Controllable synthesis of CuFe2O4 nanostructures through simple hydrothermal method in the presence of thioglycolic acid

In this paper a novel and simple route for the preparation of copper ferrite (CuFe₂O₄) is proposed. The present investigation reports, the novel synthesis of CuFe₂O₄ samples C1, C2, C3 and C4 using hydrothermal method and its physicochemical characterization. In order to elucidate the relationship between the constituent, structure, magnetic and PL properties product's particle size, morphological and structural properties were characterized by the X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), photoluminescence (PL) and magnetic properties. The crystallization, surface morphology, magnetic properties and luminescence properties of the samples have been investigated. The relatively high Ms of the samples suggests that this method is suitable for preparing high-quality nanocrystalline copper ferrites for practical applications. Different mechanisms to explain the obtained results and the correlation between magnetism and structure are discussed.     

Deep inelastic scattering with proton target in the presence of gluon condensation using holography

We study the deep inelastic scattering (DIS) of a proton-targeted lepton in the presence of gluon condensation using gauge/gravity duality. We use a modified begin{document}${rm AdS}_5$end{document} background where the modification parameter c corresponds to the gluon condensation in the boundary theory. First, by examining the electromagnetic field, we establish that a non-zero c can increase field magnitude. Our aim is to obtain the acceptable value of c for this scattering. Our method is based on setting the mass of the proton as an eigenvalue of the baryonic state equations of the DIS to find the acceptable value of the parameter c on the other side of the equations. Therefore, in the second step, we calculate wave function equations for the baryonic states where the mass of the proton target requires a value contribution of c as begin{document}$ c=0.0120 ; rm GeV^4 $end{document}. Proceeding with the electromagnetic field and baryonic states, we derive the holographic interaction action related to the amplitude of the scattering. Finally, we compute the corresponding structure functions numerically as functions of x and q, which are Bj?rken variables and the lepton momentum transfers, respectively. Comparing the Jlab Hall C data with our theoretical calculations, our results are acceptable.     

Synthesis of multi-functionalized benzofurans through the condensation of ninhydrin and phenols using SSA as a recyclable heterogeneous acid catalyst

A simple and efficient one-pot methodology has been developed for the synthesis of biologically important multi-functionalized 3-(2\(^{\prime }\)-hydroxyaryl)-2-(2\(^{\prime }\)-carboxyphenyl)benzofurans using silica sulfuric acid (SSA) as a heterogeneous acid catalyst in DMF medium. The significant advantages of this methodology are the use of SSA as a recyclable solid acid catalyst, operational simplicity, easy availability of the starting materials, and good yield of the products with high atom-economy.     

Parallel synthesis of a series of non-functional ATP/NAD analogs with activity against trypanosomatid parasites

Non-functional analogs of the cofactors ATP and NAD are putative inhibitors of ATP- or NAD-dependant enzymes. Since pathogenic protozoa rely heavily on the salvage of purine nucleosides from the bloodstream of their host, such compounds are of interest as antiplasmodial and antitrypanosomal agents with a multitude of molecular targets. By replacing the negatively charged phosphate residues with a constrained unsaturated amide spacer and the nicotinamide moiety of NAD with various lipophilic substituents, 15 new ATP/NAD analogs were obtained in screening quantities. In these compounds, a 5′-desoxyadenosine moiety was conserved as key molecular recognition motif. The inhibition of P. falciparum and T. brucei ssp. in a whole parasite in vitro assay is reported.     

Changes in wetting properties of silica surface treated with DPPC in the presence of phospholipase A2 enzyme

