Anisotropy of the nonlinear optical susceptibility χ(3) in polydiacetylene single crystals

The anisotropy of ⁽³⁾ in Poly-bis(p-Toluene Sulfonate) of 2.4-hexadiyne-1.6-diol (PTS) PolyDiAcetylene (PDA) single crystals is investigated by Degenerate Four-Wave Mixing (DFWM) at a wavelength of 720 nm. The symmetries of ⁽³⁾(–;, –,) identify the non-vanishing and independent components of the tensor. For the calculation of the ⁽³⁾ elements from the measured values, the anisotropy of both the linear optical index of refraction and the absorption coefficient is included in the coupled wave approach. A magnitude of 10^–10 esu is measured for the ⁽³⁾ component if all beam polarizations are parallel to the polymer chains. The least upper bound for all other measurable components is estimated to be 10^–12 esu. The results for the intensity dependence of the DFWM signal are explained in terms of a thermooptic effect. Measurements on the orientational dependence of the DFWM signal in the samples are carried out, and the influence of the anisotropy of the linear optical parameters on the measured curves is discussed. A method for the preparation of thin layered polymer single crystals of poly-bis (4-ButoxyCarbonyle-Methylene-Urethane) of 4.6-decadiyne-1.1-diol (4-BCMU) and the first DFWM measurements on these samples are presented.     

ВЫРАЩИВАНИЕ МОНОКРИСТАЛЛОВ ТИТА НАТА БАРИЯ

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Quark model based relativistically invariant meson exchange forces for two-nucleon scattering

A momentum space OBEP for the two-nucleon scattering is constructed starting from a relativistically invariant quark model predictions of the meson-nucleon coupling constants. Taking a relativistic meson propagators and working in a quasipotential Blankenbecler-Sugar two-nucleon dynamics the relativistic invariance of the whole problem is maintained. The NN forces are generated by an exchange of the, , , ,(600),, , and mesons. Phenomenological form factors for all meson-nucleon vertices and effective (600) and meson-nucleon couplings are utilized. The calculated NN phase shifts are in good agreement with the empirical data and with the predictions of the conventional Bonn OBEP model.The authors are indebted to G. V. Efimov, M. A. Ivanov and J. Lanik for many fruitful discussions. This work was partially supported by the Grant Agency of the Slovak Academy of Sciences under Contract No. GA-SAV-141/1992 and Contract No. GA-SAV-517/1992.     

Differential calculus on quantum spheres

Three-dimensional differential calculus on quantum spheres S _infc ^sup2 ,]–1, 1[{0}, c[0, ], is introduced and investigated. Spectra of generalized Laplacians are found. These operators are expressed by generalized directional derivatives. Classical limits of these objects are obtained and a simple approach to quantum mechanics on a quantum sphere is presented.     

On the determination of the position of the energy level of surface recombination centres

A detailed analysis of the dependence of the surface recombination velocitys on the surface potential _s leads to the conclusion that the position of the surface recombination level with respect to the centre of the energy gapE _t -E _i does not coincide with the valueq _s *, while the surface recombination velocitys decreases to half its maximum value. The difference between the two quantities is negligible only when the width of the curves( _s ) between the points corresponding to the valuess=1/2s _max is greater than 8kT.

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s _s , E _t -E _{i s} , s . , s( _s ) , s=1/2s _max, 8kT.

     

Analytic study of power spectra of the tent maps near band-splitting transitions

Successive band-splitting transitions occur in the one-dimensional map x_i+1=g(x_i),i=0, 1, 2,... withg(x)=x, (0 x 1/2) –x +, (1/2 <x 1) as the parameter is changed from 2 to 1. The transition point fromN (=2ⁿ) bands to 2Nbands is given by=(2)^1/N (n=0, 1,2,...). The time-correlation function _i=x_ix₀/(x₀)²,x_i x_i–x_i is studied in terms of the eigenvalues and eigenfunctions of the Frobenius-Perron operator of the map. It is shown that, near the transition point=2, _i–[(10–42)/17] _i,0-[(102-8)/51]_i,1 + [(7 + 42)/17](–1)ⁱe^–yi, where2(–2) is the damping constant and vanishes at=2, representing the critical slowing-down. This critical phenomenon is in strong contrast to the topologically invariant quantities, such as the Lyapunov exponent, which do not exhibit any anomaly at=2. The asymptotic expression for _i has been obtained by deriving an analytic form of _i for a sequence of which accumulates to 2 from the above. Near the transition point=(2)^1/N, the damping constant of _i fori N is given by _N=2(^N-2)/N. Numerical calculation is also carried out for arbitrary a and is shown to be consistent with the analytic results.     

