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1.
Data on classification of spectra and energy levels of atoms of rare earth elements with unfilled 4f-shells have been collected, systematized and analyzed. A brief account is given of methods for determining transition probabilities and lifetimes of the excited states of atoms and ions. Oscillator strengths for spectral lines of Nd(I), Sm(I), Eu(I), Gd(I), Dy(I), Tm(I) and Yb(I) have been measured using Rojdestvensky's hook method. Lifetimes of some of the excited states of Eu(I), Yb(I) and Yb(II) have been determined by using simultaneously the methods of delayed coincidence, hooks, and total absorption. Our results have been compared with those of other investigators. Atoms with unfilled 4f-shells show some regularities.  相似文献   

2.
An efficient diastereoselective synthesis of 7-ethyl 5,6-dialkyl 7H-[1,3]thiazolo[2,3-b][1,3]oxazin-5,6, 7-tricarboxylates and 2-ethyl 3,4-dialkyl 2H-[1,3]oxazino [2,3-b][1,3]benzothiazole-2,3,4-tricarboxylates via reaction of thiazole and benzothiazole with dialkyl acetylenedicarboxylates in the presence of ethyl pyruvate is described.  相似文献   

3.
Abstract

High resolution electron microscopy has shown that a modulated structure occurs in the Bi[sbnd]Sr[sbnd]Ca[sbnd]Cu[sbnd]O system. Electron diffraction and x-ray diffraction observations show that this modulation produces extra reflections. Diffraction patterns of the Pb-free material have superstructure reflections with wave vectors [0, 1/4.7, 1] and [0, ?1/4.7, 1]. These two waves vectors can generate all of the superstructure relections associated with each fundamental reflection. When PbO is added to the BSCCO system a new wave vector [0. 1/8.5, 0] is introduced. Observations show that within a single grain the two wave vectors coexist for a Pb and Bi ratio of about 0.25. This produces a non-uniform modulated structure which may be due to a superposition of the two wave vectors. The intensity of the [0, 1/4.7, 1] wave vector is substantially reduced in the Pb-modified material. The b' component of both wave vectors in incommensurate with the lattice period. The same superstructures occurs in both the low-Tc phase and the high-Tc phase.  相似文献   

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The possibility that diquark is a stable object in hadrons and there exists a global supersymmetry between quarks and antidiquarks is discussed. Mesons, baryons and baryoniums can be classified unitedly in the adjoint representation of the super-symmetry group. The united mass splitting formula is obtained based on the snpersymmetry and a naive physical mechanism for symmetry breaking. The mass spectra for baryonium ground states are obtained numerically and may be verified experimentally, Some significant characteristics of baryoniums are discussed and can be used as evident indications of the appearance of加ryoniums.  相似文献   

6.
The contribution of the nasal murmur and the vocalic formant transitions to perception of the [m]-[n] distinction in utterance-initial position preceding [i,a,u] was investigated, extending the recent work of Kurowski and Blumstein [J. Acoust. Soc. Am. 76, 383-390 (1984)]. A variety of waveform-editing procedures were applied to syllables produced by six different talkers. Listeners' judgments of the edited stimuli confirmed that the nasal murmur makes a significant contribution to place of articulation perception. Murmur and transition information appeared to be integrated at a genuinely perceptual, not an abstract cognitive, level. This was particularly evident in [-i] context, where only the simultaneous presence of murmur and transition components permitted accurate place of articulation identification. The perceptual information seemed to be purely relational in this case. It also seemed to be context specific, since the spectral change from the murmur to the vowel onset did not follow an invariant pattern across front and back vowels.  相似文献   

7.
This study complements earlier experiments on the perception of the [m]-[n] distinction in CV syllables [B. H. Repp, J. Acoust. Soc. Am. 79, 1987-1999 (1986); B. H. Repp, J. Acoust. Soc. Am. 82, 1525-1538 (1987)]. Six talkers produced VC syllables consisting of [m] or [n] preceded by [i, a, u]. In listening experiments, these syllables were truncated from the beginning and/or from the end, or waveform portions surrounding the point of closure were replaced with noise, so as to map out the distribution of the place of articulation information for consonant perception. These manipulations revealed that the vocalic formant transitions alone conveyed about as much place of articulation information as did the nasal murmur alone, and both signal portions were about as informative in VC as in CV syllables. Nevertheless, full VC syllables were less accurately identified than full CV syllables, especially in female speech. The reason for this was hypothesized to be the relative absence of a salient spectral change between the vowel and the murmur in VC syllables. This hypothesis was supported by the relative ineffectiveness of two additional manipulations meant to disrupt the perception of relational spectral information (channel separation or temporal separation of vowel and murmur) and by subjects' poor identification scores for brief excerpts including the point of maximal spectral change. While, in CV syllables, the abrupt spectral change from the murmur to the vowel provides important additional place of articulation information, for VC syllables it seems as if the format transitions in the vowel and the murmur spectrum functioned as independent cues.  相似文献   