Wetting properties of silica plates contacted with dipalmitoylphosphatidylcholine (DPPC) or DPPC/enzyme (phospholipase PLA₂) in NaCl solution were determined by thin layer wicking and with a help of Washburn equation. The wicking experiments were performed both for bare plates and the silica plates precontacted overnight with the probe liquid saturated vapors the silica plates, as well as untreated and DPPC (or DPPC/enzyme) treated. Adsorption of DPPC on original silica plates increases a bit hydrophobic character of silica surface in such a way that hydrocarbon chains are directed outwards and the polar part towards the silica surface. However, after the enzyme action the products of DPPC hydrolysis by PLA₂ (palmitic acid and lysophosphatidylcholine) increase again hydrophilic character of silica surface (an increase in acid-base interactions, ).The changes of silica surface wettability are evidently dependent on the time of enzyme contacting with DPPC in NaCl solution. Although, the changes of total surface free energy of silica after treatment with DPPC/enzyme solution are minor about 2-6 mJ/m², the changes of the electron-donor () and Lifshitz-van der Waals () component of the surface free energy are noticeable. Despite, these results are somehow preliminary, it seems that thin layer wicking method is an interesting tool for investigation of the effect of adsorbed DPPC on hydrophobicity/hydrophilicity of silica surface and influence of enzyme PLA₂ action.     

The inhibition of corrosion of mild steel in 0.5 M sulfuric acid solution in the presence of benzyl triphenyl phosphonium bromide

Benzyl triphenyl phosphonium bromide (BTPPB) has been evaluated as a corrosion inhibitor for mild steel in aerated 0.5 M sulfuric acid solution by galvanostatic polarization and potentiostatic polarization methods. The effect of BTPPB on the corrosion current is measured at various temperatures and concentrations. The inhibitor efficiencies, effective activation energies and heat of adsorption have been calculated. The inhibition efficiency increases with increase in inhibitor concentration to reach 99.3% for 10⁻² M. The nature of adsorption of BTPPB on the metal surface has also been examined. Probable mode of adsorption on the metal surface has been proposed using infrared spectroscopic studies. The electrochemical results have also been supplemented by surface morphological studies and quantum chemical analysis.     

Surface tracer diffusion in the presence of a solid barrier: a Monte Carlo study

We investigate, by way of Monte Carlo simulations, the diffusion of adsorbates on a square lattice. The lattice contains inaccessible sites forming linear barriers. The adsorbate atoms do not interact among themselves, except for the hard core. The tracer diffusion coefficients, reduced by their values in the absence of the barrier, are plotted versus the length of the barrier. We find that the diffusion along the barrier is not affected by its presence, whereas that perpendicular to it decreases linearly, for a large interval of the barrier, with its length. The reduced diffusion coefficient does not depend on the concentration of the diffusing particles, but its value increases with the perpendicular distance between the barriers.     

Novel multicomponent reactions involving isoquinoline or phenanthridine and activated acetylenic ester in the presence of heterocyclic NH or 1,3-dicarbonyl compounds

Multicomponent reactions involving azines (phenanthridine or isoquinoline) and dimethyl acetylenedicarboxylate were undertaken in the presence of heterocyclic NH compounds (indole, 2-methyl indole, 3-methyl indole, carbazole and 3,6-dibromocarbazole) or 1,3-dicarbonyl compounds such as N,N'-dimethylbarbituric acid, 1,3-diethyl-2-thiobarbituric acid, acetylacetone, 1,3-diphenyl-1,3-propandione and cyclopentan-1,3-dione to generate enaminoesters in good yields.     

Co-fluorescence effect of rare earth complexes with 4-aminobenzoic acid in a silica matrix

Terbium(III), yttrium(III), and neodymium(III) complexes with 4-aminobenzoic acid have been co-doped into silica matrix. For the samples, the characteristic emissions of terbium(III) increase obviously with the addition of yttrium(III) complex, while the reverse is true with the addition of neodymium(III) complex. Compared with terbium(III) complex doped silica sample, the photoacoustic signal of the ligand decreases for terbium(III)–yttrium(III) complexes co-doped sample, and increases for terbium(III)-neodymium(III) complexes co-doped sample. The fluorescence quantum yields and lifetimes of the samples have been determined. The co-fluorescence mechanism has been discussed from radiative and nonradiative relaxations. The nephelauxetic parameters and photoacoustic branching vectors of neodymium(III) in the silica samples have also been calculated. The spectral result indicates that heteronuclear complexes may form in the silica matrix upon a suitable heat treatment. The co-fluorescence effect found in the inorganic matrix can contribute to the better design and application of rare earths containing fluorescent materials.     