Perturbations of flows on Banach spaces and operator algebras

For automorphism groups of operator algebras we show how properties of the difference _t – ' _t are reflected in relations between the generators , . Indeed for a von Neumann algebraM with separable predual we show that if _t – '_t 0.28 for smallt, then = 0(+)°^-1 where is an inner automorphism ofM and is a bounded derivation ofM. If the difference _t – ' _t =O(t) ast ; 0, then = + and if _t – ' _t 0.28 for allt then =. We prove analogous results for unitary groups on a Hilbert space andC ₀,C ₀ ^* groups on a Banach space.This paper subsumes an earlier work of the same title which appeared as a report from Z.I.F. der Universität BielefeldWith partial support of the U.S. National Science Foundation     

Some properties of topological geons

We investigate the Finkelstein-Misner geons for a non-simply-connected space-time manifold (M, g ₀). We use relations between different Lorentzian structures unequivalent tog ₀ and topological properties ofM given by the Morse theory. It implies that to some pieces of geons we have to associate Wheeler's worm-holes. Geons that correspond to time-orientable Lorentz structures are related tog ₀ by Morse functions that describe the attaching of a handle of index one. In the case of geons associated to time-nonorientable Lorentzian structures, appropriate handles are related to loops along which the notion of time reverses. If we assume electromagnetic properties of geons, then only four species, v, e, p, m, of different geons can exist and geon m has to decay according to mv+p+e.     

The semi-conducting properties of CdSnAs2

The paper gives the results of measuring the temperature dependence of the electrical conductivity(T), the Hall coefficientR _H (T) and the magnetic susceptibility(T) forn-type CdSnAs₂. The effective mass of the electrons was determined by analysis of the measured dependences on the basis of the simple theory for an isotropic non-degenerate semi-conductor. It was found to bem _n /m ₀=2×10^–2 in the intrinsic region and does not depend on the temperature; the energy gap ise _g ⁰=0·26 eV and the molar susceptibility of the CdSnAs₂ lattice _G ^mol=–112× ×10^–6. The mobility of the electrons in the intrinsic region reaches a value of _n =25 000 cm²V^–1sec^–1 at 500°K and decreases exponentially _n T ^–1.67 with rising temperature. The density of CdSnAs₂ was determined pyknometrically,g9=5·35 g cm^–3. The measurements were made on ann-type polycrystalline sample consisting of crystals a few millimetres in diameter, which at a temperature of 100°K had a free electron concentration ofn _s =6×10¹⁶ cm^–3.

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CdSnAs₂

(T), R _H (T) (T) CdSnAs₂ . m _n /m ₀= =2.10^–2, ; E _G ⁰=0,26 eV, CdSnAs_{2 G} ^mol= =–112.10^–6. 500°K _n =25 000 cm²V^–1sec^–1 , _n T ^–1,67. CdSnAs₂ =5,35 g cm^–3. , , 100°K n _s =6.10¹⁶cm^–3.

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The authors would like to thank Mr. P. Jansa for help in measuring the temperature dependence of the magnetic susceptibility.     

Plasma oscillations and dynamical friction

The forceF of mutual interaction of two species of charged particles in relative motion with velocityU is, forU higher than the mean thermal velocities of particles, a decreasing function ofU. This property ofF(U) can give rise to the excitation of electrostatic oscillations.

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F, copta , U, U, , , U. F(U) .

     

Electronic processes andZ centres in NaCl and KC1 crystals

The paper gives the experimental results of the team-work study of coloured pure and Ca doped NaCl and KC1 crystals. The mechanism of the formation ofR centres by coagulation ofF centres and of the formation ofZ centres fromF centres, cation vacancies and Ca ions is discussed. An alternative model forZ ₃ centres is proposed. The possible connections between physical and chemical behaviour are indicated.

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Z- NaCl 1

NaCl KCl . R- F- Z- F-, Ca. Z ₃-. .

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This work was presented by the courtesy of Prof. R. Maurer at the Symposium on Color Centers, Corvallis, Oregon (1959).

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The authors wish to express their gratitude to K. Suk, K. Listoová and M. Javrková for carefully carrying out the measurements and I. Kunzlová and L. Nováková for preparing the crystals.     

Growth of correlation in the Hopfield model

Introducing a finite correlation ₀ between any two learned patterns (others remaining uncorrelated), we observe in a numerical simulation that the Hopfield model stores these two patterns with correlation _f such that _f0 for any loading capacity. The patterns are memorized perfectly (with _f= ₀) up to -0.05 for finite correlations ₀ not exceeding a value _c(), where _c() decreases continuously to zero at -0.05.     

Four-wave mixing in CO via the C 1Σ+ (υ′=0) state

Coherent vacuum ultraviolet (VUV) radiation was generated by four-wave difference frequency mixing (_VUV=2₁–₂) of pulsed dye laser radiation in carbon monoxide (CO). The frequency ₁ was tuned to the C ¹⁺(=0)X ¹⁺(=0) two-photon transition, while the dye laser frequency ₂ was scaned around 17650 cm^–1 which corresponds to the A ¹(=7)«C ¹⁺(=0) transition energy. The VUV intensity was found to be strongly wavelength dependent. The analysis of the spectrum revealed (i) that the VUV intensity was enhanced by the rotational levels of the A ¹(=7) state and (ii) that the off-resonance excitation in the C ¹⁺(=0)X ¹⁺(=0) two-photon transition greatly contributed to the present four-wave mixing process. The effects of pumping laser detuning, saturation and foreign gases are briefly discussed.     

