr2FeNbO6及其掺杂物Sr2FeMo0.3Nb0.7O6在室温下,20 GPa内电阻和电容随压力的变化,并发现Sr2FeNbO6在7.5 GPa左右压力下发生了相变,而Sr2FeMo0.3Nb0.7O6的相变发生在2.8 GPa左右。并结合这两个样品的高压下的同步辐射能散X射线衍射实验,进一步证明了这两种相变是电子结构相变引起的。 相似文献
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La2/3Ca1/3MnO3的巨磁熵效应 总被引:6,自引:0,他引:6
本文对超大磁阻材料La2/3Ca1/3MnO3的巨磁熵效应进行了研究,通过测量不同磁场下的磁化-温度曲线,发现伴随铁磁-顺磁相变有一个大的磁熵变化,这个结果表明钙钛矿锰氧化物可以作为磁致冷技术中的工作物质。 相似文献
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用高温高压法、在1 260 ℃和5.0 GPa条件下,成功制备出电子型掺杂层状钙钛矿结构锰氧化物La2-2xCa1+2xMn2O7(x=1.0~0.8)系列样品。样品的粉末X射线衍射实验和Rietveld精修结构分析表明,所制样品具有Sr3Ti2O7型四方结构,空间群为I4/mmm。随着电子浓度的增加,MnO6八面体畸变程度增大,晶胞体积增加。同时样品的磁化强度随La的掺入、x的增加而增强,反铁磁有序温度TN提高。由于双交换作用减小,样品的电阻增加。在测量温度范围内,没有观测到磁电阻效应。 相似文献
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利用固相反应合成了纯相的Sr2FeMoO6多晶块体,并通过机械球磨方法引入了人工晶界,研究了具有此种晶界的Sr2FeMoO6粉末磁电阻的温度特性.X射线衍射分析表明,机械球磨过程没有改变Sr2FeMoO6的晶体结构,但却在晶粒间界处引入了SrMoO4绝缘相,其量随着球磨时间的增加而增加.不同磁场下的磁电阻测量结果表明,由于一定量SrMoO4绝缘相的存在,晶粒间的绝缘隧穿势垒得到加强,更有利于自旋极化电子在晶粒间的隧穿,从而提高了Sr2FeMoO6多晶粉末的低温磁电阻值.然而随着温度的升高,磁电阻值迅速下降,表现出较强的温度依赖关系.这种现象是由于随着温度的升高,电子在晶界局域态间的非弹性跳跃逐渐增强引起的,而晶界局域态是由在晶界附近的大量缺陷构成.分析表明,晶界状态对Sr2FeMoO6多晶粉末磁电阻的温度特性有十分重要的影响. 相似文献
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We propose a new mechanism to explain the magnetic structure of a recently discovered magnetoresistive double perovskite oxide
system, Sr2FeMoO6, with the help of detailed experimental and theoretical results. This model, based on a strong antiferromagnetic coupling
between the local moment and the charge carriers arising from local hopping interactions, can give rise to ferromagnetic metallic
as well as ferromagnetic insulating ground states. The relevance of this mechanism in understanding the magnetism in dilute
magnetic semiconductors such as Ga1 − x
Mn
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As, is also discussed. 相似文献
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《Current Applied Physics》2018,18(1):27-33
Single-phase agglomerated Sr2FeMoO6-δ powders with the iron and molybdenum cations superstructural ordering of 88% were synthesized by sol-gel technique from the Sr(NO3)2 and Fe(NO3)3·9H2O solutions with pH = 4. The ultrasound dispersion enabled us to obtain 75 nm grains. Powders were pressed with 4 GPa to receive the ceramics. The additional annealing at 700 K promoted the appearance of 7.5% SrMoO4 phase. The nanocomposite with dielectric sheaths around the grains was obtained. Magnetization temperature dependences in zero-field cooled mode revealed inhomogeneous magnetic states. At temperature below 19 K, the superparamagnetic state is observed. Temperature increase leads to a realization of the stable superparamagnetic and metastable ferrimagnetic states, blocked by magnetic anisotropy energy. The resistivity temperature dependences have the semiconducting conductivity type. The charge transfer due to the hopping conductivity on the localized states in the energy band near the Fermi level dominates at 260–300 K. At 130–200 K the charge transfer is realized by electrons tunneling through the energy barrier. The electrons inelastic tunneling on conducting channels between grains, through the localized states in the dielectic interlayer dominates at low temperatures. The resistivity decreases in magnetic fields and the negative tunneling magnetoresistive effect reaching 41% occurs. 相似文献
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《中国物理快报》2017,(7)
The work functions of the(110) and(100) surfaces of LaB_6 are determined from ambient pressure to 39.1 GPa.The work function of the(110) surface slowly decreases but that of the(100) surface remains at a relatively constant value. To determine the reason for this difference, the electron density distribution(EDD) is determined from high-pressure single-crystal x-ray diffraction data by the maximum entropy method. The EDD results show that the chemical bond properties in LaB_6 play a key role. The structural stability of LaB6 under high pressure is also investigated by single-crystal x-ray diffraction. In this study, no structural or electronic phase transition is observed from ambient pressure to 39.1 GPa. 相似文献
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We conduct extensive research into the structures of BexZn1-xOO ternary alloys in a pressure range of 0-60GPa,using the ab initio total energy evolutionary algorithm and total energy calculations,finding several metastable structures.Our pressure-composition phase diagram is constructed using the enthalpy results.In addition,we calculate the electronic structures of the BexZn1-xOO structures and investigate the bandgap values at varying pressures and Be content.The calculated results show that the bandgap of the BexZn1-xOO ternary alloys increases with an increase in Be content at the same pressure.Moreover,the bandgap of the BexZn1-xOO ternary alloys increases with the increasing pressure with fixed Be content.At the same Be content,the formation enthalpy of the BexZn1-xOO ternary alloys first decreases,then increases with the increasing pressure. 相似文献