Nickel-catalyzed cross-coupling of bromophenols with Grignard reagents in the solid phase synthesis

Polymer-bound substituted bromophenols were found to readily undergo a Ni(0)-catalyzed cross-coupling reaction with Grignard reagents to give a variety of substituted phenols and hydroquinones, after cleavage from the support, in moderate to high yields. The requisite bromophenol derivatives, which were prepared from the corrresponding phenols and hydroquinone using BTMA Br₃ or TBA Br₃, were attached to the solid support by the Mitsunobu reaction.     

Synthesis of 5-aryl-1,3-dimethyl-6-(alkyl- or aryl-amino) furo [2,3-d]pyrimidine derivatives by reaction between isocyanides and pyridinecarbaldehydes in the presence of 1,3-dimethylbarbituric acid

5-Aryl-6-(alkyl- or aryl-amino)-1,3-dimethylfuro [2,3-d]pyrimidine derivatives were obtained by in situ reaction alkyl or aryl isocyanides and pyridinecarbaldehyde derivatives in the presence of 1,3-dimethylbarbituric acid in dichloromethane without any prior activation or modifications.     

含有磁性杂质双AB环的自旋极化输运

我们研究了由电子通过含有磁性杂质双AB环结构的透射系数来表示的AB干涉振荡。在这里磁性杂质提供了自旋翻转机制。磁性杂质可以导致AB干涉的部分退相干。而且我们发现在磁通反向的情况下自旋向上和向下的透射系数关于磁通是不对称的，但反射系数和总的透射系数关于磁通却是对称的     

Free and controlled motion of a body with a moving internal mass through a fluid in the presence of circulation around the body

The free and controlled motion of an arbitrary two-dimensional body with a moving internal mass and constant circulation around the body in an ideal fluid is studied. Bifurcation analysis of the free motion is performed (under the condition of a fixed internal mass). It is shown that the body can be moved to a given point by varying the position of the internal mass. Some problems related to the presence of a nonzero drift of the body with a fixed internal mass are noted.     

Spin current through a quantum dot in the presence of an oscillating magnetic field

Nonequilibrium spin transport through an interacting quantum dot is analyzed. The coherent spin oscillations in the dot provide a generating source for spin current. In the interacting regime, the Kondo effect is influenced in a significant way by the presence of the processing magnetic field. In particular, when the precession frequency is tuned to resonance between spin-up and spin-down states of the dot, Kondo singularity for each spin splits into a superposition of two resonance peaks. The Kondo-type cotunneling contribution is manifested by a large enhancement of the pumped spin current in the strong coupling low temperature regime.     

Electron transport through a quantum dot in the presence of electron-photon and electron-phonon coupling

In this study, electron transport through a mesoscopic quantum dot system (QD-system) in the presence of electron-photon (el-pt) and electron-phonon (el-ph) interactions is discussed. The role of both of these interactions is to induce additional steps in the current, and sideband peaks in the differential conductance. By calculating the current and differential conductance of a QD-system in the presence of el-pt or el-ph coupling, we have shown that photon or phonon steps and sideband peaks are induced in the current and differential conductance whenever the applied voltage resonates with their frequency. Furthermore, additional side band peaks are induced in the differential conductance when el-pt and el-ph interactions are simultaneously included in the QD. These extra sideband peaks (ESBPs) are induced when the applied voltage and the photon frequency are in close proximity with the phonon frequency. To investigate the relationship that exists between the photon and phonon frequency in inducing ESBPs in the differential conduction, we have discussed zero applied voltage differential conductance. Under such conditions, ESBP is induced only when the photon frequency resonates with the phonon frequency. With increasing el-ph coupling amplitude, more ESBPs are induced in the differential conductance.     

相互作用量子点系统中的场致自旋电流

从理论上研究了相互作用量子点在外部旋转磁场下的非平衡自旋输运性质，研究结果表明，量子点中的相干自旋振荡可以导致自旋电流的产生，当计入库仑关联相互作用后，近藤共振效应受外部进动磁场的影响很强，特别是当磁场的进动频率与塞曼能移满足共振条件时，每个自旋近藤峰就会劈裂为两个自旋共振峰的叠加，在低温强耦合区，这种近藤型共隧穿过程对自旋电流带来重要贡献。