8.
This work is devoted to the investigation of physical processes in a non-equilibrium plasma of a binary mixture of inert gases. The degree of radial separation of the mixture was found to increase with increasing pressure of buffer gas and discharge current and to decrease with growing partial pressure of the admixture. The correlation of the radial and axial types of separation was shown experimentally. The kinetics of population of the metastable states He(23S) and Xe(3P22) and of charged particles was investigated using an impulse regime. The time for the establishment of the stationary state of the radial distribution of the components was found to be several times less than the time of reestablishment of the homogeneous distribution of the atomic component after switching off the discharge impulse. The phenomenon of a decreasing effective diffusion length of the discharge was found. This effect has essential influence on the time for the establishment of the stationary state of radial cataphoresis.  相似文献   

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The parametric excitation of longitudinal waves in an infinite homogeneous plasma by a pump field E (t) = E 0(t) sin (ω0t + φ(t)) is studied on the basis of the Vlasov equation, where the amplitude E 0(t) and the phase φ(t) are slowly varying compared with ω0 periodic functions. Firstly it is assumed that ω0 is much larger than the electron plasma frequency ωLe. In the second part the parametric instabilities are considered under the resonance condition ω0 ≈ ωLe. In both parts the threshold fields for the excitation of the longitudinal waves and their growth rates are calculated. As an example these values are analysed for both a sequence of pump impulses and a phase-moduated pump field. They are compared with the results received for a monochromatic pump field.  相似文献   

11.
The plasmon turbulence parametrically excited by two strong external waves with a frequency difference close to twice the electron plasma frequency is investigated in underdense plasmas. The nonlinear stabilization of the growing plasmons due to scattering by ions is described by a nonlinear integro-differential equation for the spectral plasmon energy density. The dependence of the turbulent relaxation of the plasmon energy and its stationary level on the parameters of the plasma and the pump waves is given by analytical and numerical solutions of this equation.  相似文献   

12.
A nonlinear theory of the interaction of an external pump field with ion-acoustic and h.f. surface waves in a plasma layer with inhomogeneous boundary regions is presented for the case, when the pump field frequency is less than the electron plasma frequency. The evolution of the parametrically excited turbulence and its stationary state are both analytically treated and numerically demonstrated. Dependent on the pump field strength, two mechanisms are to be distinguished: (i) nonlinear generation of damped ion-acoustic harmonics, (ii) cascade excitation of secondary eigenmodes by growing surface oscillations. At only slight overthreshold values, mechanism (i) is responsible for the occurence of the steady state, whereas, for higher pump field strength, the wave amplitudes as well as their saturated levels are mainly determined by mechanism (ii).  相似文献   

13.
We review the problem of dark energy, including a survey of theoretical models and some aspects of numerical studies.  相似文献   

14.
A theory of the magneto-acoustic radiation from an upper-hybrid soliton moving in an inhomogeneous magnetoactive plasma is presented. The derived expression for the spatial distribution of the radiation field is analysed for a linear and two different parabolic density profiles. The energy flux density connected with the transversal part of the magneto-acoustic waves is investigated.  相似文献   

15.
Some aspects of the theory of fluctuating microfield in a system of charged particles are considered. The question concerning regions of validity for Holtsmark-like and Gauss-like microfield distributions in a rarefied and a dense plasma is discussed. The influence of finite dimensions of particles (test particles as well as field particles) on the microfield distribution is investigated. Expressions for a “dynamic” (two-time) generalization of the Holtsmark distribution are obtained for limiting cases. By methods of microfield theory certain formulas for the fluctuations of the electric charges within a finite volume of an electrolyte are derived too.  相似文献   

16.
In this Letter, we find that Morse potential(proposed about 90 years ago) could be connected to Coulomb potential(or Newton potential) and harmonic potential(or Hooke potential) by conformal mappings. We thereby design a new conformal lens from Morse potential, Eaton lens, and Luneburg lens and propose a series of generalized Eaton/Luneburg lenses. We find that this Morse lens is a perfect self-focusing asymmetric lens that differs from a Mikaelian lens. Our theory provides a new insight to Morse potential and other traditional potentials, and revisits their classical applications on designing lenses.  相似文献   

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The stability of the electromagnetic plasma confinement by powerful external s-polarized pump waves is considered. The parametric excitation of standing electromagnetic waves along the plasma boundary with frequencies close to the frequency of the pump wave leads to a periodic density modulation of the plasma boundary. The density disturbances along the direction of the external wave field are connected to the excitation of transverse p-polarized surface waves while the modulation in the direction perpendicular to the pump field are created by the parametric interaction between the external wave and s-polarized trapped leaking oscillations. Only when the leaking waves are excited the scale length of the modulation is larger than half the free space wave length of the incident radiation.  相似文献   

20.
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