Stability domain of coherent laser waves

The constant-amplitude solutions with wavelength of a semiclassical laser model exhibit three different instabilities in the (, )-plane for pumpparameters above threshold.     

Symmetries and half-sided modular inclusions of von Neumann algebras

LetN, be a von Neumann algebras on a Hilbert space , a common cyclic and separating vector. Assume to be cyclic and also separating forN . Denote by , _N , _N the modular operators to (, ), (N, ), resp (N , ). Assume now ^-it N ^it N for allt 0. (Such type of inclusions ((N U, ) , ) are called half-sided modular.) Then the modular groups ^it , _N ^ir , _N ^is ,t, r, s generate a unitary representation of the group S1(2, )/Z ₂ of positive energy.Another result is related to two half-sided modular inclusions (₁ , ) and (₂ , ). Under proper conditions the three modular groups ^it , ₁ ^ir , ₂ ^is ,t, r, s generate the three-dimensional subgroup of O(2, 1) of two commuting translations and the Lorentz transformation.Partly supported by the DFG, SFB 288 Differentialgeometrie und Quantenphysik.     

Band-gap structure of the spectrum of periodic Maxwell operators

We investigate the band-gap structure of some second-order differential operators associated with the propagation of waves in periodic two-component media. Particularly, the operator associated with the Maxwell equations with position-dependent dielectric constant (x),xR ³, is considered. The medium is assumed to consist of two components: the background, where (x) = _b , and the embedded component composed of periodically positioned disjoint cubes, where (x) = _a . We show that the spectrum of the relevant operator has gaps provided some reasonable conditions are imposed on the parameters of the medium. Particularly, we show that one can open up at least one gap in the spectrum at any preassigned point provided that the size of cubesL, the distancel=L betwen them, and the contrast = _b / _a are chosen in such a way thatL ^–2, and quantities ^-1-3/2 and ² are small enough. If these conditions are satisfied, the spectrum is located in a vicinity of widthw(^3/2)^-1 of the set {² L ^-2 k ²:kZ³}. This means, in particular, that any finite number of gaps between the elements of this discrete set can be opened simultaneously, and the corresponding bands of the spectrum can be made arbitrarily narrow. The method developed shows that if the embedded component consists of periodically positioned balls or other domains which cannot pack the space without overlapping, one should expect pseudogaps rather than real gaps in the spectrum.     

Bohr's discussion of the fourth uncertainty relation revisited

Bohr's 1930 derivation of the uncertainty relation c ² m th bears a close relationship to Einstein's 1913 derivation of the gravitational redshift via the equivalence principle. A rewording of Bohr's argument is presented here, not taking the last step of acceleration as equivalent to a uniform gravity field, thus yielding a derivation of the formula c ² m th, avoiding Treder's 1971 objection.     

The ground state energy of Sdhrödinger operators

We studye()=inf spec(-+V) and examine whene()<0 for all 0. We prove thatc ²e()–d ² for suitableV and all small ||.Research partially funded under NSF grant number DMS-9101716.     

Feynman integral and complex classical trajectories

Let _t be an analytic solution of the Schrödinger equation with the initial condition . Let _t be the solution of the Schrödinger equation with the initial condition =, where is an analytic function. When 0, then _t (x) _t (x)¹ ( _t (x)), where _t (x) trajectory starting from x. We relate this result to Feynman's sum over trajectories and complex stochastic differential equations.     

The quantum theory of multipole radiation in a dielectric

The potentials of an electromagnetic field of multipoles in a dielectric, which is realized by a dielectric sphere having a perfectly conducting surface, are derived. The diagonal values of the energy for thez component of the angular momentum and the square of the angular momentum of the field are determined and also the ratio between thez component of the angular momentum and the energy and the ratio between the square of the angular momentum and the square of the energy. It is shown that the total angular momentum can be divided in the usual way into orbital and spin parts but that these parts cannot be interpreted as the orbital and spin angular momentum because their eigenvalues cannot be the eigenvalues of any operator of infinitesimal rotation. In the commutation rules of a multipole field the vector character of the field is to a certain extent suppressed and the spin of the photon in a state with a certain value of the energy, parityz component of the angular momentum and the square of the angular momentum is not defined.

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, . ,z— , , z— . , , , , , - . , ,z— .

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In conclusion the author thanks Dr. . Muziká for directing the work, F. Samek for valuable remarks and discussion and J. Kvasnica for help in preparing the paper for publication and for adding a number of remarks.